CN102031028A - Magnesium, rare earth and titanium-containing coating for marine climate-resistant preservative treatment - Google Patents

Magnesium, rare earth and titanium-containing coating for marine climate-resistant preservative treatment Download PDF

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Publication number
CN102031028A
CN102031028A CN 201010620373 CN201010620373A CN102031028A CN 102031028 A CN102031028 A CN 102031028A CN 201010620373 CN201010620373 CN 201010620373 CN 201010620373 A CN201010620373 A CN 201010620373A CN 102031028 A CN102031028 A CN 102031028A
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coating
alloy powder
silicon alloy
nano
zinc silicon
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CN102031028B (en
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冯立新
张敏燕
缪强
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Jiangsu Linlong New Materials Co Ltd
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Jiangsu Linlong New Materials Co Ltd
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16—Antifouling paints; Underwater paints
    • C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C09D5/082—Anti-corrosive paints characterised by the anti-corrosive pigment
    • C09D5/084—Inorganic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Paints Or Removers (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Powder Metallurgy (AREA)

Abstract

The invention relates to a coating for marine climate-resistant engineering part preservative treatment. According to the formula, the coating contains the following components: aluminum, zinc and silicon alloy powder, an organic solvent, nano-oxide particle reinforcing agent, deionized water, a binder, a corrosion inhibitor, a dispersant and a thickening agent in a proportion of 30.0-50.0g:10.0-25.0mL:1.0-4.0g:15.0-30.0mL:2.0-5.0g:1.0-3.0g:0.1-2.0mL:0.1-2.0g, wherein the aluminum, zinc and silicon alloy powder consists of Al, Zn, Si, Mg, RE and Ti.

Description

Contain the coating that the marine climate resistant rotproofing of magnesium-rare earth-titanium is used
Technical field
The present invention relates to water-soluble aluminum zinc silicon coating that a kind of marine climate resistant engineering component rotproofing uses and preparation method thereof.
Background technology
Engineer equipment in coastal waters and ocean ambient atmosphere of living in is rainy, high temperature, many salt fogs and high wind stream, its service condition press ISO9225 environmental evaluation standard generally＞the C5 level, belong to extreme environment.Exposed part will be subjected to intensive atomospheric corrosion, galvanic corrosion and the comprehensive action of airflow scouring erosive, and the work-ing life of various steel construction is far below general landlocked outdoor environment.As the wind power plant of under the oceanic climate condition, being on active service since the external member of unit such as cabin, hood, pylon, root of blade flange gasket, joint bolt, connection spring etc. directly be exposed in the extreme corrosion atmosphere, adopt conventional safeguard procedures, often only several months just produce serious corrosion, therefore, the wind-powered electricity generation external member surface treatment novel material and the novel process of weather resistance＞15 year are provided, have become the active demand of wind-powered electricity generation industry development.
In addition, the corrosion prevention of boats and ships steel member also is a long-standing difficult problem, and except housing, deck, the corrosion prevention maintenance cost of various masts, antenna is very surprising.Along with the speed-raising of country to infrastructure development project, many bridge spanning the seas go into operation in succession or set up the project, as port-Australia-pearl bridge etc.In the design and construction of bridge, the importance that the corrosion prevention of the steel member of different types of rridges is handled is more and more protruded.As in the construction of Hangzhou Gulf Great Bridge, surfacecti proteon is handled with regard to more than one hundred million units.
Therefore, pressing for the engineering component rotproofing problem that solves marine climate resistant, is to solve marine climate resistant corrosive effective way in engineering component surface hot dip Al-Zn-Si series alloy coating in the prior art, has obtained a large amount of engineerings and has used.The application number that formerly proposes as the applicant is 2009102627168, and denomination of invention adopts cast aluminium alloy to do rotproofing in " a kind of marine climate resistant engineering component carries out antiseptic method " patent application, and can arrive 20 years work-ing life.Yet there is technological temperature height (greater than 800 ℃) in the hot dip alloy coat in this invention, easily causes part deformation; The wear resistance deficiency, the anti-impact erosion is indifferent; Therefore defectives such as technology, equipment are complicated, and processing of big area workpiece and field work are restricted are used still to exist greatly and are limited.
In addition, the metal surface anticorrosive treatment technology of the seventies exploitation in last century, the sheet zinc-base chromic salts protective coating as common also is used to the protective treatment of offshore engineering component corrosion.Yet this coating contains sexavalent chrome, and certain pollution is arranged.And because passivation, agglutinating need, generally all be added with the chromic anhydride of 5%-10%, and therefore Cr6+ strong toxicity and have carcinogenesis exists serious harm to environment and human body.In addition, this coating curing temperature is up to 300 ℃, and also reach about 30min set time, and energy consumption is big; Hardness is low, wears no resistance.Workpiece usually can be subjected to scratch, scratch in transportation, assembling, use, influence the outward appearance and the solidity to corrosion of product.
Summary of the invention
At these problems in the prior art, the invention provides a kind of environmental protection, water-soluble low-temperature immobilized marine climate resistant corrosive aluminium zinc silicon coating and preparation method thereof.
The coating that marine climate resistant engineering component rotproofing provided by the invention is used, wherein said coating comprises aluminium zinc silicon alloy powder, organic solvent, the nano-oxide particles toughener, deionized water, binding agent, corrosion inhibitor, dispersion agent and thickening material, wherein said formulation for coating material is with following proportioning: aluminium zinc silicon alloy powder: organic solvent: nano-oxide particles toughener: deionized water: binding agent: corrosion inhibitor: dispersion agent: thickening material=30.0-50.0g: 10.0-25.0mL: 1.0-4.0g: 15.0-30.0mL: 2.0-5.0g: 1.0-3.0g: 0.1-2.0mL: 0.1-2.0g, and wherein said aluminium zinc silicon alloy powder is by Al, Zn, Si, Mg, RE, Ti forms.
The preferred ethylene glycol of wherein said organic solvent.
Wherein said binding agent preferred boric acid fat coupling agent.
Wherein said corrosion inhibitor preferred boric acid.
The preferred Natvosol of wherein said thickening material.
The preferred polysiloxane dipropylene glycol monomethyl ether of wherein said dispersion agent.
Preferably, wherein said nano-oxide particles toughener is selected from Al 2O 3, SiO 2In one or both.
Preferred, wherein said Al 2O 3Median size be 15～60nm, described SiO 2Median size be 25～70nm.
Preferred, wherein the nano-oxide particles toughener is SiO 2And Al 2O 3, and SiO 2And Al 2O 3Mass ratio is 1: (1～3).
Preferably, wherein said each composition mass percent of aluminium zinc silicon alloy powder is: Zn:35～58%, and Si:0.3～4.0%, Mg:0.1～5.0%, RE:0.02～1.0%, Ti:0.01～0.5%, surplus is Al and unavoidable impurities.
Preferably, the mean diameter of wherein said aluminium zinc silicon alloy powder is 10-200 μ m.
On the other hand, the present invention also provides a kind of method for preparing the coating that described marine climate resistant engineering component rotproofing uses, wherein by above-mentioned prescription, take by weighing quantitative corrosion inhibitor, dissolve in the quantitative deionized water, add binding agent then, dispersion agent, organic solvent, stirring makes it dissolving, slowly adds aluminium zinc silicon alloy powder and nano-oxide particles toughener under whipped state, adds thickening material then, the temperature of control oil bath is 20-30 ℃ in the whipping process, stirs 0.5-1h.
Coating provided by the invention by the optimization to composition etc., has been developed a kind of water-soluble chromium-free low-temp first and has been solidified marine climate resistant corrosion Al-Zn-Si alloy coating.This coating has characteristics such as environmental friendliness, condition is stable, the coating preparation energy consumption is low.
Water-soluble aluminum zinc silicon coating provided by the invention has been broken through the constraint that aluminum current zinc silicon coating mainly adopts hot-dipping method to prepare.Compare with technologies such as hot dips, the present invention is by adding binding agent, dispersion agent, organic solvents etc. are made metallic paint, can utilize methods such as spraying, brushing to form coating at workpiece surface, preparation technology of coating temperature of the present invention low (200 ℃) has overcome technical barriers such as workpiece deformation that hot dip alloy coating technique temperature height (greater than 600 ℃) causes and mechanical property reduction; Can utilize methods such as spraying, brushing to form coating at workpiece surface, processing method, equipment are simple, are suitable for large complicated part and handle, and have widened the range of application of coating.
Adopt coating of the present invention to make antiseptic engineering component and have many excellent properties, as: excellent solidity to corrosion, good scour resistance, and high heat/corrosion resistance is fabulous, even coating places under the hot conditions for a long time, its outward appearance can not change yet.Coatings prepared of the present invention and basal body binding force are strong, corrosion resistant performance is excellent, wear resisting property is good, long service life.Coating not only has stronger sticking power with metallic matrix in addition, simultaneously bonding force is preferably also arranged with other various additional coatings, just do not have inferior light silver gray attractive in appearance, can also become shades of colour by additional coatings, remedied the lower deficiency of self hardness in the prior art simultaneously.
Further by aluminium zinc silicon alloy is made micron-sized powder, corrosion-resistant, wear resistance, the anti-impact erosion ability of coating are greatly improved than hot dip aluminum plating zinc silicon coating and Aluminum Coating, be applicable to that atmosphere is rainy, marine corrosive severe environment such as high temperature, many salt fogs and high wind stream, the corrosion-resistant means of defence of excellent combination property is provided for important engineering parts such as wind-powered electricity generation, boats and ships.
In sum, coating that the marine climate resistant engineering component rotproofing of the present invention's exploitation is used and preparation method thereof, solve pressing for of engineering component marine corrosion problem, in the corrosion engineering of industrial equipments such as oceanographic engineering and coastal waters wind-powered electricity generation, had important application prospects.
Embodiment
The invention provides the water-soluble aluminum zinc silicon coating that a kind of marine climate resistant engineering component rotproofing is used, wherein said coating comprises aluminium zinc silicon alloy powder, organic solvent, nano-oxide particles toughener, deionized water, binding agent, corrosion inhibitor, dispersion agent and thickening material.
Below, associative list 1 provides some preferred embodiments of formulation for coating material proportioning of the present invention, but the content of each composition of the present invention is not limited to listed numerical value in this table, for a person skilled in the art, fully can be in table rationally summarize and reasoning on the basis of listed numerical range.
Table 1 formulation for coating material proportioning
Figure BSA00000409396600041
Wherein, described aluminium zinc silicon alloy powder is by Al, Zn, Si, Mg, RE, Ti forms, below, associative list 2 provides some preferred embodiments of each composition mass percent of aluminium zinc silicon alloy powder of the present invention, but the content of each composition of aluminium zinc silicon alloy powder of the present invention is not limited to listed numerical value in this table, and of particular note, although listed the mass percent numerical value of relevant composition in the table 2, but these are described as essential features, all be as preferred condition, all to be in order providing in more detail, and to be described as prerequisite of the present invention about technical intelligence of the present invention.
Table 2: the mass percentage content (%) of each composition of aluminium zinc silicon alloy powder
Figure BSA00000409396600051
Wherein, preferred, described organic solvent is an ethylene glycol.
Preferably, described binding agent is a boric acid fat coupling agent.
Preferably, described corrosion inhibitor is a boric acid.
Preferably, described thickening material is a Natvosol.
Preferably, described dispersion agent is the polysiloxane dipropylene glycol monomethyl ether.
Preferably, described nano-oxide particles toughener is selected from Al 2O 3, SiO 2In one or both.
Preferred, wherein said Al 2O 3Median size be 15～60nm.
Preferred, wherein said SiO 2Median size be 25～70nm.
Preferred, wherein the nano-oxide particles toughener is Al 2O 3And SiO 2, and SiO 2And Al 2O 3Mass ratio is 1: (1～3), preferred, SiO wherein 2And Al 2O 3Ratio is 1: 2.
Preferably, the mean diameter of wherein said aluminium zinc silicon alloy powder is 10-200 μ m.
On the other hand, the present invention also provides a kind of and has prepared the marine climate resistant engineering component rotproofing and with the technology of feature of environmental protection water-soluble aluminum zinc silicon coating preparation be: by above-mentioned prescription, take by weighing quantitative corrosion inhibitor, dissolve in the quantitative deionized water, add binding agent then, dispersion agent, organic solvent, stirring makes it dissolving, under whipped state, slowly add aluminium zinc silicon alloy powder and nano-oxide particles toughener, add thickening material then, the temperature of control oil bath is 20-30 ℃ in the whipping process, stirs 0.5-1h.The experimental performance data:
Certain inshore wind power generating set vital part " joint bolt " (material 40CrNiMo), the former protective treatment of adopting routine only promptly produces significant corrosion after the several months.Adopt coating of the present invention to apply to form 20 μ m thick coatings, the thick polysiloxane of application 15 μ m again shows that through the accelerated corrosion analog reslt its main performance index that reaches is in seawater splash(spray)zone environment:
Neutral salt spray corrosion life: greater than 1600 hours
300 ℃ of humidity resistances: 240 hours
Coating bonding force: 50N
The quick corrosion life of ammonium nitrate: greater than 8 hours
Marine climate resistant corrosion life: greater than 20 years (short-time test)

Claims (12)

1. the coating used of marine climate resistant engineering component rotproofing, wherein said coating comprises aluminium zinc silicon alloy powder, organic solvent, the nano-oxide particles toughener, deionized water, binding agent, corrosion inhibitor, dispersion agent and thickening material, wherein said formulation for coating material is with following proportioning: aluminium zinc silicon alloy powder: organic solvent: nano-oxide particles toughener: deionized water: binding agent: corrosion inhibitor: dispersion agent: thickening material=30.0-50.0g: 10.0-25.0mL: 1.0-4.0g: 15.0-30.0mL: 2.0-5.0g: 1.0-3.0g: 0.1-2.0mL: 0.1-2.0g, and wherein said aluminium zinc silicon alloy powder is by Al, Zn, Si, Mg, RE, Ti forms.
2. coating as claimed in claim 1, the preferred ethylene glycol of wherein said organic solvent.
3. coating as claimed in claim 1, wherein said binding agent preferred boric acid fat coupling agent.
4. coating as claimed in claim 1, wherein said corrosion inhibitor preferred boric acid.
5. coating as claimed in claim 1, the preferred Natvosol of wherein said thickening material.
6. coating as claimed in claim 1, the preferred polysiloxane dipropylene glycol monomethyl ether of wherein said dispersion agent.
7. coating as claimed in claim 1, wherein said nano-oxide particles toughener is selected from Al 2O 3, SiO 2In one or both.
8. coating as claimed in claim 7, wherein said Al 2O 3Median size be 15～60nm, described SiO 2Median size be 25～70nm.
9. as claim 7 or 8 described coating, wherein the nano-oxide particles toughener is SiO 2And Al 2O 3, and SiO 2And Al 2O 3Mass ratio is 1: (1～3).
10. coating as claimed in claim 1, wherein said each composition mass percent of aluminium zinc silicon alloy powder is: Zn:35～58%, Si:0.3～4.0%, Mg:0.1～5.0%, RE:0.02～1.0%, Ti:0.01～0.5%, surplus is Al and unavoidable impurities.
11. coating as claimed in claim 1, the mean diameter of wherein said aluminium zinc silicon alloy powder is 10-200 μ m.
12. method for preparing the coating that the described marine climate resistant engineering component rotproofing of claim 1 uses, wherein, take by weighing quantitative corrosion inhibitor, dissolve in the quantitative deionized water by above-mentioned prescription, add binding agent then, dispersion agent, organic solvent stirs and makes it dissolving, under whipped state, slowly add aluminium zinc silicon alloy powder and nano-oxide particles toughener, add thickening material then, the temperature of control oil bath is 20-30 ℃ in the whipping process, stirs 0.5-1h.
CN 201010620373 2010-11-04 2010-12-19 Magnesium, rare earth and titanium-containing coating for marine climate-resistant preservative treatment Active CN102031028B (en)

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CN 201010587336 Active CN102086313B (en) 2010-11-04 2010-12-05 Magnesium-containing coating for marine climate-resistant anticorrosion treatment
CN 201010587357 Active CN102086314B (en) 2010-11-04 2010-12-05 Water-soluble aluminum-zinc-silicon paint for marine climate-resistant anticorrosion treatment
CN 201010593677 Active CN102002271B (en) 2010-11-04 2010-12-10 Rare earth-titanium-nickel-manganese-containing coating for preservative treatment resistant to marine climate
CN 201010593688 Active CN102002272B (en) 2010-11-04 2010-12-10 Anti-marine climatic coating containing magnesium-manganese for antiseptic treatment
CN 201010591241 Active CN102010624B (en) 2010-11-04 2010-12-12 Magnesium-nickel-containing coating for marine climate-resistant preservative treatment
CN 201010591243 Active CN102010625B (en) 2010-11-04 2010-12-12 Rare earth-titanium-nickel-containing sea climate resisting paint used for anti-corrosive treatment
CN 201010620373 Active CN102031028B (en) 2010-11-04 2010-12-19 Magnesium, rare earth and titanium-containing coating for marine climate-resistant preservative treatment
CN 201010620371 Active CN102146223B (en) 2010-11-04 2010-12-19 Coating containing titanium and manganese for ocean climate resistance preservative treatment
CN 201010623728 Active CN102070926B (en) 2010-11-04 2010-12-29 Rare earth-titanium-manganese-containing marine climate-resistant paint for antiseptic treatment
CN 201010623727 Active CN102146224B (en) 2010-11-04 2010-12-29 Coating containing magnesium and rare earth for ocean climate resistance preservative treatment
CN 201010623441 Active CN102070925B (en) 2010-11-04 2010-12-31 Rare-earth-containing marine-climate-resistance paint for anti-corrosive treatment
CN 201010623444 Active CN102086315B (en) 2010-11-04 2010-12-31 Magnesium-nickel-manganese-containing coating for marine climate-resistant anticorrosion treatment
CN 201110008863 Active CN102051077B (en) 2010-11-04 2011-01-07 Nickel-manganese-contained coating for anticorrosive treatment of marine climate resistant part
CN 201110008861 Active CN102167917B (en) 2010-11-04 2011-01-07 Magnesium, titanium and manganese-containing marine climate-resistant coating for antiseptic treatment
CN 201110008770 Active CN102051076B (en) 2010-11-04 2011-01-09 Nickel-containing marine-climate-resisting coating for preservative treatment
CN 201110008769 Active CN102127327B (en) 2010-11-04 2011-01-09 Magnesium-titanium-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110020601 Active CN102051078B (en) 2010-11-04 2011-01-13 Magnesium-titanium-nickel-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110020600 Active CN102153894B (en) 2010-11-04 2011-01-13 Manganese-containing coating for marine climate-resistant anti-corrosive treatment
CN 201110021550 Active CN102181180B (en) 2010-11-04 2011-01-16 Rare-earth-titanium-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110021571 Active CN102181181B (en) 2010-11-04 2011-01-16 Magnesium-titanium-nickel-manganese-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110027096 Active CN102181182B (en) 2010-11-04 2011-01-21 Maritime climate-resistant antiseptic coating containing rare earth and nickel
CN 201110027252 Active CN102181183B (en) 2010-11-04 2011-01-23 Titanium-containing coating for marine climate resistant anticorrosive treatment
CN 201110027266 Active CN102181184B (en) 2010-11-04 2011-01-23 Marine-climate-resistant anticorrosive paint containing magnesium (Mg)-rare earth (RE)-titanium (Ti)-nickel (Ni)-manganese (Mn)
CN 201110028975 Active CN102181186B (en) 2010-11-04 2011-01-25 Marine climate resistant titanium-nickel-containing coating for anticorrosion treatment
CN 201110028973 Active CN102181185B (en) 2010-11-04 2011-01-25 Maritime climate-resistant antiseptic coating containing magnesium, rare earth and nickel
CN 201110030707 Active CN102181189B (en) 2010-11-04 2011-01-26 Marine-climate-resistant anticorrosive paint containing rare-earth (RE)-nickel (Ni)-manganese (Mn)
CN 201110030700 Active CN102181188B (en) 2010-11-04 2011-01-26 Magnesium-rare earth-nickel-manganese-containing coating for marine climate resistance and antiseptic treatment
CN 201110032920 Active CN102051082B (en) 2010-11-04 2011-01-27 Rare earth-manganese-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110032928 Active CN102051079B (en) 2010-11-04 2011-01-27 Magnesium-rare earth-titanium-manganese-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110034814 Active CN102199370B (en) 2010-11-04 2011-01-28 Marine climate resistant paint composed of magnesium-rare earth-manganese and used for preservative treatment
CN 201110034815 Active CN102051080B (en) 2010-11-04 2011-01-28 Magnesium-rare earth-titanium-nickel-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110080917 Active CN102181190B (en) 2010-11-04 2011-03-27 Titanium-nickel-manganese containing coating for marine climate resistant anticorrosive treatment

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CN 201010587336 Active CN102086313B (en) 2010-11-04 2010-12-05 Magnesium-containing coating for marine climate-resistant anticorrosion treatment
CN 201010587357 Active CN102086314B (en) 2010-11-04 2010-12-05 Water-soluble aluminum-zinc-silicon paint for marine climate-resistant anticorrosion treatment
CN 201010593677 Active CN102002271B (en) 2010-11-04 2010-12-10 Rare earth-titanium-nickel-manganese-containing coating for preservative treatment resistant to marine climate
CN 201010593688 Active CN102002272B (en) 2010-11-04 2010-12-10 Anti-marine climatic coating containing magnesium-manganese for antiseptic treatment
CN 201010591241 Active CN102010624B (en) 2010-11-04 2010-12-12 Magnesium-nickel-containing coating for marine climate-resistant preservative treatment
CN 201010591243 Active CN102010625B (en) 2010-11-04 2010-12-12 Rare earth-titanium-nickel-containing sea climate resisting paint used for anti-corrosive treatment

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CN 201010620371 Active CN102146223B (en) 2010-11-04 2010-12-19 Coating containing titanium and manganese for ocean climate resistance preservative treatment
CN 201010623728 Active CN102070926B (en) 2010-11-04 2010-12-29 Rare earth-titanium-manganese-containing marine climate-resistant paint for antiseptic treatment
CN 201010623727 Active CN102146224B (en) 2010-11-04 2010-12-29 Coating containing magnesium and rare earth for ocean climate resistance preservative treatment
CN 201010623441 Active CN102070925B (en) 2010-11-04 2010-12-31 Rare-earth-containing marine-climate-resistance paint for anti-corrosive treatment
CN 201010623444 Active CN102086315B (en) 2010-11-04 2010-12-31 Magnesium-nickel-manganese-containing coating for marine climate-resistant anticorrosion treatment
CN 201110008863 Active CN102051077B (en) 2010-11-04 2011-01-07 Nickel-manganese-contained coating for anticorrosive treatment of marine climate resistant part
CN 201110008861 Active CN102167917B (en) 2010-11-04 2011-01-07 Magnesium, titanium and manganese-containing marine climate-resistant coating for antiseptic treatment
CN 201110008770 Active CN102051076B (en) 2010-11-04 2011-01-09 Nickel-containing marine-climate-resisting coating for preservative treatment
CN 201110008769 Active CN102127327B (en) 2010-11-04 2011-01-09 Magnesium-titanium-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110020601 Active CN102051078B (en) 2010-11-04 2011-01-13 Magnesium-titanium-nickel-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110020600 Active CN102153894B (en) 2010-11-04 2011-01-13 Manganese-containing coating for marine climate-resistant anti-corrosive treatment
CN 201110021550 Active CN102181180B (en) 2010-11-04 2011-01-16 Rare-earth-titanium-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110021571 Active CN102181181B (en) 2010-11-04 2011-01-16 Magnesium-titanium-nickel-manganese-containing marine-climate-resistant paint for anti-corrosion treatment
CN 201110027096 Active CN102181182B (en) 2010-11-04 2011-01-21 Maritime climate-resistant antiseptic coating containing rare earth and nickel
CN 201110027252 Active CN102181183B (en) 2010-11-04 2011-01-23 Titanium-containing coating for marine climate resistant anticorrosive treatment
CN 201110027266 Active CN102181184B (en) 2010-11-04 2011-01-23 Marine-climate-resistant anticorrosive paint containing magnesium (Mg)-rare earth (RE)-titanium (Ti)-nickel (Ni)-manganese (Mn)
CN 201110028975 Active CN102181186B (en) 2010-11-04 2011-01-25 Marine climate resistant titanium-nickel-containing coating for anticorrosion treatment
CN 201110028973 Active CN102181185B (en) 2010-11-04 2011-01-25 Maritime climate-resistant antiseptic coating containing magnesium, rare earth and nickel
CN 201110030707 Active CN102181189B (en) 2010-11-04 2011-01-26 Marine-climate-resistant anticorrosive paint containing rare-earth (RE)-nickel (Ni)-manganese (Mn)
CN 201110030700 Active CN102181188B (en) 2010-11-04 2011-01-26 Magnesium-rare earth-nickel-manganese-containing coating for marine climate resistance and antiseptic treatment
CN 201110032920 Active CN102051082B (en) 2010-11-04 2011-01-27 Rare earth-manganese-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110032928 Active CN102051079B (en) 2010-11-04 2011-01-27 Magnesium-rare earth-titanium-manganese-containing maritime-climate-resistant paint for anti-corrosion treatment
CN 201110034814 Active CN102199370B (en) 2010-11-04 2011-01-28 Marine climate resistant paint composed of magnesium-rare earth-manganese and used for preservative treatment
CN 201110034815 Active CN102051080B (en) 2010-11-04 2011-01-28 Magnesium-rare earth-titanium-nickel-containing maritime-climate-resistant paint for anti-corrosion treatment
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