CN102731209A - Amino acid humic acid organic and inorganic compound mixing fertilizer and production method thereof - Google Patents

Amino acid humic acid organic and inorganic compound mixing fertilizer and production method thereof Download PDF

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Publication number
CN102731209A
CN102731209A CN2012102158561A CN201210215856A CN102731209A CN 102731209 A CN102731209 A CN 102731209A CN 2012102158561 A CN2012102158561 A CN 2012102158561A CN 201210215856 A CN201210215856 A CN 201210215856A CN 102731209 A CN102731209 A CN 102731209A
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amino acid
humic acid
parts
inorganic compound
fertile
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CN102731209B (en
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孔东亚
孔西亚
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Shangqiu city Hong Sheng industry limited company
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HENAN NONGFEI BIOLOGICAL TECHNOLOGY Co Ltd
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Abstract

The present invention provides an amino acid humic acid organic and inorganic compound mixing fertilizer and a production method thereof. The fertilizer comprises the following raw materials, by weight, 1-2 parts of amino acid, 22-25 parts of humic acid, 22-24 parts of urea, 10-12 parts of monoammonium phosphate, 10-12 parts of ammonium chloride, 18-20 parts of the potassium sulfate, 3-5 parts of potassium fulvate, 5-7 parts of calcium powder and 0.5 parts of sodium nitrophenolate. The amino acid humic acid organic and inorganic compound mixing fertilizer of the present invention has the following advantages that: active ingredient content is high, the fertilizer is easily absorbed by crops, organic matters in soil are increased and refreshed, and physical and chemical properties of soil are improved.

Description

One seed amino acid humic acid content compound fertilizer and working method thereof
Technical field
The present invention relates to the agricultural fertilizer field, relate in particular to a seed amino acid humic acid organic inorganic compound fertilizer and a working method thereof.
Background technology
At present, the agricultural fertilizer material in the agricultural materials market has two big types substantially: the first kind is a mineral manure, and like carbon ammonium, urea, an ammonium, two ammoniums, potassium oxide, compound manure etc., composition is simple, and it is high to contain effective composition, soluble in water, decomposes soon, is prone to absorbed by root system; But life-time service can produce the soil compaction phenomenon, influences the farming growth, cause the underproduction year by year, and utilization ratio is not high.Second largest type is organic fertilizer, and general is a kind of fertilizer that raw material is made with bird ight soil, is rich in a large amount of benefit materials, comprising: multiple organic acid, peptide class and the abundant nutritive element that comprises nitrogen, phosphorus, potassium; Can not only be for farm crop provide full nutrition, and fertilizer efficiency is long, can increase and upgrade the soil organism, promotes microbial reproduction, improves the physico-chemical property and the biological activity of soil; But N-P-K content is low, supports a part deficiency, can not satisfy the needs of crop growth.
Summary of the invention
The purpose of this invention is to provide a seed amino acid humic acid organic inorganic compound fertilizer and a working method thereof, organic and inorganic composite mixed fertilizer, effective constituent high crop are prone to absorb and increase and upgrade the soil organism, improve the physico-chemical property of soil.
In order to solve the problems of the technologies described above, amino acid humic acid organic inorganic compound fertilizer provided by the invention and working method thereof are achieved in that
One seed amino acid humic acid content compound is fertile, comprises the raw material of following weight part: amino acid/11 ~ 2 part, humic acid 22-25 part; Urea 22-24 part, monoammonium phosphate 10-12 part, ammonium chloride 10-12 part; Vitriolate of tartar 18-20 part, potassium fulvate 3-5 part, 0.5 part of calcium powder 5-7 part and sodium nitrophenolate.
Optional, said humic acid is: 23 ~ 24 parts.
Optional, saidly amino acid whosely be: 1.5 parts.
Optional, the fertile also raw material of following weight part of said amino acid humic acid organic inorganic compound: 2 ~ 4 parts of solid nitrogen.
One seed amino acid humic acid organic inorganic compound fertilizer production method takes by weighing raw material according to following weight fraction: amino acid/11 ~ 2 part, humic acid 22-25 part; Urea 22-24 part; Monoammonium phosphate 10-12 part, ammonium chloride 10-12 part, vitriolate of tartar 18-20 part; Potassium fulvate 3-5 part, 0.5 part of calcium powder 5-7 part and sodium nitrophenolate; Send into granulation in the cylinder tablets press after above-mentioned raw materials mixed, import in the dryer then and dry, cooling is transported in the coating machine after sieving; The packing warehouse-in.
Optional, when being transported in the coating machine after said the sieving, on the film of coating machine, add the paste anti-caking agent of 0.4 ~ 0.6 weight part, add 2 ~ 4 parts solid nitrogen; Agent of said paste anti-caking and said solid nitrogen are adsorbed onto said compound fertilizer granule surface through coating.
Amino acid contains the aliphatics organic acid of one or more amino and carboxyl simultaneously.
Humic acid is the larger molecular organics matter that occurring in nature extensively exists, and is widely used in every field such as agricultural are herded, oil, chemical industry, building materials, medical and health, environmental protection, across tens industries.Particularly advocate ecological agriculture construction, pollution-less agriculture production, green food now.
Urea: another name carbonyl diamine, carboxamide, urea.The organic cpds of being made up of carbon, nitrogen, oxygen and hydrogen is so be named urea.Its chemical formula is CON2H4, CO (NH2) 2 or CN2H4O.Nitrogenous (N) the 45%th of urea is nitrogenous the highest in the solid nitrogenous fertilizer.
Monoammonium phosphate: molecular formula: NH4H2PO44, molecular weight: 115.03 be white in color powdery or granular substances (granulated product has higher grain compressive strength), density 1.803 (19 ℃).Fusing point is 190 ℃, and is soluble in water, is slightly soluble in alcohol, is insoluble to acetone, and the solubleness in 25 ℃ of following 100g water is 41.6g, generates hot 121.42kJ/mol, and 1% pH value of water solution is 4.5, is neutral, and normal temperature is stable down, the non-oxidation reductibility.Can be divided into agricultural level monoammonium phosphate, industrial grade monoammonium phosphate, food grade phosphoric acid one ammonium by purposes; But in agricultural, the utilization of industry and food also refinement be categorized as composite fertilizer with, fire-fighting medium with, starter with, nutrition-fortifying agent with monoammonium phosphate or the like.
Ammonium chloride: chemical formula: NH4Cl relative molecular mass: 53.49.Be colourless crystallization or white crystalline powder; Odorless, it is salty, cool to distinguish the flavor of; Have draw moist.These article are prone to dissolve slightly soluble in ethanol in water.Ammonium chloride is called for short " oronain ", claims salmiak again, is a kind of quick-acting nitrogen chemical fertilizer, and nitrogen content is 24%~25%, belongs to physiological acidic fertilizer.It is applicable to crops such as wheat, paddy rice, corn, rape, especially linen-cotton class crop is had fortifying fibre toughness and pulling force and improves the effect of quality.But, if, tend to bring some detrimentally affects to soil and farm crop because the character of ammonium chloride determines and use not satisfy the need.
Vitriolate of tartar: molecular formula: K2SO4 molecular weight: 174.24 chemical formulas: K2SO4 is colourless or white crystals, particle or powder.Odorlessness.Bitter.Matter is hard.Stable in the air.1g is dissolved in 8.3ml water, 4ml boiling water, 75ml glycerine, is insoluble to ethanol.Repone K, ammonium sulfate can increase the solubleness in its water, but the saturated solution of vitriolization ammonium hardly.It is neutral that the aqueous solution is, and pH is about 7.Specific density 2.66.1067 ℃ of fusing points.Main application have serum proteins biochemical investigation, Kjeldahl determination with catalyzer, prepare other sylvite, chemical fertilizer, medicine, preparation glass, alum etc.
Potassium fulvate: be that the active potassium element of a kind of pure natural mineral substance is fertile; Potassium fulvate includes multiple nutritional components such as trace element, REE, plant-growth regulator, viral inhibitors; Make that nutrient is more sufficient, supply is more reasonable; Thereby avoided the generation of crop because of the various physiological disturbances that lack element and cause, made the more vigorous leaf look of crop plant type more dark green, lodging tolerance is stronger.Potassium fulvate can replenish the nutrient that is run off in the soil timely; Make soil activating, have vitality, reduced the continuous cropping disease that nutrient is caused by taken in excess in the soil; Product can replace the identical vitriolate of tartar of content or Repone K and potassium magnesium sulfate fully, and natural, environmental protection.
Calcium powder: being commonly called as Wingdale, stone flour, is a kind of compound, and chemical formula is CaCO3, is alkalescence, water insoluble basically, is dissolved in acid.It is a common material on the earth, is present in the rocks such as aragonite, calcite, chalk, ls, marble, Tufa.It also is the major ingredient of animal skeleton or shell.
Sodium nitrophenolate: be a kind of powerful cell-activating agent, with can rapid permeability after the plant contact in plant materials, promote the protoplasma of cell to flow, improve cell viability.Purposes: the broad spectrum type plant-growth regulator has and promotes cellular plasm to flow, improve cell viability, quickens vine growth and development, short root strong sprout, flower and fruit protecting, raising output, strengthens anti-adversity ability etc.Both can use separately, again can with composite uses such as fertilizer, agricultural chemicals, feed.
Vinelandii a: section that belongs to bacterium.Thalline is shaft-like, oval or sphere, no endogenous spore, Gram-negative.Strict aerobic, organotrophy type, the nitrogen in the ability fixed air.Comprise Azotobacter, nitrogen monospore Pseudomonas, Bai Yelinke Bordetella and Derxia.Vinelandii fertilizer many members by Azotobacter process.
Amino acid humic acid organic inorganic compound provided by the invention is fertile; Be applicable to all farm crop; Particularly the cash crop effect is remarkable; Product of the present invention is the polypeptide humic acid biological compound organic and inorganic fertilizer that utilizes polypeptide, humic acids, potassium fulvate and biological bacteria to combine with n-p-k element to process, and not only contains macronutrient nitrogen, phosphorus, potassium; But also contain abundant organic matter, humic acids, potassium fulvate, biological bacteria etc.It not only has the long-acting of fertilizer, also has the quick-acting characteristics of inorganic fertilizer, and long-acting slow nutrient combines; Can improve soil physical and chemical property; It is applicable to all kinds of soil, does not contain heavy metal and hormone, nontoxic, pollution-free, noresidue, is the green fertilizer of producing non-polluted farm product.
Amino acid humic acid organic inorganic compound provided by the invention is fertile, and the raising the output of crop mu reaches more than 5% on year-on-year basis, and soil obviously improves, and does not loosely harden.
Embodiment
In order to make the object of the invention, technical scheme and advantage clearer,, the present invention is further elaborated below in conjunction with embodiment.Should be appreciated that specific embodiment described herein only in order to explanation the present invention, and be not used in qualification the present invention.
Embodiment one
Get amino acid 20g, humic acid 220g, urea 240g, monoammonium phosphate 12g, ammonium chloride 10g, vitriolate of tartar 18g, potassium fulvate 5g, calcium powder 7g and sodium nitrophenolate 0.5g.Behind the uniform mixing, send into granulation in the cylinder tablets press, import in the dryer then and dry, cool off in the cooler, be transported in the coating machine after sieving, on film, add the paste anti-caking agent of 4g, add the solid nitrogen of 20g; Agent of paste anti-caking and solid nitrogen are adsorbed onto the compound fertilizer granule surface through coating, the packing warehouse-in.
Embodiment two
Get amino acid/11 0g, humic acid 250g, urea 220g, monoammonium phosphate 10g, ammonium chloride 12g, vitriolate of tartar 20g, potassium fulvate 3g, calcium powder 5g and sodium nitrophenolate 0.5g.Behind the uniform mixing, send into granulation in the cylinder tablets press, import in the dryer then and dry, cool off in the cooler, be transported in the coating machine after sieving, blooming packing warehouse-in.
Embodiment three
Get amino acid/11 0g, humic acid 250g, urea 220g, monoammonium phosphate 10g, ammonium chloride 12g, vitriolate of tartar 20g, potassium fulvate 3g, calcium powder 5g and sodium nitrophenolate 0.5g.Behind the uniform mixing, send into granulation in the cylinder tablets press, import in the dryer then and dry, cool off in the cooler, be transported in the coating machine after sieving, on film, add the paste anti-caking agent of 6g, add the solid nitrogen of 40g; Agent of paste anti-caking and solid nitrogen are adsorbed onto the compound fertilizer granule surface through coating, the packing warehouse-in.
Embodiment four
Get amino acid/11 5g, humic acid 240g, urea 230g, monoammonium phosphate 11g, ammonium chloride 11g, vitriolate of tartar 19g, potassium fulvate 4g, calcium powder 6g and sodium nitrophenolate 0.5g.Behind the uniform mixing, send into granulation in the cylinder tablets press, import in the dryer then and dry, cool off in the cooler, be transported in the coating machine after sieving, on film, add the paste anti-caking agent of 5g, add the solid nitrogen of 30g; Agent of paste anti-caking and solid nitrogen are adsorbed onto the compound fertilizer granule surface through coating, the packing warehouse-in.
Amino acid humic acid organic inorganic compound provided by the invention is fertile, and the raising the output of crop mu reaches more than 5% on year-on-year basis, and soil obviously improves, and does not loosely harden.Specifically shown in table one:
Figure BDA00001817568100051
Figure BDA00001817568100061
Table one
The above is merely preferred embodiment of the present invention, not in order to restriction the present invention, all any modifications of within spirit of the present invention and principle, being done, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.

Claims (6)

1. a seed amino acid humic acid content compound is fertile, it is characterized in that, comprises the raw material of following weight part: amino acid/11 ~ 2 part; Humic acid 22-25 part, urea 22-24 part, monoammonium phosphate 10-12 part; Ammonium chloride 10-12 part; Vitriolate of tartar 18-20 part, potassium fulvate 3-5 part, 0.5 part of calcium powder 5-7 part and sodium nitrophenolate.
2. amino acid humic acid organic inorganic compound according to claim 1 is fertile, it is characterized in that said humic acid is: 23 ~ 24 parts.
3. amino acid humic acid organic inorganic compound according to claim 1 is fertile, it is characterized in that, saidly amino acid whosely is: 1.5 parts.
4. amino acid humic acid organic inorganic compound according to claim 1 is fertile, it is characterized in that, the fertile also raw material of following weight part of said amino acid humic acid organic inorganic compound: 2 ~ 4 parts of solid nitrogen.
5. the amino acid humic acid organic inorganic compound fertilizer production method described in claim 1 is characterized in that, takes by weighing raw material according to following weight fraction: amino acid/11 ~ 2 part; Humic acid 22-25 part, urea 22-24 part, monoammonium phosphate 10-12 part; Ammonium chloride 10-12 part; Vitriolate of tartar 18-20 part, potassium fulvate 3-5 part, 0.5 part of calcium powder 5-7 part and sodium nitrophenolate; Send in the cylinder tablets press granulation after above-mentioned raw materials mixed and import in the dryer then and dry, cooling is transported in the coating machine after sieving; The packing warehouse-in.
6. amino acid humic acid organic inorganic compound fertilizer production method according to claim 5 is characterized in that, when being transported in the coating machine after said the sieving, on the film of coating machine, adds the paste anti-caking agent of 0.4 ~ 0.6 weight part, adds 2 ~ 4 parts solid nitrogen; Agent of said paste anti-caking and said solid nitrogen are adsorbed onto said compound fertilizer granule surface through coating.
CN201210215856.1A 2012-06-27 2012-06-27 Amino acid humic acid organic and inorganic compound mixing fertilizer and production method thereof Expired - Fee Related CN102731209B (en)

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Cited By (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103172429A (en) * 2013-03-11 2013-06-26 内蒙古自治区农牧业科学院 Special organic-inorganic fertilizer applied to seed bed for raising paper tube seedlings of beets
CN103360140A (en) * 2013-07-03 2013-10-23 宁波致富宝生物科技有限公司 Dual-potassium fertilizer
CN103588578A (en) * 2013-11-20 2014-02-19 焦作市地丰肥业有限公司 Humic acid ecological fertilizer and production method thereof
CN104211491A (en) * 2014-06-27 2014-12-17 胡红辉 Compound fertilizer preparation method for improving utilization rate of phosphorus element
CN104355884A (en) * 2014-11-17 2015-02-18 砀山县沃福农业发展有限公司 Fruit and vegetable water flush fertilizer
CN104402652A (en) * 2014-11-20 2015-03-11 柳州市源晨农副产品有限公司 Special fertilizer for grape culture
CN105111011A (en) * 2015-07-24 2015-12-02 安徽蒙特尔肥业有限公司 Potassium fulvate compound fertilizer
CN105175100A (en) * 2015-07-07 2015-12-23 郑州金正生物化工有限公司 Organic and inorganic composite fertilizer and preparation method therefor
CN105900631A (en) * 2016-04-18 2016-08-31 安徽大川生态农业开发有限公司 High-yield codonopsis pilosula planting method
CN106478279A (en) * 2015-08-24 2017-03-08 安徽亚环生物科技有限公司 A kind of water solublity organic and inorganic active humic acid fertilizer and preparation method thereof
CN106631518A (en) * 2017-01-17 2017-05-10 四川天农农资有限公司 Biochemical fulvate compounded fertilizer
CN107410365A (en) * 2017-06-08 2017-12-01 青岛中诺盛大生物科技有限公司 A kind of trichodermaharzianum microbial inoculum and its preparation method and application
CN111333460A (en) * 2020-03-09 2020-06-26 王志 Fulvic acid chelated fertilizer and preparation method thereof

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CN101792353A (en) * 2010-03-23 2010-08-04 齐绍春 Multifunctional compound fertilizer capable of killing pests, preventing diseases and increasing yield
CN101948353A (en) * 2010-09-20 2011-01-19 张彦超 Organic/inorganic salt and alkali resistant long-acting corn fertilizer
CN102108038A (en) * 2009-12-28 2011-06-29 任春和 Fertilizer containing FHJH
CN102503676A (en) * 2011-10-25 2012-06-20 广西力源宝农林科技发展有限责任公司 Base fertilizer type eucalyptus ecological fertilizer

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JP2008247998A (en) * 2007-03-29 2008-10-16 Tochigi Prefecture Calcareous granule and its manufacturing method
CN101066901A (en) * 2007-04-03 2007-11-07 张国忠 Soline alkali resisting rice fertilizer
CN102108038A (en) * 2009-12-28 2011-06-29 任春和 Fertilizer containing FHJH
CN101792353A (en) * 2010-03-23 2010-08-04 齐绍春 Multifunctional compound fertilizer capable of killing pests, preventing diseases and increasing yield
CN101948353A (en) * 2010-09-20 2011-01-19 张彦超 Organic/inorganic salt and alkali resistant long-acting corn fertilizer
CN102503676A (en) * 2011-10-25 2012-06-20 广西力源宝农林科技发展有限责任公司 Base fertilizer type eucalyptus ecological fertilizer

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103172429A (en) * 2013-03-11 2013-06-26 内蒙古自治区农牧业科学院 Special organic-inorganic fertilizer applied to seed bed for raising paper tube seedlings of beets
CN103172429B (en) * 2013-03-11 2015-06-24 内蒙古自治区农牧业科学院 Special organic-inorganic fertilizer applied to seed bed for raising paper tube seedlings of beets
CN103360140A (en) * 2013-07-03 2013-10-23 宁波致富宝生物科技有限公司 Dual-potassium fertilizer
CN103588578A (en) * 2013-11-20 2014-02-19 焦作市地丰肥业有限公司 Humic acid ecological fertilizer and production method thereof
CN103588578B (en) * 2013-11-20 2016-08-17 焦作市地丰肥业有限公司 A kind of functional humic acid ecological fertilizer and production method thereof
CN104211491A (en) * 2014-06-27 2014-12-17 胡红辉 Compound fertilizer preparation method for improving utilization rate of phosphorus element
CN104355884A (en) * 2014-11-17 2015-02-18 砀山县沃福农业发展有限公司 Fruit and vegetable water flush fertilizer
CN104402652A (en) * 2014-11-20 2015-03-11 柳州市源晨农副产品有限公司 Special fertilizer for grape culture
CN105175100A (en) * 2015-07-07 2015-12-23 郑州金正生物化工有限公司 Organic and inorganic composite fertilizer and preparation method therefor
CN105175100B (en) * 2015-07-07 2019-01-18 金正生物化工有限公司 A kind of composite organic-inorganic fertilizer and preparation method thereof
CN105111011A (en) * 2015-07-24 2015-12-02 安徽蒙特尔肥业有限公司 Potassium fulvate compound fertilizer
CN106478279A (en) * 2015-08-24 2017-03-08 安徽亚环生物科技有限公司 A kind of water solublity organic and inorganic active humic acid fertilizer and preparation method thereof
CN105900631A (en) * 2016-04-18 2016-08-31 安徽大川生态农业开发有限公司 High-yield codonopsis pilosula planting method
CN106631518A (en) * 2017-01-17 2017-05-10 四川天农农资有限公司 Biochemical fulvate compounded fertilizer
CN107410365A (en) * 2017-06-08 2017-12-01 青岛中诺盛大生物科技有限公司 A kind of trichodermaharzianum microbial inoculum and its preparation method and application
CN111333460A (en) * 2020-03-09 2020-06-26 王志 Fulvic acid chelated fertilizer and preparation method thereof

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