CN102613176A - Mildewproof spray - Google Patents
Mildewproof spray Download PDFInfo
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- CN102613176A CN102613176A CN2012100570612A CN201210057061A CN102613176A CN 102613176 A CN102613176 A CN 102613176A CN 2012100570612 A CN2012100570612 A CN 2012100570612A CN 201210057061 A CN201210057061 A CN 201210057061A CN 102613176 A CN102613176 A CN 102613176A
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- mildew resistant
- spraying agent
- resistant spraying
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Abstract
The invention relates to a mildewproof spray, which comprises the following components in percentage by weight: 0.02 to 0.5 percent of bacteriostatic active substances, 0.01 to 1.5 percent of nonionic surfactant, 0.004 to 0.25 percent of porous inorganic nano particles and the balance of water, wherein the bacteriostatic active substances are distillation extracts of litsea cubeba, mustard, cassia bark, cinnamon and garlic. The long-acting mildewproof spray is prepared from bacteriostatic active ingredients of pure natural plants through the adsorption of the inorganic nano particles and a technology of the dispersion of the surfactant, so that the mildewproof spray can be used for walls, fabrics, furniture and the like, and is safe, non-toxic, low in using amount and long in time for maintaining a bacteriostatic effect.
Description
[technical field]
The present invention relates to a kind of mildew resistant spraying agent, relate in particular to a kind of mildew resistant spraying agent that utilizes the natural plant extracts preparation.
[background technology]
Social now, people are to the quality of life, and especially comfort living has higher pursuit, but mould and mycotoxin contamination are seen everywhere in life, have become problem very important in the daily life.Because rhythm of life constantly accelerates, most of working clans do not have the unnecessary time to do housework, or sweep untimely, indoor the growing of mould that just have of long duration.Especially at southern area each monthly mean temperature of warm humidity from May to September more than 20 ℃, average relative humidity is more than 80%, especially at plum rain season (3～June); The fungus growth breeding is the most vigorous; Amblent air temperature is well suited for fungus growth, all is easy to generate a large amount of mould bacterial plaques like positions such as household, clothing, curtain, floor, body of wall, ceramic tiles, and it is attractive in appearance not only to influence the room; Also be prone to cause foreign flavor indoors, have a strong impact on living environment.
Existing in the market family expenses mould remover product is many to be active substance with organic acid, organic acid salt and organic acid esters.These materials have a lot of shortcomings and limitation; For example receive environment (especially pH value) influence big; Wherein some active antibacterial component is because of factors such as volatilization, oxidation cause the anti-mold effect poor stability, the weak point of holding time; And some material has corrosivity and excitant, and health is impacted.So it is significant to the quality of the life that improves people to develop mould inhibitor safely and effectively.
[summary of the invention]
Based on this, be necessary to provide a kind of safe and effective and stable mildew resistant spraying agent preferably.
A kind of mildew resistant spraying agent; By weight percentage; Contain 0.02%～0.5% bacteriostatic activity material, 0.01%～1.5% nonionic surface active agent and 0.004%～0.25% porous, inorganic nano particle; Surplus is a water, wherein, and the distillation extraction thing that said bacteriostatic activity material is the fruit of a cubeb litsea tree, mustard, Chinese cassia tree, cassia bark and garlic.
In a preferred embodiment, said bacteriostatic activity material is prepared by following method:
Fruit of a cubeb litsea tree fruit after will drying is used steam distillation, obtains litsea cubeba oil through the refining of fractionation appearance then;
Litsea cubeba oil, cinnamon oil, cassia oil are used bisulf iotate-treated, separate the back refining with alkali again and obtain.
In a preferred embodiment, said bacteriostatic activity material comprises citral and cinnamic aldehyde.
In a preferred embodiment, said nonionic surface active agent is tween80 or Span20.
In a preferred embodiment, said porous, inorganic nano particle is nano silicon, nano zine oxide or nano titanium oxide.
In a preferred embodiment, the particle diameter of said porous, inorganic nano particle is 1～10 micron.
A kind of mildew resistant spraying agent; By weight percentage; Contain 0.02%～0.5% bacteriostatic activity material, 0.01%～1.5% nonionic surface active agent and 0.006%～0.25% porous polymer microsphere; Surplus is a water, wherein, and the distillation extraction thing that said bacteriostatic activity material is the fruit of a cubeb litsea tree, mustard, Chinese cassia tree, cassia bark and garlic.
In a preferred embodiment, said bacteriostatic activity material is prepared by following method:
Fruit of a cubeb litsea tree fruit after will drying is used steam distillation, obtains litsea cubeba oil through the refining of fractionation appearance then;
Litsea cubeba oil, cinnamon oil, cassia oil are used bisulf iotate-treated, separate the back refining with alkali again and obtain.
In a preferred embodiment, said porous polymer microsphere is poly (methyl methacrylate) micro-sphere, polymethyl methacrylate-butyl acrylate copolymer microballoon, polyethyl acrylate microballoon, butyl polyacrylate microballoon, polystyrene microsphere.
In a preferred embodiment, the particle diameter of said porous polymer microsphere is 0.5～5 micron.
To take from the bacteriostatic active ingredients of pure natural plant,, utilize the surfactant-dispersed technology through the absorption of inorganic nanoparticles; Process long-acting mildew resistant spraying agent, it can be used for body of wall, fabric, furniture etc., safety non-toxic; Consumption is low, the fungistatic effect length of holding time.
[description of drawings]
Through specifying of the preferred embodiments of the present invention shown in the accompanying drawing, above-mentioned and other purpose, characteristic and advantage of the present invention will become more clear.
Fig. 1 and Fig. 2 are that mildew resistant spraying agent and the Comparative Examples of embodiment 1 tested photo to the effect comparison of the growth of inhibition strepto-;
Fig. 3 and Fig. 4 are that mildew resistant spraying agent and the Comparative Examples of embodiment 1 tested photo to the effect comparison of the growth of inhibition aspergillus.
[embodiment]
For make above-mentioned purpose of the present invention, feature and advantage can be more obviously understandable, does detailed explanation below in conjunction with the accompanying drawing specific embodiments of the invention.A lot of details have been set forth in the following description so that make much of the present invention.But the present invention can implement much to be different from alternate manner described here, and those skilled in the art can do similar improvement under the situation of intension of the present invention, so the present invention does not receive the restriction of following disclosed practical implementation.
The mildew resistant spraying agent of embodiment one; By weight percentage; Contain 0.02%～0.5% bacteriostatic activity material, 0.01%～1.5% nonionic surface active agent and 0.004%～0.25% porous, inorganic nano particle; Surplus is a water, wherein, and the distillation extraction thing that said bacteriostatic activity material is the fruit of a cubeb litsea tree, mustard, Chinese cassia tree, cassia bark and garlic.
The bacteriostatic activity material of present embodiment contains citral and cinnamic acid, and it adopts mainly antibacterial, mildew-resistant component of natural plant extracts conduct.Safe, nontoxic, environment and health are had no adverse effects.
The bacteriostatic activity material of present embodiment can be prepared by following method:
Fruit of a cubeb litsea tree fruit is made essential oil with steam distillation after drying, the essential oil after the distillation obtains litsea cubeba oil through the refining of fractionation appearance, and wherein citral content is 85%; Cassia oil and cinnamon oil are purchased in the perfumery, Jiangxi, and its cinnamic aldehyde content is 85%; Litsea cubeba oil, cinnamon oil, cassia oil are become addition product with bisulf iotate-treated, separate refining then with alkali again, promptly obtain above-mentioned bacteriostatic activity material.
Said nonionic surface active agent is preferably tween80 or Span20.
Said porous, inorganic nano particle is nano silicon, nano zine oxide or nano titanium oxide, and its particle diameter is 1～10 μ m.
This embodiment through the absorption of inorganic nanoparticles, utilizes the surfactant-dispersed technology to take from the bacteriostatic active ingredients of pure natural plant; Process long-acting mildew resistant spraying agent, can be used for body of wall, fabric, furniture etc.; Safety non-toxic, consumption is low, the fungistatic effect length of holding time.
The mildew resistant spraying agent of embodiment two; By weight percentage; Contain 0.02%～0.5% bacteriostatic activity material, 0.01%～1.5% nonionic surface active agent and 0.006%～0.25% porous polymer microsphere; Surplus is a water, wherein, and the distillation extraction thing that said bacteriostatic activity material is the fruit of a cubeb litsea tree, mustard, Chinese cassia tree, cassia bark and garlic.
The difference of the mildew resistant spraying agent of embodiment two and embodiment one is, operating weight percentage is the carrier that 0.006%～0.25% porous polymer microsphere is used as the bacteriostatic activity material.Said porous polymer microsphere is poly (methyl methacrylate) micro-sphere, polymethyl methacrylate-butyl acrylate copolymer microballoon, polyethyl acrylate microballoon, butyl polyacrylate microballoon, polystyrene microsphere.The particle diameter of said porous polymer microsphere is 0.5～5 micron.
Use the cinnamon oil of taking from plant fully and cassia oil as the natural bacteriostatic component in above-mentioned two kinds of embodiments, avoided the use of the antipathogenic composition of chemosynthesis.Adopted inorganic subparticle to be added in the mold proof product; When helping oil-soluble antipathogenic composition effectively to disperse fast; Mold proof product can be absorbed by body of wall fast and effectively; In stable the adhering to of material surfaces such as body of wall, ceramic tile, even still can play mould control steady in a long-term to it through the flushing of water repeatedly.Use the inorganic nanoparticles, porous polymer particles of bigger serface carrier, suppress volatilization, the oxidation of antipathogenic composition on the one hand, realize the effect of long-acting mould fungus inhibition on the other hand through the slow release of porous material as the oil-soluble antipathogenic composition.
Further specify below in conjunction with specific embodiment.
Embodiment 1
The bacteriostatic activity material is fully mixed with non-ionic surface active agent, porous, inorganic nano particle (average grain diameter is 10 μ m), and add a large amount of water and fully stir homogeneous, obtain the aqueous dispersions of clear.Wherein, the percentage by weight of bacteriostatic active ingredients in aqua is 0.5%; Nonionic surface active agent is elected tween80 as, and content is 1.2%; The porous, inorganic nano particle is a nano silicon, and content is 0.25%.
Embodiment 2
The bacteriostatic activity material is fully mixed with non-ionic surface active agent, porous polymer microsphere (average grain diameter is 5 μ m), and add a large amount of water and fully stir homogeneous, obtain the aqueous dispersions of clear.Wherein, the percentage by weight of bacteriostatic active ingredients in aqua is 0.1%; Nonionic surface active agent is elected Span20 as, and content is 0.3%; Porous polymer microsphere is a poly (methyl methacrylate) micro-sphere, and content is 0.04%.
Comparative Examples
The bacteriostatic activity material is fully mixed with non-ionic surface active agent, and add a large amount of water and fully stir homogeneous, obtain the aqueous dispersions of clear.Wherein, the percentage by weight of bacteriostatic active ingredients in aqua is 0.5%; Nonionic surface active agent is elected tween80 as, and content is 1.2%.
Performance test
See also Fig. 1; With strepto-common in the home environment is experimental strain; With the streptomycete spore suspension be coated on the medium (left side) that do not contain antipathogenic composition respectively, the medium that sprayed the mould inhibitor of Comparative Examples (in) and sprayed on the medium (right side) of mould inhibitor of embodiment 1 continuous culture 2 days (48 hours) under 27 ℃ of conditions.
Experimental result shows, having sprayed in the medium of mould inhibitor of embodiment 1 does not have mould to grow, and sprayed on the medium of mould inhibitor of Comparative Examples also not grow mould; Do not overgrow with mould and add in the medium of mould inhibitor.Explain carrier loaded mildew resistant spraying agent and the mildew resistant spraying agent that does not add carrier all can be in 48 hours the growth of mould fungus inhibition.
See also Fig. 2; After 1 week; After promptly cultivating, do not add as having grown a large amount of fungal hyphaes on the medium of any antipathogenic composition, have a small amount of fungal hyphae to grow on the medium of mildew resistant spraying agent in the Comparative Examples yet and go into through continuous 168 hours; Explain that the mould inhibitor in the Comparative Examples almost lost efficacy after a week to the inhibition effect of strepto-, do not see that fungal hyphae grows and sprayed in the medium of carrier loaded mould inhibitor among the embodiment 1.
See also Fig. 3; With aspergillus common in the home environment is experimental strain; With the Aspergillus spore suspension be coated on the medium (left side) that do not contain antipathogenic composition respectively, the medium that sprayed the mould inhibitor of Comparative Examples (in) and sprayed on the medium (right side) of mould inhibitor of embodiment 1 continuous culture 2 days (48 hours) under 27 ℃ of conditions.
Experimental result shows, having sprayed in the medium of mould inhibitor of embodiment 1 does not have mould to grow, and sprayed on the medium of mould inhibitor of Comparative Examples also not grow mould; Do not overgrow with mould and add in the medium of mould inhibitor.Explain carrier loaded mildew resistant spraying agent and the mildew resistant spraying agent that does not add carrier all can be in 48 hours the growth of mould fungus inhibition.
See also Fig. 4; After 1 week; After promptly cultivating, do not add as having grown a large amount of fungal hyphaes on the medium of any antipathogenic composition, have a small amount of fungal hyphae to grow on the medium of mildew resistant spraying agent in the Comparative Examples yet and go into through continuous 168 hours; Explain that the mould inhibitor in the Comparative Examples almost lost efficacy after a week to the inhibition effect of strepto-, do not see that fungal hyphae grows and sprayed in the medium of carrier loaded mould inhibitor among the embodiment 1.
The above embodiment has only expressed several kinds of embodiments of the present invention, and it describes comparatively concrete and detailed, but can not therefore be interpreted as the restriction to claim of the present invention.Should be pointed out that for the person of ordinary skill of the art under the prerequisite that does not break away from the present invention's design, can also make some distortion and improvement, these all belong to protection scope of the present invention.Therefore, the protection domain of patent of the present invention should be as the criterion with accompanying claims.
Claims (10)
1. mildew resistant spraying agent; It is characterized in that; By weight percentage, contain 0.02%～0.5% bacteriostatic activity material, 0.01%～1.5% nonionic surface active agent and 0.004%～0.25% porous, inorganic nano particle, surplus is a water; Wherein, the said bacteriostatic activity material distillation extraction thing that is the fruit of a cubeb litsea tree, mustard, Chinese cassia tree, cassia bark and garlic.
2. mildew resistant spraying agent according to claim 1 is characterized in that: said bacteriostatic activity material is prepared by following method:
Fruit of a cubeb litsea tree fruit after will drying is used steam distillation, obtains litsea cubeba oil through the refining of fractionation appearance then;
Litsea cubeba oil, cinnamon oil, cassia oil are used bisulf iotate-treated, separate the back refining with alkali again and obtain.
3. mildew resistant spraying agent according to claim 1 is characterized in that: said bacteriostatic activity material comprises citral and cinnamic aldehyde.
4. mildew resistant spraying agent according to claim 1 is characterized in that: said nonionic surface active agent is tween80 or Span20.
5. mildew resistant spraying agent according to claim 1 is characterized in that: said porous, inorganic nano particle is nano silicon, nano zine oxide or nano titanium oxide.
6. mildew resistant spraying agent according to claim 1 is characterized in that: the particle diameter of said porous, inorganic nano particle is 1～10 micron.
7. mildew resistant spraying agent; It is characterized in that; By weight percentage, contain 0.02%～0.5% bacteriostatic activity material, 0.01%～1.5% nonionic surface active agent and 0.006%～0.25% porous polymer microsphere, surplus is a water; Wherein, the said bacteriostatic activity material distillation extraction thing that is the fruit of a cubeb litsea tree, mustard, Chinese cassia tree, cassia bark and garlic.
8. mildew resistant spraying agent according to claim 7 is characterized in that: said bacteriostatic activity material is prepared by following method:
Fruit of a cubeb litsea tree fruit after will drying is used steam distillation, obtains litsea cubeba oil through the refining of fractionation appearance then;
Litsea cubeba oil, cinnamon oil, cassia oil are used bisulf iotate-treated, separate the back refining with alkali again and obtain.
9. mildew resistant spraying agent according to claim 7 is characterized in that: said porous polymer microsphere is poly (methyl methacrylate) micro-sphere, polymethyl methacrylate-butyl acrylate copolymer microballoon, polyethyl acrylate microballoon, butyl polyacrylate microballoon, polystyrene microsphere.
10. mildew resistant spraying agent according to claim 7 is characterized in that: the particle diameter of said porous polymer microsphere is 0.5～5 micron.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN2012100570612A CN102613176A (en) | 2012-03-06 | 2012-03-06 | Mildewproof spray |
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| CN2012100570612A CN102613176A (en) | 2012-03-06 | 2012-03-06 | Mildewproof spray |
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| CN2012100570612A Pending CN102613176A (en) | 2012-03-06 | 2012-03-06 | Mildewproof spray |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN104645395A (en) * | 2014-11-26 | 2015-05-27 | 彭科 | Plant-source deodorant for urban garbage disposal |
| CN107173396A (en) * | 2017-06-05 | 2017-09-19 | 冯新平 | A kind of nontoxic mildew resistant spraying agent and its preparation technology |
| CN107722733A (en) * | 2017-11-07 | 2018-02-23 | 上海纳米技术及应用国家工程研究中心有限公司 | Antibacterial antifogging spray and its preparation method and application |
| CN107916566A (en) * | 2017-10-31 | 2018-04-17 | 苏州梅香雅筑工艺品有限公司 | A kind of preparation method of covering of the fan Mould-proof shell fabric |
| CN108077335A (en) * | 2017-12-06 | 2018-05-29 | 滕晓明 | A kind of mould inhibitor with traditional Chinese medicine ingredients |
| CN109845765A (en) * | 2019-01-15 | 2019-06-07 | 马金 | A kind of preparation method of bracketplant leaching liquid and nano-titanium dioxide composite sterilizer disinfection hydrojet |
| CN112625303A (en) * | 2020-12-16 | 2021-04-09 | 南京旭智材料科技有限公司 | Preparation method of antibacterial master batch |
| CN113729037A (en) * | 2021-09-28 | 2021-12-03 | 北京化工大学 | Plant fungus antibacterial agent, antibacterial film and preparation method thereof |
| CN114668023A (en) * | 2022-04-08 | 2022-06-28 | 广州暨明科技有限公司 | Natural antibacterial mildew preventive and macromolecular active antibacterial mildew-proof slow-release packaging film |
| CN115500444A (en) * | 2022-09-20 | 2022-12-23 | 广东省科学院微生物研究所(广东省微生物分析检测中心) | Formula of efficient mildew-proof compound essential oil as well as preparation method and application of efficient mildew-proof compound essential oil |
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Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104645395A (en) * | 2014-11-26 | 2015-05-27 | 彭科 | Plant-source deodorant for urban garbage disposal |
| CN107173396A (en) * | 2017-06-05 | 2017-09-19 | 冯新平 | A kind of nontoxic mildew resistant spraying agent and its preparation technology |
| CN107916566A (en) * | 2017-10-31 | 2018-04-17 | 苏州梅香雅筑工艺品有限公司 | A kind of preparation method of covering of the fan Mould-proof shell fabric |
| CN107722733B (en) * | 2017-11-07 | 2020-06-19 | 上海纳米技术及应用国家工程研究中心有限公司 | Antibacterial antifogging spray and preparation method and application thereof |
| CN107722733A (en) * | 2017-11-07 | 2018-02-23 | 上海纳米技术及应用国家工程研究中心有限公司 | Antibacterial antifogging spray and its preparation method and application |
| CN108077335A (en) * | 2017-12-06 | 2018-05-29 | 滕晓明 | A kind of mould inhibitor with traditional Chinese medicine ingredients |
| CN109845765A (en) * | 2019-01-15 | 2019-06-07 | 马金 | A kind of preparation method of bracketplant leaching liquid and nano-titanium dioxide composite sterilizer disinfection hydrojet |
| CN112625303A (en) * | 2020-12-16 | 2021-04-09 | 南京旭智材料科技有限公司 | Preparation method of antibacterial master batch |
| CN113729037A (en) * | 2021-09-28 | 2021-12-03 | 北京化工大学 | Plant fungus antibacterial agent, antibacterial film and preparation method thereof |
| CN113729037B (en) * | 2021-09-28 | 2022-07-05 | 北京化工大学 | Plant fungus antibacterial agent, antibacterial film and preparation method thereof |
| CN114668023A (en) * | 2022-04-08 | 2022-06-28 | 广州暨明科技有限公司 | Natural antibacterial mildew preventive and macromolecular active antibacterial mildew-proof slow-release packaging film |
| CN114668023B (en) * | 2022-04-08 | 2023-09-05 | 广州暨明科技有限公司 | Natural antibacterial mildew inhibitor and high-molecular active antibacterial mildew-proof slow-release packaging film |
| CN115500444A (en) * | 2022-09-20 | 2022-12-23 | 广东省科学院微生物研究所(广东省微生物分析检测中心) | Formula of efficient mildew-proof compound essential oil as well as preparation method and application of efficient mildew-proof compound essential oil |
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