JP5604010B2 - Water-based paint for anti-corrosion treatment in marine climate and its production method - Google Patents
Water-based paint for anti-corrosion treatment in marine climate and its production method Download PDFInfo
- Publication number
- JP5604010B2 JP5604010B2 JP2013536978A JP2013536978A JP5604010B2 JP 5604010 B2 JP5604010 B2 JP 5604010B2 JP 2013536978 A JP2013536978 A JP 2013536978A JP 2013536978 A JP2013536978 A JP 2013536978A JP 5604010 B2 JP5604010 B2 JP 5604010B2
- Authority
- JP
- Japan
- Prior art keywords
- paint
- alloy powder
- aluminum zinc
- silicon alloy
- zinc silicon
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 238000005260 corrosion Methods 0.000 title claims description 35
- 239000003973 paint Substances 0.000 title claims description 34
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims description 18
- 238000004519 manufacturing process Methods 0.000 title claims 3
- -1 aluminum zinc silicon Chemical compound 0.000 claims description 43
- 229910000676 Si alloy Inorganic materials 0.000 claims description 32
- 230000007797 corrosion Effects 0.000 claims description 32
- 239000000843 powder Substances 0.000 claims description 30
- 238000010276 construction Methods 0.000 claims description 26
- 239000002245 particle Substances 0.000 claims description 21
- 238000000034 method Methods 0.000 claims description 17
- 239000012744 reinforcing agent Substances 0.000 claims description 16
- 239000011230 binding agent Substances 0.000 claims description 15
- 239000002270 dispersing agent Substances 0.000 claims description 15
- 239000003960 organic solvent Substances 0.000 claims description 15
- 239000003112 inhibitor Substances 0.000 claims description 14
- 239000002562 thickening agent Substances 0.000 claims description 14
- 239000008367 deionised water Substances 0.000 claims description 12
- 229910021641 deionized water Inorganic materials 0.000 claims description 12
- 238000002156 mixing Methods 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 229910018072 Al 2 O 3 Inorganic materials 0.000 claims description 8
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 7
- 238000000576 coating method Methods 0.000 claims description 7
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 239000011777 magnesium Substances 0.000 claims description 4
- 239000011572 manganese Substances 0.000 claims description 4
- 239000010936 titanium Substances 0.000 claims description 4
- 229910052725 zinc Inorganic materials 0.000 claims description 4
- 229910052749 magnesium Inorganic materials 0.000 claims description 3
- 229910052748 manganese Inorganic materials 0.000 claims description 3
- 239000003921 oil Substances 0.000 claims description 3
- 229910052719 titanium Inorganic materials 0.000 claims description 3
- 102000009123 Fibrin Human genes 0.000 claims description 2
- 108010073385 Fibrin Proteins 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 2
- 239000004327 boric acid Substances 0.000 claims description 2
- 239000007822 coupling agent Substances 0.000 claims description 2
- 229950003499 fibrin Drugs 0.000 claims description 2
- 239000012535 impurity Substances 0.000 claims description 2
- 229910052759 nickel Inorganic materials 0.000 claims description 2
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 2
- 150000002910 rare earth metals Chemical class 0.000 claims description 2
- 239000011247 coating layer Substances 0.000 description 20
- 238000010248 power generation Methods 0.000 description 5
- 238000007598 dipping method Methods 0.000 description 4
- 230000003628 erosive effect Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000005299 abrasion Methods 0.000 description 3
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- FJMNNXLGOUYVHO-UHFFFAOYSA-N aluminum zinc Chemical compound [Al].[Zn] FJMNNXLGOUYVHO-UHFFFAOYSA-N 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000005265 energy consumption Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000007711 solidification Methods 0.000 description 2
- 230000008023 solidification Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 229910000838 Al alloy Inorganic materials 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910000611 Zinc aluminium Inorganic materials 0.000 description 1
- HXFVOUUOTHJFPX-UHFFFAOYSA-N alumane;zinc Chemical compound [AlH3].[Zn] HXFVOUUOTHJFPX-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000011651 chromium Substances 0.000 description 1
- 229940117975 chromium trioxide Drugs 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N chromium trioxide Inorganic materials O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- JOPOVCBBYLSVDA-UHFFFAOYSA-N chromium(6+) Chemical compound [Cr+6] JOPOVCBBYLSVDA-UHFFFAOYSA-N 0.000 description 1
- GAMDZJFZMJECOS-UHFFFAOYSA-N chromium(6+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Cr+6] GAMDZJFZMJECOS-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007123 defense Effects 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000006056 electrooxidation reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009440 infrastructure construction Methods 0.000 description 1
- 239000010410 layer Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 230000007935 neutral effect Effects 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 239000011253 protective coating Substances 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/10—Anti-corrosive paints containing metal dust
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
- C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
- C09D5/084—Inorganic compounds
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Powder Metallurgy (AREA)
Description
本発明は、耐海洋気候の工事部品の防食処理用の水性アルミ亜鉛シリコン塗料及びその調製方法に係る。 The present invention relates to a water-based aluminum zinc silicon paint for anticorrosion treatment of construction parts in a marine resistant climate and a method for preparing the same.
近海及び海洋の工事装置が置かれている場所は、多雨、高温、含塩空気、及び強風の環境である。その稼動条件は、ＩＳＯ９２２５環境評価基準によれば、一般的に＞Ｃ５級であり、極端に過酷な環境に属する。外部に露出した部品は激しい大気腐食、電気化学的な腐食及び気流浸食・腐食の総合作用により、各種の鉄骨構造の使用寿命は、通常の内陸の屋外環境で使用するものよりも遥かに低下する。例えば、海洋気候の条件で使用される風力発電設備は、機械室、ボンネット、塔屋、羽根元のフランジ座金、連結ボルト、連結スプリングなどのシステムの外部構造が、極端な腐食大気に直接露出している。そのため、従来の防御対策を採用すると、わずか数ヶ月で激しい腐食が発生する。したがって、耐久性＞１５年の風力発電の外部構造の表面処理の新材料及び新工程を提供することは、既に風力発電産業の発展のための切実な要求となった。 The place where the near sea and marine construction equipment is located is a heavy rain, high temperature, salty air, and strong wind environment. The operating conditions are generally> C5 class according to the ISO 9225 environmental evaluation standard, and belong to extremely severe environments. Parts exposed to the outside are subject to severe atmospheric corrosion, electrochemical corrosion, and airflow erosion / corrosion combined so that the service life of various steel structures is much lower than that used in normal inland outdoor environments. . For example, wind power generation equipment used in marine climate conditions, the external structure of the system such as machine room, bonnet, tower, flange washer at the blade, connecting bolt, connecting spring, etc. are directly exposed to the extreme corrosive atmosphere. Yes. Therefore, if conventional defense measures are adopted, severe corrosion will occur in just a few months. Therefore, the provision of new materials and new processes for surface treatment of the external structure of wind power generation with durability> 15 years has already become a urgent need for the development of the wind power industry.
また、船舶の鉄骨構造の防食も従前からの難題であり、外装、デッキのほかに、各種の帆柱、アンテナの防食の保守コストは驚くほど莫大な金額である。国のインフラストラクチャー建設を加速させることにつれ、例えば香港−マカオ−珠海大橋などの多くの海上大橋が相次いで着工され、または建設計画に入った。橋の設計及び工事において、各種の橋の鉄骨構造の防食処理がますます重要になる。例えば杭州湾大橋の建設では、表面保護処理に１億元以上の金額が掛かっている。 Corrosion protection of ship steel structures has also been a challenge for some time, and the maintenance costs for the anticorrosion of various sail pillars and antennas in addition to the exterior and deck are surprisingly huge. Many marine bridges, such as Hong Kong-Macau-Zhuhai Bridge, have started construction or entered into construction plans as the country's infrastructure construction has accelerated. In bridge design and construction, anti-corrosion treatment of various steel structures is becoming increasingly important. For example, in the construction of Hangzhou Bay Bridge, the surface protection treatment costs over 100 million yuan.
したがって、耐海洋気候の工事部品の防食処理の問題を解決するのは切実な要求である。従来技術において、工事部品の表面にＡｌ−Ｚｎ−Ｓｉ系合金塗層を溶融めっきすることは、耐海洋気候腐食を解決する有効な手段であり、既に多くの工事に応用されている。例えば、本出願人が以前に出願した出願号2009102627168、発明名称「耐海洋気候の工事部品に対する防食処理の方法」を、鋳造アルミ合金を防食処理に使用すれば、使用寿命を２０年に延ばせる。しかし、該発明の溶融めっき合金塗層には、工程温度が高いため（８００℃より高い）、部品が変形しやすく、耐磨耗性が低いため、耐浸食能力が低く、工程及び装備が複雑なため、大面積のワーク処理及び屋外作業が制限されるなどの改善点が存在している。そのため、応用上まだ大きな改善余地がある。 Therefore, it is an urgent need to solve the problem of anticorrosion treatment of construction parts in marine resistant climate. In the prior art, hot-plating an Al—Zn—Si alloy coating layer on the surface of a construction part is an effective means for solving marine climate corrosion resistance, and has already been applied to many constructions. For example, if a cast aluminum alloy is used for the anticorrosion treatment according to the application No. 2009102627168, which was previously filed by the present applicant, and the invention name “method of anticorrosion treatment for construction parts with a marine climate resistance”, the service life can be extended to 20 years. However, the hot-dip alloy coating layer of the present invention has a high process temperature (higher than 800 ° C.), so the parts are easily deformed and the wear resistance is low, so the erosion resistance is low and the process and equipment are complicated. For this reason, there are improvements such as large-area work processing and outdoor work being restricted. Therefore, there is still much room for improvement in application.
また、前世紀７０年代に開発された金属表面防食処理技術、例えばよく見られるフレーク状のクロム酸亜鉛保護塗層も、近海工事部品の防食処理に用いられている。しかし、このような塗層は６価クロムを含み、ある程度の汚染を起こしてしまう。且つ鈍化、結合の必要のため、一般的に５％〜１０％の三酸化クロムを添加しているが、Ｃｒ６＋は強い毒性があり、且つ発癌作用があるため、環境及び人体に対して重大な危険性が存在する。また、この塗層の固化温度は３００℃ほどであり、固化時間も約３０分ほどであるため、エネルギー消耗が激しく、硬度及び耐磨耗性が低い。ワークを運搬、装着、使用する過程において、擦り傷を付けられることがしばしばあるため、製品の外観及び耐食性に影響を及ぼす。 Further, a metal surface anticorrosion treatment technology developed in the 70s of the last century, for example, a flaky zinc chromate protective coating layer, which is often seen, is also used for anticorrosion treatment of inshore construction parts. However, such a coating layer contains hexavalent chromium and causes some contamination. In general, 5% to 10% chromium trioxide is added because of the need for dulling and bonding, but Cr 6+ is highly toxic and has carcinogenic effects, so it is serious for the environment and the human body. Danger exists. Moreover, since the solidification temperature of this coating layer is about 300 degreeC and the solidification time is also about 30 minutes, energy consumption is intense and hardness and abrasion resistance are low. In the process of transporting, mounting and using the workpiece, it is often scratched, which affects the appearance and corrosion resistance of the product.
従来技術の上記問題に対して本発明は、エコロジーまたはエコノミーであり、水性であり、低温固化が可能であり、耐海洋気候腐食性のあるアルミ亜鉛シリコン塗料及びその調製方法を提供する。 In view of the above problems of the prior art, the present invention provides an aluminum zinc silicon paint that is ecological or economical, water-based, can be solidified at low temperature, and has marine climate corrosion resistance, and a method for preparing the same.
本発明が提供する耐海洋気候の工事部品の防食処理用塗料において、前記塗料はアルミ亜鉛シリコン合金粉、有機溶剤、ナノ酸化物粒子補強剤、脱イオン水、結合剤、腐食抑制剤、分散剤、及び増ちょう剤を含む。前記塗料は、以下の配合比率「アルミ亜鉛シリコン合金粉：有機溶剤：ナノ酸化物粒子補強剤：脱イオン水：結合剤：腐食抑制剤：分散剤：増ちょう剤＝30.0〜50.0g：10.0〜25.0mL：1.0〜4.0g：15.0〜30.0mL：2.0〜5.0g：1.0〜3.0g：0.1〜2.0mL：0.1〜2.0g」で調合される。前記アルミ亜鉛シリコン合金粉は、Al、Zn、Siからなる。 In the anti-corrosion treatment paint for construction parts of marine climate resistant provided by the present invention, the paint is aluminum zinc silicon alloy powder, organic solvent, nano-oxide particle reinforcing agent, deionized water, binder, corrosion inhibitor, dispersant. And a thickener. The paint has the following blending ratio “aluminum zinc silicon alloy powder: organic solvent: nano-oxide particle reinforcing agent: deionized water: binder: corrosion inhibitor: dispersant: thickener = 30.0-50.0 g: 10.0- 25.0 mL: 1.0 to 4.0 g: 15.0 to 30.0 mL: 2.0 to 5.0 g: 1.0 to 3.0 g: 0.1 to 2.0 mL: 0.1 to 2.0 g ”. The aluminum zinc silicon alloy powder is made of Al, Zn, and Si.
本発明の提供する他の耐海洋気候の工事部品の防食処理用塗料において、前記塗料はアルミ亜鉛シリコン合金粉、有機溶剤、ナノ酸化物粒子補強剤、脱イオン水、結合剤、腐食抑制剤、分散剤、及び増ちょう剤を含む。前記塗料は、以下の配合比率「アルミ亜鉛シリコン合金粉：有機溶剤：ナノ酸化物粒子補強剤：脱イオン水：結合剤：腐食抑制剤：分散剤：増ちょう剤＝30.0〜50.0g：10.0〜25.0mL：1.0〜4.0g：15.0〜30.0mL：2.0〜5.0g：1.0〜3.0g：0.1〜2.0mL：0.1〜2.0g」で調合される。前記アルミ亜鉛シリコン合金粉は、Al、Zn、Siの３つの基本元素を含み、さらにマグネシウム、レアアース、チタン、ニッケル、マンガンのうちから選ばれる１種または複数種の元素を含む。 In the anticorrosion treatment paint for other marine-resistant construction parts provided by the present invention, the paint is aluminum zinc silicon alloy powder, organic solvent, nano-oxide particle reinforcing agent, deionized water, binder, corrosion inhibitor, Contains dispersants and thickeners. The paint has the following blending ratio “aluminum zinc silicon alloy powder: organic solvent: nano-oxide particle reinforcing agent: deionized water: binder: corrosion inhibitor: dispersant: thickener = 30.0-50.0 g: 10.0- 25.0 mL: 1.0 to 4.0 g: 15.0 to 30.0 mL: 2.0 to 5.0 g: 1.0 to 3.0 g: 0.1 to 2.0 mL: 0.1 to 2.0 g ”. The aluminum zinc silicon alloy powder includes three basic elements of Al, Zn, and Si, and further includes one or more elements selected from magnesium, rare earth, titanium, nickel, and manganese.
前記有機溶剤としてエチレングリコールが好ましい。 As the organic solvent, ethylene glycol is preferable.
前記結合剤として硼酸エステルカップリング剤が好ましい。 As the binder, a borate ester coupling agent is preferable.
前記腐食抑制剤として硼酸が好ましい。 Boric acid is preferred as the corrosion inhibitor.
前記増ちょう剤としてヒドロキシエチル繊維素が好ましい。 The thickener is preferably hydroxyethyl fibrin.
前記分散剤としてポリシロキサンジプロピレングリコールモノメチルエーテルが好ましい。 As the dispersant, polysiloxane dipropylene glycol monomethyl ether is preferable.
好ましくは、前記ナノ酸化物粒子補強剤はAl2O3、SiO2のうちから選ばれる１種または２種である。 Preferably, the nano-oxide particle reinforcing agent is one or two selected from Al 2 O 3 and SiO 2 .
さらに好ましくは、前記Al2O3の平均粒子径は15〜60nmであり、前記SiO2の平均粒子径は25〜70nmである。 More preferably, the average particle diameter of the Al 2 O 3 is 15 to 60 nm, and the average particle diameter of the SiO 2 is 25 to 70 nm.
さらに好ましくは、前記ナノ酸化物粒子補強剤はSiO2とAl2O3であり、且つSiO2とAl2O3の質量比は１：（１〜３）である。 More preferably, the nano oxide particle reinforcing agent is SiO 2 and Al 2 O 3 , and the mass ratio of SiO 2 and Al 2 O 3 is 1: (1-3).
好ましくは、前記アルミ亜鉛シリコン合金粉の平均直径は10〜200μmである。 Preferably, the average diameter of the aluminum zinc silicon alloy powder is 10 to 200 μm.
好ましくは、前記アルミ亜鉛シリコン合金粉のうちのＺｎの質量百分率は35〜58%である。 Preferably, the mass percentage of Zn in the aluminum zinc silicon alloy powder is 35 to 58%.
好ましくは、前記アルミ亜鉛シリコン合金粉のうちのＳｉの質量百分率は0.3〜4.0%である。 Preferably, the mass percentage of Si in the aluminum zinc silicon alloy powder is 0.3 to 4.0%.
好ましくは、前記アルミ亜鉛シリコン合金粉のうちのＭｇの質量百分率は0.1〜5.0%である。 Preferably, the mass percentage of Mg in the aluminum zinc silicon alloy powder is 0.1 to 5.0%.
好ましくは、前記アルミ亜鉛シリコン合金粉のうちのＲｅの質量百分率は0.02〜1.0%である。 Preferably, the mass percentage of Re in the aluminum zinc silicon alloy powder is 0.02 to 1.0%.
好ましくは、前記アルミ亜鉛シリコン合金粉のうちのＴｉの質量百分率は0.01〜0.5%である。 Preferably, the mass percentage of Ti in the aluminum zinc silicon alloy powder is 0.01 to 0.5%.
好ましくは、前記アルミ亜鉛シリコン合金粉のうちのＮｉの質量百分率は0.1〜3.0%である。 Preferably, the mass percentage of Ni in the aluminum zinc silicon alloy powder is 0.1 to 3.0%.
好ましくは、前記アルミ亜鉛シリコン合金粉のうちのＭｎの質量百分率は0.01〜1.0%である。 Preferably, the mass percentage of Mn in the aluminum zinc silicon alloy powder is 0.01 to 1.0%.
好ましくは、前記アルミ亜鉛シリコン合金粉の各構成成分の余剰量はAl及び不可避な不純物である。 Preferably, the surplus amount of each constituent component of the aluminum zinc silicon alloy powder is Al and inevitable impurities.
一方、本発明はさらに前記耐海洋気候の工事部品の防食処理用塗料を調製する方法を提供する。上記の配合に従い、所定量の腐食抑制剤を計量し、所定量の脱イオン水に溶解させ、それから結合剤、分散剤、有機溶剤を投入し、撹拌して溶解させ、撹拌状態においてアルミ亜鉛シリコン合金粉とナノ酸化物粒子補強剤を緩慢に投入し、それから増ちょう剤を投入し、撹拌過程において油浴の温度を20〜30℃に制御し、0.5〜1時間撹拌する。 On the other hand, the present invention further provides a method for preparing a coating material for anticorrosion treatment of construction parts in the marine-resistant climate. In accordance with the above formulation, a predetermined amount of corrosion inhibitor is weighed and dissolved in a predetermined amount of deionized water, and then a binder, a dispersant, and an organic solvent are added and dissolved by stirring. The alloy powder and the nano-oxide particle reinforcing agent are slowly added, and then a thickener is added, and the temperature of the oil bath is controlled at 20 to 30 ° C. and stirred for 0.5 to 1 hour in the stirring process.
本発明の提供する塗料は、構成成分などに対する最適化により、水性であり、クロムフリーであり、低温固化可能であり、耐海洋気候腐食性を有するＡｌ−Ｚｎ−Ｓｉ合金塗料として、初めて開発された。該塗料は環境に優しく、性質が安定で、塗層調製のエネルギー消耗が少ないなどの特徴を有している。 The paint provided by the present invention has been developed for the first time as an Al-Zn-Si alloy paint that is water-based, chromium-free, can be solidified at a low temperature, and has marine climate corrosion resistance by optimization with respect to components and the like. It was. The paint is characterized by being environmentally friendly, stable in properties, and less energy consumption for preparing the coating layer.
本発明が提供する水性アルミ亜鉛シリコン塗料は、現在のアルミ亜鉛シリコン塗層が主に溶融めっき方法で調製されるという限定を突破した。本発明は結合剤、分散剤、有機溶剤などを投入することで金属塗料を調製し、スプレー塗布、ブラシ塗布などの方法でワーク表面に塗層を形成することができる。溶融めっきなどの工程と比べて、本発明の塗層の調製工程の温度は低い（２００℃）。溶融めっきで合金塗層を施す工程の温度は高い（６００℃より高い）。そのため本発明は、ワークに変形が生じ、また機械的性質が低下するなどの技術問題を克服し、スプレー塗布、ブラシ塗布などの方法でワークの表面に塗層を形成させることができ、工程方法及び設備が簡単で、大型の複雑部品の処理に適しており、塗料の応用範囲を広げる。 The water-based aluminum zinc silicon paint provided by the present invention has overcome the limitation that the current aluminum zinc silicon coating layer is prepared mainly by a hot dipping method. In the present invention, a metal paint can be prepared by adding a binder, a dispersant, an organic solvent, and the like, and a coating layer can be formed on the work surface by a method such as spray coating or brush coating. Compared with processes, such as hot dipping, the temperature of the preparation process of the coating layer of this invention is low (200 degreeC). The temperature of the step of applying the alloy coating layer by hot dipping is high (higher than 600 ° C.). Therefore, the present invention overcomes technical problems such as deformation of the workpiece and deterioration of mechanical properties, and can form a coating layer on the surface of the workpiece by a method such as spray coating or brush coating. And the equipment is simple and suitable for the processing of large complex parts, expanding the application range of paint.
本発明の塗層を防食処理に用いた工事部品は様々な優れた性能を有している。例えば、優れた耐食性、優れた耐侵食性能、且つ耐熱エッチングの性能が高く、たとえ長時間にわたって塗層を高温条件に放置しても、その外観に変化が生じることはない。本発明で調製した塗層は、素地との結合力が高く、耐食性、耐磨耗性に優れ、使用寿命が長い。また、前記塗層は金属素地に対して強い付着力を有するだけでなく、同時にその他の各種の付加塗層に対してもよい結合力を有し、美しいマットシルバーグレーの色だけでなく、様々な色に付加塗装することができると同時に、従来技術において自身の硬度が低いという欠点を補った。 Construction parts using the coating layer of the present invention for anticorrosion treatment have various excellent performances. For example, excellent corrosion resistance, excellent erosion resistance, and high heat etching performance are high, and even if the coating layer is left under a high temperature condition for a long time, its appearance does not change. The coating layer prepared in the present invention has a high bonding strength with the substrate, is excellent in corrosion resistance and abrasion resistance, and has a long service life. Moreover, the coating layer not only has a strong adhesion to the metal substrate, but also has a good bonding force to other various additional coating layers, not only a beautiful matte silver gray color, but also various In addition to being able to be applied to various colors, the conventional technique compensated for the disadvantage of low hardness.
さらに、アルミ亜鉛シリコン合金をミクロンサイズの粉粒体にすることで、塗層の耐食性、耐磨耗性、及び耐侵食能力は、溶融めっきで作製されるアルミ亜鉛シリコン塗層及び亜鉛アルミ塗層よりも大幅に向上する。そのため、多雨、高温、含塩空気、及び強風などの過酷な海洋腐食性環境に適しており、風力発電、船舶などの重要工事部品に対して総合性能に優れた耐食保護方法を提供する。 Furthermore, by making the aluminum zinc silicon alloy into micron-sized particles, the corrosion resistance, abrasion resistance, and erosion resistance of the coating layer can be improved by the aluminum zinc silicon coating layer and zinc aluminum coating layer produced by hot dipping. Significantly improved. Therefore, it is suitable for severe marine corrosive environments such as heavy rain, high temperature, salt-containing air, and strong wind, and provides an anticorrosion protection method with excellent overall performance for important construction parts such as wind power generation and ships.
上記記載のように、本発明が開発した耐海洋気候の工事部品の防食処理用塗料及びその調製方法により、工事部品の海洋腐食問題による切実な要求を満たし、海洋工事及び近海風力発電などの産業装置の耐食工程の応用において高いポテンシャルを有している。 As described above, the anticorrosion treatment paint for marine-resistant construction parts developed by the present invention and the preparation method thereof satisfy the urgent demands due to the marine corrosion problem of construction parts, and the industries such as marine construction and near-shore wind power generation It has high potential in the application of corrosion resistance process of equipment.
本発明は耐海洋気候の工事部品の防食処理用の水性アルミ亜鉛シリコン塗料を提供し、前記塗料は、アルミ亜鉛シリコン合金粉、有機溶剤、ナノ酸化物粒子補強剤、脱イオン水、結合剤、腐食抑制剤、分散剤、及び増ちょう剤を含む。 The present invention provides a water-based aluminum zinc silicon paint for anticorrosion treatment of construction parts in a marine-resistant climate, the paint comprising an aluminum zinc silicon alloy powder, an organic solvent, a nano-oxide particle reinforcing agent, deionized water, a binder, Includes corrosion inhibitors, dispersants, and thickeners.
以下では、本発明に記載の塗料の配合成分の配合比率の、一部の好ましい実施例を表１に示す。しかし本発明の配合成分の含有量は、該表に記載される数値に限定されることなく、当業者にとって、表に記載される数値範囲に基づいて合理的な概括及び推理を行うことは十分できる。
以下では、本発明におけるアルミ亜鉛シリコン合金粉の各構成元素の含有量（質量百分率）の一部の好ましい実施例を、表２〜３３に示す。しかし、本発明のアルミ亜鉛シリコン合金粉の各構成元素の含有量は、これらの表に記載される数値に限定されることはない。かつ、特に説明すべきなのは、表２〜３３において関連成分の質量百分率数値を記載したものの、これらは須要な技術的特徴として説明するのではなく、いずれも好ましい条件として、本発明の技術情報をより詳しく示すためのものに過ぎず、本発明の須要な条件として説明するわけではない。
実験性能データ：
某海辺に近い風力発電ユニットのキーパーツ「連結ボルト」（材質４０ＣｒＮｉＭｏ）について、本来一般的な保護処理を施したが、僅か数ヶ月で著しい腐食が発生した。
Experimental performance data:
The key part “connection bolt” (material 40CrNiMo) of the wind power generation unit near the coastal seaside was originally subjected to general protection treatment, but significant corrosion occurred in only a few months.
同様の「連結ボルト」に、本発明の各種塗料を塗布し、厚さ２０μｍの塗層を形成させ、さらに厚さ１５μｍのポリシロキサンを塗装した。加速腐食シミュレーション実験の示した結果により、海水が飛び散る環境において、その主要性能は下記指標に達している。
中性含塩空気腐食における寿命：１６００時間以上
３００℃耐湿熱性：２４０時間
塗層結合力：５０Ｎ
硝酸アンモニウムによる加速腐食試験における寿命：８時間以上
耐海洋気候腐食寿命：２０年以上（加速実験）
Various coating materials of the present invention were applied to the same “connection bolt” to form a coating layer having a thickness of 20 μm, and further a polysiloxane having a thickness of 15 μm was applied. According to the results of accelerated corrosion simulation experiments, the main performance has reached the following index in an environment where seawater scatters.
Life in neutral salt-containing air corrosion: 1600 hours or more 300 ° C. Moisture and heat resistance: 240 hours Coating layer bond strength: 50 N
Lifetime in accelerated corrosion test with ammonium nitrate: 8 hours or more Ocean corrosion life: 20 years or more (accelerated experiment)
Claims (10)
前記塗料は、アルミ亜鉛シリコン合金粉、有機溶剤、ナノ酸化物粒子補強剤、脱イオン水、結合剤、腐食抑制剤、分散剤、及び増ちょう剤を含み、
前記塗料は、以下の配合比率で調合され、
［配合比率］アルミ亜鉛シリコン合金粉：有機溶剤：ナノ酸化物粒子補強剤：脱イオン水：結合剤：腐食抑制剤：分散剤：増ちょう剤＝30.0〜50.0g：10.0〜25.0mL：1.0〜4.0g：15.0〜30.0mL：2.0〜5.0g：1.0〜3.0g：0.1〜2.0mL：0.1〜2.0g
前記アルミ亜鉛シリコン合金粉が、Al、ZnおよびSiからなる、耐海洋気候の工事部品の防食処理用塗料。 It is a coating for anticorrosion treatment of construction parts in a marine-resistant climate,
The paint includes aluminum zinc silicon alloy powder, organic solvent, nano oxide particle reinforcing agent, deionized water, binder, corrosion inhibitor, dispersant, and thickener,
The paint is formulated with the following blending ratio:
[Blending ratio] Aluminum zinc silicon alloy powder: Organic solvent: Nano-oxide particle reinforcing agent: Deionized water: Binder: Corrosion inhibitor: Dispersant: Thickener = 30.0-50.0g: 10.0-25.0mL: 1.0- 4.0 g: 15.0-30.0 mL: 2.0-5.0 g: 1.0-3.0 g: 0.1-2.0 mL: 0.1-2.0 g
A paint for anticorrosion treatment of construction parts in an ocean-resistant climate, wherein the aluminum zinc silicon alloy powder is made of Al, Zn and Si.
前記塗料は、アルミ亜鉛シリコン合金粉、有機溶剤、ナノ酸化物粒子補強剤、脱イオン水、結合剤、腐食抑制剤、分散剤、及び増ちょう剤を含み、
前記塗料は、以下の配合比率で調合され、
［配合比率］アルミ亜鉛シリコン合金粉：有機溶剤：ナノ酸化物粒子補強剤：脱イオン水：結合剤：腐食抑制剤：分散剤：増ちょう剤＝30.0〜50.0g：10.0〜25.0mL：1.0〜4.0g：15.0〜30.0mL：2.0〜5.0g：1.0〜3.0g：0.1〜2.0mL：0.1〜2.0g
前記アルミ亜鉛シリコン合金粉が、Al、ZnおよびSiの３つの基本元素を含み、さらにマグネシウム、レアアース、チタン、ニッケルおよびマンガンのうちから選ばれる１種または複数種の元素を含む、耐海洋気候の工事部品の防食処理用塗料。 It is a coating for anticorrosion treatment of construction parts in a marine-resistant climate,
The paint includes an aluminum zinc silicon alloy powder, an organic solvent, a nano-oxide particle reinforcing agent, deionized water, a binder, a corrosion inhibitor, a dispersant, and a thickener,
The paint is formulated with the following blending ratio:
[Blending ratio] Aluminum zinc silicon alloy powder: Organic solvent: Nano-oxide particle reinforcing agent: Deionized water: Binder: Corrosion inhibitor: Dispersant: Thickener = 30.0-50.0g: 10.0-25.0mL: 1.0- 4.0 g: 15.0-30.0 mL: 2.0-5.0 g: 1.0-3.0 g: 0.1-2.0 mL: 0.1-2.0 g
The aluminum zinc silicon alloy powder includes three basic elements of Al, Zn, and Si, and further includes one or more elements selected from magnesium, rare earth, titanium, nickel, and manganese. Paint for anticorrosion treatment of construction parts.
前記結合剤は、硼酸エステルカップリング剤を含み、
前記腐食抑制剤は、硼酸を含み、
前記増ちょう剤は、ヒドロキシエチル繊維素を含み、
前記分散剤は、ポリシロキサンジプロピレングリコールモノメチルエーテルを含む、
請求項１または２に記載の塗料。 The organic solvent includes ethylene glycol,
The binder includes a borate ester coupling agent,
The corrosion inhibitor includes boric acid,
The thickener comprises hydroxyethyl fibrin,
The dispersant includes polysiloxane dipropylene glycol monomethyl ether.
The paint according to claim 1 or 2.
前記配合比率に従って、所定量の腐食抑制剤を計量して、所定量の脱イオン水に溶解させ、
さらに結合剤、分散剤および有機溶剤を投入し、撹拌して溶解させ、
撹拌状態において、アルミ亜鉛シリコン合金粉とナノ酸化物粒子補強剤を、徐々に投入し、さらに増ちょう剤を投入し、
前記撹拌過程において油浴の温度を20〜30℃に制御し、0.5〜1時間撹拌する、
防食処理用塗料を製造する方法。
A method for producing a paint for anticorrosion treatment of construction parts in an ocean-resistant climate according to any one of claims 1 to 9,
According to the blending ratio, a predetermined amount of corrosion inhibitor is weighed and dissolved in a predetermined amount of deionized water,
Furthermore, a binder, a dispersant and an organic solvent are added, dissolved by stirring,
In the stirring state, gradually add aluminum zinc silicon alloy powder and nano oxide particle reinforcing agent, and then add thickener,
In the stirring process, the temperature of the oil bath is controlled at 20 to 30 ° C. and stirred for 0.5 to 1 hour.
A method for producing an anticorrosion coating.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010531689 | 2010-11-04 | ||
| CN201010531689.2 | 2010-11-04 | ||
| PCT/CN2010/079676 WO2012058839A1 (en) | 2010-11-04 | 2010-12-10 | Water-soluble coating for anti-corrosion treatment of oceanic climate-resisting engineering parts and preparing method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2013544925A JP2013544925A (en) | 2013-12-19 |
| JP5604010B2 true JP5604010B2 (en) | 2014-10-08 |
Family
ID=43809984
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2013536978A Active JP5604010B2 (en) | 2010-11-04 | 2010-12-10 | Water-based paint for anti-corrosion treatment in marine climate and its production method |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5604010B2 (en) |
| KR (1) | KR101464287B1 (en) |
| CN (32) | CN102086313B (en) |
| WO (1) | WO2012058839A1 (en) |
Families Citing this family (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102086313B (en) * | 2010-11-04 | 2012-08-29 | 江苏麟龙新材料股份有限公司 | Magnesium-containing coating for marine climate-resistant anticorrosion treatment |
| JP2014025015A (en) * | 2012-07-30 | 2014-02-06 | Kubota Corp | Coating material |
| CN102850873B (en) * | 2012-08-09 | 2015-03-18 | 义乌潘季涂料有限公司 | Fluorescence electrophoretic paint and preparation method and application thereof |
| CN103087562B (en) * | 2013-01-03 | 2015-04-15 | 张军 | Magnesium-titanium-manganese-containing non-chrome zinc-aluminum coating anticorrosive paint |
| CN103232736B (en) * | 2013-01-03 | 2015-09-23 | 魏放 | A kind of Non-chromium Zn-al Coating protective system containing manganese-silicon |
| CN103059615B (en) * | 2013-01-03 | 2015-04-22 | 解波 | Titanium-manganese-silicon-containing chromium-free zinc aluminum coating corrosion-resistant coating |
| CN103275527B (en) * | 2013-01-03 | 2015-08-19 | 魏放 | A kind of Non-chromium Zn-al Coating protective system containing manganese |
| CN103044984B (en) * | 2013-01-03 | 2015-06-17 | 管卫峰 | Nickel-titanium-manganese-silicon-containing chromium-free zinc-aluminum coating anti-corrosive paint |
| CN103059616B (en) * | 2013-01-03 | 2015-05-13 | 宿迁市三石包装容器有限公司 | Nickel-magnesium-titanium-manganese-containing chromium-free zinc aluminum coating corrosion-resistant coating |
| CN103275526B (en) * | 2013-01-03 | 2015-12-02 | 新昌县康泓机械科技有限公司 | A kind of Non-chromium Zn-al Coating protective system of nickel-manganese-contained-silicon |
| CN103059614B (en) * | 2013-01-03 | 2014-12-31 | 刘海生 | Nickel-magnesium-containing chromium-free zinc aluminum coating corrosion-resistant coating |
| CN103044987B (en) * | 2013-01-03 | 2015-05-27 | 张军 | Nickel-titanium-silicon-containing chromium-free zinc-aluminum coating anti-corrosive paint |
| CN103087560B (en) * | 2013-01-03 | 2014-12-31 | 李姗姗 | Chrome-free zinc-aluminum-coating anti-corrosion paint containing Mg, Ti, Mn and Si |
| CN103232737B (en) * | 2013-01-03 | 2015-07-22 | 魏放 | Chrome-free zinc-aluminum coating anticorrosive paint comprising nickel-titanium-manganese |
| CN103275528B (en) * | 2013-01-03 | 2015-09-23 | 魏放 | A kind of Non-chromium Zn-al Coating protective system of titaniferous-manganese |
| CN103087561B (en) * | 2013-01-03 | 2014-12-31 | 李姗姗 | Chrome-free zinc-aluminum-coating anti-corrosion paint containing Ni, Mg and Mn |
| CN103031009B (en) * | 2013-01-03 | 2014-12-31 | 刘海生 | Non-chrome zinc-aluminum coating anticorrosive paint containing nickel-magnesium-silicon |
| CN103242686A (en) * | 2013-03-28 | 2013-08-14 | 南京航空航天大学 | High-corrosion-resistant water soluble zinc aluminium multielement alloy-based nano anticorrosion paint as well as preparation method and application thereof |
| CN103254733B (en) * | 2013-05-20 | 2015-03-18 | 山东龙泉管道工程股份有限公司 | Ocean heavy anti-corrosion epoxy aluminum-rare earth-rich nano-coating and preparation method thereof |
| CN103242738B (en) * | 2013-05-20 | 2015-04-22 | 山东龙泉管道工程股份有限公司 | Marine heavy anti-corrosion epoxy nano coating rich in aluminium, magnesium and rare earth and preparation method thereof |
| CN103242737B (en) * | 2013-05-20 | 2015-04-22 | 山东龙泉管道工程股份有限公司 | Marine heavy anti-corrosion epoxy nano coating rich in aluminium, manganese and rare earth and preparation method thereof |
| CN103254726B (en) * | 2013-05-20 | 2015-06-24 | 山东龙泉管道工程股份有限公司 | Ocean heavy anti-corrosion epoxy aluminum-magnesium-manganese-rare earth-rich nano-coating and preparation method thereof |
| CN103421994B (en) * | 2013-07-31 | 2015-06-24 | 江苏麟龙新材料股份有限公司 | Scale-like multi-element aluminum zinc silicon alloy powder containing La and Pr, and preparation method thereof |
| CN103788729A (en) * | 2013-12-11 | 2014-05-14 | 青岛海洋新材料科技有限公司 | Antirust coating |
| CN103709852B (en) * | 2013-12-12 | 2016-06-22 | 青岛海洋新材料科技有限公司 | A kind of marine climate resistant antirusting paint |
| CN104759399A (en) * | 2014-01-07 | 2015-07-08 | 无锡新大中薄板有限公司 | Method for manufacturing flocked aluminum alloy coating flower-blown plate for ocean engineering |
| CN104449254A (en) * | 2014-11-20 | 2015-03-25 | 南京航空航天大学 | Aluminum-zinc multi-component alloy-containing water-based epoxy coating for anti-corrosive treatment of submarine oil and gas pipelines and preparation method of water-based epoxy coating |
| CN105295585A (en) * | 2015-11-30 | 2016-02-03 | 沈阳工业大学 | Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint |
| CN105585883B (en) * | 2016-03-04 | 2017-09-19 | 浙江大学 | Low-temperature sintering coating and its painting method for steel bar anti-corrosion |
| CN108485323A (en) * | 2018-03-29 | 2018-09-04 | 南京信息工程大学 | A kind of coating material and preparation method thereof |
| CN113667382A (en) * | 2021-09-14 | 2021-11-19 | 惠州市汉惠河环境科技有限公司 | Water-based heavy-duty anticorrosion primer and preparation method thereof |
| CN116550577B (en) * | 2023-04-14 | 2024-02-13 | 烟台大学 | Coating treatment process for marine climate resistant engineering part surface coating |
Family Cites Families (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5868819A (en) * | 1996-05-20 | 1999-02-09 | Metal Coatings International Inc. | Water-reducible coating composition for providing corrosion protection |
| JP2000064024A (en) * | 1998-08-17 | 2000-02-29 | Nittetsu Hard Kk | Molten metal-corrosion resistant film forming material and formation of film |
| US7138184B2 (en) * | 2000-05-11 | 2006-11-21 | Dow Corning Corporation | Coating composition |
| EP1330499A2 (en) * | 2000-10-11 | 2003-07-30 | Chemteall GmbH | Method for pretreating and subsequently coating metallic surfaces with a paint-type coating prior to forming and use of substrates coated in this way |
| WO2002088262A1 (en) * | 2001-05-01 | 2002-11-07 | Dow Corning Corporation | Protective coating composition |
| JP4250080B2 (en) * | 2001-09-11 | 2009-04-08 | アクゾ ノーベル コーティングス インターナショナル ビー ヴィ | Coating composition for metal substrates |
| WO2003066927A1 (en) * | 2002-02-08 | 2003-08-14 | Nichols Aluminium | Method and apparatus for producing a solution heat treated sheet |
| CN1786091A (en) * | 2005-11-14 | 2006-06-14 | 长春吉大化学有限公司 | magnesium alloy non-chromium dacro solution paint and its preparation method |
| JP5190238B2 (en) * | 2006-09-28 | 2013-04-24 | 新日鐵住金株式会社 | High corrosion resistance rust-proof paint, high corrosion resistance steel material and steel structure |
| JP2008144059A (en) * | 2006-12-11 | 2008-06-26 | Tsubakimoto Chain Co | Water-based rust-prevention coating |
| JP5130071B2 (en) * | 2007-02-08 | 2013-01-30 | 新日鐵住金株式会社 | Rust prevention method for marine steel |
| CN101613559A (en) * | 2008-06-25 | 2009-12-30 | 云南格兰工业发展有限公司 | Hydrophilic nano zinc based composite coating |
| CN101333350B (en) * | 2008-07-02 | 2010-06-02 | 大连海事大学 | Conductive anti-pollution paint for sea and method for preparing same |
| CN101338091B (en) * | 2008-08-15 | 2010-06-09 | 上海达克罗涂复工业有限公司 | Chromium-free metal anti-corrosive paint, preparation method and use method |
| CN101343506B (en) * | 2008-08-28 | 2011-12-28 | 胡仲寅 | Zinc metallic coating |
| CN101481553A (en) * | 2008-11-06 | 2009-07-15 | 常州市纳罗可涂料有限公司 | Normal temperature cured self-assembly composite nano oxide anti-corrosive paint |
| CN101418154A (en) * | 2008-11-21 | 2009-04-29 | 哈尔滨工程大学 | Method for preparing corrosion inhibition anion intercalated layered double hydroxides/oxide composite material and application |
| CN101693811B (en) * | 2009-09-28 | 2011-09-07 | 常州捷迈特表面工程技术有限公司 | Chromium-free waterborne corrosion resistant coating used for surface of metal and preparation method thereof |
| CN101709162B (en) * | 2009-11-27 | 2014-03-05 | 沈阳黎明航空发动机(集团)有限责任公司 | Coating for GH907 products under ocean environment and preparation and use methods thereof |
| CN101736222B (en) * | 2009-12-28 | 2012-02-22 | 江苏麟龙新材料股份有限公司 | Aluminum-silicon-zinc-rare earth-copper-containing hot dip coating alloy and method for preparing same |
| CN101748353B (en) * | 2009-12-28 | 2012-02-15 | 江苏麟龙新材料股份有限公司 | Method for antiseptic treatment of marine climate resistant engineering component |
| CN102086313B (en) * | 2010-11-04 | 2012-08-29 | 江苏麟龙新材料股份有限公司 | Magnesium-containing coating for marine climate-resistant anticorrosion treatment |
-
2010
- 2010-12-05 CN CN 201010587336 patent/CN102086313B/en active Active
- 2010-12-05 CN CN 201010587357 patent/CN102086314B/en active Active
- 2010-12-10 CN CN 201010593677 patent/CN102002271B/en active Active
- 2010-12-10 JP JP2013536978A patent/JP5604010B2/en active Active
- 2010-12-10 KR KR1020137014411A patent/KR101464287B1/en active IP Right Grant
- 2010-12-10 WO PCT/CN2010/079676 patent/WO2012058839A1/en active Application Filing
- 2010-12-10 CN CN 201010593688 patent/CN102002272B/en active Active
- 2010-12-12 CN CN 201010591241 patent/CN102010624B/en active Active
- 2010-12-12 CN CN 201010591243 patent/CN102010625B/en active Active
- 2010-12-19 CN CN 201010620373 patent/CN102031028B/en active Active
- 2010-12-19 CN CN 201010620371 patent/CN102146223B/en active Active
- 2010-12-29 CN CN 201010623728 patent/CN102070926B/en active Active
- 2010-12-29 CN CN 201010623727 patent/CN102146224B/en active Active
- 2010-12-31 CN CN 201010623441 patent/CN102070925B/en active Active
- 2010-12-31 CN CN 201010623444 patent/CN102086315B/en active Active
-
2011
- 2011-01-07 CN CN 201110008863 patent/CN102051077B/en active Active
- 2011-01-07 CN CN 201110008861 patent/CN102167917B/en active Active
- 2011-01-09 CN CN 201110008770 patent/CN102051076B/en active Active
- 2011-01-09 CN CN 201110008769 patent/CN102127327B/en active Active
- 2011-01-13 CN CN 201110020601 patent/CN102051078B/en active Active
- 2011-01-13 CN CN 201110020600 patent/CN102153894B/en active Active
- 2011-01-16 CN CN 201110021550 patent/CN102181180B/en active Active
- 2011-01-16 CN CN 201110021571 patent/CN102181181B/en active Active
- 2011-01-21 CN CN 201110027096 patent/CN102181182B/en active Active
- 2011-01-23 CN CN 201110027252 patent/CN102181183B/en active Active
- 2011-01-23 CN CN 201110027266 patent/CN102181184B/en active Active
- 2011-01-25 CN CN 201110028975 patent/CN102181186B/en active Active
- 2011-01-25 CN CN 201110028973 patent/CN102181185B/en active Active
- 2011-01-26 CN CN 201110030707 patent/CN102181189B/en active Active
- 2011-01-26 CN CN 201110030700 patent/CN102181188B/en active Active
- 2011-01-27 CN CN 201110032920 patent/CN102051082B/en active Active
- 2011-01-27 CN CN 201110032928 patent/CN102051079B/en active Active
- 2011-01-28 CN CN 201110034814 patent/CN102199370B/en active Active
- 2011-01-28 CN CN 201110034815 patent/CN102051080B/en active Active
- 2011-03-27 CN CN 201110080917 patent/CN102181190B/en active Active
Also Published As
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5604010B2 (en) | Water-based paint for anti-corrosion treatment in marine climate and its production method |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20140806 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20140819 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20140822 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5604010 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |