CN102666386B - 高活性的小晶体zsm-12 - Google Patents
高活性的小晶体zsm-12 Download PDFInfo
- Publication number
- CN102666386B CN102666386B CN201080052053.8A CN201080052053A CN102666386B CN 102666386 B CN102666386 B CN 102666386B CN 201080052053 A CN201080052053 A CN 201080052053A CN 102666386 B CN102666386 B CN 102666386B
- Authority
- CN
- China
- Prior art keywords
- composition
- zsm
- crystalline material
- mixture
- porous crystalline
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/02—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants; After-treatment thereof
- C01B39/42—Type ZSM-12
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J29/00—Catalysts comprising molecular sieves
- B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
- B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
- B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
- B01J29/7034—MTW-type, e.g. ZSM-12, NU-13, TPZ-12 or Theta-3
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C6/00—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
- C07C6/08—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond
- C07C6/12—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring
- C07C6/126—Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions by conversion at a saturated carbon-to-carbon bond of exclusively hydrocarbons containing a six-membered aromatic ring of more than one hydrocarbon
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S423/00—Chemistry of inorganic compounds
- Y10S423/33—MTW, e.g. ZSM-12, NU-13, CZH-5, TPZ-3
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- General Chemical & Material Sciences (AREA)
- Catalysts (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Diaphragms For Electromechanical Transducers (AREA)
- Finger-Pressure Massage (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/590,952 US8202506B2 (en) | 2009-11-17 | 2009-11-17 | High activity small crystal ZSM-12 |
US12/590,952 | 2009-11-17 | ||
PCT/US2010/056656 WO2011062855A1 (en) | 2009-11-17 | 2010-11-15 | High activity small crystal zsm-12 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102666386A CN102666386A (zh) | 2012-09-12 |
CN102666386B true CN102666386B (zh) | 2014-12-03 |
Family
ID=43466952
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201080052053.8A Active CN102666386B (zh) | 2009-11-17 | 2010-11-15 | 高活性的小晶体zsm-12 |
Country Status (9)
Families Citing this family (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US8202506B2 (en) * | 2009-11-17 | 2012-06-19 | Exxonmobil Research And Engineering Company | High activity small crystal ZSM-12 |
WO2013090534A1 (en) | 2011-12-16 | 2013-06-20 | Shell Oil Company | A titania-bound zsm-12 zeolite composition and method of making and using such composition |
CN103435065B (zh) * | 2013-08-23 | 2014-12-03 | 黑龙江大学 | 一种纳米zsm-12分子筛的制备方法 |
CN104445262A (zh) * | 2013-09-24 | 2015-03-25 | 中国石油化工股份有限公司 | 具有特定晶体取向的zsm-12分子筛及其制备方法 |
US10053403B2 (en) | 2015-02-04 | 2018-08-21 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and their use in transalkylation of heavy aromatics to xylenes |
US10118165B2 (en) | 2015-02-04 | 2018-11-06 | Exxonmobil Chemical Patents Inc. | Catalyst compositions and use in heavy aromatics conversion processes |
WO2017205091A1 (en) * | 2016-05-25 | 2017-11-30 | Uop Llc | High charge density metallophosphate molecular sieves |
WO2018080640A1 (en) | 2016-10-24 | 2018-05-03 | Chevron U.S.A. Inc. | Synthesis of mtw framework type molecular sieves |
JP6912564B2 (ja) | 2016-11-17 | 2021-08-04 | シェブロン ユー.エス.エー. インコーポレイテッド | ゼオライト転換によるmtwフレームワーク型ゼオライトの合成 |
HUE060395T2 (hu) | 2016-12-16 | 2023-02-28 | Shell Int Research | Viaszmentesítõ katalizátoros rendszer |
CN109665541B (zh) * | 2017-10-17 | 2022-04-01 | 中国石油化工股份有限公司 | 低硅铝比zsm-12型沸石分子筛的合成方法 |
JP7138697B2 (ja) * | 2017-10-27 | 2022-09-16 | シェブロン ユー.エス.エー. インコーポレイテッド | モレキュラーシーブssz-112、その合成及び使用 |
CA3086339A1 (en) * | 2017-12-21 | 2019-06-27 | Exxonmobil Research And Engineering Company | Emm-31 materials and processes and uses thereof |
KR102433148B1 (ko) | 2018-03-30 | 2022-08-17 | 엑손모빌 케미칼 패턴츠 인코포레이티드 | 혼합 크실렌 및 고옥탄가 c9+ 방향족의 공생산 방법 |
EP3781308A1 (en) | 2018-04-17 | 2021-02-24 | Shell Internationale Research Maatschappij B.V. | Catalyst system for dewaxing |
CN115959678A (zh) * | 2021-10-11 | 2023-04-14 | 中国石油天然气股份有限公司 | 一种zsm-12分子筛及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4585639A (en) * | 1984-04-16 | 1986-04-29 | Mobil Oil Corporation | Preparation of crystalline silicate ZSM-12 |
CN1397493A (zh) * | 2002-06-03 | 2003-02-19 | 刘希尧 | 一类十二员环结构两相共生分子筛及其合成方法 |
CN100404419C (zh) * | 2002-11-15 | 2008-07-23 | 埃克森美孚化学专利公司 | 高活性小晶体zsm-12 |
Family Cites Families (17)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3354078A (en) | 1965-02-04 | 1967-11-21 | Mobil Oil Corp | Catalytic conversion with a crystalline aluminosilicate activated with a metallic halide |
US3832449A (en) | 1971-03-18 | 1974-08-27 | Mobil Oil Corp | Crystalline zeolite zsm{14 12 |
US4452769A (en) | 1979-03-21 | 1984-06-05 | Mobil Oil Corporation | Method of preparing crystalline zeolite |
US4537758A (en) | 1979-03-21 | 1985-08-27 | Mobil Oil Corporation | Process for preparing highly siliceous porous ZSM-12 type crystalline material |
US4391785A (en) | 1981-12-21 | 1983-07-05 | Mobil Oil Corporation | Preparation of ZSM-12 type zeolites |
US4482531A (en) * | 1983-04-29 | 1984-11-13 | Mobil Oil Corporation | Synthesis of ZSM-12 zeolite |
US4552739A (en) | 1983-12-09 | 1985-11-12 | Mobil Oil Corporation | Method of preparing crystalline zeolite ZSM-12 and product |
US4539193A (en) | 1984-05-23 | 1985-09-03 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-12 |
US4552738A (en) | 1984-05-25 | 1985-11-12 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-12 |
CA1239385A (en) | 1984-06-26 | 1988-07-19 | Mae K. Rubin | Preparation of zeolite zsm-12 |
US4585637A (en) | 1984-06-26 | 1986-04-29 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-12 |
US4585746A (en) | 1984-06-27 | 1986-04-29 | Mobil Oil Corporation | Synthesis of crystalline silicate ZSM-12 |
US5021141A (en) | 1990-09-14 | 1991-06-04 | Mobil Oil Corp. | Synthesis of crystalline ZSM-12 type structure |
US5192521A (en) | 1991-11-19 | 1993-03-09 | Mobil Oil Corp. | Synthesis of crystalline silicate ZSM-12 |
DE10314753A1 (de) * | 2003-04-01 | 2004-10-14 | Süd-Chemie AG | Synthetischer Zeolith, insbesondere für die katalytische Hydroisomerisierung von höheren Paraffinen |
JP4954854B2 (ja) * | 2007-11-22 | 2012-06-20 | ユーオーピー エルエルシー | 層状化モレキュラーシーブ組成物の調製方法 |
US8202506B2 (en) * | 2009-11-17 | 2012-06-19 | Exxonmobil Research And Engineering Company | High activity small crystal ZSM-12 |
-
2009
- 2009-11-17 US US12/590,952 patent/US8202506B2/en active Active
-
2010
- 2010-11-15 CN CN201080052053.8A patent/CN102666386B/zh active Active
- 2010-11-15 WO PCT/US2010/056656 patent/WO2011062855A1/en active Application Filing
- 2010-11-15 CA CA2779371A patent/CA2779371C/en active Active
- 2010-11-15 IN IN4748DEN2012 patent/IN2012DN04748A/en unknown
- 2010-11-15 KR KR1020127015491A patent/KR20120106954A/ko active Search and Examination
- 2010-11-15 JP JP2012539050A patent/JP5716036B2/ja not_active Expired - Fee Related
- 2010-11-15 EP EP10779193.1A patent/EP2501654B1/en active Active
-
2012
- 2012-05-16 ZA ZA2012/03584A patent/ZA201203584B/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4585639A (en) * | 1984-04-16 | 1986-04-29 | Mobil Oil Corporation | Preparation of crystalline silicate ZSM-12 |
CN1397493A (zh) * | 2002-06-03 | 2003-02-19 | 刘希尧 | 一类十二员环结构两相共生分子筛及其合成方法 |
CN100404419C (zh) * | 2002-11-15 | 2008-07-23 | 埃克森美孚化学专利公司 | 高活性小晶体zsm-12 |
Also Published As
Publication number | Publication date |
---|---|
JP2013510793A (ja) | 2013-03-28 |
IN2012DN04748A (US20100009293A1-20100114-C00010.png) | 2015-08-07 |
CA2779371C (en) | 2016-10-04 |
EP2501654A1 (en) | 2012-09-26 |
CN102666386A (zh) | 2012-09-12 |
ZA201203584B (en) | 2013-01-30 |
EP2501654B1 (en) | 2017-12-27 |
KR20120106954A (ko) | 2012-09-27 |
JP5716036B2 (ja) | 2015-05-13 |
US20110118520A1 (en) | 2011-05-19 |
US8202506B2 (en) | 2012-06-19 |
CA2779371A1 (en) | 2011-05-26 |
WO2011062855A1 (en) | 2011-05-26 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |