CN102584016A - Method for manufacturing infusion bottles by using broken glass - Google Patents

Method for manufacturing infusion bottles by using broken glass Download PDF

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Publication number
CN102584016A
CN102584016A CN2011100203727A CN201110020372A CN102584016A CN 102584016 A CN102584016 A CN 102584016A CN 2011100203727 A CN2011100203727 A CN 2011100203727A CN 201110020372 A CN201110020372 A CN 201110020372A CN 102584016 A CN102584016 A CN 102584016A
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China
Prior art keywords
kilograms
glass
kilogram
glass cullet
powder
Prior art date
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Pending
Application number
CN2011100203727A
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Chinese (zh)
Inventor
谈宇宏
赵新江
冯爱霞
王海军
徐汉尧
刁国贤
徐德华
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WUHAN HUAXIA GLASSWORK CO Ltd
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WUHAN HUAXIA GLASSWORK CO Ltd
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Priority to CN2011100203727A priority Critical patent/CN102584016A/en
Publication of CN102584016A publication Critical patent/CN102584016A/en
Pending legal-status Critical Current

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  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

Provided is a method for manufacturing infusion bottles by using broken glass. Powder materials containing the following components by weight are added in each 1000 kg of broken glass: 52-57 kg of quartz sand, 15-18 kg of sodium carbonate, 12-15 kg of calcite, 6-10 kg of feldspar, 4-5 kg of sodium sulfate, 1-5 kg of fluorite, 4-5 kg of sodium nitrate, 0.3-0.6 kg of ceric oxide and 0-5 kg of borax. The method can improve use ratio of broken glass, guarantees glass quality such as impact resistance, water resistance and alkali resistance, can be suitable for manufacturing of infusion bottles, and simultaneously has the advantages of saving resources, reducing cost and environment pollution and the like.

Description

A kind of method of utilizing glass cullet to prepare infusion bottle
Technical field
The present invention relates to the manufacturing of vial, specifically is a kind of method of utilizing glass cullet to prepare infusion bottle.
Background technology
How a large amount of discarded glass cullet that the daily productive life of people produces utilize effectively again, are domestic at present and even one of problem that global glazier author needs to be resolved hurrily.Prior art mainly is to be used for low-grade horizontal drawing sheet glass, mosaic glass etc. quality index such as glass impurities are required lower glass to the recycling of waste and old (or discarded) glass.And for the demanding glass kind of quality index, for example float glass does not generally add discarded glass as raw material." recycling of scrap glass " (Jiang Wenjiu " Shanghai building materials " the 3rd phase in 2003) discloses the applicable cases of prior art to discarded glass cullet, and its disclosed content quotation is in this.
Glass cullet can reduce energy consumption and production costs, practice thrift the resources of production, reduce the environment generation of waste as a kind of reclaimed materials, reduce environmental pollution.But because at present the waste and old glass cullet kind in the society is numerous and diverse, and color, composition all are not quite similar.If can not these problems be solved, just can not produce qualified infusion bottle.
The infusion bottle fragility of utilizing waste and old glass cullet to produce in addition merely is higher, and intensity is low, and is simultaneously withstand voltage defective with shock resistance.So produce in the prescription of infusion bottle at the waste and old glass cullet of existing usefulness, the content of waste and old glass cullet is all below 70%, this also is to cause the product cost major reason for higher.
Summary of the invention
The present invention provides a kind of method of utilizing glass cullet to prepare infusion bottle, can improve the glass cullet utilization ratio, ensures glass quality, like water tolerance, alkali resistance etc., makes it can be applicable to the manufacturing of infusion bottle; Has advantages such as economizing on resources, reduce cost, reduce environmental pollution simultaneously.
A kind of method of utilizing glass cullet to prepare infusion bottle is added the powder that comprises following composition and weight thereof: silica sand 52-57 kilogram, soda ash 15-18 kilogram, calcite 12-15 kilogram, feldspar 6-10 kilogram, sodium sulfate, 4-5 kilogram, fluorite 1-5 kilogram, SODIUMNITRATE 4-5 kilogram, cerium dioxide 0.3-0.6 kilogram, borax 0-5 kilogram in per 1000 kilograms of glass cullet.
The method for making of infusion bottle of the present invention is basic identical with general infusion bottle method for making, compares with other prior aries, and beneficial effect of the present invention is:
1) the present invention adds an amount of SiO in glass cullet 2, Al 2O 3, B 2O 3The powder of composition (silica sand, feldspar, borax), the adjustable glass chemistry is formed, and replenishes the loss of glass cullet some composition when remelting, improves physical and chemical indexs such as infusion bottle physical strength, water tolerance, alkali resistance.
2) in the glass slag, add an amount of R that contains 2The powder of O oxide compound (R represents Na or K), for example feldspar, soda ash etc. can quicken the fusing of glass on the one hand, can also replenish the R in the glass cullet 2The O loss keeps the glass composition stable.
3) the present invention adds an amount of finings and discoloring agent in glass cullet, like Na 2SO 4, NaNO 3And cerium dioxide (CeO 2) wait oxide compound, particularly cerium dioxide, as the distinguishing feature of finings and discoloring agent be temperature when the pyrolytic decomposition near the clarifying temp of glass, at this moment the viscosity of glass is little, the O of release 2Higher, be ideal high temperature finings and discoloring agent, can reduce the viscosity of glass; Improve the clarifying speed of glass; Reinforced glass liquid homogenizing quality can be got rid of bubble rapidly, and the glass physical and chemical index is more excellent; Thereby prevent to occur the problem that glass is difficult to clarify, bubble is difficult to overflow when using glass cullet, improve the utilization ratio of glass cullet a large amount of.The content of glass cullet of the present invention can reach 89-91%, so can make the production cost of infusion bottle reduce greatly.
Embodiment
Below in conjunction with specific embodiment the technical scheme among the present invention is carried out clear, intactly description.
Embodiment 1: with silica sand 52-57 kilogram, soda ash 15-18 kilogram, calcite 12-15 kilogram, feldspar 6-10 kilogram, sodium sulfate (saltcake) 4-5 kilogram, fluorite 1-5 kilogram, SODIUMNITRATE 4-5 kilogram, cerium dioxide 0.3-0.6 kilogram, borax 0-5 kilogram; Add and to close the material machine and mix and process powder; The uniformity coefficient of powder is reached>=95%; Add 1000 kilograms of glass cullet meeting the infusion bottle specification of quality again; With the powder thorough mixing, the moisture of compound≤8% is processed infusion bottle according to the complete processing of vial then once more.
Embodiment 2: with 57 kilograms of silica sands, 16 kilograms of soda ash, 13 kilograms in calcite, 6 kilograms of feldspars, 4 kilograms in sodium sulfate (saltcake), 5 kilograms in fluorite, 4 kilograms in SODIUMNITRATE, 0.5 kilogram of cerium dioxide, 5 kilograms of boraxs; Add and to close the material machine and mix and process powder; The uniformity coefficient of powder is reached>=95%, add 1000 kilograms of glass cullet meeting the infusion bottle specification of quality again, once more with the powder thorough mixing; The moisture of compound≤8% is processed infusion bottle according to the complete processing of vial then.
Embodiment 3: with 55 kilograms of silica sands, 15 kilograms of soda ash, 15 kilograms in calcite, 8 kilograms of feldspars, 4.5 kilograms in sodium sulfate (saltcake), 3 kilograms in fluorite, 5 kilograms in SODIUMNITRATE, 0.6 kilogram of cerium dioxide, 2 kilograms of boraxs; Add and to close the material machine and mix and process powder; The uniformity coefficient of powder is reached>=95%; Add 1000 kilograms of glass cullet meeting the infusion bottle specification of quality again; With the powder thorough mixing, the moisture of compound≤8% is processed infusion bottle according to the complete processing of vial then once more.
In the foregoing description, 1000 kilograms of glass cullet that wherein prepare infusion bottle comprise 50-100% infusion bottle glass, the general white glass of 0-20%, 0-20% white pharmaceutical glass, the assorted glass of 0-10% white, and the granularity of said glass cullet is the 10-40 millimeter.
When using glass cullet, confirm globule size, consumption, adding method, the rational melting system of glass cullet, with founding fast and homogenizing of favourable assurance glass.The granularity of glass cullet of the present invention is designed to the 10-40 millimeter.The granularity of glass cullet can not be too little, and is more much bigger than powder, otherwise the soda ash in the raw material can react with glass cullet earlier, causes silica sand raw material fusing difficulty, and the whole process of founding will slack-offly degenerate, and does not reach the desired design effect.
The above; Be merely embodiment of the present invention, but protection scope of the present invention is not limited thereto, any technician who belongs to the present technique field is in the technical scope that the present invention discloses; The variation that can expect easily or replacement all should be encompassed within protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claim.

Claims (6)

1. a method of utilizing glass cullet to prepare infusion bottle is characterized in that: in per 1000 kilograms of glass cullet, add the powder that comprises following composition and weight thereof: silica sand 52-57 kilogram, soda ash 15-18 kilogram, calcite 12-15 kilogram, feldspar 6-10 kilogram, sodium sulfate, 4-5 kilogram, fluorite 1-5 kilogram, SODIUMNITRATE 4-5 kilogram, cerium dioxide 0.3-0.6 kilogram, borax 0-5 kilogram.
2. the method for claim 1; It is characterized in that the composition of said powder and weight thereof are: 57 kilograms of silica sands, 16 kilograms of soda ash, 13 kilograms in calcite, 6 kilograms of feldspars, 4 kilograms in sodium sulfate, 5 kilograms in fluorite, 4 kilograms in SODIUMNITRATE, 0.5 kilogram of cerium dioxide, 5 kilograms of boraxs.
3. the method for claim 1; It is characterized in that the composition of said powder and weight thereof are: 55 kilograms of silica sands, 15 kilograms of soda ash, 15 kilograms in calcite, 8 kilograms of feldspars, 4.5 kilograms in sodium sulfate, 3 kilograms in fluorite, 5 kilograms in SODIUMNITRATE, 0.6 kilogram of cerium dioxide, 2 kilograms of boraxs.
4. like each described method of claim 1-3, it is characterized in that: said glass cullet comprise 50-100% infusion bottle glass, the general white glass of 0-20%, 0-20% white pharmaceutical glass, the assorted glass of 0-10% white.
5. the method for claim 1 is characterized in that: moisture≤8% of compound after the uniformity coefficient of said powder>=95%, glass cullet water cut≤5%, glass cullet mix with powder.
6. the method for claim 1, it is characterized in that: the granularity of said glass cullet is the 10-40 millimeter.
CN2011100203727A 2011-01-18 2011-01-18 Method for manufacturing infusion bottles by using broken glass Pending CN102584016A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102826754A (en) * 2012-09-20 2012-12-19 张家港市俊锋玻璃制品有限公司 Formulation of high-clarity glass bottle
CN102826755A (en) * 2012-09-20 2012-12-19 张家港市俊锋玻璃制品有限公司 Manufacturing method of high-clarity glass bottle
CN103641311A (en) * 2013-12-11 2014-03-19 昆明云海印铁制盖有限公司 High-calcium and lightweight glass bottle formula
CN107365074A (en) * 2017-09-08 2017-11-21 金玛瑙香水(明光)有限公司 A kind of stained glass bottle and its production method
CN107572780A (en) * 2017-09-29 2018-01-12 浙江才府玻璃股份有限公司 A kind of production technology of the presetting bottle of high internal pressure resistance
CN107586019A (en) * 2017-09-08 2018-01-16 金玛瑙香水(明光)有限公司 A kind of medicine bottle formula and preparation method thereof
CN111925118A (en) * 2020-06-29 2020-11-13 福建华兴玻璃有限公司 Preparation formula for producing high-whiteness glass by recycling printed cullet

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020073898A1 (en) * 2000-08-16 2002-06-20 Siegfried Schelinski Porous silicate granular material and method for producing it
CN101148317A (en) * 2007-08-22 2008-03-26 东营力诺玻璃制品有限责任公司 Formulation for medicinal neutral boron silicate glass
CN101941800A (en) * 2010-07-30 2011-01-12 青岛崂山玻璃有限公司 Glass bear bottle containing rear earth cerium and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20020073898A1 (en) * 2000-08-16 2002-06-20 Siegfried Schelinski Porous silicate granular material and method for producing it
CN101148317A (en) * 2007-08-22 2008-03-26 东营力诺玻璃制品有限责任公司 Formulation for medicinal neutral boron silicate glass
CN101941800A (en) * 2010-07-30 2011-01-12 青岛崂山玻璃有限公司 Glass bear bottle containing rear earth cerium and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102826754A (en) * 2012-09-20 2012-12-19 张家港市俊锋玻璃制品有限公司 Formulation of high-clarity glass bottle
CN102826755A (en) * 2012-09-20 2012-12-19 张家港市俊锋玻璃制品有限公司 Manufacturing method of high-clarity glass bottle
CN102826755B (en) * 2012-09-20 2014-08-13 张家港市俊锋玻璃制品有限公司 Manufacturing method of high-clarity glass bottle
CN103641311A (en) * 2013-12-11 2014-03-19 昆明云海印铁制盖有限公司 High-calcium and lightweight glass bottle formula
CN107365074A (en) * 2017-09-08 2017-11-21 金玛瑙香水(明光)有限公司 A kind of stained glass bottle and its production method
CN107586019A (en) * 2017-09-08 2018-01-16 金玛瑙香水(明光)有限公司 A kind of medicine bottle formula and preparation method thereof
CN107572780A (en) * 2017-09-29 2018-01-12 浙江才府玻璃股份有限公司 A kind of production technology of the presetting bottle of high internal pressure resistance
CN111925118A (en) * 2020-06-29 2020-11-13 福建华兴玻璃有限公司 Preparation formula for producing high-whiteness glass by recycling printed cullet

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Application publication date: 20120718