CN102703199B - Preparation method of cutting fluid for hardware alloy cutter or processed workpiece as hardware alloy - Google Patents
Preparation method of cutting fluid for hardware alloy cutter or processed workpiece as hardware alloy Download PDFInfo
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- CN102703199B CN102703199B CN201210177434.XA CN201210177434A CN102703199B CN 102703199 B CN102703199 B CN 102703199B CN 201210177434 A CN201210177434 A CN 201210177434A CN 102703199 B CN102703199 B CN 102703199B
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Abstract
The invention discloses a preparation method of a cutting fluid fora hardware alloy cutter or a processed workpiece as a hardware alloy. The preparation method of the cutting fluid comprises the following steps of: adding 5-7 percent of boracic acid and 24-26 percent of 2-amino-2-methyl-1-propanolamine into water; stirring the mixture under the condition of 40-50DEG C to be completely dissolved; cooling the dissolved solution to 25-35DEG C; then adding 3-5 percent of polyoxyethylene octadecyl phosphate, 5-7 percent of polyoxyethylene phenyl phosphate, 2-4 percent of dibutyl phthalate, 6-8 percent of phenol ether phosphate, 2-4 percent of sodium benzoate, 2-4 percent of propanetriol, 0.4-0.6 percent of isothiazolin one, 0.6-0.8 percent of benzotriazol and 0.3-0.5 percent of nonylphenol polyoxyethylene ether one by one and fully stirring; after the substances are completely dissolved, adding 0.6-1.0 percent of methyl silicone oil and then stirring for 60-90 minutes; and finally, adjusting the pH value to 8.5-9.5, wherein various components are counted according to weight percentage and the balance of water is counted according to weight percentage.
Description
Technical field
The present invention relates to metal cutting process technical field, particularly relating to a kind of inserted tool or work piece of adopting is the preparation method of the cutting fluid of Wimet.
Background technology
Aqueous cutting fluid can be divided into soluble oil (emulsion), semi-synthetic cutting fluid (microemulsion) and fully synthetic cutting fluid three kinds.Compared with soluble oil and semi-synthetic cutting fluid, fully synthetic cutting fluid is not containing mineral oil, and its each component is as all water-soluble in multiple additives such as rust-preventive agent, extreme-pressure anti-friction additive, tensio-active agent, sanitas and defoamers, diluent transparent shape or translucent.Totally synthesized cutting fluid good cooling results, processing site is clean, product performance are stablized, and are the metal working fluids that a class has wide range of applications.
But usually containing trolamine in Totally synthesized cutting fluid, trolamine is as the important additives of fully synthetic cutting fluid, contribute to cutting fluid to infiltrate, permeate and cut interface in mill (cutting), give full play to the cleaning of fully synthetic cutting fluid, lubrication and rust inhibition.But, the Ammonia additives such as trolamine to the cobalt in the Wimet such as WC-Co have immersion Zn (see Pat.Brutto.Water hazard.Cutting ToolEngineering, 1996, (12): 50; See Zhang Xiuling, Gao Jun. containing the harm of trolamine grinding fluid to inserted tool. Wimet, 2000,17 (4): 231-232).And cobalt metal is the binding agent of the Wimet such as WC-Co, if at use inserted tool or when carrying out ground finish to Wimet, cobalt element in WC-Co Wimet is leached, directly affect on the one hand the performances such as the tenacity of Wimet and shock resistance, cause the surface of WC-Co hard metal article to occur color fringe on the other hand, directly affect the outward appearance of goods.
In use inserted tool or the occasion of Wimet being carried out to ground finish, in order to avoid fully synthetic cutting fluid is to the immersion Zn of the cobalt in the Wimet such as tungsten cobalt or titanium cobalt, triethanolamine oleate is replaced trolamine by domestic scholars, partly can reduce the immersion Zn of cobalt in fully synthetic cutting fluid alloy like this, but still can not suppress completely cobalt element leaching (see Zhang Haoqiang. inserted tool cobalt element Leaching Mechanism of Refractory and countermeasure, Institutes Of Technology Of Hebei's master thesis, 2005).
Therefore, cutting fluid of the prior art is unsuitable for adopting inserted tool processing, or is unsuitable for carrying out machining to Wimet.
Summary of the invention
The object of the invention is to propose a kind of inserted tool or work piece of adopting is the preparation method of the cutting fluid of Wimet, cutting fluid prepared by employing method is suitable for the machining adopting inserted tool to carry out, and is also suitable for the machining that work piece relates to Wimet.
For reaching this object, the present invention by the following technical solutions:
A kind of inserted tool or work piece of adopting is the preparation method of the cutting fluid of Wimet, described cutting fluid is made up of following component by weight percentage: 2-amino-2-methyl-1-propanol amine 24-26%, boric acid 5-7%, polyoxyethylene stearyl base phosphoric acid ester 3-5%, polyoxyethylene phenyl phosphate ester 5-7%, phenolic ether phosphoric acid ester 6-8%, dibutyl phthalate 2-4%, Sodium Benzoate 2-4%, glycerol 2-4%, different plug azoles quinoline ketone 0.4-0.6%, benzotriazole 0.6-0.8%, polyoxyethylene nonylphenol ether 0.3-0.5%, methyl-silicone oil 0.6-1.0%, deionized water surplus, the preparation method of described cutting fluid comprises the steps: boric acid, 2-amino-2-methyl-1-propanol amine is added to the water, stirring under 40-50 DEG C of condition makes it dissolve completely, be cooled to 25-35 DEG C, then polyoxyethylene stearyl base phosphoric acid ester is added item by item, polyoxyethylene phenyl phosphate ester, dibutyl phthalate, phenolic ether phosphoric acid ester, Sodium Benzoate, glycerol, different plug azoles quinoline ketone, benzotriazole, polyoxyethylene nonylphenol ether fully stirs, dissolve completely until above-mentioned substance and add methyl-silicone oil, stir 60-90 minute again, finally pH value is adjusted to 8.5-9.5.
Composition Mechanism of the present invention is: do not adopt trolamine, but adopt 2-amino-2-methyl-1-propanol amine to suppress the precipitation of cobalt, and on this basis, composite boric acid, polyoxyethylene stearyl base phosphoric acid ester, polyoxyethylene phenyl phosphate ester, phenolic ether phosphoric acid ester, the various additive such as dibutyl phthalate, adopt Sodium Benzoate as antirust composition, at other additive composite in right amount, and on great many of experiments basis, determine the adding proportion of each component, make to reach synergistic action effect between each component, there is make cutting fluid except the effect of suppression cobalt precipitation, also have the lubrication required by conventional cutting liquid concurrently, antirust, cooling and cleanup action.
Compared with prior art the present invention has following outstanding advantage and beneficial effect:
1) cutting fluid that prepared by the inventive method can prevent cobalt from separating out, and is applicable to the machining adopting inserted tool to carry out, is also suitable for the machining that work piece relates to Wimet.
2) cutting fluid that prepared by the inventive method is lubricated in use, antirust, and cooling and cleaning performance are given prominence to, and meet user demand completely.
3) the cutting fluid environmental protection prepared of the inventive method, preparation technology is simple, and cost is low, long service life.
Embodiment
Embodiment one
A kind of inserted tool or work piece of adopting is the preparation method of the cutting fluid of Wimet, described cutting fluid is made up of following component by weight percentage: 2-amino-2-methyl-1-propanol amine 24%, boric acid 7%, polyoxyethylene stearyl base phosphoric acid ester 3%, polyoxyethylene phenyl phosphate ester 7%, phenolic ether phosphoric acid ester 6%, dibutyl phthalate 4%, Sodium Benzoate 2%, glycerol 4%, different plug azoles quinoline ketone 0.4%, benzotriazole 0.8%, polyoxyethylene nonylphenol ether 0.3%, methyl-silicone oil 1.0%, deionized water surplus; The preparation method of described cutting fluid comprises the steps: boric acid, 2-amino-2-methyl-1-propanol amine to be added to the water, stirring under 40 DEG C of conditions makes it dissolve completely, be cooled to 35 DEG C, then polyoxyethylene stearyl base phosphoric acid ester, polyoxyethylene phenyl phosphate ester, dibutyl phthalate, phenolic ether phosphoric acid ester, Sodium Benzoate, glycerol is added item by item, different plug azoles quinoline ketone, benzotriazole, polyoxyethylene nonylphenol ether fully stir, dissolve completely until above-mentioned substance and add methyl-silicone oil, stir 60 minutes again, finally pH value is adjusted to 9.5.
Embodiment two
A kind of inserted tool or work piece of adopting is the preparation method of the cutting fluid of Wimet, described cutting fluid is made up of following component by weight percentage: 2-amino-2-methyl-1-propanol amine 26%, boric acid 5%, polyoxyethylene stearyl base phosphoric acid ester 5%, polyoxyethylene phenyl phosphate ester 5%, phenolic ether phosphoric acid ester 8%, dibutyl phthalate 2%, Sodium Benzoate 4%, glycerol 2%, different plug azoles quinoline ketone 0.6%, benzotriazole 0.6%, polyoxyethylene nonylphenol ether 0.5%, methyl-silicone oil 0.6%, deionized water surplus; The preparation method of described cutting fluid comprises the steps: boric acid, 2-amino-2-methyl-1-propanol amine to be added to the water, stirring under 50 DEG C of conditions makes it dissolve completely, be cooled to 25 DEG C, then polyoxyethylene stearyl base phosphoric acid ester, polyoxyethylene phenyl phosphate ester, dibutyl phthalate, phenolic ether phosphoric acid ester, Sodium Benzoate, glycerol is added item by item, different plug azoles quinoline ketone, benzotriazole, polyoxyethylene nonylphenol ether fully stir, dissolve completely until above-mentioned substance and add methyl-silicone oil, stir 90 minutes again, finally pH value is adjusted to 8.5.
Embodiment three
A kind of inserted tool or work piece of adopting is the preparation method of the cutting fluid of Wimet, described cutting fluid is made up of following component by weight percentage: 2-amino-2-methyl-1-propanol amine 25%, boric acid 6%, polyoxyethylene stearyl base phosphoric acid ester 4%, polyoxyethylene phenyl phosphate ester 6%, phenolic ether phosphoric acid ester 7%, dibutyl phthalate 3%, Sodium Benzoate 3%, glycerol 3%, different plug azoles quinoline ketone 0.5%, benzotriazole 0.7%, polyoxyethylene nonylphenol ether 0.4%, methyl-silicone oil 0.8%, deionized water surplus; The preparation method of described cutting fluid comprises the steps: boric acid, 2-amino-2-methyl-1-propanol amine to be added to the water, stirring under 45 DEG C of conditions makes it dissolve completely, be cooled to 30 DEG C, then polyoxyethylene stearyl base phosphoric acid ester, polyoxyethylene phenyl phosphate ester, dibutyl phthalate, phenolic ether phosphoric acid ester, Sodium Benzoate, glycerol is added item by item, different plug azoles quinoline ketone, benzotriazole, polyoxyethylene nonylphenol ether fully stir, dissolve completely until above-mentioned substance and add methyl-silicone oil, stir 75 minutes again, finally pH value is adjusted to 9.0.
Claims (1)
1. one kind adopts inserted tool or work piece to be the preparation method of the cutting fluid of Wimet, it is characterized in that, described cutting fluid is made up of following component by weight percentage: 2-amino-2-methyl-1-propanol amine 24-26%, boric acid 5-7%, polyoxyethylene stearyl base phosphoric acid ester 3-5%, polyoxyethylene phenyl phosphate ester 5-7%, phenolic ether phosphoric acid ester 6-8%, dibutyl phthalate 2-4%, Sodium Benzoate 2-4%, glycerol 2-4%, isothiazolinone 0.4-0.6%, benzotriazole 0.6-0.8%, polyoxyethylene nonylphenol ether 0.3-0.5%, methyl-silicone oil 0.6-1.0%, deionized water surplus, the preparation method of described cutting fluid comprises the steps: boric acid, 2-amino-2-methyl-1-propanol amine is added to the water, stirring under 40-50 DEG C of condition makes it dissolve completely, be cooled to 25-35 DEG C, then polyoxyethylene stearyl base phosphoric acid ester is added item by item, polyoxyethylene phenyl phosphate ester, dibutyl phthalate, phenolic ether phosphoric acid ester, Sodium Benzoate, glycerol, isothiazolinone, benzotriazole, polyoxyethylene nonylphenol ether fully stirs, dissolve completely until above-mentioned substance and add methyl-silicone oil, stir 60-90 minute again, finally pH value is adjusted to 8.5-9.5.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201210177434.XA CN102703199B (en) | 2012-05-31 | 2012-05-31 | Preparation method of cutting fluid for hardware alloy cutter or processed workpiece as hardware alloy |
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| CN201210177434.XA CN102703199B (en) | 2012-05-31 | 2012-05-31 | Preparation method of cutting fluid for hardware alloy cutter or processed workpiece as hardware alloy |
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| CN102703199A CN102703199A (en) | 2012-10-03 |
| CN102703199B true CN102703199B (en) | 2015-04-15 |
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Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102977357B (en) * | 2012-10-30 | 2015-04-01 | 菏泽茂坤环保科技有限公司 | Polyoxyethane ether-based glycerol phosphite polymer, preparation method for same and near-dry cutting fluid prepared from same for gear machining |
| CN105238533A (en) * | 2015-09-16 | 2016-01-13 | 东莞市伟思化学科技有限公司 | Steel total-synthesis metal processing fluid and preparation method thereof |
| CN106244295A (en) * | 2016-07-13 | 2016-12-21 | 天长市润达金属防锈助剂有限公司 | A kind of extreme boundary lubrication metalworking fluid |
| CN106190480A (en) * | 2016-07-13 | 2016-12-07 | 天长市润达金属防锈助剂有限公司 | A kind of anti-rust metal cutting fluid of high lubricating property |
| CN115700274B (en) * | 2022-11-28 | 2024-03-26 | 广东红日星实业有限公司 | Cutting fluid and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6383991B1 (en) * | 1998-04-03 | 2002-05-07 | Kao Corporation | Cutting oil composition |
| CN101230305A (en) * | 2007-12-29 | 2008-07-30 | 广州机械科学研究院 | Totally synthesized cutting fluid adapted for cobalt-containing alloy material and preparation method thereof |
| CN102311860A (en) * | 2011-04-26 | 2012-01-11 | 东莞市安美润滑科技有限公司 | Water-based cutting fluid used for processing neodymium-iron-boron material slices and application method thereof |
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2012
- 2012-05-31 CN CN201210177434.XA patent/CN102703199B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6383991B1 (en) * | 1998-04-03 | 2002-05-07 | Kao Corporation | Cutting oil composition |
| CN101230305A (en) * | 2007-12-29 | 2008-07-30 | 广州机械科学研究院 | Totally synthesized cutting fluid adapted for cobalt-containing alloy material and preparation method thereof |
| CN102311860A (en) * | 2011-04-26 | 2012-01-11 | 东莞市安美润滑科技有限公司 | Water-based cutting fluid used for processing neodymium-iron-boron material slices and application method thereof |
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