CN102604288A - Formula of low-consumption modified polyvinylidene fluoride - Google Patents
Formula of low-consumption modified polyvinylidene fluoride Download PDFInfo
- Publication number
- CN102604288A CN102604288A CN2012100691354A CN201210069135A CN102604288A CN 102604288 A CN102604288 A CN 102604288A CN 2012100691354 A CN2012100691354 A CN 2012100691354A CN 201210069135 A CN201210069135 A CN 201210069135A CN 102604288 A CN102604288 A CN 102604288A
- Authority
- CN
- China
- Prior art keywords
- accounts
- modified polyvinilidene
- prescription
- low
- polyvinilidene difluoroethylene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002033 PVDF binder Substances 0.000 title abstract description 7
- 229920002981 polyvinylidene fluoride Polymers 0.000 title abstract description 7
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 14
- 239000007822 coupling agent Substances 0.000 claims abstract description 8
- WFLOTYSKFUPZQB-UHFFFAOYSA-N 1,2-difluoroethene Chemical group FC=CF WFLOTYSKFUPZQB-UHFFFAOYSA-N 0.000 claims description 27
- -1 nucleator Substances 0.000 claims description 12
- XTNRHLDLGNQMCW-UHFFFAOYSA-N acetic acid;1,1'-biphenyl Chemical group CC(O)=O.C1=CC=CC=C1C1=CC=CC=C1 XTNRHLDLGNQMCW-UHFFFAOYSA-N 0.000 claims description 9
- RZJRJXONCZWCBN-UHFFFAOYSA-N alpha-octadecene Natural products CCCCCCCCCCCCCCCCCC RZJRJXONCZWCBN-UHFFFAOYSA-N 0.000 claims description 9
- 229940038384 octadecane Drugs 0.000 claims description 9
- DTMHTVJOHYTUHE-UHFFFAOYSA-N thiocyanogen Chemical compound N#CSSC#N DTMHTVJOHYTUHE-UHFFFAOYSA-N 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000001737 promoting effect Effects 0.000 claims description 6
- 239000012190 activator Substances 0.000 abstract 2
- 239000002667 nucleating agent Substances 0.000 abstract 2
- WBJWXIQDBDZMAW-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carbonyl chloride Chemical compound C1=CC=CC2=C(C(Cl)=O)C(O)=CC=C21 WBJWXIQDBDZMAW-UHFFFAOYSA-N 0.000 abstract 1
- HKMVWLQFAYGKSI-UHFFFAOYSA-N 3-triethoxysilylpropyl thiocyanate Chemical compound CCO[Si](OCC)(OCC)CCCSC#N HKMVWLQFAYGKSI-UHFFFAOYSA-N 0.000 abstract 1
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 abstract 1
- PYHXGXCGESYPCW-UHFFFAOYSA-N alpha-phenylbenzeneacetic acid Natural products C=1C=CC=CC=1C(C(=O)O)C1=CC=CC=C1 PYHXGXCGESYPCW-UHFFFAOYSA-N 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 239000000463 material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000011161 development Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention discloses a formula of low-consumption modified polyvinylidene fluoride, which comprises modified polyvinylidene fluoride, anti-friction composition, nucleating agent, coupling agent, accelerator and activator, wherein the octadecyl amine serves as the anti-friction composition, diphenylacetic acid serves as the nucleating agent, thiocyanatopropyl triethoxysilane serves as the coupling agent, dibutylamine serves as the accelerator, and zinc stearate serves as the activator. The low-consumption modified polyvinylidene fluoride prepared by the formula has the advantages of small friction, low loss and low cost.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of low consumption modified polyvinilidene difluoroethylene.
Background technology
PVDF is a kind of fluorocarbon resin of novelty, has very high physical strength and wear resistance, and weathering resistance and thermostability have outstanding erosion resistance in addition, so the raw material that must use in chemical industry, any metal all can't substitute.PVDF again in Fluroplast-4 physical strength the highest.Along with the depth development of various industries, PVDF is extensively adopted, and has good piezoelectricity, radiation hardness, and thermostability is also fine, so extensively adopted by electron trade, X-former manufacturing.Also be used in fields such as aerospace, military field, sea water desaltination, metallurgy, electric wire, electric elements, machinofacture.
But, reach in the requirement of component of machinofacture of some special dimension, or some is insufficient.As everyone knows, steel is the necessary material of manufacturing machine, but the strong acid, alkali, salt, the polar solvent aspect that are used in chemical industry are obsolete., perplexing for a long time that the material of this respect is a kind of well not to be developed, some material can be used but processing difficulties, and can not use repeatedly, so in the deep-etching chemical industry, every year is all costly.All do not reach requirement in effectiveness, performance, work-ing life.The task of top priority must solve the exotic materials of research and development this respect, makes chemical industry obtain stablizing long-range development.
Summary of the invention
The object of the present invention is to provide a kind of prescription of the low consumption modified polyvinilidene difluoroethylene that rubs little, that loss is little, cost is low.
Technical scheme of the present invention is; A kind of prescription of low consumption modified polyvinilidene difluoroethylene comprises modified polyvinilidene difluoroethylene, anti-friction composition, nucleator, coupling agent, promotor and promoting agent, and described anti-friction composition is an octadecane amine; Nucleator is a phenylbenzene acetic acid; Coupling agent is the thiocyanogen propyl-triethoxysilicane, and promotor is di-n-butyl amine, and promoting agent is a Zinic stearas.
In preferred embodiment of the present invention; Each composition weight proportion of the prescription of said low consumption modified polyvinilidene difluoroethylene accounts for 77%-88% for the modified polyvinilidene difluoroethylene; Octadecane amine accounts for 3%-5%, and phenylbenzene acetic acid accounts for 2%-4%, and the thiocyanogen propyl-triethoxysilicane accounts for 2%-4%; Di-n-butyl amine accounts for 3%-6%, and Zinic stearas accounts for 2%-4%.
In preferred embodiment of the present invention; Each composition weight proportion of the prescription of said low consumption modified polyvinilidene difluoroethylene accounts for 68%-79% for the modified polyvinilidene difluoroethylene; Octadecane amine accounts for 5%-7%, and phenylbenzene acetic acid accounts for 6%-9%, and the thiocyanogen propyl-triethoxysilicane accounts for 4%-5%; Di-n-butyl amine accounts for 3%-5%, and Zinic stearas accounts for 3%-6%.
According to the invention is a kind of prescription of low consumption modified polyvinilidene difluoroethylene, makes the low consumption modified polyvinilidene difluoroethylene that makes have the effect that friction is little, loss is little, cost is low.
Embodiment
Set forth in detail in the face of preferred embodiment of the present invention down, thereby protection scope of the present invention is made more explicit defining so that advantage of the present invention and characteristic can be easier to it will be appreciated by those skilled in the art that.
According to the invention is a kind of prescription of low consumption modified polyvinilidene difluoroethylene; Comprise modified polyvinilidene difluoroethylene, anti-friction composition, nucleator, coupling agent, promotor and promoting agent; Described anti-friction composition is an octadecane amine, and nucleator is a phenylbenzene acetic acid, and coupling agent is the thiocyanogen propyl-triethoxysilicane; Promotor is di-n-butyl amine, and promoting agent is a Zinic stearas.
Further; Each composition weight proportion of the prescription of said low consumption modified polyvinilidene difluoroethylene accounts for 77%-88% for the modified polyvinilidene difluoroethylene; Octadecane amine accounts for 3%-5%, and phenylbenzene acetic acid accounts for 2%-4%, and the thiocyanogen propyl-triethoxysilicane accounts for 2%-4%; Di-n-butyl amine accounts for 3%-6%, and Zinic stearas accounts for 2%-4%.
Further; Each composition weight proportion of the prescription of said low consumption modified polyvinilidene difluoroethylene accounts for 68%-79% for the modified polyvinilidene difluoroethylene; Octadecane amine accounts for 5%-7%, and phenylbenzene acetic acid accounts for 6%-9%, and the thiocyanogen propyl-triethoxysilicane accounts for 4%-5%; Di-n-butyl amine accounts for 3%-5%, and Zinic stearas accounts for 3%-6%.
Can debug according to different ratios according to different demands, thereby reach different results of use.
According to the invention is a kind of prescription of low consumption modified polyvinilidene difluoroethylene, makes the low consumption modified polyvinilidene difluoroethylene that makes have the effect that friction is little, loss is little, cost is low.
The above is merely embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed; Variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the prescription of a low consumption modified polyvinilidene difluoroethylene; It is characterized in that: comprise modified polyvinilidene difluoroethylene, anti-friction composition, nucleator, coupling agent, promotor and promoting agent; Described anti-friction composition is an octadecane amine, and nucleator is a phenylbenzene acetic acid, and coupling agent is the thiocyanogen propyl-triethoxysilicane; Promotor is di-n-butyl amine, and promoting agent is a Zinic stearas.
2. the prescription of low consumption modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of the prescription of said low consumption modified polyvinilidene difluoroethylene accounts for 77%-88% for the modified polyvinilidene difluoroethylene; Octadecane amine accounts for 3%-5%, and phenylbenzene acetic acid accounts for 2%-4%, and the thiocyanogen propyl-triethoxysilicane accounts for 2%-4%; Di-n-butyl amine accounts for 3%-6%, and Zinic stearas accounts for 2%-4%.
3. the prescription of low consumption modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of the prescription of said low consumption modified polyvinilidene difluoroethylene accounts for 68%-79% for the modified polyvinilidene difluoroethylene; Octadecane amine accounts for 5%-7%, and phenylbenzene acetic acid accounts for 6%-9%, and the thiocyanogen propyl-triethoxysilicane accounts for 4%-5%; Di-n-butyl amine accounts for 3%-5%, and Zinic stearas accounts for 3%-6%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210069135.4A CN102604288B (en) | 2012-03-16 | 2012-03-16 | Formula of low-consumption modified polyvinylidene fluoride |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210069135.4A CN102604288B (en) | 2012-03-16 | 2012-03-16 | Formula of low-consumption modified polyvinylidene fluoride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102604288A true CN102604288A (en) | 2012-07-25 |
| CN102604288B CN102604288B (en) | 2014-05-28 |
Family
ID=46522092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210069135.4A Expired - Fee Related CN102604288B (en) | 2012-03-16 | 2012-03-16 | Formula of low-consumption modified polyvinylidene fluoride |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102604288B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5883197A (en) * | 1992-05-29 | 1999-03-16 | Ausimont S.P.A. | Compositions based on elastomeric polymers of vinylindene fluoride, hexafluoropropene and optionally tetrafluoroethylene, suitable for providing microcellular foamed articles |
| CN1794369A (en) * | 2005-12-30 | 2006-06-28 | 上海维安热电材料股份有限公司 | Manufacturing method of improved high temperature polymer PTC beat-sensitire resistor |
| WO2010126773A1 (en) * | 2009-05-01 | 2010-11-04 | Arkema Inc. | Foamed polyvinylidene fluoride structure |
-
2012
- 2012-03-16 CN CN201210069135.4A patent/CN102604288B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5883197A (en) * | 1992-05-29 | 1999-03-16 | Ausimont S.P.A. | Compositions based on elastomeric polymers of vinylindene fluoride, hexafluoropropene and optionally tetrafluoroethylene, suitable for providing microcellular foamed articles |
| CN1794369A (en) * | 2005-12-30 | 2006-06-28 | 上海维安热电材料股份有限公司 | Manufacturing method of improved high temperature polymer PTC beat-sensitire resistor |
| WO2010126773A1 (en) * | 2009-05-01 | 2010-11-04 | Arkema Inc. | Foamed polyvinylidene fluoride structure |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102604288B (en) | 2014-05-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5604010B2 (en) | Water-based paint for anti-corrosion treatment in marine climate and its production method | |
| CN102775691B (en) | Composite wire and cable sheath material | |
| CN102634407A (en) | Novel total-synthesis water-soluble magnesium alloy cutting solution and preparation method thereof | |
| CN102250677A (en) | High-performance environment-friendly magnetic material cutting fluid | |
| CN102585407A (en) | Formula of multifunctional modified polyvinylidene fluoride | |
| CN102603987B (en) | Formula of safe modified polyvinylidene fluoride | |
| CN102604288B (en) | Formula of low-consumption modified polyvinylidene fluoride | |
| CN103980576B (en) | Sea water conveying pipelines corrosion protective lining chloroprene rubber plate | |
| CN105483731A (en) | Steel structure surface rust removing agent | |
| CN105401096A (en) | High-hardness heat-resisting metal material | |
| CN102585410A (en) | Formula of ultraviolet-resistant modified polyvinylidene fluoride | |
| CN102604278A (en) | Formula of protective modified polyvinylidene fluoride | |
| CN102604284A (en) | Formula of wear-resisting modified polyvinylidene fluoride (PVDF) | |
| CN102604277A (en) | Formula of high-strength modified polyvinylidene fluoride | |
| CN102604285A (en) | Formula of high-physical-performance modified polyvinylidene fluoride | |
| CN102532760A (en) | Prescription of toughness-resistant modified polyvinylidene fluoride | |
| CN108505024A (en) | Chemical plating ni-sn-aluminium-phosphorus amorphous state multifunctional alloy plating solution and its coating | |
| CN102633947A (en) | Formula of physical-property polyvinylidene fluoride | |
| CN102634143A (en) | Formula of chemical performance polyvinylidene fluoride | |
| CN102585409A (en) | Prescription of light modified kynar | |
| CN102604283A (en) | Formula of novel modified polyvinylidene fluoride | |
| CN102604276A (en) | Formula of high-performance modified polyvinylidene fluoride (PVDF) | |
| CN102585408A (en) | Formula of lubricating modified polyvinylidene fluoride | |
| CN102604286A (en) | Formula of antioxidative modified polyvinylidene fluoride (PVDF) | |
| CN102634145A (en) | Formula of weather-proof polyvinylidene fluoride |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent of invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yang Guosheng Inventor after: Zhu Yingxu Inventor after: Lu Huaping Inventor before: Lu Huaping |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LU HUAPING TO: YANG GUOSHENG ZHU YINGXU LU HUAPING |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Ke Litian Inventor before: Yang Guosheng Inventor before: Zhu Yingxu Inventor before: Lu Huaping |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170405 Address after: 215300 Qingyang Road, Kunshan Development Zone, Jiangsu, No. 298 Patentee after: Bailigai (Kunshan) Co., Ltd. Address before: 215000 Songshan Road, Suzhou New District, Jiangsu, No. Patentee before: Suzhou New District Teflon Plastic Products Factory |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140528 Termination date: 20170316 |