CN102731209B - Amino acid humic acid organic and inorganic compound mixing fertilizer and production method thereof - Google Patents

Amino acid humic acid organic and inorganic compound mixing fertilizer and production method thereof Download PDF

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CN102731209B
CN102731209B CN201210215856.1A CN201210215856A CN102731209B CN 102731209 B CN102731209 B CN 102731209B CN 201210215856 A CN201210215856 A CN 201210215856A CN 102731209 B CN102731209 B CN 102731209B
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amino acid
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humic acid
fertilizer
production method
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CN102731209A (en
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孔东亚
孔西亚
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Shangqiu city Hong Sheng industry limited company
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HENAN NONGFEI BIOLOGICAL TECHNOLOGY Co Ltd
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Abstract

The present invention provides an amino acid humic acid organic and inorganic compound mixing fertilizer and a production method thereof. The fertilizer comprises the following raw materials, by weight, 1-2 parts of amino acid, 22-25 parts of humic acid, 22-24 parts of urea, 10-12 parts of monoammonium phosphate, 10-12 parts of ammonium chloride, 18-20 parts of the potassium sulfate, 3-5 parts of potassium fulvate, 5-7 parts of calcium powder and 0.5 parts of sodium nitrophenolate. The amino acid humic acid organic and inorganic compound mixing fertilizer of the present invention has the following advantages that: active ingredient content is high, the fertilizer is easily absorbed by crops, organic matters in soil are increased and refreshed, and physical and chemical properties of soil are improved.

Description

One seed amino acid humic acid content Chemical Mixed Fertilizer and production method thereof
Technical field
The present invention relates to agricultural fertilizer field, relate in particular to seed amino acid humic acid organic inorganic Chemical Mixed Fertilizer and a production method thereof.
Background technology
At present, the agricultural fertilizer material in agricultural materials market has two large classes substantially: the first kind is mineral manure, and as carbon ammonium, urea, an ammonium, two ammoniums, potassium oxide, compound manure etc., composition is simple, high, soluble in water containing effective constituent, decomposes soon, easily by Root Absorption; But life-time service can produce soil compaction phenomenon, affect farming growth, cause the underproduction year by year, and utilization ratio is not high.Second largest class is organic fertilizer, and a kind of fertilizer being generally made take poultry dung as raw material, is rich in a large amount of benefit materials, including: multiple organic acid, peptide class and comprise the abundant nutritive element nitrogen, phosphorus, potassium; Can not only be for farm crop provide full nutrition, and fertilizer efficiency is long, can increase and upgrade the soil organism, promotes microbial reproduction, improves physico-chemical property and the biological activity of soil; But N-P-K content is low, nutrient deficiency, can not meet the needs of crop growth.
Summary of the invention
The object of this invention is to provide seed amino acid humic acid organic inorganic Chemical Mixed Fertilizer and a production method thereof, organic and inorganic composite mixed fertilizer, effective constituent high crop easily absorbs and increases and upgrade the soil organism, improves the physico-chemical property of soil.
In order to solve the problems of the technologies described above, amino acid humic acid organic inorganic Chemical Mixed Fertilizer provided by the invention and production method thereof are achieved in that
One seed amino acid humic acid content Chemical Mixed Fertilizer, comprises the raw material of following weight part: amino acid/11 ~ 2 part, humic acid 22-25 part, urea 22-24 part, monoammonium phosphate 10-12 part, ammonium chloride 10-12 part, potassium sulfate 18-20 part, potassium fulvate 3-5 part, 0.5 part of calcium powder 5-7 part and sodium nitrophenolate.
Optionally, described humic acid is: 23 ~ 24 parts.
Optionally, be describedly amino acid whosely: 1.5 parts.
Optionally, the also raw material of following weight part of described amino acid humic acid organic inorganic Chemical Mixed Fertilizer: 2 ~ 4 parts of solid nitrogen.
One seed amino acid humic acid organic inorganic compound fertilizer production method, according to following weight fraction, take raw material: amino acid/11 ~ 2 part, humic acid 22-25 part, urea 22-24 part, monoammonium phosphate 10-12 part, ammonium chloride 10-12 part, potassium sulfate 18-20 part, potassium fulvate 3-5 part, 0.5 part of calcium powder 5-7 part and sodium nitrophenolate; After above-mentioned raw materials is mixed, send into granulation in roller pelletizer, then input in dryer and dry, cooling, after sieving, be transported in coating machine; Packing warehouse-in.
Optionally, described in while being transported in coating machine after sieving, on the film of coating machine, add the paste anti-caking agent of 0.4 ~ 0.6 weight part, add the solid nitrogen of 2 ~ 4 parts; The agent of described paste anti-caking and described solid nitrogen are adsorbed onto described compound fertilizer granule surface by coating.
Amino acid contains the aliphatics organic acid of one or more amino and carboxyl simultaneously.
Humic acid, is the larger molecular organics matter that occurring in nature extensively exists, and is widely used in the every field such as Agriculture, forestry And Animal Husbandry, oil, chemical industry, building materials, medical and health, environmental protection, across tens industries.Particularly advocate now ecological agriculture construction, pollution-less agriculture production, green food.
Urea: another name carbonyl diamine, carboxamide, urea.The organic compound being comprised of carbon, nitrogen, oxygen and hydrogen, so be named urea.Its chemical formula is CON2H4, CO (NH2) 2 or CN2H4O.Nitrogenous (N) the 45%th of urea is nitrogenous the highest in solid nitrogenous fertilizer.
Monoammonium phosphate: molecular formula: NH4H2PO44, molecular weight: 115.03 be white in color powdery or granular substances (granulated product has higher grain compressive strength), density 1.803(19 ℃).Fusing point is 190 ℃, soluble in water, is slightly soluble in alcohol, is insoluble to acetone, and the solubleness at 25 ℃ in 100g water is 41.6g, Heat of Formation 121.42kJ/mol, and 1% pH value of water solution is 4.5, is neutral, stable under normal temperature, non-oxidation reductibility.By purposes, can be divided into agricultural level monoammonium phosphate, industrial grade monoammonium phosphate, food grade phosphoric acid one ammonium; At agricultural, industry and food, also can classification in using be composite fertilizer with, fire-fighting medium, starter, nutrition-fortifying agent monoammonium phosphate etc.
Ammonium chloride: chemical formula: NH4Cl relative molecular mass: 53.49.For colourless crystallization or white crystalline powder; Odorless, taste is salty, cool; Have draw moist.This product is easily molten in water, slightly soluble in ethanol.Ammonium chloride is called for short " oronain ", claims again salmiak, is a kind of quick-acting nitrogen chemical fertilizer, and nitrogen content is 24%~25%, belongs to physiological acidic fertilizer.It is applicable to the crops such as wheat, paddy rice, corn, rape, especially cotton crudefiber crop is had to fortifying fibre toughness and pulling force and improves the effect of quality.But, if because the character of ammonium chloride determines and use not satisfy the need, tend to serve detrimentally affect to soil and farm crop band.
Potassium sulfate: molecular formula: K2SO4 molecular weight: 174.24 chemical formulas: K2SO4 is colourless or white crystals, particle or powder.Odorlessness.Bitter.Matter is hard.Stable in the air.1g is dissolved in 8.3ml water, 4ml boiling water, 75ml glycerine, is insoluble to ethanol.Repone K, ammonium sulfate can increase the solubleness in its water, but the saturated solution of vitriolization ammonium hardly.It is neutral that the aqueous solution is, and pH is about 7.Relative density 2.66.1067 ℃ of fusing points.Main application has serum protein biochemical investigation, catalyzer for Kjeldahl determination, prepare other sylvite, chemical fertilizer, medicine, prepare glass, alum etc.
Potassium fulvate: be a kind of pure natural mineral substance active potassium element fertilizer, potassium fulvate includes the multiple nutritional components such as trace element, rare earth element, plant-growth regulator, viral inhibitors, make that nutrient is more sufficient, supply is more reasonable, thereby avoided the generation of crop because of the various physiological disturbances that lack element and cause, make the more vigorous leaf look of crop plant type more dark green, lodging tolerance is stronger.Potassium fulvate can supplement the nutrient running off in soil timely, make soil activating, there is vitality, reduced the continuous cropping disease that in soil, nutrient is caused by taken in excess, product can replace potassium sulfate or Repone K and the potassium magnesium sulfate that content is identical completely, and natural, environmental protection.
Calcium powder: being commonly called as Wingdale, stone flour, is a kind of compound, and chemical formula is CaCO3, is alkalescence, substantially water insoluble, is dissolved in acid.It is common material on the earth, is present in the rocks such as aragonite, calcite, chalk, limestone, marble, Tufa.Also be the major ingredient of animal skeleton or shell.
Sodium nitrophenolate: be a kind of powerful cell-activating agent, in plant materials, promote the protoplasma of cell to flow with energy rapid permeability after plant contact, improve cell viability.Purposes: broad spectrum type plant-growth regulator, has that the cellular plasm of promotion flows, improves cell viability, accelerates vine growth and development, short root strong sprout, flower and fruit protecting, raising output, strengthens anti-adversity ability etc.Both can be used alone, again can with the composite uses such as fertilizer, agricultural chemicals, feed.
Vinelandii a: section that belongs to bacterium.Thalline is shaft-like, oval or spherical, without endogenous spore, and Gram-negative.Strict aerobic, organotrophy type, the nitrogen in energy fixed air.Comprise Azotobacter, nitrogen monospore Pseudomonas, Bai Yelin Kocuria and Derxia.Vinelandii fertilizer is many to be made by the member of Azotobacter.
Amino acid humic acid organic inorganic Chemical Mixed Fertilizer provided by the invention, be applicable to all farm crop, particularly cash crop effect is remarkable, product of the present invention is the polypeptide humic acid biological compound organic and inorganic fertilizer that utilizes polypeptide, humic acids, potassium fulvate and biological bacteria to combine with n-p-k element to process, and not only contains macronutrient nitrogen, phosphorus, potassium; But also contain abundant organic matter, humic acids, potassium fulvate, biological bacteria etc.It not only has the long-acting of fertilizer, also has the quick-acting characteristics of inorganic fertilizer, and long-acting slow nutrient combines, can improve soil physical and chemical property, it is applicable to all kinds of soil, does not contain heavy metal and hormone, nontoxic, pollution-free, noresidue, is the green fertilizer of producing non-polluted farm product.
Amino acid humic acid organic inorganic Chemical Mixed Fertilizer provided by the invention, crop mu volume increase reaches more than 5% on year-on-year basis, and soil obviously improves, and does not loosely harden.
Embodiment
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
Embodiment mono-
Get amino acid 20g, humic acid 220g, urea 240g, monoammonium phosphate 12g, ammonium chloride 10g, potassium sulfate 18g, potassium fulvate 5g, calcium powder 7g and sodium nitrophenolate 0.5g.After evenly mixing, send into granulation in roller pelletizer, then input in dryer and dry, cooling in cooler, after sieving, be transported in coating machine, on film, add the paste anti-caking agent of 4g, add the solid nitrogen of 20g; The agent of paste anti-caking and solid nitrogen are adsorbed onto compound fertilizer granule surface by coating, packing warehouse-in.
Embodiment bis-
Get amino acid/11 0g, humic acid 250g, urea 220g, monoammonium phosphate 10g, ammonium chloride 12g, potassium sulfate 20g, potassium fulvate 3g, calcium powder 5g and sodium nitrophenolate 0.5g.After evenly mixing, send into granulation in roller pelletizer, then input in dryer and dry, cooling in cooler, after sieving, be transported in coating machine blooming packing warehouse-in.
Embodiment tri-
Get amino acid/11 0g, humic acid 250g, urea 220g, monoammonium phosphate 10g, ammonium chloride 12g, potassium sulfate 20g, potassium fulvate 3g, calcium powder 5g and sodium nitrophenolate 0.5g.After evenly mixing, send into granulation in roller pelletizer, then input in dryer and dry, cooling in cooler, after sieving, be transported in coating machine, on film, add the paste anti-caking agent of 6g, add the solid nitrogen of 40g; The agent of paste anti-caking and solid nitrogen are adsorbed onto compound fertilizer granule surface by coating, packing warehouse-in.
Embodiment tetra-
Get amino acid/11 5g, humic acid 240g, urea 230g, monoammonium phosphate 11g, ammonium chloride 11g, potassium sulfate 19g, potassium fulvate 4g, calcium powder 6g and sodium nitrophenolate 0.5g.After evenly mixing, send into granulation in roller pelletizer, then input in dryer and dry, cooling in cooler, after sieving, be transported in coating machine, on film, add the paste anti-caking agent of 5g, add the solid nitrogen of 30g; The agent of paste anti-caking and solid nitrogen are adsorbed onto compound fertilizer granule surface by coating, packing warehouse-in.
Amino acid humic acid organic inorganic Chemical Mixed Fertilizer provided by the invention, crop mu volume increase reaches more than 5% on year-on-year basis, and soil obviously improves, and does not loosely harden.Specifically as shown in Table 1:
Figure BDA00001817568100051
Figure BDA00001817568100061
Table one
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.

Claims (2)

1. a seed amino acid humic acid organic inorganic compound fertilizer production method, it is characterized in that, according to following weight fraction, take raw material: amino acid/11~2 part, humic acid 22-25 part, urea 22-24 part, monoammonium phosphate 10-12 part, ammonium chloride 10-12 part, potassium sulfate 18-20 part, potassium fulvate 3-5 part, 0.5 part of calcium powder 5-7 part and sodium nitrophenolate; After above-mentioned raw materials is mixed, send into granulation in roller pelletizer and then input in dryer and dry, cooling, after sieving, be transported in coating machine, on the film of coating machine, add the paste anti-caking agent of 0.4~0.6 weight part, add the solid nitrogen of 2~4 parts; The agent of described paste anti-caking and described solid nitrogen are adsorbed onto described compound fertilizer granule surface by coating; Packing warehouse-in.
2. a seed amino acid humic acid organic inorganic Chemical Mixed Fertilizer, is characterized in that, described Chemical Mixed Fertilizer comprises the raw material of following weight part: amino acid/11~2 part, humic acid 22-25 part, urea 22-24 part, monoammonium phosphate 10-12 part, ammonium chloride 10-12 part, potassium sulfate 18-20 part, potassium fulvate 3-5 part, calcium powder 5-7 part, 0.5 part of sodium nitrophenolate, 2~4 parts of solid nitrogen, and be prepared from according to compound fertilizer production method claimed in claim 1.
CN201210215856.1A 2012-06-27 2012-06-27 Amino acid humic acid organic and inorganic compound mixing fertilizer and production method thereof Expired - Fee Related CN102731209B (en)

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CN103360140A (en) * 2013-07-03 2013-10-23 宁波致富宝生物科技有限公司 Dual-potassium fertilizer
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CN104211491A (en) * 2014-06-27 2014-12-17 胡红辉 Compound fertilizer preparation method for improving utilization rate of phosphorus element
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Address after: 477200 Luyi County Industrial Park, Henan, Zhoukou

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