CN102604288B - Formula of low-consumption modified polyvinylidene fluoride - Google Patents
Formula of low-consumption modified polyvinylidene fluoride Download PDFInfo
- Publication number
- CN102604288B CN102604288B CN201210069135.4A CN201210069135A CN102604288B CN 102604288 B CN102604288 B CN 102604288B CN 201210069135 A CN201210069135 A CN 201210069135A CN 102604288 B CN102604288 B CN 102604288B
- Authority
- CN
- China
- Prior art keywords
- polyvinylidene fluoride
- accounts
- modified polyvinylidene
- formula
- low
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920002981 polyvinylidene fluoride Polymers 0.000 title claims abstract description 34
- 239000002033 PVDF binder Substances 0.000 title claims abstract description 31
- JQVDAXLFBXTEQA-UHFFFAOYSA-N dibutylamine Chemical compound CCCCNCCCC JQVDAXLFBXTEQA-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000203 mixture Substances 0.000 claims abstract description 14
- HKMVWLQFAYGKSI-UHFFFAOYSA-N 3-triethoxysilylpropyl thiocyanate Chemical compound CCO[Si](OCC)(OCC)CCCSC#N HKMVWLQFAYGKSI-UHFFFAOYSA-N 0.000 claims abstract description 10
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000007822 coupling agent Substances 0.000 claims abstract description 8
- XTNRHLDLGNQMCW-UHFFFAOYSA-N acetic acid;1,1'-biphenyl Chemical group CC(O)=O.C1=CC=CC=C1C1=CC=CC=C1 XTNRHLDLGNQMCW-UHFFFAOYSA-N 0.000 claims description 9
- -1 nucleator Substances 0.000 claims description 9
- 239000003795 chemical substances by application Substances 0.000 claims description 6
- 230000001737 promoting effect Effects 0.000 claims description 6
- 239000012190 activator Substances 0.000 abstract 2
- 239000002667 nucleating agent Substances 0.000 abstract 2
- WBJWXIQDBDZMAW-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carbonyl chloride Chemical compound C1=CC=CC2=C(C(Cl)=O)C(O)=CC=C21 WBJWXIQDBDZMAW-UHFFFAOYSA-N 0.000 abstract 1
- PYHXGXCGESYPCW-UHFFFAOYSA-N alpha-phenylbenzeneacetic acid Natural products C=1C=CC=CC=1C(C(=O)O)C1=CC=CC=C1 PYHXGXCGESYPCW-UHFFFAOYSA-N 0.000 abstract 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract 1
- 239000000463 material Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 3
- 238000011161 development Methods 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 description 1
- 229920002313 fluoropolymer Polymers 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention discloses a formula of low-consumption modified polyvinylidene fluoride, which comprises modified polyvinylidene fluoride, anti-friction composition, nucleating agent, coupling agent, accelerator and activator, wherein the octadecyl amine serves as the anti-friction composition, diphenylacetic acid serves as the nucleating agent, thiocyanatopropyl triethoxysilane serves as the coupling agent, dibutylamine serves as the accelerator, and zinc stearate serves as the activator. The low-consumption modified polyvinylidene fluoride prepared by the formula has the advantages of small friction, low loss and low cost.
Description
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of formula of low consumption modified polyvinylidene fluoride.
Background technology
Poly(vinylidene fluoride) is a kind of fluorocarbon resin of novelty, has very high physical strength and wear resistance, and weathering resistance and thermostability have outstanding erosion resistance in addition, so the raw material that must use in chemical industry, any metal all cannot substitute.Poly(vinylidene fluoride) again in fluoroplastics physical strength the highest.Along with the depth development of various industries, poly(vinylidene fluoride) is widely adopted, and has good piezoelectricity, radiation hardness, and thermostability is also fine, so extensively adopted by electron trade, transformer manufacture.Also be used in the fields such as aerospace, military field, sea water desaltination, metallurgy, electric wire, electric elements, machinofacture.
But, reach in the requirement of component of the machinofacture of some special dimension, or some deficiency.As everyone knows, steel is the necessary material of manufacturing machine, but the strong acid, alkali, salt, the polar solvent aspect that are used in chemical industry are obsolete., perplexing for a long time the material one of this respect and well do not developed, some material can with but processing difficulties, and can not Reusability, thus in deep-etching chemical industry, all costly every year.All do not reach requirement in effect, performance, work-ing life.The task of top priority must solve the exotic materials of research and development this respect, makes chemical industry obtain stablizing long-range development.
Summary of the invention
The object of the present invention is to provide a kind of formula of the low consumption modified polyvinylidene fluoride little, loss is little, cost is low that rubs.
Technical scheme of the present invention is, a kind of formula of low consumption modified polyvinylidene fluoride, comprise modified polyvinylidene fluoride, anti-friction composition, nucleator, coupling agent, promotor and promoting agent, described anti-friction composition is octadecylamine, nucleator is phenylbenzene acetic acid, coupling agent is thiocyanatopropyltriethoxysilane, and promotor is di-n-butyl amine, and promoting agent is Zinic stearas.
In a preferred embodiment of the present invention, the each composition weight proportion of formula of described low consumption modified polyvinylidene fluoride is that modified polyvinylidene fluoride accounts for 77%-88%, octadecylamine accounts for 3%-5%, phenylbenzene acetic acid accounts for 2%-4%, thiocyanatopropyltriethoxysilane accounts for 2%-4%, di-n-butyl amine accounts for 3%-6%, and Zinic stearas accounts for 2%-4%.
In a preferred embodiment of the present invention, the each composition weight proportion of formula of described low consumption modified polyvinylidene fluoride is that modified polyvinylidene fluoride accounts for 68%-79%, octadecylamine accounts for 5%-7%, phenylbenzene acetic acid accounts for 6%-9%, thiocyanatopropyltriethoxysilane accounts for 4%-5%, di-n-butyl amine accounts for 3%-5%, and Zinic stearas accounts for 3%-6%.
Of the present invention is a kind of formula of low consumption modified polyvinylidene fluoride, makes the low consumption modified polyvinylidene fluoride making have the effect that friction is little, loss is little, cost is low.
Embodiment
Below preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
Of the present invention is a kind of formula of low consumption modified polyvinylidene fluoride, comprise modified polyvinylidene fluoride, anti-friction composition, nucleator, coupling agent, promotor and promoting agent, described anti-friction composition is octadecylamine, nucleator is phenylbenzene acetic acid, coupling agent is thiocyanatopropyltriethoxysilane, promotor is di-n-butyl amine, and promoting agent is Zinic stearas.
Further, the each composition weight proportion of formula of described low consumption modified polyvinylidene fluoride is that modified polyvinylidene fluoride accounts for 77%-88%, octadecylamine accounts for 3%-5%, phenylbenzene acetic acid accounts for 2%-4%, thiocyanatopropyltriethoxysilane accounts for 2%-4%, di-n-butyl amine accounts for 3%-6%, and Zinic stearas accounts for 2%-4%.
Further, the each composition weight proportion of formula of described low consumption modified polyvinylidene fluoride is that modified polyvinylidene fluoride accounts for 68%-79%, octadecylamine accounts for 5%-7%, phenylbenzene acetic acid accounts for 6%-9%, thiocyanatopropyltriethoxysilane accounts for 4%-5%, di-n-butyl amine accounts for 3%-5%, and Zinic stearas accounts for 3%-6%.
Can debug according to different ratios according to different demands, thereby reach different results of use.
Of the present invention is a kind of formula of low consumption modified polyvinylidene fluoride, makes the low consumption modified polyvinylidene fluoride making have the effect that friction is little, loss is little, cost is low.
The foregoing is only the specific embodiment of the present invention; but protection scope of the present invention is not limited to this; any those of ordinary skill in the art are in the disclosed technical scope of the present invention; the variation that can expect without creative work or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.
Claims (3)
1. a low consumption modified polyvinylidene fluoride, it is characterized in that: comprise modified polyvinylidene fluoride, anti-friction composition, nucleator, coupling agent, promotor and promoting agent, described anti-friction composition is octadecylamine, nucleator is phenylbenzene acetic acid, coupling agent is thiocyanatopropyltriethoxysilane, promotor is di-n-butyl amine, and promoting agent is Zinic stearas.
2. low consumption modified polyvinylidene fluoride according to claim 1, it is characterized in that: the each composition weight proportion of described low consumption modified polyvinylidene fluoride is that modified polyvinylidene fluoride accounts for 77%-88%, octadecylamine accounts for 3%-5%, phenylbenzene acetic acid accounts for 2%-4%, thiocyanatopropyltriethoxysilane accounts for 2%-4%, di-n-butyl amine accounts for 3%-6%, and Zinic stearas accounts for 2%-4%.
3. low consumption modified polyvinylidene fluoride according to claim 1, it is characterized in that: the each composition weight proportion of described low consumption modified polyvinylidene fluoride is that modified polyvinylidene fluoride accounts for 68%-79%, octadecylamine accounts for 5%-7%, phenylbenzene acetic acid accounts for 6%-9%, thiocyanatopropyltriethoxysilane accounts for 4%-5%, di-n-butyl amine accounts for 3%-5%, and Zinic stearas accounts for 3%-6%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210069135.4A CN102604288B (en) | 2012-03-16 | 2012-03-16 | Formula of low-consumption modified polyvinylidene fluoride |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210069135.4A CN102604288B (en) | 2012-03-16 | 2012-03-16 | Formula of low-consumption modified polyvinylidene fluoride |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102604288A CN102604288A (en) | 2012-07-25 |
| CN102604288B true CN102604288B (en) | 2014-05-28 |
Family
ID=46522092
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210069135.4A Expired - Fee Related CN102604288B (en) | 2012-03-16 | 2012-03-16 | Formula of low-consumption modified polyvinylidene fluoride |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102604288B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5883197A (en) * | 1992-05-29 | 1999-03-16 | Ausimont S.P.A. | Compositions based on elastomeric polymers of vinylindene fluoride, hexafluoropropene and optionally tetrafluoroethylene, suitable for providing microcellular foamed articles |
| CN1794369A (en) * | 2005-12-30 | 2006-06-28 | 上海维安热电材料股份有限公司 | Manufacturing method of improved high temperature polymer PTC beat-sensitire resistor |
| WO2010126773A1 (en) * | 2009-05-01 | 2010-11-04 | Arkema Inc. | Foamed polyvinylidene fluoride structure |
-
2012
- 2012-03-16 CN CN201210069135.4A patent/CN102604288B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5883197A (en) * | 1992-05-29 | 1999-03-16 | Ausimont S.P.A. | Compositions based on elastomeric polymers of vinylindene fluoride, hexafluoropropene and optionally tetrafluoroethylene, suitable for providing microcellular foamed articles |
| CN1794369A (en) * | 2005-12-30 | 2006-06-28 | 上海维安热电材料股份有限公司 | Manufacturing method of improved high temperature polymer PTC beat-sensitire resistor |
| WO2010126773A1 (en) * | 2009-05-01 | 2010-11-04 | Arkema Inc. | Foamed polyvinylidene fluoride structure |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102604288A (en) | 2012-07-25 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102775691B (en) | Composite wire and cable sheath material | |
| CN105256318A (en) | Novel imidazoline compound corrosion inhibitor and preparation method thereof | |
| Avdeev | Protection of metals in phosphoric acid solutions by corrosion inhibitors. A review | |
| CN102603987B (en) | Formula of safe modified polyvinylidene fluoride | |
| CN102585407A (en) | Formula of multifunctional modified polyvinylidene fluoride | |
| CN102604288B (en) | Formula of low-consumption modified polyvinylidene fluoride | |
| CN105131454A (en) | PVC building material | |
| Verma et al. | Polyvinyl alcohol (PVA) as a biodegradable polymeric anticorrosive material: A review on present advancements and future directions | |
| CN105401096A (en) | High-hardness heat-resisting metal material | |
| CN102604278A (en) | Formula of protective modified polyvinylidene fluoride | |
| CN102585410A (en) | Formula of ultraviolet-resistant modified polyvinylidene fluoride | |
| CN107217268B (en) | Chlorination containing 2-, the corrosion inhibiter of the poly- hydroxypropyl isopropylamine quaternary surfactant of 3- | |
| CN108505024A (en) | Chemical plating ni-sn-aluminium-phosphorus amorphous state multifunctional alloy plating solution and its coating | |
| CN102604277A (en) | Formula of high-strength modified polyvinylidene fluoride | |
| CN102604284A (en) | Formula of wear-resisting modified polyvinylidene fluoride (PVDF) | |
| CN102604285A (en) | Formula of high-physical-performance modified polyvinylidene fluoride | |
| CN102585409A (en) | Prescription of light modified kynar | |
| CN102604276A (en) | Formula of high-performance modified polyvinylidene fluoride (PVDF) | |
| CN102532760A (en) | Prescription of toughness-resistant modified polyvinylidene fluoride | |
| CN112830701A (en) | Environment-friendly composite steel bar rust inhibitor for marine environment and preparation method thereof | |
| CN102604283A (en) | Formula of novel modified polyvinylidene fluoride | |
| CN102585408A (en) | Formula of lubricating modified polyvinylidene fluoride | |
| CN102634152B (en) | Formula of anti-coking polyvinylidene fluoride | |
| CN102604286A (en) | Formula of antioxidative modified polyvinylidene fluoride (PVDF) | |
| CN102604279A (en) | Formula of pressure-resistant modified polyvinylidene fluoride |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C53 | Correction of patent for invention or patent application | ||
| CB03 | Change of inventor or designer information |
Inventor after: Yang Guosheng Inventor after: Zhu Yingxu Inventor after: Lu Huaping Inventor before: Lu Huaping |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: LU HUAPING TO: YANG GUOSHENG ZHU YINGXU LU HUAPING |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Ke Litian Inventor before: Yang Guosheng Inventor before: Zhu Yingxu Inventor before: Lu Huaping |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170405 Address after: 215300 Qingyang Road, Kunshan Development Zone, Jiangsu, No. 298 Patentee after: Bailigai (Kunshan) Co., Ltd. Address before: 215000 Songshan Road, Suzhou New District, Jiangsu, No. Patentee before: Suzhou New District Teflon Plastic Products Factory |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20140528 Termination date: 20170316 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |