CN102741210B - 控制混合配体加氢甲酰化工艺中的正构∶异构醛比率 - Google Patents

控制混合配体加氢甲酰化工艺中的正构∶异构醛比率 Download PDF

Info

Publication number
CN102741210B
CN102741210B CN201080062977.6A CN201080062977A CN102741210B CN 102741210 B CN102741210 B CN 102741210B CN 201080062977 A CN201080062977 A CN 201080062977A CN 102741210 B CN102741210 B CN 102741210B
Authority
CN
China
Prior art keywords
ligand
ratio
transition metal
catalyst
hydroformylation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201080062977.6A
Other languages
English (en)
Chinese (zh)
Other versions
CN102741210A (zh
Inventor
T·C·埃森施密德
J·S·索里
G·A·米勒
M·A·布拉默
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dow Technology Investments LLC
Original Assignee
Dow Technology Investments LLC
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=43770586&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=CN102741210(B) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Dow Technology Investments LLC filed Critical Dow Technology Investments LLC
Publication of CN102741210A publication Critical patent/CN102741210A/zh
Application granted granted Critical
Publication of CN102741210B publication Critical patent/CN102741210B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C45/00—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds
    • C07C45/49—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide
    • C07C45/50—Preparation of compounds having >C = O groups bound only to carbon or hydrogen atoms; Preparation of chelates of such compounds by reaction with carbon monoxide by oxo-reactions
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/582—Recycling of unreacted starting or intermediate materials

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)
CN201080062977.6A 2009-12-22 2010-12-15 控制混合配体加氢甲酰化工艺中的正构∶异构醛比率 Active CN102741210B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US28918909P 2009-12-22 2009-12-22
US61/289,189 2009-12-22
PCT/US2010/060480 WO2011087690A1 (en) 2009-12-22 2010-12-15 Controlling the normal : iso aldehyde ratio in a mixed ligand hydroformylation process

Publications (2)

Publication Number Publication Date
CN102741210A CN102741210A (zh) 2012-10-17
CN102741210B true CN102741210B (zh) 2016-02-24

Family

ID=43770586

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080062977.6A Active CN102741210B (zh) 2009-12-22 2010-12-15 控制混合配体加氢甲酰化工艺中的正构∶异构醛比率

Country Status (7)

Country Link
US (1) US8598390B2 (enExample)
EP (2) EP2516373B2 (enExample)
JP (1) JP2013515061A (enExample)
CN (1) CN102741210B (enExample)
PL (1) PL2942343T3 (enExample)
WO (1) WO2011087690A1 (enExample)
ZA (1) ZA201204575B (enExample)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2848073C2 (ru) * 2021-03-31 2025-10-16 Дау Текнолоджи Инвестментс Ллк Процессы гидроформилирования

Families Citing this family (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2516371B2 (en) † 2009-12-22 2022-08-17 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
EP2797861A1 (en) * 2011-12-27 2014-11-05 Shell Internationale Research Maatschappij B.V. Process for the production of alcohols
WO2013098196A1 (en) 2011-12-27 2013-07-04 Shell Internationale Research Maatschappij B.V. Process for the production of alcohols
CN104602815B (zh) * 2012-08-29 2017-03-01 陶氏技术投资有限责任公司 催化剂制备方法
EP2740535A1 (en) * 2012-12-04 2014-06-11 Dow Technology Investments LLC Bidentate ligands for hydroformylation of ethylene
CN104725170B (zh) 2013-12-19 2019-08-23 陶氏技术投资有限责任公司 加氢甲酰化方法
CN106103399B (zh) 2013-12-19 2019-07-09 陶氏技术投资有限责任公司 氢甲酰化方法
KR101962094B1 (ko) * 2015-09-30 2019-03-26 주식회사 엘지화학 하이드로포밀화 반응용 촉매 조성물 및 이를 이용한 하이드로포밀화 방법
KR102092803B1 (ko) * 2016-01-13 2020-03-24 주식회사 엘지화학 인계 리간드를 포함하는 촉매 조성물을 이용한 하이드로포밀화 방법
TW201840363A (zh) * 2016-11-08 2018-11-16 美商陶氏科技投資有限公司 處理氫甲醯化催化劑溶液之方法
KR102131788B1 (ko) 2017-05-29 2020-07-09 주식회사 엘지화학 히드로포밀화 반응용 촉매 조성물 및 이를 이용한 알데히드 제조방법
CN109311002B (zh) * 2017-05-29 2021-12-10 Lg化学株式会社 用于加氢甲酰化反应的催化剂组合物和使用其制备醛的方法
CN114929660A (zh) * 2019-12-19 2022-08-19 陶氏技术投资有限责任公司 用于制备异戊二烯和包含至少六个碳原子的单烯烃的方法
CN112010906B (zh) * 2020-08-31 2021-09-28 中国海洋石油集团有限公司 一种双亚磷酸酯及其制备方法和应用
CA3213539A1 (en) * 2021-03-31 2022-10-06 Jason F. GILES Hydroformylation processes
CN113996347A (zh) * 2021-12-06 2022-02-01 万华化学集团股份有限公司 一种氢甲酰化催化剂组合物及烯丙醇氢甲酰化反应制备羟基丁醛的方法
CN115286503B (zh) * 2022-08-04 2024-04-09 万华化学集团股份有限公司 一种醋酸烯丙酯高效氢甲酰化的方法
GB202213997D0 (en) 2022-09-26 2022-11-09 Johnson Matthey Davy Technologies Ltd Parallel zone hydroformylation reaction
GB202303617D0 (en) 2023-03-13 2023-04-26 Johnson Matthey Davy Technologies Ltd Method and apparatus for producing aldehyde

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5741945A (en) * 1995-12-06 1998-04-21 Union Carbide Chemicals & Plastics Technology Corporation Processes employing indicator ligands
CN1867403A (zh) * 2004-06-12 2006-11-22 Lg化学株式会社 含磷催化剂组合物和使用该组合物的醛化方法
WO2008115740A1 (en) * 2007-03-20 2008-09-25 Union Carbide Chemicals & Plastics Technology Llc Hydroformylation process with improved control over product isomers
CN101443302A (zh) * 2006-05-15 2009-05-27 陶氏环球技术公司 具有改良铑回收的加氢甲酰基化方法和产品分离

Family Cites Families (61)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3415906A (en) 1964-05-29 1968-12-10 Hooker Chemical Corp Phosphite phospholane and phosphorinane compounds
US3527809A (en) 1967-08-03 1970-09-08 Union Carbide Corp Hydroformylation process
US4148830A (en) 1975-03-07 1979-04-10 Union Carbide Corporation Hydroformylation of olefins
US4247486A (en) 1977-03-11 1981-01-27 Union Carbide Corporation Cyclic hydroformylation process
US4169861A (en) 1977-08-19 1979-10-02 Celanese Corporation Hydroformylation process
GB8334359D0 (en) 1983-12-23 1984-02-01 Davy Mckee Ltd Process
US4599206A (en) 1984-02-17 1986-07-08 Union Carbide Corporation Transition metal complex catalyzed reactions
US5110990A (en) 1984-03-30 1992-05-05 Union Carbide Chemicals & Plastics Technology Corporation Process for recovery of phosphorus ligand from vaporized aldehyde
CA1259331A (en) † 1984-03-30 1989-09-12 Gregory J. Dembowski Process for recovery of phosphorus ligand from vaporized aldehyde
US4567302A (en) 1984-07-20 1986-01-28 Angus Chemical Polymeric quaternary ammonium salts possessing antimicrobial activity and methods for preparation and use thereof
US4737588A (en) 1984-12-28 1988-04-12 Union Carbide Corporation Transition metal complex catalyzed reactions
US4668651A (en) 1985-09-05 1987-05-26 Union Carbide Corporation Transition metal complex catalyzed processes
US4885401A (en) 1985-09-05 1989-12-05 Union Carbide Corporation Bis-phosphite compounds
US4748261A (en) † 1985-09-05 1988-05-31 Union Carbide Corporation Bis-phosphite compounds
US4774361A (en) 1986-05-20 1988-09-27 Union Carbide Corporation Transition metal complex catalyzed reactions
US4835299A (en) 1987-03-31 1989-05-30 Union Carbide Corporation Process for purifying tertiary organophosphites
US5059710A (en) 1988-08-05 1991-10-22 Union Carbide Chemicals And Plastics Technology Corporation Ionic phosphites and their use in homogeneous transition metal catalyzed processes
US5113022A (en) 1988-08-05 1992-05-12 Union Carbide Chemicals & Plastics Technology Corporation Ionic phosphites used in homogeneous transition metal catalyzed processes
US4873213A (en) 1988-08-12 1989-10-10 Puckette Thomas A Low pressure rhodium catalyzed hydroformylation of olefins
US5114473A (en) 1988-08-25 1992-05-19 Union Carbide Chemicals And Plastics Technology Corporation Transition metal recovery
US5277532A (en) 1989-07-31 1994-01-11 Cefin S.P.A. Mechanical acceleration device in can welding machines
US5210318A (en) 1990-05-04 1993-05-11 Union Carbide Chemicals & Plastics Technology Corporation Catalysts and processes useful in producing 1,3-diols and/or 3-hydroxyldehydes
DE4026406A1 (de) 1990-08-21 1992-02-27 Basf Ag Rhodiumhydroformylierungskatalysatoren mit bis-phosphit-liganden
US5179055A (en) 1990-09-24 1993-01-12 New York University Cationic rhodium bis(dioxaphosphorus heterocycle) complexes and their use in the branched product regioselective hydroformylation of olefins
JP2893929B2 (ja) † 1990-10-29 1999-05-24 三菱化学株式会社 アルデヒドの製造方法
US5102505A (en) † 1990-11-09 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Mixed aldehyde product separation by distillation
TW213465B (enExample) † 1991-06-11 1993-09-21 Mitsubishi Chemicals Co Ltd
DE4204808A1 (de) 1992-02-18 1993-08-19 Basf Ag Verfahren zur herstellung von (omega)-formylalkancarbonsaeureestern
US5312996A (en) 1992-06-29 1994-05-17 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process for producing 1,6-hexanedials
US5288918A (en) † 1992-09-29 1994-02-22 Union Carbide Chemicals & Plastics Technology Corporation Hydroformylation process
US5364950A (en) 1992-09-29 1994-11-15 Union Carbide Chimicals & Plastics Technology Corporation Process for stabilizing phosphite ligands in hydroformylation reaction mixtures
WO1994020510A1 (en) † 1993-03-09 1994-09-15 Board Of Supervisors Of Louisiana State University And Agricultural And Mechanical College Homogeneous bimetallic hydroformylation catalysts and processes utilizing these catalysts for conducting hydroformylation reactions
US5756855A (en) † 1994-08-19 1998-05-26 Union Carbide Chemicals & Plastics Technology Corporation Stabilization of phosphite ligands in hydroformylation process
EP0839787A1 (en) 1996-11-04 1998-05-06 Dsm N.V. Process for the preparation of an aldehyde
ZA9610314B (en) † 1996-11-26 1998-09-07 Union Carbide Chem Plastic Metal-ligand complex catalyzed processes
US5874640A (en) 1996-11-26 1999-02-23 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
US5892119A (en) 1996-11-26 1999-04-06 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
EP0922691B1 (en) † 1997-12-03 2004-04-28 Shell Internationale Research Maatschappij B.V. Hydroformylation process
US5952530A (en) † 1998-02-02 1999-09-14 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
DE19810794A1 (de) † 1998-03-12 1999-09-16 Basf Ag Katalysator, umfassend einen Komplex eines Metalls der VIII. Nebengruppe auf Basis eines Phosphonitliganden und Verfahren zur Hydroformylierung
EP1073520B1 (en) * 1998-04-16 2004-06-16 E.I. Du Pont De Nemours And Company Hydrocyanation of olefins and isomerisation of nonconjugated 2-alkyl-3-monoalkenenitriles
US6090987A (en) † 1998-07-06 2000-07-18 Union Carbide Chemicals & Plastics Technology Corporation Metal-ligand complex catalyzed processes
DE19842368A1 (de) † 1998-09-16 2000-03-23 Oxeno Olefinchemie Gmbh Verfahren zur Herstellung von höheren Oxoalkoholen aus Olefingemischen durch zweistufige Hydroformylierung
US6352500B1 (en) † 1999-09-13 2002-03-05 Isotron, Inc. Neutron brachytherapy device and method
US6294700B1 (en) † 2000-03-15 2001-09-25 Union Carbide Chemicals & Plastics Technology Corporation Separation processes
DE10034360A1 (de) † 2000-07-14 2002-01-24 Oxeno Olefinchemie Gmbh Mehrstufiges Verfahren zur Herstellung von Oxo-Aldehyden und/oder Alkoholen
JP2002047294A (ja) † 2000-07-28 2002-02-12 Mitsubishi Chemicals Corp 二座リン化合物及びそれを用いるヒドロホルミル化方法
GB0113080D0 (en) † 2001-05-30 2001-07-18 Kvaerner Process Tech Ltd Process
DE10164720B4 (de) † 2001-07-07 2013-12-19 Oxea Gmbh Verfahren zur Herstellung von Aldehyden
BR0308432A (pt) † 2002-03-15 2006-06-06 Oxeno Olefinchemie Gmbh processo para a hidroformilação de olefinas
ATE401292T1 (de) 2003-10-21 2008-08-15 Basf Se Verfahren zur kontinuierlichen herstellung von aldehyden
KR100596365B1 (ko) 2004-06-12 2006-07-03 주식회사 엘지화학 인을 포함하는 촉매 조성물 및 이를 이용한히드로포르밀화 방법
EP1776328B2 (en) 2004-08-02 2025-03-26 Dow Technology Investments LLC Stabilization of a hydroformylation process
US7586010B2 (en) * 2006-12-21 2009-09-08 Eastman Chemical Company Phosphonite-containing catalysts for hydroformylation processes
WO2008123740A1 (en) * 2007-04-09 2008-10-16 Lg Chem, Ltd. Catalyst composition including phosphite ligands and hydroformylation method using the same
CN101293818B (zh) 2007-04-28 2010-07-07 中国石油化工股份有限公司 混合丁烯氢甲酰化的两段反应方法
DE102007061648A1 (de) 2007-12-20 2009-07-02 Evonik Oxeno Gmbh Mehrstufiges kontinuierliches Verfahren zur Hydroformylierung von höheren Olefinen oder Olefingemischen
WO2009080695A1 (en) † 2007-12-21 2009-07-02 Akzo Nobel N.V. Compositions for protection and release of active materials
CN101565353B (zh) 2008-04-25 2013-01-02 中国石油化工股份有限公司 一种2-丙基庚醇的制备方法
EP2516371B2 (en) † 2009-12-22 2022-08-17 Dow Technology Investments LLC Controlling the normal:iso aldehyde ratio in a mixed ligand hydroformylation process by controlling the olefin partial pressure
PL2722325T5 (pl) * 2009-12-22 2019-07-31 Dow Technology Investments Llc Regulowanie stosunku aldehyd normalny : izoaldehyd w procesie hydroformylowania z mieszanymi ligandami przez regulowanie ciśnienia cząsteczkowego gazu syntezowego

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5741945A (en) * 1995-12-06 1998-04-21 Union Carbide Chemicals & Plastics Technology Corporation Processes employing indicator ligands
CN1867403A (zh) * 2004-06-12 2006-11-22 Lg化学株式会社 含磷催化剂组合物和使用该组合物的醛化方法
CN101443302A (zh) * 2006-05-15 2009-05-27 陶氏环球技术公司 具有改良铑回收的加氢甲酰基化方法和产品分离
WO2008115740A1 (en) * 2007-03-20 2008-09-25 Union Carbide Chemicals & Plastics Technology Llc Hydroformylation process with improved control over product isomers

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2848073C2 (ru) * 2021-03-31 2025-10-16 Дау Текнолоджи Инвестментс Ллк Процессы гидроформилирования

Also Published As

Publication number Publication date
EP2942343B1 (en) 2019-09-04
WO2011087690A1 (en) 2011-07-21
EP2516373B2 (en) 2020-08-12
ZA201204575B (en) 2013-09-25
EP2942343A1 (en) 2015-11-11
EP2516373B1 (en) 2016-09-21
CN102741210A (zh) 2012-10-17
EP2516373A1 (en) 2012-10-31
PL2942343T3 (pl) 2020-02-28
US8598390B2 (en) 2013-12-03
US20120259142A1 (en) 2012-10-11
JP2013515061A (ja) 2013-05-02

Similar Documents

Publication Publication Date Title
CN102741210B (zh) 控制混合配体加氢甲酰化工艺中的正构∶异构醛比率
CN102741209B (zh) 通过控制烯烃分压来控制混合配体加氢甲酰化工艺中的正构∶异构醛比率
CN102753511B (zh) 在混合配体加氢甲酰化工艺中通过控制合成气分压来控制正构:异构醛的比率
CN102365258B (zh) 使用双开端二亚磷酸酯配体的加氢甲酰基化方法
EP2699350B1 (en) Methods to store transition metal organophosphorous ligand based catalysts

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant