CN102585410A - Formula of ultraviolet-resistant modified polyvinylidene fluoride - Google Patents
Formula of ultraviolet-resistant modified polyvinylidene fluoride Download PDFInfo
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- CN102585410A CN102585410A CN2012100641478A CN201210064147A CN102585410A CN 102585410 A CN102585410 A CN 102585410A CN 2012100641478 A CN2012100641478 A CN 2012100641478A CN 201210064147 A CN201210064147 A CN 201210064147A CN 102585410 A CN102585410 A CN 102585410A
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Abstract
The invention discloses a formula of ultraviolet-resistant modified polyvinylidene fluoride. The ultraviolet-resistant modified polyvinylidene fluoride comprises modified polyvinylidene fluoride, an anti-aging agent, an anti-static agent, a nucleating agent, a stabilizing agent and a wear resisting agent, wherein the anti-aging agent is octylated diphenylamine, the anti-static agent is alanine sodium, the nucleating agent is sodium parachlorobenzoate, the stabilizing agent is calcium stearate, and the wear resisting agent is dioleic acid phosphite ester. According to the invention, the prepared ultraviolet-resistant modified polyvinylidene fluoride is ultraviolet-resistant, aging-resistant, oxidation-resistant and anti-static.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of antiultraviolet modified polyvinilidene difluoroethylene.
Background technology
PVDF is a kind of fluorocarbon resin of novelty, has very high physical strength and wear resistance, and weathering resistance and thermostability have outstanding erosion resistance in addition, so the raw material that must use in chemical industry, any metal all can't substitute.PVDF again in Fluroplast-4 physical strength the highest.Along with the depth development of various industries, PVDF is extensively adopted, and has good piezoelectricity, radiation hardness, and thermostability is also fine, so extensively adopted by electron trade, X-former manufacturing.Also be used in fields such as aerospace, military field, sea water desaltination, metallurgy, electric wire, electric elements, machinofacture.
But, reach in the requirement of component of machinofacture of some special dimension, or some is insufficient.As everyone knows, steel is the necessary material of manufacturing machine, but the strong acid, alkali, salt, the polar solvent aspect that are used in chemical industry are obsolete., perplexing for a long time that the material of this respect is a kind of well not to be developed, some material can be used but processing difficulties, and can not use repeatedly, so in the deep-etching chemical industry, every year is all costly.All do not reach requirement in effectiveness, performance, work-ing life.The task of top priority must solve the exotic materials of research and development this respect, makes chemical industry obtain stablizing long-range development.
Summary of the invention
The object of the present invention is to provide the prescription of the antiultraviolet modified polyvinilidene difluoroethylene of a kind of Ginkgo Biloba Leaf Extract, anti-aging, anti-oxidant, anti-electrostatic.
Technical scheme of the present invention is; A kind of prescription of antiultraviolet modified polyvinilidene difluoroethylene comprises modified polyvinilidene difluoroethylene, anti-aging agent, static inhibitor, nucleator, stablizer and anti-friction composition, and described anti-aging agent is an octylated diphenylamine; Static inhibitor is a Beta Alanine sodium; Nucleator is a mikrobin, and stablizer is a calcium stearate, and anti-friction composition is two oleic acid phosphorous acid esters.
In preferred embodiment of the present invention; Each composition weight proportion of the prescription of said antiultraviolet modified polyvinilidene difluoroethylene accounts for 76%-84% for the modified polyvinilidene difluoroethylene; Octylated diphenylamine accounts for 5%-7%, and Beta Alanine sodium accounts for 4%-6%, and mikrobin accounts for 1%-3%; Calcium stearate accounts for 4%-5%, and two oleic acid phosphorous acid esters account for 2%-3%.
In preferred embodiment of the present invention; Each composition weight proportion of the prescription of said antiultraviolet modified polyvinilidene difluoroethylene accounts for 70%-78% for the modified polyvinilidene difluoroethylene; Octylated diphenylamine accounts for 6%-9%, and Beta Alanine sodium accounts for 5%-7%, and mikrobin accounts for 2%-3%; Calcium stearate accounts for 4%-5%, and two oleic acid phosphorous acid esters account for 5%-6%.
According to the invention is a kind of prescription of antiultraviolet modified polyvinilidene difluoroethylene, makes the antiultraviolet modified polyvinilidene difluoroethylene that makes have the effect of Ginkgo Biloba Leaf Extract, anti-aging, anti-oxidant, anti-electrostatic.
Embodiment
Set forth in detail in the face of preferred embodiment of the present invention down, thereby protection scope of the present invention is made more explicit defining so that advantage of the present invention and characteristic can be easier to it will be appreciated by those skilled in the art that.
According to the invention is a kind of prescription of antiultraviolet modified polyvinilidene difluoroethylene; Comprise modified polyvinilidene difluoroethylene, anti-aging agent, static inhibitor, nucleator, stablizer and anti-friction composition; Described anti-aging agent is an octylated diphenylamine, and static inhibitor is a Beta Alanine sodium, and nucleator is a mikrobin; Stablizer is a calcium stearate, and anti-friction composition is two oleic acid phosphorous acid esters.
Further; Each composition weight proportion of the prescription of said antiultraviolet modified polyvinilidene difluoroethylene accounts for 76%-84% for the modified polyvinilidene difluoroethylene; Octylated diphenylamine accounts for 5%-7%, and Beta Alanine sodium accounts for 4%-6%, and mikrobin accounts for 1%-3%; Calcium stearate accounts for 4%-5%, and two oleic acid phosphorous acid esters account for 2%-3%.
Further; Each composition weight proportion of the prescription of said antiultraviolet modified polyvinilidene difluoroethylene accounts for 70%-78% for the modified polyvinilidene difluoroethylene; Octylated diphenylamine accounts for 6%-9%, and Beta Alanine sodium accounts for 5%-7%, and mikrobin accounts for 2%-3%; Calcium stearate accounts for 4%-5%, and two oleic acid phosphorous acid esters account for 5%-6%.
Can debug according to different ratios according to different demands, thereby reach different results of use.
According to the invention is a kind of prescription of antiultraviolet modified polyvinilidene difluoroethylene, makes the antiultraviolet modified polyvinilidene difluoroethylene that makes have the effect of Ginkgo Biloba Leaf Extract, anti-aging, anti-oxidant, anti-electrostatic.
The above is merely embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed; Variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. the prescription of an antiultraviolet modified polyvinilidene difluoroethylene; It is characterized in that: comprise modified polyvinilidene difluoroethylene, anti-aging agent, static inhibitor, nucleator, stablizer and anti-friction composition; Described anti-aging agent is an octylated diphenylamine, and static inhibitor is a Beta Alanine sodium, and nucleator is a mikrobin; Stablizer is a calcium stearate, and anti-friction composition is two oleic acid phosphorous acid esters.
2. the prescription of antiultraviolet modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of the prescription of said antiultraviolet modified polyvinilidene difluoroethylene accounts for 76%-84% for the modified polyvinilidene difluoroethylene; Octylated diphenylamine accounts for 5%-7%, and Beta Alanine sodium accounts for 4%-6%, and mikrobin accounts for 1%-3%; Calcium stearate accounts for 4%-5%, and two oleic acid phosphorous acid esters account for 2%-3%.
3. the prescription of antiultraviolet modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of the prescription of said antiultraviolet modified polyvinilidene difluoroethylene accounts for 70%-78% for the modified polyvinilidene difluoroethylene; Octylated diphenylamine accounts for 6%-9%, and Beta Alanine sodium accounts for 5%-7%, and mikrobin accounts for 2%-3%; Calcium stearate accounts for 4%-5%, and two oleic acid phosphorous acid esters account for 5%-6%.
Priority Applications (1)
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CN2012100641478A CN102585410A (en) | 2012-03-13 | 2012-03-13 | Formula of ultraviolet-resistant modified polyvinylidene fluoride |
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CN2012100641478A CN102585410A (en) | 2012-03-13 | 2012-03-13 | Formula of ultraviolet-resistant modified polyvinylidene fluoride |
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CN102585410A true CN102585410A (en) | 2012-07-18 |
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CN2012100641478A Pending CN102585410A (en) | 2012-03-13 | 2012-03-13 | Formula of ultraviolet-resistant modified polyvinylidene fluoride |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109135166A (en) * | 2017-06-16 | 2019-01-04 | 合肥杰事杰新材料股份有限公司 | A kind of nylon composite material and preparation method thereof |
CN109135165A (en) * | 2017-06-16 | 2019-01-04 | 合肥杰事杰新材料股份有限公司 | A kind of permanent antistatic polyoxymethylene composition material and preparation method thereof |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5883197A (en) * | 1992-05-29 | 1999-03-16 | Ausimont S.P.A. | Compositions based on elastomeric polymers of vinylindene fluoride, hexafluoropropene and optionally tetrafluoroethylene, suitable for providing microcellular foamed articles |
CN1794369A (en) * | 2005-12-30 | 2006-06-28 | 上海维安热电材料股份有限公司 | Manufacturing method of improved high temperature polymer PTC beat-sensitire resistor |
WO2010126773A1 (en) * | 2009-05-01 | 2010-11-04 | Arkema Inc. | Foamed polyvinylidene fluoride structure |
-
2012
- 2012-03-13 CN CN2012100641478A patent/CN102585410A/en active Pending
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5883197A (en) * | 1992-05-29 | 1999-03-16 | Ausimont S.P.A. | Compositions based on elastomeric polymers of vinylindene fluoride, hexafluoropropene and optionally tetrafluoroethylene, suitable for providing microcellular foamed articles |
CN1794369A (en) * | 2005-12-30 | 2006-06-28 | 上海维安热电材料股份有限公司 | Manufacturing method of improved high temperature polymer PTC beat-sensitire resistor |
WO2010126773A1 (en) * | 2009-05-01 | 2010-11-04 | Arkema Inc. | Foamed polyvinylidene fluoride structure |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109135166A (en) * | 2017-06-16 | 2019-01-04 | 合肥杰事杰新材料股份有限公司 | A kind of nylon composite material and preparation method thereof |
CN109135165A (en) * | 2017-06-16 | 2019-01-04 | 合肥杰事杰新材料股份有限公司 | A kind of permanent antistatic polyoxymethylene composition material and preparation method thereof |
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Application publication date: 20120718 |