CN102604278A - Formula of protective modified polyvinylidene fluoride - Google Patents

Formula of protective modified polyvinylidene fluoride Download PDF

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Publication number
CN102604278A
CN102604278A CN201210064150XA CN201210064150A CN102604278A CN 102604278 A CN102604278 A CN 102604278A CN 201210064150X A CN201210064150X A CN 201210064150XA CN 201210064150 A CN201210064150 A CN 201210064150A CN 102604278 A CN102604278 A CN 102604278A
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CN
China
Prior art keywords
accounts
modified polyvinilidene
prescription
polyvinilidene difluoroethylene
difluoroethylene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201210064150XA
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Chinese (zh)
Inventor
陆华平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou New District Teflon Plastic Products Factory
Original Assignee
Suzhou New District Teflon Plastic Products Factory
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou New District Teflon Plastic Products Factory filed Critical Suzhou New District Teflon Plastic Products Factory
Priority to CN201210064150XA priority Critical patent/CN102604278A/en
Publication of CN102604278A publication Critical patent/CN102604278A/en
Pending legal-status Critical Current

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  • Organic Insulating Materials (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

The invention discloses a formula of protective modified polyvinylidene fluoride, which comprises modified polyvinylidene fluoride, stabilizer, anti-static agent, promoter and antiager, wherein the stabilizer is dibasic lead stearate, the anti-static agent is stearic acid polyoxyethylene ester, the promoter is hexamine, and the antiager is poly carbodiimide. The protective modified polyvinylidene fluoride prepared by the formula has the advantages of compact texture, ageing resistance and electrostatic resistance.

Description

A kind of prescription that protects the modified polyvinilidene difluoroethylene
Technical field
The present invention relates to a kind of plastic formula, be specifically related to a kind of prescription that protects the modified polyvinilidene difluoroethylene.
Background technology
PVDF is a kind of fluorocarbon resin of novelty, has very high physical strength and wear resistance, and weathering resistance and thermostability have outstanding erosion resistance in addition, so the raw material that must use in chemical industry, any metal all can't substitute.PVDF again in Fluroplast-4 physical strength the highest.Along with the depth development of various industries, PVDF is extensively adopted, and has good piezoelectricity, radiation hardness, and thermostability is also fine, so extensively adopted by electron trade, X-former manufacturing.Also be used in fields such as aerospace, military field, sea water desaltination, metallurgy, electric wire, electric elements, machinofacture.
But, reach in the requirement of component of machinofacture of some special dimension, or some is insufficient.As everyone knows, steel is the necessary material of manufacturing machine, but the strong acid, alkali, salt, the polar solvent aspect that are used in chemical industry are obsolete., perplexing for a long time that the material of this respect is a kind of well not to be developed, some material can be used but processing difficulties, and can not use repeatedly, so in the deep-etching chemical industry, every year is all costly.All do not reach requirement in effectiveness, performance, work-ing life.The task of top priority must solve the exotic materials of research and development this respect, makes chemical industry obtain stablizing long-range development.
Summary of the invention
The object of the present invention is to provide the prescription of tight, anti-aging, the anlistatig protection modified polyvinilidene of a kind of quality difluoroethylene.
Technical scheme of the present invention is; A kind of prescription that protects the modified polyvinilidene difluoroethylene; Comprise modified polyvinilidene difluoroethylene, stablizer, static inhibitor, promotor and protective agent, described stablizer is a dibasic lead stearate, and static inhibitor is a Triple Pressed Stearic Acid polyoxyethylene ester; Promotor is vulkacit H, and protective agent is a polycarbodiimide.
In preferred embodiment of the present invention; Each composition weight proportion of the prescription of said protection modified polyvinilidene difluoroethylene accounts for 80%-90% for the modified polyvinilidene difluoroethylene; Dibasic lead stearate accounts for 2%-4%; Triple Pressed Stearic Acid polyoxyethylene ester accounts for 3%-5%, and vulkacit H accounts for 1%-2%, and polycarbodiimide accounts for 4%-9%.
In preferred embodiment of the present invention; Each composition weight proportion of the prescription of said protection modified polyvinilidene difluoroethylene accounts for 75%-85% for the modified polyvinilidene difluoroethylene; Dibasic lead stearate accounts for 4%-5%; Triple Pressed Stearic Acid polyoxyethylene ester accounts for 4%-7%, and vulkacit H accounts for 2%-5%, and polycarbodiimide accounts for 5%-8%.
According to the invention is a kind of prescription that protects the modified polyvinilidene difluoroethylene, makes the protection modified polyvinilidene difluoroethylene that makes have tight, anti-aging, the anlistatig effect of quality.
Embodiment
Set forth in detail in the face of preferred embodiment of the present invention down, thereby protection scope of the present invention is made more explicit defining so that advantage of the present invention and characteristic can be easier to it will be appreciated by those skilled in the art that.
According to the invention is a kind of prescription that protects the modified polyvinilidene difluoroethylene; Comprise modified polyvinilidene difluoroethylene, stablizer, static inhibitor, promotor and protective agent; Stablizer is a dibasic lead stearate; Static inhibitor is a Triple Pressed Stearic Acid polyoxyethylene ester, and promotor is vulkacit H, and protective agent is a polycarbodiimide.
Further; Each composition weight proportion of prescription of protection modified polyvinilidene difluoroethylene accounts for 80%-90% for the modified polyvinilidene difluoroethylene, and dibasic lead stearate accounts for 2%-4%, and Triple Pressed Stearic Acid polyoxyethylene ester accounts for 3%-5%; Vulkacit H accounts for 1%-2%, and polycarbodiimide accounts for 4%-9%.
Further; Each composition weight proportion of prescription of protection modified polyvinilidene difluoroethylene accounts for 75%-85% for the modified polyvinilidene difluoroethylene, and dibasic lead stearate accounts for 4%-5%, and Triple Pressed Stearic Acid polyoxyethylene ester accounts for 4%-7%; Vulkacit H accounts for 2%-5%, and polycarbodiimide accounts for 5%-8%.
Can debug according to different ratios according to different demands, thereby reach different results of use.
According to the invention is a kind of prescription that protects the modified polyvinilidene difluoroethylene, makes the protection modified polyvinilidene difluoroethylene that makes have tight, anti-aging, the anlistatig effect of quality.
The above is merely embodiment of the present invention; But protection scope of the present invention is not limited thereto; Any those of ordinary skill in the art are in the technical scope that the present invention disclosed; Variation or the replacement that can expect without creative work all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain that claims were limited.

Claims (3)

1. prescription that protects the modified polyvinilidene difluoroethylene; It is characterized in that: comprise modified polyvinilidene difluoroethylene, stablizer, static inhibitor, promotor and protective agent; Described stablizer is a dibasic lead stearate; Static inhibitor is a Triple Pressed Stearic Acid polyoxyethylene ester, and promotor is vulkacit H, and protective agent is a polycarbodiimide.
2. the prescription of protection modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of the prescription of said protection modified polyvinilidene difluoroethylene accounts for 80%-90% for the modified polyvinilidene difluoroethylene; Dibasic lead stearate accounts for 2%-4%; Triple Pressed Stearic Acid polyoxyethylene ester accounts for 3%-5%, and vulkacit H accounts for 1%-2%, and polycarbodiimide accounts for 4%-9%.
3. the prescription of protection modified polyvinilidene difluoroethylene according to claim 1; It is characterized in that: each composition weight proportion of the prescription of said protection modified polyvinilidene difluoroethylene accounts for 75%-85% for the modified polyvinilidene difluoroethylene; Dibasic lead stearate accounts for 4%-5%; Triple Pressed Stearic Acid polyoxyethylene ester accounts for 4%-7%, and vulkacit H accounts for 2%-5%, and polycarbodiimide accounts for 5%-8%.
CN201210064150XA 2012-03-13 2012-03-13 Formula of protective modified polyvinylidene fluoride Pending CN102604278A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201210064150XA CN102604278A (en) 2012-03-13 2012-03-13 Formula of protective modified polyvinylidene fluoride

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201210064150XA CN102604278A (en) 2012-03-13 2012-03-13 Formula of protective modified polyvinylidene fluoride

Publications (1)

Publication Number Publication Date
CN102604278A true CN102604278A (en) 2012-07-25

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105968667A (en) * 2016-07-29 2016-09-28 苏州新区特氟龙塑料制品厂 Antistatic hard Teflon engineering plastic
CN105968663A (en) * 2016-07-29 2016-09-28 苏州新区特氟龙塑料制品厂 Heat-conductive anti-static Teflon engineering plastic

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5883197A (en) * 1992-05-29 1999-03-16 Ausimont S.P.A. Compositions based on elastomeric polymers of vinylindene fluoride, hexafluoropropene and optionally tetrafluoroethylene, suitable for providing microcellular foamed articles
CN101875751A (en) * 2009-04-29 2010-11-03 成都水膜方科技有限责任公司 Modified polyvinylidene fluoride material as well as preparation method and application thereof in hollow fiber membrane material
CN102010554A (en) * 2010-11-09 2011-04-13 杭州福膜新材料科技有限公司 Material special for polyvinylidene fluoride film

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5883197A (en) * 1992-05-29 1999-03-16 Ausimont S.P.A. Compositions based on elastomeric polymers of vinylindene fluoride, hexafluoropropene and optionally tetrafluoroethylene, suitable for providing microcellular foamed articles
CN101875751A (en) * 2009-04-29 2010-11-03 成都水膜方科技有限责任公司 Modified polyvinylidene fluoride material as well as preparation method and application thereof in hollow fiber membrane material
CN102010554A (en) * 2010-11-09 2011-04-13 杭州福膜新材料科技有限公司 Material special for polyvinylidene fluoride film

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
肖卫东等: "《聚合物材料用化学助剂》", 31 August 2003, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105968667A (en) * 2016-07-29 2016-09-28 苏州新区特氟龙塑料制品厂 Antistatic hard Teflon engineering plastic
CN105968663A (en) * 2016-07-29 2016-09-28 苏州新区特氟龙塑料制品厂 Heat-conductive anti-static Teflon engineering plastic

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Application publication date: 20120725