CN102199370B - Marine climate resistant paint composed of magnesium-rare earth-manganese and used for preservative treatment - Google Patents

Marine climate resistant paint composed of magnesium-rare earth-manganese and used for preservative treatment Download PDF

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Publication number
CN102199370B
CN102199370B CN 201110034814 CN201110034814A CN102199370B CN 102199370 B CN102199370 B CN 102199370B CN 201110034814 CN201110034814 CN 201110034814 CN 201110034814 A CN201110034814 A CN 201110034814A CN 102199370 B CN102199370 B CN 102199370B
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coating
alloy powder
silicon alloy
oxide particles
zinc silicon
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CN102199370A (en
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冯立新
张敏燕
缪强
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Jiangsu Linlong New Materials Co Ltd
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Jiangsu Linlong New Materials Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084—Inorganic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention relates to a marine climate resistant paint used for preservative treatment of engineering parts. The paint includes aluminium-zinc-silicon alloy powder, an organic solvent, a reinforcing agent of nanometer oxide particles, deionized water, a binder, a corrosion inhibitor, a dispersant and a thickening agent. And the aluminium-zinc-silicon alloy powder, the organic solvent, the reinforcing agent of nanometer oxide particles, the deionized water, the binder, the corrosion inhibitor, the dispersant and the thickening agent contained in the paint are in a ratio of 30.0-50.0g:10.0-25.0mL:1.0-4.0g:15.0-30.0mL:2.0-5.0g:1.0-3.0g:0.1-2.0mL:0.1-2.0g. Wherein, the aluminium-zinc-silicon alloy powder comprises A1, Zn, Si, Mg, RE and Mn.

Description

Contain the coating that the marine climate resistant rotproofing of magnesium-rare earth-manganese is used
Technical field
The present invention relates to water-soluble aluminum zinc silicon coating that a kind of marine climate resistant engineering component rotproofing uses and preparation method thereof.
Background technology
Engineer equipment in coastal waters and ocean ambient atmosphere of living in is rainy, high temperature, many salt fogs and high wind stream, and its service condition is pressed ISO9225 environmental evaluation Standard General＞C5 level, belongs to extreme environment.Exposed part will be subject to the comprehensive action that strong atomospheric corrosion, galvanic corrosion and airflow scouring corrode, and the work-ing life of various steel construction is far below general landlocked outdoor environment.Such as the wind power plant of under the oceanic climate condition, being on active service since the external member of unit such as cabin, hood, pylon, root of blade flange gasket, joint bolt, linking springs etc. directly be exposed in the extreme corrosion atmosphere, adopt conventional safeguard procedures, often only several months just produce serious corrosion, therefore, wind-powered electricity generation external member surface treatment novel material and the novel process of weather resistance＞15 year are provided, have become the active demand of Wind Power Generation Industry development.
In addition, the corrosion prevention of boats and ships steel member also is a long-standing difficult problem, and except housing, deck, the corrosion prevention maintenance cost of various masts, antenna is very surprising.Along with the speed-raising of country to infrastructure development project, many bridge spanning the seas in succession go into operation or set up the project, such as port-Australia-pearl bridge etc.In the design and construction of bridge, the importance that the corrosion prevention of the steel member of different types of rridges is processed is more and more protruded.As in the construction of Hangzhou Gulf Great Bridge, surfacecti proteon is processed with regard to more than one hundred million units.
Therefore, the engineering component rotproofing problem of marine climate resistant in the urgent need to address is the effective way that solves the marine climate resistant corrosion in engineering component surface hot dip Al-Zn-Si series alloy coating in the prior art, has obtained a large amount of engineerings and has used.The application number that formerly proposes such as the applicant is 2009102627168, and denomination of invention adopts cast aluminium alloy to do rotproofing in " a kind of marine climate resistant engineering component carries out antiseptic method " patent application, and can arrive 20 years work-ing life.Yet there is technological temperature high (greater than 800 ℃) in the hot galvalizing alloy coating in this invention, easily causes part deformation; Wear resistance is not enough, and erosion resistance is not strong; Therefore the defectives such as technique, equipment are complicated, and the processing of big area workpiece and field work are restricted are used still to exist greatly and are limited.
In addition, the metal surface anticorrosive treatment technology of the seventies exploitation in last century, the sheet zinc-base chromic salts protective coating as common also is used to the protective treatment of offshore engineering component corrosion.Yet this coating contains sexavalent chrome, and certain pollution is arranged.And because the needs of passivation, bonding, generally all be added with the chromic anhydride of 5%-10%, and therefore Cr6+ strong toxicity and have carcinogenesis exists serious harm to environment and human body.In addition, this coating curing temperature is up to 300 ℃, and also reach about 30min set time, and energy consumption is large; Hardness is low, wears no resistance.Workpiece usually can be subject to scratch, scratch in transportation, assembling, use procedure, affect outward appearance and the solidity to corrosion of product.
Summary of the invention
For these problems in the prior art, the invention provides aluminium zinc silicon coating of a kind of environmental protection, the corrosion of water-soluble low-temperature immobilized marine climate resistant and preparation method thereof.
The coating that marine climate resistant engineering component rotproofing provided by the invention is used, wherein said coating comprises aluminium zinc silicon alloy powder, organic solvent, the nano-oxide particles toughener, deionized water, binding agent, corrosion inhibitor, dispersion agent and thickening material, wherein said formulation for coating material is with following proportioning: aluminium zinc silicon alloy powder: organic solvent: nano-oxide particles toughener: deionized water: binding agent: corrosion inhibitor: dispersion agent: thickening material=30.0-50.0g: 10.0-25.0mL: 1.0-4.0g: 15.0-30.0mL: 2.0-5.0g: 1.0-3.0g: 0.1-2.0mL: 0.1-2.0g, and wherein said aluminium zinc silicon alloy powder is by Al, Zn, Si, Mg, RE and Mn form.
The preferred ethylene glycol of wherein said organic solvent.
Wherein said binding agent preferred boric acid ester coupling agent.
Wherein said corrosion inhibitor preferred boric acid.
The preferred Natvosol of wherein said thickening material.
The preferred polysiloxane dipropylene glycol monomethyl ether of wherein said dispersion agent.
Preferably, wherein said nano-oxide particles toughener is selected from Al 2O 3, SiO 2In one or both.
Preferred, wherein said Al 2O 3Median size be 15～60nm, described SiO 2Median size be 25～70nm.
Preferred, wherein the nano-oxide particles toughener is SiO 2And Al 2O 3, and SiO 2And Al 2O 3Mass ratio is 1: (1～3).
Preferably, wherein said each composition mass percent of aluminium zinc silicon alloy powder is: Zn:35～58%, and Si:0.3～4.0%, Mg:0.1～5.0%, RE:0.02～1.0%, Mn:0.01～1.0%, surplus is Al and inevitable impurity.
Preferably, the mean diameter of wherein said aluminium zinc silicon alloy powder is 10-200 μ m.
On the other hand, the present invention also provides a kind of method for preparing the coating that described marine climate resistant engineering component rotproofing uses, wherein by above-mentioned prescription, take by weighing quantitative corrosion inhibitor, dissolve in the quantitative deionized water, then add binding agent, dispersion agent, organic solvent, stirring makes it dissolving, slowly adds aluminium zinc silicon alloy powder and nano-oxide particles toughener under whipped state, then adds thickening material, the temperature of control oil bath is 20-30 ℃ in the whipping process, stirs 0.5-1h.
Coating provided by the invention by the optimization to composition etc., has been developed first a kind of water-soluble chromium-free low-temp and has been solidified marine climate resistant corrosion Al-Zn-Si alloy coating.This coating has that environmental friendliness, condition are stable, coating prepares the characteristics such as energy consumption is low.
Water-soluble aluminum zinc silicon coating provided by the invention has been broken through the constraint that aluminum current zinc silicon coating mainly adopts hot-dipping method to prepare.Compare with techniques such as hot dips, the present invention is by adding binding agent, dispersion agent, organic solvents etc. are made metallic paint, can utilize the methods such as spraying, brushing to form coating at workpiece surface, preparation technology of coating temperature of the present invention low (200 ℃) has overcome the technical barriers such as workpiece deformation that hot galvalizing alloy coating process temperature high (greater than 600 ℃) causes and mechanical property reduction; Can utilize the methods such as spraying, brushing to form coating at workpiece surface, processing method, equipment are simple, are suitable for large complicated part and process, and have widened the Application of coatings scope.
Adopt coating of the present invention to make antiseptic engineering component and have many excellent properties, as: excellent solidity to corrosion, good scour resistance, and high heat/corrosion resistance is fabulous, even coating places under the hot conditions for a long time, its outward appearance can not change yet.Coating and the basal body binding force that the present invention is prepared is strong, corrosion resistant performance is excellent, wear resisting property good, long service life.Coating not only has stronger sticking power with metallic matrix in addition, simultaneously with other various additional coatings preferably bonding force is arranged also, just do not have inferior light silver gray attractive in appearance, can also become shades of colour by additional coatings, remedied simultaneously the lower deficiency of self hardness in the prior art.
Further by aluminium zinc silicon alloy is made micron-sized powder, corrosion-resistant, wear resistance, the erosion resistance of coating are greatly improved than hot dip aluminum plating zinc silicon coating and Aluminum Coating, be applicable to that atmosphere is rainy, the marine corrosive severe environment such as high temperature, many salt fogs and high wind stream, the corrosion-resistant means of defence of excellent combination property is provided for important engineering parts such as wind-powered electricity generation, boats and ships.
In sum, coating that the marine climate resistant engineering component rotproofing of the present invention's exploitation is used and preparation method thereof, solved engineering component marine corrosion problem in the urgent need to, in the corrosion engineering of the industrial equipments such as oceanographic engineering and coastal waters wind-powered electricity generation, have important application prospect.
Embodiment
The invention provides the water-soluble aluminum zinc silicon coating that a kind of marine climate resistant engineering component rotproofing is used, wherein said coating comprises aluminium zinc silicon alloy powder, organic solvent, nano-oxide particles toughener, deionized water, binding agent, corrosion inhibitor, dispersion agent and thickening material.
Below, associative list 1 provides some preferred embodiments of formulation for coating material proportioning of the present invention, but the content of each composition of the present invention is not limited to listed numerical value in this table, for a person skilled in the art, can in table, rationally summarize and reasoning on the basis of listed numerical range fully.
Table 1 formulation for coating material proportioning
Figure GSB00000843585000041
Wherein, described aluminium zinc silicon alloy powder is by Al, Zn, Si, Mg, RE and Mn form, below, associative list 2 provides some preferred embodiments of each composition mass percent of aluminium zinc silicon alloy powder of the present invention, but the content of each composition of aluminium zinc silicon alloy powder of the present invention is not limited to listed numerical value in this table, and of particular note, although listed the mass percent numerical value of relevant composition in the table 2, but these are described as essential features, all be as preferred condition, all to be in order providing in more detail about technical intelligence of the present invention, and to be described as prerequisite of the present invention.
Table 2: the mass percentage content (%) of each composition of aluminium zinc silicon alloy powder
Wherein, preferred, described organic solvent is ethylene glycol.
Preferably, described binding agent is boric acid ester coupler.
Preferably, described corrosion inhibitor is boric acid.
Preferably, described thickening material is Natvosol.
Preferably, described dispersion agent is the polysiloxane dipropylene glycol monomethyl ether.
Preferably, described nano-oxide particles toughener is selected from Al 2O 3, SiO 2In one or both.
Preferred, wherein said Al 2O 3Median size be 15～60nm.
Preferred, wherein said SiO 2Median size be 25～70nm.
Preferred, wherein the nano-oxide particles toughener is Al 2O 3And SiO 2, and SiO 2And Al 2O 3Mass ratio is 1: (1～3), preferred, SiO wherein 2And Al 2O 3Ratio is 1: 2.
Preferably, the mean diameter of wherein said aluminium zinc silicon alloy powder is 10-200 μ m.
On the other hand, the present invention also provides a kind of and has prepared the marine climate resistant engineering component rotproofing and with the technique of feature of environmental protection water-soluble aluminum zinc silicon coating preparation be: by above-mentioned prescription, take by weighing quantitative corrosion inhibitor, dissolve in the quantitative deionized water, then add binding agent, dispersion agent, organic solvent, stirring makes it dissolving, under whipped state, slowly add aluminium zinc silicon alloy powder and nano-oxide particles toughener, then add thickening material, the temperature of control oil bath is 20-30 ℃ in the whipping process, stirs 0.5-1h.The experimental performance data:
Certain inshore wind power generating set vital part " joint bolt " (material 40CrNiMo), the former protective treatment of adopting routine only namely produces significant corrosion after the several months.Adopt coating of the present invention to apply to form 20 μ m thick coatings, the thick polysiloxane of application 15 μ m again shows that through the accelerated corrosion analog reslt its main performance index that reaches is in seawater splash band environment:
Neutral salt spray corrosion life: greater than 1600 hours
300 ℃ of humidity resistances: 240 hours
Coating binding force: 50N
The quick corrosion life of ammonium nitrate: greater than 8 hours
Marine climate resistant corrosion life: greater than 20 years (short-time test)

Claims (11)

1. the coating used of marine climate resistant engineering component rotproofing, wherein said coating comprises aluminium zinc silicon alloy powder, organic solvent, the nano-oxide particles toughener, deionized water, binding agent, corrosion inhibitor, dispersion agent and thickening material, wherein said formulation for coating material is with following proportioning: aluminium zinc silicon alloy powder: organic solvent: nano-oxide particles toughener: deionized water: binding agent: corrosion inhibitor: dispersion agent: thickening material=30.0-50.0g: 10.0-25.0mL: 1.0-4.0g: 15.0-30.0mL: 2.0-5.0g: 1.0-3.0g: 0.1-2.0mL: 0.1-2.0g, wherein said aluminium zinc silicon alloy powder is by Al, Zn, Si, Mg, RE and Mn form, wherein said each composition mass percent of aluminium zinc silicon alloy powder is: Zn:35～58%, Si:0.3～4.0%, Mg:0.1～5.0%, RE:0.02～1.0%, Mn:0.01～1.0%, surplus are Al and inevitable impurity.
2. coating as claimed in claim 1, the preferred ethylene glycol of wherein said organic solvent.
3. coating as claimed in claim 1, wherein said binding agent preferred boric acid ester coupling agent.
4. coating as claimed in claim 1, wherein said corrosion inhibitor preferred boric acid.
5. coating as claimed in claim 1, the preferred Natvosol of wherein said thickening material.
6. coating as claimed in claim 1, the preferred polysiloxane dipropylene glycol monomethyl ether of wherein said dispersion agent.
7. coating as claimed in claim 1, wherein said nano-oxide particles toughener is selected from Al 2O 3, SiO 2In one or both.
8. coating as claimed in claim 7, wherein said Al 2O 3Median size be 15～60nm, described SiO 2Median size be 25～70nm.
9. such as claim 7 or 8 described coating, wherein the nano-oxide particles toughener is SiO 2And Al 2O 3, and SiO 2And Al 2O 3Mass ratio is 1: (1～3).
10. coating as claimed in claim 1, the mean diameter of wherein said aluminium zinc silicon alloy powder is 10-200 μ m.
11. method for preparing the coating that the described marine climate resistant engineering component rotproofing of claim 1 uses, wherein by above-mentioned prescription, take by weighing quantitative corrosion inhibitor, dissolve in the quantitative deionized water, then add binding agent, dispersion agent, organic solvent stirs and makes it dissolving, under whipped state, slowly add aluminium zinc silicon alloy powder and nano-oxide particles toughener, then add thickening material, the temperature of control oil bath is 20-30 ℃ in the whipping process, stirs 0.5-1h.
CN 201110034814 2010-11-04 2011-01-28 Marine climate resistant paint composed of magnesium-rare earth-manganese and used for preservative treatment Active CN102199370B (en)

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CN 201010587336 Active CN102086313B (en) 2010-11-04 2010-12-05 Magnesium-containing coating for marine climate-resistant anticorrosion treatment
CN 201010587357 Active CN102086314B (en) 2010-11-04 2010-12-05 Water-soluble aluminum-zinc-silicon paint for marine climate-resistant anticorrosion treatment
CN 201010593677 Active CN102002271B (en) 2010-11-04 2010-12-10 Rare earth-titanium-nickel-manganese-containing coating for preservative treatment resistant to marine climate
CN 201010593688 Active CN102002272B (en) 2010-11-04 2010-12-10 Anti-marine climatic coating containing magnesium-manganese for antiseptic treatment
CN 201010591241 Active CN102010624B (en) 2010-11-04 2010-12-12 Magnesium-nickel-containing coating for marine climate-resistant preservative treatment
CN 201010591243 Active CN102010625B (en) 2010-11-04 2010-12-12 Rare earth-titanium-nickel-containing sea climate resisting paint used for anti-corrosive treatment
CN 201010620373 Active CN102031028B (en) 2010-11-04 2010-12-19 Magnesium, rare earth and titanium-containing coating for marine climate-resistant preservative treatment
CN 201010620371 Active CN102146223B (en) 2010-11-04 2010-12-19 Coating containing titanium and manganese for ocean climate resistance preservative treatment
CN 201010623728 Active CN102070926B (en) 2010-11-04 2010-12-29 Rare earth-titanium-manganese-containing marine climate-resistant paint for antiseptic treatment
CN 201010623727 Active CN102146224B (en) 2010-11-04 2010-12-29 Coating containing magnesium and rare earth for ocean climate resistance preservative treatment
CN 201010623441 Active CN102070925B (en) 2010-11-04 2010-12-31 Rare-earth-containing marine-climate-resistance paint for anti-corrosive treatment
CN 201010623444 Active CN102086315B (en) 2010-11-04 2010-12-31 Magnesium-nickel-manganese-containing coating for marine climate-resistant anticorrosion treatment
CN 201110008863 Active CN102051077B (en) 2010-11-04 2011-01-07 Nickel-manganese-contained coating for anticorrosive treatment of marine climate resistant part
CN 201110008861 Active CN102167917B (en) 2010-11-04 2011-01-07 Magnesium, titanium and manganese-containing marine climate-resistant coating for antiseptic treatment
CN 201110008770 Active CN102051076B (en) 2010-11-04 2011-01-09 Nickel-containing marine-climate-resisting coating for preservative treatment
CN 201110008769 Active CN102127327B (en) 2010-11-04 2011-01-09 Magnesium-titanium-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110020601 Active CN102051078B (en) 2010-11-04 2011-01-13 Magnesium-titanium-nickel-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110020600 Active CN102153894B (en) 2010-11-04 2011-01-13 Manganese-containing coating for marine climate-resistant anti-corrosive treatment
CN 201110021550 Active CN102181180B (en) 2010-11-04 2011-01-16 Rare-earth-titanium-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110021571 Active CN102181181B (en) 2010-11-04 2011-01-16 Magnesium-titanium-nickel-manganese-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110027096 Active CN102181182B (en) 2010-11-04 2011-01-21 Maritime climate-resistant antiseptic coating containing rare earth and nickel
CN 201110027252 Active CN102181183B (en) 2010-11-04 2011-01-23 Titanium-containing coating for marine climate resistant anticorrosive treatment
CN 201110027266 Active CN102181184B (en) 2010-11-04 2011-01-23 Marine-climate-resistant anticorrosive paint containing magnesium (Mg)-rare earth (RE)-titanium (Ti)-nickel (Ni)-manganese (Mn)
CN 201110028975 Active CN102181186B (en) 2010-11-04 2011-01-25 Marine climate resistant titanium-nickel-containing coating for anticorrosion treatment
CN 201110028973 Active CN102181185B (en) 2010-11-04 2011-01-25 Maritime climate-resistant antiseptic coating containing magnesium, rare earth and nickel
CN 201110030707 Active CN102181189B (en) 2010-11-04 2011-01-26 Marine-climate-resistant anticorrosive paint containing rare-earth (RE)-nickel (Ni)-manganese (Mn)
CN 201110030700 Active CN102181188B (en) 2010-11-04 2011-01-26 Magnesium-rare earth-nickel-manganese-containing coating for marine climate resistance and antiseptic treatment
CN 201110032920 Active CN102051082B (en) 2010-11-04 2011-01-27 Rare earth-manganese-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110032928 Active CN102051079B (en) 2010-11-04 2011-01-27 Magnesium-rare earth-titanium-manganese-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110034814 Active CN102199370B (en) 2010-11-04 2011-01-28 Marine climate resistant paint composed of magnesium-rare earth-manganese and used for preservative treatment
CN 201110034815 Active CN102051080B (en) 2010-11-04 2011-01-28 Magnesium-rare earth-titanium-nickel-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110080917 Active CN102181190B (en) 2010-11-04 2011-03-27 Titanium-nickel-manganese containing coating for marine climate resistant anticorrosive treatment

Family Applications Before (29)

Application Number Title Priority Date Filing Date
CN 201010587336 Active CN102086313B (en) 2010-11-04 2010-12-05 Magnesium-containing coating for marine climate-resistant anticorrosion treatment
CN 201010587357 Active CN102086314B (en) 2010-11-04 2010-12-05 Water-soluble aluminum-zinc-silicon paint for marine climate-resistant anticorrosion treatment
CN 201010593677 Active CN102002271B (en) 2010-11-04 2010-12-10 Rare earth-titanium-nickel-manganese-containing coating for preservative treatment resistant to marine climate
CN 201010593688 Active CN102002272B (en) 2010-11-04 2010-12-10 Anti-marine climatic coating containing magnesium-manganese for antiseptic treatment
CN 201010591241 Active CN102010624B (en) 2010-11-04 2010-12-12 Magnesium-nickel-containing coating for marine climate-resistant preservative treatment
CN 201010591243 Active CN102010625B (en) 2010-11-04 2010-12-12 Rare earth-titanium-nickel-containing sea climate resisting paint used for anti-corrosive treatment
CN 201010620373 Active CN102031028B (en) 2010-11-04 2010-12-19 Magnesium, rare earth and titanium-containing coating for marine climate-resistant preservative treatment
CN 201010620371 Active CN102146223B (en) 2010-11-04 2010-12-19 Coating containing titanium and manganese for ocean climate resistance preservative treatment
CN 201010623728 Active CN102070926B (en) 2010-11-04 2010-12-29 Rare earth-titanium-manganese-containing marine climate-resistant paint for antiseptic treatment
CN 201010623727 Active CN102146224B (en) 2010-11-04 2010-12-29 Coating containing magnesium and rare earth for ocean climate resistance preservative treatment
CN 201010623441 Active CN102070925B (en) 2010-11-04 2010-12-31 Rare-earth-containing marine-climate-resistance paint for anti-corrosive treatment
CN 201010623444 Active CN102086315B (en) 2010-11-04 2010-12-31 Magnesium-nickel-manganese-containing coating for marine climate-resistant anticorrosion treatment
CN 201110008863 Active CN102051077B (en) 2010-11-04 2011-01-07 Nickel-manganese-contained coating for anticorrosive treatment of marine climate resistant part
CN 201110008861 Active CN102167917B (en) 2010-11-04 2011-01-07 Magnesium, titanium and manganese-containing marine climate-resistant coating for antiseptic treatment
CN 201110008770 Active CN102051076B (en) 2010-11-04 2011-01-09 Nickel-containing marine-climate-resisting coating for preservative treatment
CN 201110008769 Active CN102127327B (en) 2010-11-04 2011-01-09 Magnesium-titanium-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110020601 Active CN102051078B (en) 2010-11-04 2011-01-13 Magnesium-titanium-nickel-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110020600 Active CN102153894B (en) 2010-11-04 2011-01-13 Manganese-containing coating for marine climate-resistant anti-corrosive treatment
CN 201110021550 Active CN102181180B (en) 2010-11-04 2011-01-16 Rare-earth-titanium-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110021571 Active CN102181181B (en) 2010-11-04 2011-01-16 Magnesium-titanium-nickel-manganese-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110027096 Active CN102181182B (en) 2010-11-04 2011-01-21 Maritime climate-resistant antiseptic coating containing rare earth and nickel
CN 201110027252 Active CN102181183B (en) 2010-11-04 2011-01-23 Titanium-containing coating for marine climate resistant anticorrosive treatment
CN 201110027266 Active CN102181184B (en) 2010-11-04 2011-01-23 Marine-climate-resistant anticorrosive paint containing magnesium (Mg)-rare earth (RE)-titanium (Ti)-nickel (Ni)-manganese (Mn)
CN 201110028975 Active CN102181186B (en) 2010-11-04 2011-01-25 Marine climate resistant titanium-nickel-containing coating for anticorrosion treatment
CN 201110028973 Active CN102181185B (en) 2010-11-04 2011-01-25 Maritime climate-resistant antiseptic coating containing magnesium, rare earth and nickel
CN 201110030707 Active CN102181189B (en) 2010-11-04 2011-01-26 Marine-climate-resistant anticorrosive paint containing rare-earth (RE)-nickel (Ni)-manganese (Mn)
CN 201110030700 Active CN102181188B (en) 2010-11-04 2011-01-26 Magnesium-rare earth-nickel-manganese-containing coating for marine climate resistance and antiseptic treatment
CN 201110032920 Active CN102051082B (en) 2010-11-04 2011-01-27 Rare earth-manganese-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110032928 Active CN102051079B (en) 2010-11-04 2011-01-27 Magnesium-rare earth-titanium-manganese-containing maritime-climate-resistant paint for anti-corrosion treatment

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Families Citing this family (32)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102086313B (en) * 2010-11-04 2012-08-29 江苏麟龙新材料股份有限公司 Magnesium-containing coating for marine climate-resistant anticorrosion treatment
JP2014025015A (en) * 2012-07-30 2014-02-06 Kubota Corp Coating material
CN102850873B (en) * 2012-08-09 2015-03-18 义乌潘季涂料有限公司 Fluorescence electrophoretic paint and preparation method and application thereof
CN103087562B (en) * 2013-01-03 2015-04-15 张军 Magnesium-titanium-manganese-containing non-chrome zinc-aluminum coating anticorrosive paint
CN103232736B (en) * 2013-01-03 2015-09-23 魏放 A kind of Non-chromium Zn-al Coating protective system containing manganese-silicon
CN103059615B (en) * 2013-01-03 2015-04-22 解波 Titanium-manganese-silicon-containing chromium-free zinc aluminum coating corrosion-resistant coating
CN103275527B (en) * 2013-01-03 2015-08-19 魏放 A kind of Non-chromium Zn-al Coating protective system containing manganese
CN103044984B (en) * 2013-01-03 2015-06-17 管卫峰 Nickel-titanium-manganese-silicon-containing chromium-free zinc-aluminum coating anti-corrosive paint
CN103059616B (en) * 2013-01-03 2015-05-13 宿迁市三石包装容器有限公司 Nickel-magnesium-titanium-manganese-containing chromium-free zinc aluminum coating corrosion-resistant coating
CN103275526B (en) * 2013-01-03 2015-12-02 新昌县康泓机械科技有限公司 A kind of Non-chromium Zn-al Coating protective system of nickel-manganese-contained-silicon
CN103059614B (en) * 2013-01-03 2014-12-31 刘海生 Nickel-magnesium-containing chromium-free zinc aluminum coating corrosion-resistant coating
CN103044987B (en) * 2013-01-03 2015-05-27 张军 Nickel-titanium-silicon-containing chromium-free zinc-aluminum coating anti-corrosive paint
CN103087560B (en) * 2013-01-03 2014-12-31 李姗姗 Chrome-free zinc-aluminum-coating anti-corrosion paint containing Mg, Ti, Mn and Si
CN103232737B (en) * 2013-01-03 2015-07-22 魏放 Chrome-free zinc-aluminum coating anticorrosive paint comprising nickel-titanium-manganese
CN103275528B (en) * 2013-01-03 2015-09-23 魏放 A kind of Non-chromium Zn-al Coating protective system of titaniferous-manganese
CN103087561B (en) * 2013-01-03 2014-12-31 李姗姗 Chrome-free zinc-aluminum-coating anti-corrosion paint containing Ni, Mg and Mn
CN103031009B (en) * 2013-01-03 2014-12-31 刘海生 Non-chrome zinc-aluminum coating anticorrosive paint containing nickel-magnesium-silicon
CN103242686A (en) * 2013-03-28 2013-08-14 南京航空航天大学 High-corrosion-resistant water soluble zinc aluminium multielement alloy-based nano anticorrosion paint as well as preparation method and application thereof
CN103254733B (en) * 2013-05-20 2015-03-18 山东龙泉管道工程股份有限公司 Ocean heavy anti-corrosion epoxy aluminum-rare earth-rich nano-coating and preparation method thereof
CN103242738B (en) * 2013-05-20 2015-04-22 山东龙泉管道工程股份有限公司 Marine heavy anti-corrosion epoxy nano coating rich in aluminium, magnesium and rare earth and preparation method thereof
CN103242737B (en) * 2013-05-20 2015-04-22 山东龙泉管道工程股份有限公司 Marine heavy anti-corrosion epoxy nano coating rich in aluminium, manganese and rare earth and preparation method thereof
CN103254726B (en) * 2013-05-20 2015-06-24 山东龙泉管道工程股份有限公司 Ocean heavy anti-corrosion epoxy aluminum-magnesium-manganese-rare earth-rich nano-coating and preparation method thereof
CN103421994B (en) * 2013-07-31 2015-06-24 江苏麟龙新材料股份有限公司 Scale-like multi-element aluminum zinc silicon alloy powder containing La and Pr, and preparation method thereof
CN103788729A (en) * 2013-12-11 2014-05-14 青岛海洋新材料科技有限公司 Antirust coating
CN103709852B (en) * 2013-12-12 2016-06-22 青岛海洋新材料科技有限公司 A kind of marine climate resistant antirusting paint
CN104759399A (en) * 2014-01-07 2015-07-08 无锡新大中薄板有限公司 Method for manufacturing flocked aluminum alloy coating flower-blown plate for ocean engineering
CN104449254A (en) * 2014-11-20 2015-03-25 南京航空航天大学 Aluminum-zinc multi-component alloy-containing water-based epoxy coating for anti-corrosive treatment of submarine oil and gas pipelines and preparation method of water-based epoxy coating
CN105295585A (en) * 2015-11-30 2016-02-03 沈阳工业大学 Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint
CN105585883B (en) * 2016-03-04 2017-09-19 浙江大学 Low-temperature sintering coating and its painting method for steel bar anti-corrosion
CN108485323A (en) * 2018-03-29 2018-09-04 南京信息工程大学 A kind of coating material and preparation method thereof
CN113667382A (en) * 2021-09-14 2021-11-19 惠州市汉惠河环境科技有限公司 Water-based heavy-duty anticorrosion primer and preparation method thereof
CN116550577B (en) * 2023-04-14 2024-02-13 烟台大学 Coating treatment process for marine climate resistant engineering part surface coating

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5868819A (en) * 1996-05-20 1999-02-09 Metal Coatings International Inc. Water-reducible coating composition for providing corrosion protection
JP2000064024A (en) * 1998-08-17 2000-02-29 Nittetsu Hard Kk Molten metal-corrosion resistant film forming material and formation of film
US7138184B2 (en) * 2000-05-11 2006-11-21 Dow Corning Corporation Coating composition
EP1330499A2 (en) * 2000-10-11 2003-07-30 Chemteall GmbH Method for pretreating and subsequently coating metallic surfaces with a paint-type coating prior to forming and use of substrates coated in this way
WO2002088262A1 (en) * 2001-05-01 2002-11-07 Dow Corning Corporation Protective coating composition
JP4250080B2 (en) * 2001-09-11 2009-04-08 アクゾ ノーベル コーティングス インターナショナル ビー ヴィ Coating composition for metal substrates
WO2003066927A1 (en) * 2002-02-08 2003-08-14 Nichols Aluminium Method and apparatus for producing a solution heat treated sheet
CN1786091A (en) * 2005-11-14 2006-06-14 长春吉大化学有限公司 magnesium alloy non-chromium dacro solution paint and its preparation method
JP5190238B2 (en) * 2006-09-28 2013-04-24 新日鐵住金株式会社 High corrosion resistance rust-proof paint, high corrosion resistance steel material and steel structure
JP2008144059A (en) * 2006-12-11 2008-06-26 Tsubakimoto Chain Co Water-based rust-prevention coating
JP5130071B2 (en) * 2007-02-08 2013-01-30 新日鐵住金株式会社 Rust prevention method for marine steel
CN101613559A (en) * 2008-06-25 2009-12-30 云南格兰工业发展有限公司 Hydrophilic nano zinc based composite coating
CN101333350B (en) * 2008-07-02 2010-06-02 大连海事大学 Conductive anti-pollution paint for sea and method for preparing same
CN101338091B (en) * 2008-08-15 2010-06-09 上海达克罗涂复工业有限公司 Chromium-free metal anti-corrosive paint, preparation method and use method
CN101343506B (en) * 2008-08-28 2011-12-28 胡仲寅 Zinc metallic coating
CN101481553A (en) * 2008-11-06 2009-07-15 常州市纳罗可涂料有限公司 Normal temperature cured self-assembly composite nano oxide anti-corrosive paint
CN101418154A (en) * 2008-11-21 2009-04-29 哈尔滨工程大学 Method for preparing corrosion inhibition anion intercalated layered double hydroxides/oxide composite material and application
CN101693811B (en) * 2009-09-28 2011-09-07 常州捷迈特表面工程技术有限公司 Chromium-free waterborne corrosion resistant coating used for surface of metal and preparation method thereof
CN101709162B (en) * 2009-11-27 2014-03-05 沈阳黎明航空发动机(集团)有限责任公司 Coating for GH907 products under ocean environment and preparation and use methods thereof
CN101736222B (en) * 2009-12-28 2012-02-22 江苏麟龙新材料股份有限公司 Aluminum-silicon-zinc-rare earth-copper-containing hot dip coating alloy and method for preparing same
CN101748353B (en) * 2009-12-28 2012-02-15 江苏麟龙新材料股份有限公司 Method for antiseptic treatment of marine climate resistant engineering component
CN102086313B (en) * 2010-11-04 2012-08-29 江苏麟龙新材料股份有限公司 Magnesium-containing coating for marine climate-resistant anticorrosion treatment

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