CN105295585A - Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint - Google Patents
Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint Download PDFInfo
- Publication number
- CN105295585A CN105295585A CN201510850528.2A CN201510850528A CN105295585A CN 105295585 A CN105295585 A CN 105295585A CN 201510850528 A CN201510850528 A CN 201510850528A CN 105295585 A CN105295585 A CN 105295585A
- Authority
- CN
- China
- Prior art keywords
- parts
- oxide
- nano
- metal component
- antifouling
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention belongs to the technical field of metal corrosion resistance, and particularly relates to novel paint for anti-fouling and anti-corrosion treatment on a marine metal component. The novel paint comprises the following ingredients: 15-20 parts of epoxy resin, 1-5 parts of a corrosion inhibitor, 15-24 parts of fluorocarbon resin, 1-3 parts of a dispersing agent, 15-25 parts of Al-Zn-Ni alloy powder, 0.6-1 part of a bonding agent, 15-20 parts of an organic solvent, 2-9 parts of an anti-foaming agent, 5-10 parts of a nanometer oxide or a modified nanometer oxide, 1-4 parts of a thickening agent and 10-20 parts of deionized water. A preparation method of the novel paint comprises the following steps: (1) adding the organic solvent, the deionized water, epoxy resin and fluorocarbon resin in sequence according to a certain ratio; (2) adding the anti-foaming agent and the dispersing agent in sequence; (3) adding the Al-Zn-Ni alloy powder, the nanometer oxide or the modified nanometer oxide, the corrosion inhibitor, the thickening agent and the bonding agent in sequence; (4) continuously stirring the mixture to obtain a target product, namely the novel paint. The novel paint is high in bonding property, long in corrosion life, ideal in moisture and heat resistance, and remarkable in environmental protection performance.
Description
Technical field
The invention belongs to technical field of metal anti-corrosion, particularly relate to that a kind of marine metal component is antifouling, rotproofing new coating and preparation method thereof.
Background technology
China has more than 18000 kilometer of shoreline, has abundant oceanic resources and flourish marine industries, but due to the singularity of briny environment (containing Cl-and a large amount of microorganisms etc.), and ocean environment is very harsh and have severe corrosive.Seawater has that saltiness is high, electroconductibility is strong, O2 and CO2 is tending towards saturated in surface seawater, pH value reaches about 8.2, specific conductivity is considerably beyond river and rain electrical conductivity of water, there is corrosive natural electrolytes solution, cause the immersion metal generation galvanic action in the seawater that makes in seawater to cause galvanic effect.In addition, the marine organisms of kind more than 210,000 of living in seawater have, and wherein have some animals and plants and microbes to be attached on oceanographic engineering material, form biodeterioration.Add up according to investigations, there is the marine fouling organism of about 2000 kinds in the whole world, and in China's Coastal Areas, main fouling organism is approximately 200 kinds, and they are perched mostly at bank and bay place, and biodeterioration also can aggravate oceanographic engineering material corrosion.Result of study shows, marine organisms adhere to the marime fouling caused at marine surface will increase roughness, the reduction speed of a ship or plane, the increase fuel consumption of hull surface, increase maintenance meaningless in a large number and running cost.China is not less than 90,000,000,000 yuan because corroding the economy damage caused every year, and the ratio of marine corrosion reaches more than 30%, and wherein 30% of marine material corrosion total amount is relevant with marine microorganism attachment.
In recent years, along with the progress of science and technology, marine industry obtains fast development, and the major fields that offshore drilling, seawater are fished for, ocean shipping, coastal engineering etc. have become people's development & construction, the vast oceans will give great riches more.But the corrosion of ocean and pollution problem again moment challenger people develop the means of ocean, be also determine one of key developing ocean success and failure simultaneously.In the important means that engineering component external coating coating is solution marine anti-pollution, Anticorrosion, along with the rise of marine cause, Marine Paints also obtain huge development.But some contains the heavy metal ion such as copper, tin in existing coating, meeting Marine Pollution to a certain extent, the physical strength of some coating is not high, can not meet actual needs, also has the high cost of some coating, and inapplicable industrialization is produced.So research and development one class environmental friendliness and can meet that the green of needs of production is anticorrosion, antifouling paint just seems very important.
Summary of the invention
The present invention is intended to overcome the deficiencies in the prior art part and provide a kind of bonding force high, and corrosion life is long, and humidity resistance is desirable, and environmental protection efficacy significant marine metal component is antifouling, rotproofing new coating and preparation method thereof.
For solving the problems of the technologies described above, the present invention realizes like this.
When adopting nano-oxide, marine metal component of the present invention is antifouling, rotproofing new coating, in mass parts, comprises following component:
Epoxy resin 15 ~ 20 parts; Corrosion inhibitor 1 ~ 5 part;
Fluorocarbon resin 15 ~ 24 parts; Dispersion agent 1 ~ 3 part;
15 ~ 25 parts, aluminium admiro powder; Binding agent 0.6 ~ 1 part;
Organic solvent 15 ~ 20 parts; Defoamer 2 ~ 9 parts;
Nano-oxide 5 ~ 10 parts; Thickening material 1 ~ 4 part;
Deionized water 10 ~ 20 parts.
Preferably, nano-oxide of the present invention is one or more the mixture in nano aluminium oxide, nano-titanium oxide, nano zine oxide.
Further, organic solvent of the present invention is ethylene glycol; Described defoamer is propyl carbinol; Described corrosion inhibitor is boric acid; Described dispersion agent is dipropylene glycol.
Above-mentioned marine metal component is antifouling, rotproofing new coating, can implement as follows.
(1) by measuring the organic solvent, deionized water, epoxy resin, the fluorocarbon resin that add successively under agitation.
(2) defoamer and dispersion agent is added successively.
(3) aluminium admiro powder, nano-oxide, corrosion inhibitor, thickening material and binding agent is added successively after continuing stirring.
(4) Keep agitation, obtains object product.
Further, in step of the present invention (1), low whipping speed is add organic solvent, deionized water, epoxy resin, fluorocarbon resin successively under the condition of 200r/min; In described step (2), after stirring 60 ~ 80min, add defoamer, dispersion agent successively; In described step (3), after continuing stirring 80 ~ 120min, add aluminium admiro powder, nano-oxide, corrosion inhibitor, thickening material and binding agent successively; In described step (4), Keep agitation 30 ~ 60min, obtains object product.
When adopting modified nano oxide compound, marine metal component of the present invention is antifouling, rotproofing new coating, in mass parts, comprises following component:
Epoxy resin 15 ~ 20 parts; Corrosion inhibitor 1 ~ 5 part;
Fluorocarbon resin 15 ~ 24 parts; Dispersion agent 1 ~ 3 part;
15 ~ 25 parts, aluminium admiro powder; Binding agent 0.6 ~ 1 part;
Organic solvent 15 ~ 20 parts; Defoamer 2 ~ 9 parts;
Modified nano oxide compound 5 ~ 10 parts; Thickening material 1 ~ 4 part;
Deionized water 10 ~ 20 parts.
Further, modified nano oxide compound of the present invention is one or more the mixture in modified nano-alumina, modified Nano titanium oxide, modified nano zinc oxide.
Further, organic solvent of the present invention is ethylene glycol; Described defoamer is propyl carbinol; Described corrosion inhibitor is boric acid; Described dispersion agent is dipropylene glycol.
Further, the preparation method of modified nano oxide compound of the present invention implements as follows: the ratio being followed successively by 6.5:0.1:1 in quality proportioning takes propyl alcohol, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester and nano-oxide respectively; First propyl alcohol and sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester are mixed, then nano-oxide is added, after at ambient temperature gained mixture being stirred 2 hours with the stirring velocity of 250r/min, utilize vacuum filtration to carry out solid-liquid separation, after being dried under 70 DEG C of conditions by solid, namely obtain modified nano oxide compound.
Above-mentioned marine metal component is antifouling, rotproofing new coating, it is characterized in that, implements as follows:
(1) by measuring the organic solvent, deionized water, epoxy resin, the fluorocarbon resin that add successively under agitation;
(2) defoamer and dispersion agent is added successively;
(3) aluminium admiro powder, modified nano oxide compound, corrosion inhibitor, thickening material and binding agent is added successively after continuing stirring;
(4) Keep agitation, obtains object product.
Bonding force of the present invention is high, and corrosion life is long, and humidity resistance is desirable, and environmental protection efficacy is remarkable.Adopt coating of the present invention on Q235 steel disc, apply the thick coating of formation 80 μm, show that its bonding force is higher than 70N in seawater splash band environment through accelerated corrosion analog reslt, the Neutral Salt Spray Corrosion life-span is greater than 1800 hours, 300 DEG C of humidity resistances are greater than 260 hours, the ammonium nitrate fast erosion life-span is greater than 10 hours, and marine climate resistant corrosion life is greater than 22 years (quick life-span).
Embodiment
Below in conjunction with specific embodiment, the invention will be further described.Protection scope of the present invention is not only confined to the statement of following content.
Embodiment 1.
Marine metal component is antifouling, rotproofing new coating, in mass parts, comprises following component:
Organic solvent (ethylene glycol) 15 parts; 5 parts, modification rod-like nano aluminum oxide;
Deionized water 20 parts; Epoxy resin 15 parts;
Fluorocarbon resin 24 parts; Defoamer (propyl carbinol) 2 parts;
Dispersion agent (dipropylene glycol) 1 part; Thickening material (diatomite) 1 part;
15 parts, the aluminium admiro powder mass ratio 3:2:5 of metallic aluminium, zinc, nickel (in the alloy);
Corrosion inhibitor (boric acid) 1 part; Binding agent (boric acid coupling agent) 1 part.
Above-mentioned marine metal component is antifouling, the preparation method of rotproofing new coating, can implement as follows.
1. low whipping speed is add the organic solvent (ethylene glycol) of 15 parts, the deionized water of 20 parts, the epoxy resin of 15 parts, the fluorocarbon resin of 24 parts under the condition of 200r/min successively; 2. 2 parts of defoamers (propyl carbinol), 1 part of dispersion agent (dipropylene glycol) is added successively after stirring 80min; 3. continue to stir and to add the 15 parts of aluminium admiro powder mass ratio 3:2:5 of metallic aluminium, zinc, nickel (in the alloy), 5 parts of modification rod-like nano aluminum oxide, 1 part of corrosion inhibitor (boric acid), 1 part of thickening material (diatomite), 1 part of binding agent (boric acid coupling agent) after 80min successively; 4. after all the components interpolation, Keep agitation 60min obtains qualified coating.
The preparation method of described modification rod-like nano aluminum oxide implements as follows: the ratio being followed successively by 6.5:0.1:1 in quality proportioning takes propyl alcohol, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester and rod-like nano aluminum oxide respectively; First propyl alcohol and sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester are mixed, then rod-like nano aluminum oxide is added, after at ambient temperature gained mixture being stirred 2 hours with the stirring velocity of 250r/min, utilize vacuum filtration to carry out solid-liquid separation, after being dried under 70 DEG C of conditions by solid, namely obtain modification rod-like nano aluminum oxide.
Adopt coating of the present invention on Q235 steel disc, apply the thick coating of formation 80 μm, show that its bonding force is higher than 70N in seawater splash band environment through accelerated corrosion analog reslt, the Neutral Salt Spray Corrosion life-span is greater than 1800 hours, 300 DEG C of humidity resistances are greater than 260 hours, the ammonium nitrate fast erosion life-span is greater than 10 hours, and marine climate resistant corrosion life is greater than 22 years (quick life-span).
Embodiment 2.
Marine metal component is antifouling, rotproofing new coating, in mass parts, comprises following component:
Organic solvent (ethylene glycol) 20 parts; Deionized water 10 parts;
Epoxy resin 20 parts; Fluorocarbon resin 15 parts;
Defoamer (propyl carbinol) 9 parts; Dispersion agent (dipropylene glycol) 3 parts;
15 parts, the aluminium admiro powder mass ratio 2:5:3 of metallic aluminium, zinc, nickel (in the alloy);
Modified sheeted nanometer titanium oxide 5 parts; Corrosion inhibitor (boric acid) 1 part;
Thickening material (diatomite) 1 part; Binding agent (boric acid coupling agent) 1 part.
Above-mentioned marine metal component is antifouling, the preparation method of rotproofing new coating, can implement as follows.
1. low whipping speed is add the organic solvent (ethylene glycol) of 20 parts, the deionized water of 10 parts, the epoxy resin of 20 parts, the fluorocarbon resin of 15 parts under the condition of 200r/min successively; 2. 9 parts of defoamers (propyl carbinol), 3 parts of dispersion agents (dipropylene glycol) are added successively after stirring 60min; 3. continue to stir and to add the 15 parts of aluminium admiro powder mass ratio 2:5:3 of metallic aluminium, zinc, nickel (in the alloy), 5 parts of modified sheeted nanometer titanium oxide, 1 part of corrosion inhibitor (boric acid), 1 part of thickening material (diatomite), 1 part of binding agent (boric acid coupling agent) after 120min successively; 4. after all the components interpolation, Keep agitation 50min obtains qualified coating.
The preparation method of described modified sheeted nanometer titanium oxide implements as follows: the ratio being followed successively by 6.5:0.1:1 in quality proportioning takes propyl alcohol, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester and flake nano titanium oxide respectively; First propyl alcohol and sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester are mixed, then flake nano titanium oxide is added, after at ambient temperature gained mixture being stirred 2 hours with the stirring velocity of 250r/min, utilize vacuum filtration to carry out solid-liquid separation, after being dried under 70 DEG C of conditions by solid, namely obtain modified sheeted nanometer titanium oxide.
Adopt coating of the present invention on Q235 steel disc, apply the thick coating of formation 80 μm, show that its bonding force is higher than 70N in seawater splash band environment through accelerated corrosion analog reslt, the Neutral Salt Spray Corrosion life-span is greater than 1800 hours, 300 DEG C of humidity resistances are greater than 260 hours, the ammonium nitrate fast erosion life-span is greater than 10 hours, and marine climate resistant corrosion life is greater than 22 years (quick life-span).
Embodiment 3.
Marine metal component is antifouling, rotproofing new coating, in mass parts, comprises following component:
Organic solvent (ethylene glycol) 15 parts; Deionized water 10 parts;
Epoxy resin 15 parts of fluorocarbon resins 15 parts;
Defoamer (propyl carbinol) 3 parts; Dispersion agent (dipropylene glycol) 2.4 parts;
25 parts, the aluminium admiro powder mass ratio 1:5:4 of metallic aluminium, zinc, nickel (in the alloy);
5 parts, modified sheeted nanometer zinc oxide; Corrosion inhibitor (boric acid) 5 parts;
Thickening material (diatomite) 4 parts; Binding agent (boric acid coupling agent) 0.6 part.
Above-mentioned marine metal component is antifouling, the preparation method of rotproofing new coating, can implement as follows.
1. low whipping speed is add the organic solvent (ethylene glycol) of 15 parts, the deionized water of 10 parts, the epoxy resin of 15 parts, the fluorocarbon resin of 15 parts under the condition of 200r/min successively; 2. 3 parts of defoamers (propyl carbinol), 2.4 parts of dispersion agents (dipropylene glycol) are added successively after stirring 60min; 3. continue to stir and to add the 25 parts of aluminium admiro powder mass ratio 1:5:4 of metallic aluminium, zinc, nickel (in the alloy), 5 parts of modified sheeted nanometer zinc oxide, 5 parts of corrosion inhibitors (boric acid), 4 parts of thickening materials (diatomite), 0.6 part of binding agent (boric acid coupling agent) after 120min successively; 4. after all the components interpolation, Keep agitation 60min obtains qualified coating.
The preparation method of described modified sheeted nanometer zinc oxide implements as follows: the ratio being followed successively by 6.5:0.1:1 in quality proportioning takes propyl alcohol, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester and flaky nanometer zinc oxide respectively; First propyl alcohol and sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester are mixed, then flaky nanometer zinc oxide is added, after at ambient temperature gained mixture being stirred 2 hours with the stirring velocity of 250r/min, utilize vacuum filtration to carry out solid-liquid separation, after being dried under 70 DEG C of conditions by solid, namely obtain modified sheeted nanometer zinc oxide.
Adopt coating of the present invention on Q235 steel disc, apply the thick coating of formation 80 μm, show that its bonding force is higher than 70N in seawater splash band environment through accelerated corrosion analog reslt, the Neutral Salt Spray Corrosion life-span is greater than 1800 hours, 300 DEG C of humidity resistances are greater than 260 hours, the ammonium nitrate fast erosion life-span is greater than 10 hours, and marine climate resistant corrosion life is greater than 22 years (quick life-span).
Embodiment 4.
Marine metal component is antifouling, rotproofing new coating, in mass parts, comprises following component:
Organic solvent (ethylene glycol) 15 parts; Deionized water 10 parts;
Epoxy resin 17 parts; Fluorocarbon resin 16 parts;
Defoamer (propyl carbinol) 5 parts; Dispersion agent (dipropylene glycol) 2 parts.
18 parts, the aluminium admiro powder mass ratio 2:3:5 of metallic aluminium, zinc, nickel (in the alloy),
Modified nano oxide compound (mixture of modified nano-alumina, modified Nano titanium oxide, modified nano zinc oxide, wherein the mass values of modified nano-alumina, modified Nano titanium oxide, modified nano zinc oxide is 1:3:1) 10 parts.
Corrosion inhibitor (boric acid) 2 parts; Thickening material (diatomite) 4 parts; Binding agent (boric acid coupling agent) 1 part.
Above-mentioned marine metal component is antifouling, the preparation method of rotproofing new coating, can implement as follows.
1. low whipping speed is add the organic solvent (ethylene glycol) of 15 parts, the deionized water of 10 parts, the epoxy resin of 17 parts, the fluorocarbon resin of 16 parts under the condition of 200r/min successively; 2. 5 parts of defoamers (propyl carbinol), 2 parts of dispersion agents (dipropylene glycol) are added successively after stirring 70min; 3. continue to stir and to add the 18 parts of aluminium admiro powder mass ratio 2:3:5 of metallic aluminium, zinc, nickel (in the alloy), 10 parts of modified nano oxide compounds (mixture of aluminum oxide, titanium oxide, zinc oxide, wherein the mass values of aluminum oxide, titanium oxide, zinc oxide is 1:3:1), 2 parts of corrosion inhibitors (boric acid), 4 parts of thickening materials (diatomite), 1 part of binding agent (boric acid coupling agent) after 100min successively; 4. after all the components interpolation, Keep agitation 50min obtains qualified coating.
The preparation method of described modified nano-alumina, modified Nano titanium oxide or modified nano zinc oxide implements as follows: the ratio being followed successively by 6.5:0.1:1 in quality proportioning takes propyl alcohol, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester and nano aluminium oxide, nano-titanium oxide or nano zine oxide respectively; First propyl alcohol and sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester are mixed, then nano aluminium oxide, nano-titanium oxide or nano zine oxide is added, after at ambient temperature gained mixture being stirred 2 hours with the stirring velocity of 250r/min, utilize vacuum filtration to carry out solid-liquid separation, after being dried under 70 DEG C of conditions by solid, namely obtain modified nano-alumina, modified Nano titanium oxide or modified nano zinc oxide.Adopt coating of the present invention on Q235 steel disc, apply the thick coating of formation 80 μm, show that its bonding force is higher than 70N in seawater splash band environment through accelerated corrosion analog reslt, the Neutral Salt Spray Corrosion life-span is greater than 1800 hours, 300 DEG C of humidity resistances are greater than 260 hours, the ammonium nitrate fast erosion life-span is greater than 10 hours, and marine climate resistant corrosion life is greater than 22 years (quick life-span).
Embodiment 5.
Marine metal component is antifouling, rotproofing new coating, it is characterized in that, in mass parts, comprises following component:
Epoxy resin 18 parts; Corrosion inhibitor 3 parts;
Fluorocarbon resin 18 parts; Dispersion agent 2 parts;
17 parts, aluminium admiro powder; Binding agent (boric acid coupling agent) 0.8 part;
Organic solvent 16 parts; Defoamer 6 parts;
Nano zine oxide 8 parts; Thickening material (diatomite) 3 parts;
Deionized water 12 parts.
Above-mentioned marine metal component is antifouling, the preparation method of rotproofing new coating, can implement as follows.
1. low whipping speed is add 16 parts of organic solvents (ethylene glycol), the deionized water of 12 parts, the epoxy resin of 18 parts, the fluorocarbon resin of 18 parts under the condition of 200r/min successively; 2. 6 parts of defoamers (propyl carbinol), 2 parts of dispersion agents (dipropylene glycol) are added successively after stirring 60min; 3. continue to stir and to add the 17 parts of aluminium admiro powder mass ratio 1:5:4 of metallic aluminium, zinc, nickel (in the alloy), 8 parts of nano zine oxides, 3 parts of corrosion inhibitors (boric acid), 3 parts of thickening materials, 0.8 part of binding agent after 120min successively; 4. after all the components interpolation, Keep agitation 60min obtains qualified coating.
Adopt coating of the present invention on Q235 steel disc, apply the thick coating of formation 80 μm, show that its bonding force is higher than 70N in seawater splash band environment through accelerated corrosion analog reslt, the Neutral Salt Spray Corrosion life-span is greater than 1800 hours, 300 DEG C of humidity resistances are greater than 260 hours, the ammonium nitrate fast erosion life-span is greater than 10 hours, and marine climate resistant corrosion life is greater than 22 years (quick life-span).
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. antifouling, the rotproofing new coating of marine metal component, is characterized in that, in mass parts, comprise following component:
Epoxy resin 15 ~ 20 parts; Corrosion inhibitor 1 ~ 5 part;
Fluorocarbon resin 15 ~ 24 parts; Dispersion agent 1 ~ 3 part;
15 ~ 25 parts, aluminium admiro powder; Binding agent 0.6 ~ 1 part;
Organic solvent 15 ~ 20 parts; Defoamer 2 ~ 9 parts;
Nano-oxide 5 ~ 10 parts; Thickening material 1 ~ 4 part;
Deionized water 10 ~ 20 parts.
2. antifouling, the rotproofing new coating of marine metal component according to claim 1, is characterized in that: described nano-oxide is one or more the mixture in nano aluminium oxide, nano-titanium oxide, nano zine oxide.
3. antifouling, the rotproofing new coating of marine metal component according to claim 2, is characterized in that: described organic solvent is ethylene glycol; Described defoamer is propyl carbinol; Described corrosion inhibitor is boric acid; Described dispersion agent is dipropylene glycol.
4. antifouling, the rotproofing new coating of marine metal component as claimed in claim 1, is characterized in that: implement as follows:
(1) by measuring the organic solvent, deionized water, epoxy resin, the fluorocarbon resin that add successively under agitation;
(2) defoamer and dispersion agent is added successively;
(3) aluminium admiro powder, nano-oxide, corrosion inhibitor, thickening material and binding agent is added successively after continuing stirring;
(5) Keep agitation, obtains object product.
5. the preparation method of antifouling, the rotproofing new coating of marine metal component according to claim 4, it is characterized in that: in described step (1), low whipping speed is add organic solvent, deionized water, epoxy resin, fluorocarbon resin successively under the condition of 200r/min; In described step (2), after stirring 60 ~ 80min, add defoamer, dispersion agent successively; In described step (3), after continuing stirring 80 ~ 120min, add aluminium admiro powder, nano-oxide, corrosion inhibitor, thickening material and binding agent successively; In described step (4), Keep agitation 30 ~ 60min, obtains object product.
6. antifouling, the rotproofing new coating of marine metal component, is characterized in that, in mass parts, comprise following component:
Epoxy resin 15 ~ 20 parts; Corrosion inhibitor 1 ~ 5 part;
Fluorocarbon resin 15 ~ 24 parts; Dispersion agent 1 ~ 3 part;
15 ~ 25 parts, aluminium admiro powder; Binding agent 0.6 ~ 1 part;
Organic solvent 15 ~ 20 parts; Defoamer 2 ~ 9 parts;
Modified nano oxide compound 5 ~ 10 parts; Thickening material 1 ~ 4 part;
Deionized water 10 ~ 20 parts.
7. antifouling, the rotproofing new coating of marine metal component according to claim 6, is characterized in that: described modified nano oxide compound is one or more the mixture in modified nano-alumina, modified Nano titanium oxide, modified nano zinc oxide.
8. antifouling, the rotproofing new coating of marine metal component according to claim 7, is characterized in that: described organic solvent is ethylene glycol; Described defoamer is propyl carbinol; Described corrosion inhibitor is boric acid; Described dispersion agent is dipropylene glycol.
9. antifouling, the rotproofing new coating of marine metal component according to claim 8, is characterized in that: the preparation method of described modified nano oxide compound implements as follows: the ratio being followed successively by 6.5:0.1:1 in quality proportioning takes propyl alcohol, sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester and nano-oxide respectively; First propyl alcohol and sec.-propyl three (dioctyl phosphoric acid acyloxy) titanic acid ester are mixed, then nano-oxide is added, after at ambient temperature gained mixture being stirred 2 hours with the stirring velocity of 250r/min, utilize vacuum filtration to carry out solid-liquid separation, after being dried under 70 DEG C of conditions by solid, namely obtain modified nano oxide compound.
10. antifouling, the rotproofing new coating of marine metal component according to claim 9, is characterized in that, implements as follows:
(1) by measuring the organic solvent, deionized water, epoxy resin, the fluorocarbon resin that add successively under agitation;
(2) defoamer and dispersion agent is added successively;
(3) aluminium admiro powder, modified nano oxide compound, corrosion inhibitor, thickening material and binding agent is added successively after continuing stirring;
(5) Keep agitation, obtains object product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510850528.2A CN105295585A (en) | 2015-11-30 | 2015-11-30 | Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510850528.2A CN105295585A (en) | 2015-11-30 | 2015-11-30 | Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105295585A true CN105295585A (en) | 2016-02-03 |
Family
ID=55193452
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510850528.2A Pending CN105295585A (en) | 2015-11-30 | 2015-11-30 | Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105295585A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325687A (en) * | 2017-08-11 | 2017-11-07 | 金华联创塑粉科技有限公司 | A kind of high abrasion anticorrosive coating and preparation method thereof |
| CN107674473A (en) * | 2017-09-14 | 2018-02-09 | 常熟市方塔涂料化工有限公司 | A kind of steel structure surface High-solid anticorrosive paint and its spraying method |
| CN108148474A (en) * | 2017-12-15 | 2018-06-12 | 广州前延新材料发展有限公司 | It is a kind of for composite coating of marine settings and its preparation method and application |
| CN109054592A (en) * | 2018-08-20 | 2018-12-21 | 常州市天安特种涂料有限公司 | Anti-corrosion weather-resistant coating more than naval vessel waterline and preparation method thereof |
| CN109161300A (en) * | 2018-08-20 | 2019-01-08 | 常州市天安特种涂料有限公司 | The water corrosion-resistant epoxy paint and preparation method thereof of naval vessel underwater |
| CN109566652A (en) * | 2017-09-29 | 2019-04-05 | 信越化学工业株式会社 | Deodorization/antibacterial/antifungal agent, preparation method and on the surface have deodorization/antibacterial/antifungal agent component |
| CN109566648A (en) * | 2017-09-29 | 2019-04-05 | 信越化学工业株式会社 | Have and has photochemical catalyst/alloy film component on antibacterium/fungoid photochemical catalyst/alloy particle dispersion liquid, the preparation method and surface |
| CN113005492A (en) * | 2021-03-22 | 2021-06-22 | 河南兴安邦机电装备制造有限公司 | Anticorrosive electrodeposition process for marine ship parts |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004331969A (en) * | 2003-05-05 | 2004-11-25 | Northrop Grumman Corp | Protective autologous decontamination or autologous cleaning coating against deleterious biological pathogen and toxic chemical |
| CN102030987A (en) * | 2009-09-30 | 2011-04-27 | E.I.内穆尔杜邦公司 | Corrosion-resistant film and product containing same |
| CN102051076A (en) * | 2010-11-04 | 2011-05-11 | 江苏麟龙新材料股份有限公司 | Nickel-containing marine-climate-resisting coating for preservative treatment |
| CN103509430A (en) * | 2013-09-27 | 2014-01-15 | 无锡阳工机械制造有限公司 | Corrosion-resistant coating for metals and preparation method for corrosion-resistant coating |
-
2015
- 2015-11-30 CN CN201510850528.2A patent/CN105295585A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004331969A (en) * | 2003-05-05 | 2004-11-25 | Northrop Grumman Corp | Protective autologous decontamination or autologous cleaning coating against deleterious biological pathogen and toxic chemical |
| CN102030987A (en) * | 2009-09-30 | 2011-04-27 | E.I.内穆尔杜邦公司 | Corrosion-resistant film and product containing same |
| CN102051076A (en) * | 2010-11-04 | 2011-05-11 | 江苏麟龙新材料股份有限公司 | Nickel-containing marine-climate-resisting coating for preservative treatment |
| CN103509430A (en) * | 2013-09-27 | 2014-01-15 | 无锡阳工机械制造有限公司 | Corrosion-resistant coating for metals and preparation method for corrosion-resistant coating |
Non-Patent Citations (1)
| Title |
|---|
| 乔玉林: "《纳米微米的润滑和自修复技术》", 30 September 2005, 国防工业出版社 * |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107325687A (en) * | 2017-08-11 | 2017-11-07 | 金华联创塑粉科技有限公司 | A kind of high abrasion anticorrosive coating and preparation method thereof |
| CN107674473A (en) * | 2017-09-14 | 2018-02-09 | 常熟市方塔涂料化工有限公司 | A kind of steel structure surface High-solid anticorrosive paint and its spraying method |
| CN109566652A (en) * | 2017-09-29 | 2019-04-05 | 信越化学工业株式会社 | Deodorization/antibacterial/antifungal agent, preparation method and on the surface have deodorization/antibacterial/antifungal agent component |
| CN109566648A (en) * | 2017-09-29 | 2019-04-05 | 信越化学工业株式会社 | Have and has photochemical catalyst/alloy film component on antibacterium/fungoid photochemical catalyst/alloy particle dispersion liquid, the preparation method and surface |
| CN109566648B (en) * | 2017-09-29 | 2022-12-23 | 信越化学工业株式会社 | Photocatalyst/alloy fine particle dispersion liquid having antibacterial/antifungal properties, method for producing the same, and member having photocatalyst/alloy film on surface thereof |
| CN109566652B (en) * | 2017-09-29 | 2022-12-23 | 信越化学工业株式会社 | Deodorant/antibacterial/antifungal agent, method for producing the same, and member having deodorant/antibacterial/antifungal agent on surface |
| CN108148474A (en) * | 2017-12-15 | 2018-06-12 | 广州前延新材料发展有限公司 | It is a kind of for composite coating of marine settings and its preparation method and application |
| CN109054592A (en) * | 2018-08-20 | 2018-12-21 | 常州市天安特种涂料有限公司 | Anti-corrosion weather-resistant coating more than naval vessel waterline and preparation method thereof |
| CN109161300A (en) * | 2018-08-20 | 2019-01-08 | 常州市天安特种涂料有限公司 | The water corrosion-resistant epoxy paint and preparation method thereof of naval vessel underwater |
| CN113005492A (en) * | 2021-03-22 | 2021-06-22 | 河南兴安邦机电装备制造有限公司 | Anticorrosive electrodeposition process for marine ship parts |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105295585A (en) | Novel paint for anti-fouling and anti-corrosion treatment on marine metal component and preparation method of novel paint | |
| CN102604509B (en) | Nanofiber heavy-duty anti-corrosive coating, preparation method and spraying method of nanofiber heavy-duty anti-corrosive coating | |
| CN103254701B (en) | Novel anti-corrosion, anti-ultraviolet, anti-bacteria and wear-resistant paint and preparation method for same | |
| CN101116855B (en) | Method for preparing corrosion-protection composite coating for the steel metalwork | |
| CN108997889A (en) | A kind of ocean naval vessel graphene heavy antisepsis priming paint and preparation method thereof | |
| CN105086529B (en) | Environment-friendly water-based ceramic base anti-corrosion material | |
| CN105131665A (en) | Aqueous inorganic zinc-rich prime coat and preparation method thereof | |
| CN102974519B (en) | Anticorrosive technology used for marine environment fastener | |
| CN102807797B (en) | Efficient marine antifouling coating and broad-spectrum controlled-release antifouling agent for same | |
| CN102977744A (en) | Nano-composite marine anti-fouling coating material and preparation method thereof | |
| CN103666202A (en) | Environment-friendly oily antirust paint and preparation method thereof | |
| CN104403448A (en) | Nano cuprous oxide and nano silver compounded sea anti-fouling paint | |
| CN109439187A (en) | Modified chromium-free Dyclo paint of a kind of graphene and preparation method thereof | |
| CN103160205A (en) | Ionic liquid marine antifouling coating | |
| CN103540393B (en) | Brown high-build quick-drying antirust oil applicable to diesel engines of ships and warships and preparation method thereof | |
| CN104559579A (en) | Environment-friendly type self-polishing anti-fouling paint with high adhesive force | |
| CN105017927A (en) | Medical magnetic red lead antirust paint and preparation method thereof | |
| CN111423752A (en) | Water-based inorganic zinc-rich primer for heavy corrosion protection | |
| CN103254725A (en) | Ocean heavy anti-corrosion epoxy aluminum-nickel-rich nano-coating and preparation method thereof | |
| CN106833274A (en) | A kind of Seawater-corrosion-ppaintting paintting peculiar to vessel and preparation method thereof | |
| CN105925092A (en) | Waterborne over-rust coating for steel and preparation method thereof | |
| CN111217583B (en) | Graphene modified nano coating and preparation method thereof | |
| CN107384136A (en) | Steel iron facilities antirusting paint and preparation method thereof under the conditions of one kind is maritime | |
| CN107641419A (en) | A kind of steel ship gas-phase anti-corrosion paint and preparation method thereof | |
| CN104387972A (en) | Multicolor hard film rust preventive oil applied to boat bottom and preparation method of oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160203 |
|
| RJ01 | Rejection of invention patent application after publication |