CN108069602A - A kind of high calcium and light-weighted vial formula - Google Patents
A kind of high calcium and light-weighted vial formula Download PDFInfo
- Publication number
- CN108069602A CN108069602A CN201610986142.9A CN201610986142A CN108069602A CN 108069602 A CN108069602 A CN 108069602A CN 201610986142 A CN201610986142 A CN 201610986142A CN 108069602 A CN108069602 A CN 108069602A
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- formula
- raw material
- light
- vial
- high calcium
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/002—Use of waste materials, e.g. slags
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- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
A kind of high calcium and light-weighted vial formula, inventive formulation are：1）Raw material：According to weight percent：Quartz sand SiO2:70~75%, soda ash NaCO3:12~16%, calcite CaCO3:9~12%, aluminium oxide Al 2O3:2~3%, prodan Na2SiF6:0.3~0.7%, sodium nitrate NaNO3:0.4~0.8%, zincium selenious acid ZnSeO3.2H2O0.002~0.007%；2）Clinker：Glass dregs are the 60% of raw material weight.The present invention provides a kind of manufactured vial intensity height, and color, lightness are good, scrap glass utilization rate height, the high high calcium of the qualification rate of finished product and light-weighted vial formula.
Description
Technical field
The invention belongs to the formulas that vial material prescription, especially solid waste glass recycle melting making vial use
Technical field.
Background technology
At present, produced glass bottle is formulated using existing recycled to solid waste glass, is susceptible to bubble；By force
Degree is inadequate, and maximum impact resistance is usually 0.5 to 0.6J；For finished product qualification rate than relatively low, qualification rate is only 85% to 90%.It should
Existing formula is,
1）, raw material：Quartz sand SiO2, soda ash NaCO3, calcite CaCO3, feldspar powder Al2O3, fluorite CaF2:, anhydrous sodium sulphate
Na2SO4, sodium nitrate NaNO3, selenium-cobalt decolorising agent；
2）, clinker：Glass dregs.
Wherein commonly used precise formulations are：
1）, raw material：Quartz sand SiO2:72.0%th, soda ash NaCO3:14.8%th, calcite CaCO3:9.8%th, feldspar powder Al2O3:
3.0%th, fluorite CaF2:0.8%th, anhydrous sodium sulphate Na2SO4:0.9%th, sodium nitrate NaNO3:0.6%th, selenium-cobalt decolorising agent 8g/200KG（Before
It looks unfamiliar the weight of material）；
2）, clinker：Glass dregs are the 40% of raw material weight.
Above-mentioned existing solid waste glass recycles the formula material that melting making vial uses and has a defect that：It is existing
Feldspar powder in formula belongs to mineral products, and there are many slag, aluminium element therein is mainly used using feldspar powder, due to wherein containing
Iron, iron can influence the Forming Quality of vial and the intensity of vial；Fluorite in existing formula mainly uses its inside
Fluorine element, for glass metal clarification.Fluorite belongs to mineral products, wherein certainly existing other elements, can not use completely,
The element wherein having can also influence product quality, such as iron, magnesium elements；Anhydrous sodium sulphate in existing formula, long-time service can corrode
Kiln pond reduces kiln pond service life；Selenium-cobalt decolorising agent in existing formula, cobalt therein can influence the quality of vial；It is existing
Clinker in actual formula is also not very high to a kind of utilization rate of scrap glass used in everyday using 40% glass dregs.
The formula of the above-mentioned prior art also makes manufactured vial easily generate bubble, and impact resistance is also poor, product
The qualification rate of finished product is not also high.
A kind of system is provided the purpose of the present invention is to overcome the problems of the above-mentioned prior art and shortcoming
Into vial intensity it is high, color, lightness are good, scrap glass utilization rate is high, the qualification rate of finished product is high high calcium and
Light-weighted vial formula.
The purpose of the present invention is by following technical solution to realize.
A kind of high calcium and light-weighted vial formula, inventive formulation are：1）, raw material：According to weight percent：
CN103641311A specifications quartz sand SiO2 of page 3,2/3 4:70~75%, soda ash NaCO3:12~16%, calcite CaCO3:9~
12%th, aluminium oxide Al 2O3:2~3%, prodan Na2SiF6:0.3~0.7%, sodium nitrate NaNO3:0.4~0.8%, selenous acid
Zinc ZnSeO3.2H2O0.002~0.007%；2）, clinker：Glass dregs are the 60% of raw material weight.
Optimum formula of the present invention is：
1）, raw material：According to weight percent：Quartz sand SiO2:72.5%th, soda ash NaCO3:13.8%th, calcite CaCO3:
10.296%th, aluminium oxide Al 2O3:2.3%th, prodan Na2SiF6:0.5%th, sodium nitrate NaNO3:0.6%th, zincium selenious acid
ZnSeO3.2H2O0.004%；
2）, clinker：Glass dregs are the 60% of raw material weight.
The invention has the advantages that manufactured vial intensity is high, color, lightness are good, scrap glass utilization rate
High, finished product qualification rate is high.
The bottle of formula production using the present invention, bottle bubble-free；Impact resistance increases up to 0.7J to 1.0J, intensity
By force；Finished product qualification rate is up to more than 97%.
The present invention is changed to aluminium oxide by original feldspar powder：Bringing into for other slags is avoided, ensure that glass product matter
Amount.
The present invention is changed to prodan by fluorite originally so that and the ratio of other raw materials is adjusted, because it
All the components can all use（Such as fluorine, silica, sodium oxide molybdena）, effectively control cost.And use, in glass
It can play the role of during fusing to glass metal clear.
The present invention does not use anhydrous sodium sulphate, as long as because long-time service can corrode kiln pond, reduces kiln pond service life.
Selenium-cobalt decolorising agent is changed to zincium selenious acid by the present invention, and the quality of vial can be influenced by being primarily due to wherein cobalt.Change
Into zincium selenious acid, because its is readily volatilized, it is ensured that the transparency of vial and other color quality is avoided to influence product matter
Amount.
Clinker of the present invention is changed to 60% by 40% original glass dregs, effectively has to one kind of scrap glass used in everyday
Effect utilizes, and reduces cost, also protects environment.
The present invention, also further by test of many times and analysis, has been found out most on the basis of prior art formula is changed
Good formula, the optimum formula have very significant said effect, become a kind of the preferred of inventive formulation.
Specific embodiment
Embodiment one
A kind of high calcium and light-weighted vial formula, inventive formulation are：
1）, raw material：According to weight percent：Quartz sand SiO2:70%th, soda ash NaCO3:16%th, calcite CaCO3:10.493%、
Aluminium oxide Al 2O3:2%th, prodan Na2SiF6:0.7%th, sodium nitrate NaNO3:0.8%th, zincium selenious acid
ZnSeO3.2H2O0.007%；
2）, clinker：Glass dregs are the 60% of raw material weight.
Embodiment two
A kind of high calcium and light-weighted vial formula, inventive formulation are：
1）, raw material：According to weight percent：Quartz sand SiO2:75%th, soda ash NaCO3:12%th, calcite CaCO3:9.298%th, oxygen
Change aluminium Al2O3:3%th, prodan Na2SiF6:0.3%th, sodium nitrate NaNO3:0.4%th, zincium selenious acid ZnSeO3.2H2O0.002%；
2）, clinker：Glass dregs are the 60% of raw material weight.
Claims (2)
1. a kind of high calcium and light-weighted vial formula, it is characterized in that, it is formulated and is：
Raw material：According to weight percent：Quartz sand SiO2:70~75%, soda ash NaCO3:12~16%, calcite CaCO3:9~
12%th, aluminium oxide Al 2O3:2~3%, prodan Na2SiF6:0.3~0.7%, sodium nitrate NaNO3:0.4~0.8%, selenous acid
Zinc ZnSeO3.2H2O0.002~0.007%；
Clinker：Glass dregs are the 60% of raw material weight.
2. a kind of high calcium according to claim 1 and light-weighted vial formula, it is characterized in that, optimum formula is：
Raw material：According to weight percent：Quartz sand SiO2:72.5%th, soda ash NaCO3:13.8%th, calcite CaCO3:10.296%、
Aluminium oxide Al 2O3:2.3%th, prodan Na2SiF6:0.5%th, sodium nitrate NaNO3:0.6%th, zincium selenious acid
ZnSeO3.2H2O0.004%；
Clinker：Glass dregs are the 60% of raw material weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610986142.9A CN108069602A (en) | 2016-11-09 | 2016-11-09 | A kind of high calcium and light-weighted vial formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610986142.9A CN108069602A (en) | 2016-11-09 | 2016-11-09 | A kind of high calcium and light-weighted vial formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108069602A true CN108069602A (en) | 2018-05-25 |
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ID=62154071
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610986142.9A Pending CN108069602A (en) | 2016-11-09 | 2016-11-09 | A kind of high calcium and light-weighted vial formula |
Country Status (1)
| Country | Link |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109534678A (en) * | 2019-01-22 | 2019-03-29 | 山东景耀玻璃集团有限公司 | A kind of low cost common white material glass and preparation method |
| CN111943508A (en) * | 2020-08-05 | 2020-11-17 | 郑州市华源玻璃制品有限公司 | Production process of beverage bottle |
-
2016
- 2016-11-09 CN CN201610986142.9A patent/CN108069602A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109534678A (en) * | 2019-01-22 | 2019-03-29 | 山东景耀玻璃集团有限公司 | A kind of low cost common white material glass and preparation method |
| CN111943508A (en) * | 2020-08-05 | 2020-11-17 | 郑州市华源玻璃制品有限公司 | Production process of beverage bottle |
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| PB01 | Publication | ||
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| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180525 |