CN102666515B - 高选择性氧化乙烯催化剂启动的方法 - Google Patents

高选择性氧化乙烯催化剂启动的方法 Download PDF

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Publication number
CN102666515B
CN102666515B CN201080058923.2A CN201080058923A CN102666515B CN 102666515 B CN102666515 B CN 102666515B CN 201080058923 A CN201080058923 A CN 201080058923A CN 102666515 B CN102666515 B CN 102666515B
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temperature
catalyst
moderator
silver
ppm
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Expired - Fee Related
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CN201080058923.2A
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Chinese (zh)
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CN102666515A (zh
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纳比勒·里兹卡拉
诺尔玛·B·卡斯塔尼奥拉
吉里什·德赛
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Scientific Design Co Inc
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Scientific Design Co Inc
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/36—Rhenium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C07C11/04—Ethene
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
    • C07D303/02—Compounds containing oxirane rings
    • C07D303/04—Compounds containing oxirane rings containing only hydrogen and carbon atoms in addition to the ring oxygen atoms

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201080058923.2A 2009-12-23 2010-12-20 高选择性氧化乙烯催化剂启动的方法 Expired - Fee Related CN102666515B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US28971909P 2009-12-23 2009-12-23
US61/289,719 2009-12-23
PCT/US2010/061192 WO2011079056A2 (en) 2009-12-23 2010-12-20 A process for initiating a highly selective ethylene oxide catalyst

Publications (2)

Publication Number Publication Date
CN102666515A CN102666515A (zh) 2012-09-12
CN102666515B true CN102666515B (zh) 2015-05-20

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ID=44152005

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Country Link
US (1) US8487123B2 (enExample)
EP (1) EP2521718B1 (enExample)
JP (1) JP2013515730A (enExample)
KR (1) KR101815664B1 (enExample)
CN (1) CN102666515B (enExample)
BR (1) BR112012015219B1 (enExample)
CA (1) CA2784603C (enExample)
IN (1) IN2012DN05077A (enExample)
MX (1) MX2012007440A (enExample)
RU (1) RU2538969C2 (enExample)
TW (1) TWI485142B (enExample)
WO (1) WO2011079056A2 (enExample)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012141942A1 (en) * 2011-04-11 2012-10-18 Dow Technology Investments Llc Process for conditioning a high efficiency ethylene oxide catalyst
CN104203931A (zh) * 2011-10-18 2014-12-10 哈桑·伊萨·阿拉哈迈迪 具有添加缓和剂的环氧化方法
CN104884443B (zh) * 2012-12-31 2017-07-04 科学设计公司 用于环氧乙烷催化剂的启动方法
CN105008339B (zh) * 2013-01-11 2017-09-12 科学设计公司 具有后调节步骤的环氧化工艺
EP3087061B1 (en) * 2013-12-23 2018-04-11 Scientific Design Company Inc. Epoxidation process
WO2019055773A1 (en) 2017-09-15 2019-03-21 MultiPhase Solutions, Inc. GAS PHASE CHROMATOGRAPHY OF SELECTIVE HALOGEN DETECTION FOR ONLINE ANALYSIS AND CONTROL OF SELECTIVE OXIDATION CHEMICAL PRODUCTION PROCESSES
CN114057670B (zh) * 2020-07-29 2024-06-07 中国石油化工股份有限公司 一种用于启动乙烯环氧化工艺的方法
CN114057669B (zh) * 2020-07-29 2023-12-08 中国石油化工股份有限公司 一种乙烯环氧化恒温开车方法
CN114436998A (zh) * 2020-11-05 2022-05-06 中国石油化工股份有限公司 一种乙烯环氧化开车方法
CA3214971A1 (en) * 2021-04-08 2022-10-13 Shell Internationale Research Maatschappij B.V. Moderator and catalyst performance optimization for epoxidation of ethylene

Citations (4)

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Publication number Priority date Publication date Assignee Title
CN1040794A (zh) * 1988-07-25 1990-03-28 国际壳牌研究有限公司 环氧乙烷反应器的启动方法
CN1297445A (zh) * 1998-04-16 2001-05-30 阿克奥化学技术有限公司 环氧化方法
US7553980B2 (en) * 2007-09-26 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for initiating a highly selective ethylene oxide catalyst
US20090281339A1 (en) * 2008-05-07 2009-11-12 Marek Matusz Process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine

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US2279469A (en) * 1942-04-14 Process of making olefin oxides
SE321462B (enExample) 1962-10-10 1970-03-09 Halcon International Inc
GB1170663A (en) * 1967-03-22 1969-11-12 Shell Int Research Process for preparing Silver Catalysts
US3702259A (en) * 1970-12-02 1972-11-07 Shell Oil Co Chemical production of metallic silver deposits
US4761394A (en) * 1986-10-31 1988-08-02 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4766105A (en) * 1986-10-31 1988-08-23 Shell Oil Company Ethylene oxide catalyst and process for preparing the catalyst
US4908343A (en) * 1987-02-20 1990-03-13 Union Carbide Chemicals And Plastics Company Inc. Catalyst composition for oxidation of ethylene to ethylene oxide
US5057481A (en) * 1987-02-20 1991-10-15 Union Carbide Chemicals And Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
CA1339317C (en) 1988-07-25 1997-08-19 Ann Marie Lauritzen Process for producing ethylene oxide
DE68925767T2 (de) * 1988-08-30 1996-08-14 Union Carbide Corp Katalysatoren für die Herstellung von Ethylenoxid und Verfahren zur deren Herstellung
US5187140A (en) * 1989-10-18 1993-02-16 Union Carbide Chemicals & Plastics Technology Corporation Alkylene oxide catalysts containing high silver content
US5102848A (en) * 1990-09-28 1992-04-07 Union Carbide Chemicals & Plastics Technology Corporation Catalyst composition for oxidation of ethylene to ethylene oxide
US5155242A (en) * 1991-12-05 1992-10-13 Shell Oil Company Process for starting-up an ethylene oxide reactor
US5407888A (en) * 1992-05-12 1995-04-18 Basf Aktiengesellschaft Silver catalyst
US6492065B2 (en) * 1997-12-05 2002-12-10 Victor Company Of Japan, Limited Hologram color filter, production method of the same hologram color filter and space light modulating apparatus using the same hologram color filter
JP4042332B2 (ja) 2001-02-27 2008-02-06 三菱化学株式会社 レニウム含有触媒を用いるオレフィンオキシドの製造方法
MX257124B (es) * 2002-06-28 2008-05-14 Shell Int Research Metodo para iniciar un proceso de epoxidacion, catalizador y proceso de epoxidacion de una olefina.
AU2003243757A1 (en) 2002-06-28 2004-01-19 Shell Oil Company A method for improving the selectivity of a catalyst and a process for the epoxidation of an olefin
MX245604B (es) * 2002-06-28 2007-05-04 Shell Int Research Metodo para iniciar un proceso de epoxidacion y proceso de epoxidacion de una olefina.
US6992209B2 (en) * 2002-12-09 2006-01-31 Battelle Memorial Institute Methods of forming alpha, beta-unsaturated acids and esters
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US7696368B2 (en) 2007-05-11 2010-04-13 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Start-up of high selectivity catalysts in olefin oxide plants

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1040794A (zh) * 1988-07-25 1990-03-28 国际壳牌研究有限公司 环氧乙烷反应器的启动方法
CN1297445A (zh) * 1998-04-16 2001-05-30 阿克奥化学技术有限公司 环氧化方法
US7553980B2 (en) * 2007-09-26 2009-06-30 Sd Lizenzverwertungsgesellschaft Mbh & Co. Kg Process for initiating a highly selective ethylene oxide catalyst
US20090281339A1 (en) * 2008-05-07 2009-11-12 Marek Matusz Process for the start-up of an epoxidation process, a process for the production of ethylene oxide, a 1,2-diol, a 1,2-diol ether, a 1,2-carbonate, or an alkanolamine

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
环氧乙烷生产工艺的改进;唐永良;《化学工程》;20060930;第34卷(第9期);第75-78页 *

Also Published As

Publication number Publication date
KR101815664B1 (ko) 2018-01-05
CA2784603A1 (en) 2011-06-30
EP2521718B1 (en) 2014-07-02
WO2011079056A3 (en) 2011-11-17
TW201139392A (en) 2011-11-16
US20110152549A1 (en) 2011-06-23
CN102666515A (zh) 2012-09-12
CA2784603C (en) 2018-06-12
KR20120108029A (ko) 2012-10-04
TWI485142B (zh) 2015-05-21
BR112012015219B1 (pt) 2018-04-03
US8487123B2 (en) 2013-07-16
RU2538969C2 (ru) 2015-01-10
JP2013515730A (ja) 2013-05-09
BR112012015219A2 (pt) 2015-09-22
RU2012131369A (ru) 2014-01-27
EP2521718A4 (en) 2013-06-19
EP2521718A2 (en) 2012-11-14
MX2012007440A (es) 2012-07-23
IN2012DN05077A (enExample) 2015-10-09
WO2011079056A2 (en) 2011-06-30

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