CN102604286A - Formula of antioxidative modified polyvinylidene fluoride (PVDF) - Google Patents

Formula of antioxidative modified polyvinylidene fluoride (PVDF) Download PDF

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Publication number
CN102604286A
CN102604286A CN2012100641529A CN201210064152A CN102604286A CN 102604286 A CN102604286 A CN 102604286A CN 2012100641529 A CN2012100641529 A CN 2012100641529A CN 201210064152 A CN201210064152 A CN 201210064152A CN 102604286 A CN102604286 A CN 102604286A
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CN
China
Prior art keywords
accounts
modified polyvinilidene
prescription
polyvinilidene difluoroethylene
oxidant
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Pending
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CN2012100641529A
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Chinese (zh)
Inventor
陆华平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou New District Teflon Plastic Products Factory
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Suzhou New District Teflon Plastic Products Factory
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Application filed by Suzhou New District Teflon Plastic Products Factory filed Critical Suzhou New District Teflon Plastic Products Factory
Priority to CN2012100641529A priority Critical patent/CN102604286A/en
Publication of CN102604286A publication Critical patent/CN102604286A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a formula of antioxidative modified polyvinylidene fluoride (PVDF). The formula comprises PDVF, an antioxidant, a heat stabilizer, an anti-scorching agent and an anti-aging agent, wherein dibutyl hydroxyl toluene is used as the antioxidant, dibasic lead phthalate is used as the heat stabilizer, trichloromelamine is used as the anti-scorching agent, and styrenated phenol is used as the anti-aging agent. Therefore, the prepared antioxidative modified PVDF has the effects of antioxidation, anti-aging and anti-scorching performances and stable property.

Description

A kind of prescription of anti-oxidant modified polyvinilidene difluoroethylene
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription of anti-oxidant modified polyvinilidene difluoroethylene.
Background technology
PVDF is a kind of fluorocarbon resin of novelty, has very high physical strength and wear resistance, and weathering resistance and thermostability have outstanding erosion resistance in addition, so the raw material that must use in chemical industry, any metal all can't substitute.PVDF again in Fluroplast-4 physical strength the highest.Along with the depth development of various industries, PVDF is extensively adopted, and has good piezoelectricity, radiation hardness, and thermostability is also fine, so extensively adopted by electron trade, X-former manufacturing.Also be used in fields such as aerospace, military field, sea water desaltination, metallurgy, electric wire, electric elements, machinofacture.
But, reach in the requirement of component of machinofacture of some special dimension, or some is insufficient.As everyone knows, steel is the necessary material of manufacturing machine, but the strong acid, alkali, salt, the polar solvent aspect that are used in chemical industry are obsolete., perplexing for a long time that the material of this respect is a kind of well not to be developed, some material can be used but processing difficulties, and can not use repeatedly, so in the deep-etching chemical industry, every year is all costly.All do not reach requirement in effectiveness, performance, work-ing life.The task of top priority must solve the exotic materials of research and development this respect, makes chemical industry obtain stablizing long-range development.
Summary of the invention
The object of the present invention is to provide the prescription of the anti-oxidant modified polyvinilidene difluoroethylene of a kind of anti-oxidant, anti-aging, anti-scorch, stable performance.
Technical scheme of the present invention is; A kind of prescription of anti-oxidant modified polyvinilidene difluoroethylene; Comprise modified polyvinilidene difluoroethylene, inhibitor, thermo-stabilizer, scorch retarder and anti-aging agent, described inhibitor is a butylated hydroxytoluene, and described thermo-stabilizer is a Dythal; Described scorch retarder is three filter trimeric cyanamides, and described anti-aging agent is a styrenated phenol.
In preferred embodiment of the present invention; Each composition weight proportion of the prescription of said anti-oxidant modified polyvinilidene difluoroethylene accounts for 65%-70% for the modified polyvinilidene difluoroethylene; Butylated hydroxytoluene accounts for 8%-9%; Dythal accounts for 7%-8%, and three filter trimeric cyanamides account for 7%-9%, and styrenated phenol accounts for 8%-9%.
In preferred embodiment of the present invention; Each composition weight proportion of the prescription of said anti-oxidant modified polyvinilidene difluoroethylene accounts for 65%-75% for the modified polyvinilidene difluoroethylene; Styrene butadiene thermoplasticelastomer accounts for 6%-10%; DOP accounts for 6%-7%, and polyoxyethylene glycol accounts for 5%-8%, and the ultra abrasion resistant carbon black of high structure accounts for 8%-10%.
According to the invention is a kind of prescription of anti-oxidant modified polyvinilidene difluoroethylene, makes the anti-oxidant modified polyvinilidene difluoroethylene that makes have the effect of anti-oxidant, anti-aging, anti-scorch, stable performance.
Embodiment
Set forth in detail in the face of preferred embodiment of the present invention down, thereby protection scope of the present invention is made more explicit defining so that advantage of the present invention and characteristic can be easier to it will be appreciated by those skilled in the art that.
According to the invention is a kind of prescription of anti-oxidant modified polyvinilidene difluoroethylene; Comprise modified polyvinilidene difluoroethylene, inhibitor, thermo-stabilizer, scorch retarder and anti-aging agent; Described inhibitor is a butylated hydroxytoluene; Described thermo-stabilizer is a Dythal, and described scorch retarder is three filter trimeric cyanamides, and described anti-aging agent is a styrenated phenol.
Further; Each composition weight proportion of the prescription of said anti-oxidant modified polyvinilidene difluoroethylene accounts for 65%-70% for the modified polyvinilidene difluoroethylene, and butylated hydroxytoluene accounts for 8%-9%, and Dythal accounts for 7%-8%; Three filter trimeric cyanamides account for 7%-9%, and styrenated phenol accounts for 8%-9%.
Further; Each composition weight proportion of the prescription of anti-oxidant modified polyvinilidene difluoroethylene accounts for 65%-75% for the modified polyvinilidene difluoroethylene, and styrene butadiene thermoplasticelastomer accounts for 6%-10%, and DOP accounts for 6%-7%; Polyoxyethylene glycol accounts for 5%-8%, and the ultra abrasion resistant carbon black of high structure accounts for 8%-10%.
Can debug according to different ratios according to different demands, thereby reach different results of use.
According to the invention is a kind of prescription of anti-oxidant modified polyvinilidene difluoroethylene, makes the anti-oxidant modified polyvinilidene difluoroethylene that makes have the effect of anti-oxidant, anti-aging, anti-scorch, stable performance.
The above is merely embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed; Variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.

Claims (3)

1. the prescription of an anti-oxidant modified polyvinilidene difluoroethylene; It is characterized in that: comprise modified polyvinilidene difluoroethylene, inhibitor, thermo-stabilizer, scorch retarder and anti-aging agent; Described inhibitor is a butylated hydroxytoluene; Described thermo-stabilizer is a Dythal, and described scorch retarder is three filter trimeric cyanamides, and described anti-aging agent is a styrenated phenol.
2. the prescription of anti-oxidant modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of the prescription of said anti-oxidant modified polyvinilidene difluoroethylene accounts for 65%-70% for the modified polyvinilidene difluoroethylene; Butylated hydroxytoluene accounts for 8%-9%; Dythal accounts for 7%-8%, and three filter trimeric cyanamides account for 7%-9%, and styrenated phenol accounts for 8%-9%.
3. the prescription of anti-oxidant modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of the prescription of said anti-oxidant modified polyvinilidene difluoroethylene accounts for 65%-75% for the modified polyvinilidene difluoroethylene; Styrene butadiene thermoplasticelastomer accounts for 6%-10%; DOP accounts for 6%-7%, and polyoxyethylene glycol accounts for 5%-8%, and the ultra abrasion resistant carbon black of high structure accounts for 8%-10%.
CN2012100641529A 2012-03-13 2012-03-13 Formula of antioxidative modified polyvinylidene fluoride (PVDF) Pending CN102604286A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2012100641529A CN102604286A (en) 2012-03-13 2012-03-13 Formula of antioxidative modified polyvinylidene fluoride (PVDF)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2012100641529A CN102604286A (en) 2012-03-13 2012-03-13 Formula of antioxidative modified polyvinylidene fluoride (PVDF)

Publications (1)

Publication Number Publication Date
CN102604286A true CN102604286A (en) 2012-07-25

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Family Applications (1)

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CN2012100641529A Pending CN102604286A (en) 2012-03-13 2012-03-13 Formula of antioxidative modified polyvinylidene fluoride (PVDF)

Country Status (1)

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CN (1) CN102604286A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106009223A (en) * 2016-07-11 2016-10-12 苏州泰尚新材料有限公司 High-temperature-resistant cable sheath and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106009223A (en) * 2016-07-11 2016-10-12 苏州泰尚新材料有限公司 High-temperature-resistant cable sheath and preparation method thereof

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Application publication date: 20120725