CN102211874B - Microcrystalline glass and preparation method thereof - Google Patents
Microcrystalline glass and preparation method thereof Download PDFInfo
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- CN102211874B CN102211874B CN 201110119884 CN201110119884A CN102211874B CN 102211874 B CN102211874 B CN 102211874B CN 201110119884 CN201110119884 CN 201110119884 CN 201110119884 A CN201110119884 A CN 201110119884A CN 102211874 B CN102211874 B CN 102211874B
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- 239000011521 glass Substances 0.000 title claims abstract description 83
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 84
- 239000010935 stainless steel Substances 0.000 claims abstract description 84
- 239000002893 slag Substances 0.000 claims abstract description 49
- 239000002994 raw material Substances 0.000 claims abstract description 33
- 239000002956 ash Substances 0.000 claims abstract description 31
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 24
- 238000000034 method Methods 0.000 claims abstract description 24
- 239000006004 Quartz sand Substances 0.000 claims abstract description 22
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000010881 fly ash Substances 0.000 claims description 22
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 21
- 238000000137 annealing Methods 0.000 claims description 18
- 238000002425 crystallisation Methods 0.000 claims description 18
- 230000008025 crystallization Effects 0.000 claims description 18
- 239000006063 cullet Substances 0.000 claims description 18
- 238000002844 melting Methods 0.000 claims description 16
- 230000008018 melting Effects 0.000 claims description 16
- 238000005498 polishing Methods 0.000 claims description 16
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 10
- 238000005266 casting Methods 0.000 claims description 9
- 239000000203 mixture Substances 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- 239000000156 glass melt Substances 0.000 claims 2
- 239000004615 ingredient Substances 0.000 claims 1
- 239000011651 chromium Substances 0.000 abstract description 32
- 239000002910 solid waste Substances 0.000 abstract description 9
- 239000000126 substance Substances 0.000 abstract description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 abstract description 6
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 5
- 239000010883 coal ash Substances 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 239000002699 waste material Substances 0.000 abstract description 3
- 238000009776 industrial production Methods 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- QDOXWKRWXJOMAK-UHFFFAOYSA-N dichromium trioxide Chemical compound O=[Cr]O[Cr]=O QDOXWKRWXJOMAK-UHFFFAOYSA-N 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 238000005536 corrosion prevention Methods 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 238000007500 overflow downdraw method Methods 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 18
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 12
- 239000000395 magnesium oxide Substances 0.000 description 10
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 230000002829 reductive effect Effects 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 239000004568 cement Substances 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 238000003912 environmental pollution Methods 0.000 description 4
- 238000004064 recycling Methods 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 230000001351 cycling effect Effects 0.000 description 3
- 239000011174 green composite Substances 0.000 description 3
- 230000003260 anti-sepsis Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229910001430 chromium ion Inorganic materials 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003317 industrial substance Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000002667 nucleating agent Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 206010028980 Neoplasm Diseases 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- WGLPBDUCMAPZCE-UHFFFAOYSA-N Trioxochromium Chemical compound O=[Cr](=O)=O WGLPBDUCMAPZCE-UHFFFAOYSA-N 0.000 description 1
- 208000025865 Ulcer Diseases 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 1
- 235000010261 calcium sulphite Nutrition 0.000 description 1
- 201000011510 cancer Diseases 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- -1 chromium hydroxide compound Chemical class 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000009851 ferrous metallurgy Methods 0.000 description 1
- 239000011790 ferrous sulphate Substances 0.000 description 1
- 235000003891 ferrous sulphate Nutrition 0.000 description 1
- 239000010922 glass waste Substances 0.000 description 1
- 239000002440 industrial waste Substances 0.000 description 1
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 1
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 1
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 231100000397 ulcer Toxicity 0.000 description 1
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- Glass Compositions (AREA)
Abstract
The invention provides microcrystalline glass and a preparation method thereof. In the method, one or more of stainless steel dedusting ash, quartz sand, coal ash and waste glass are used so as to regulate stainless steel slag to a component range suitable for preparing the microcrystalline glass. The microcrystalline glass comprises the following components by weight percent: 45-60% of SiO2, 20-28% of CaO, 10-15% of MgO, 2-9% of Al2O3, 0-8% of Na2O, 0.5-5% of Fe2O3, 0.4-2.5% of Cr2O3, 0.5-1.5% of F and 0.1-6% of TiO2. The microcrystalline glass is prepared by using a fusion method. The preparation method has the advantages that stainless steel slag, stainless steel dedusting ash, quartz sand, coal ash and waste glass solid are used as raw materials, other chemical raw materials are not added, and the microcrystalline glass is prepared through component blending, thus various solid wastes are comprehensively recycled, and the environment pollution problem caused by heavy metal chromium is solved. The microcrystalline glass prepared by the method in the invention has the advantages of low cost and wide raw material sources, is suitable for large-scale industrial production, and can be widely applied to the fields of building, decoration and industrial corrosion prevention.
Description
Technical field
The invention belongs to solid waste resource reutilization field, be specifically related to take stainless steel slag as main raw material and dedusting ash of stainless steel, quartz sand, flyash, cullet in one or more be auxiliary material through devitrified glass of allotment and preparation method thereof.
Background technology
Along with the development of steel industry, the output of ferrous metallurgy slag is increasing.China's stainless steel output reached 1,130 ten thousand tons in 2010, had produced stainless steel slag and 200,000 tons of dedusting ash of stainless steel of 2,260,000 tons.In stainless steel slag and dedusting ash of stainless steel, it is different from other metallurgical slag because containing heavy metal chromium, and oozing out of heavy metal chromium has serious environmental risk, belongs to danger wastes.At present, the stainless steel slag of domestic each stainless steel manufacturer and dedusting ash of stainless steel carry out that the slag field is stacked, preparation cement, build the road etc., and the stainless steel slag of stacking and dedusting ash of stainless steel are easy to ooze out Cr
+ 3And be oxidized to Cr under physical environment
+ 6, chromium ion is easy to ooze out from concrete, cement products under certain sour environment simultaneously, the water-soluble migration, and extend in time the seepage discharge increase, and cause serious water to pollute, cause even cancer of human body mucosal ulcer.Therefore, the green composite utilization of stainless steel slag and dedusting ash of stainless steel is the metallurgy industry urgent need to solve the problem.
At present, a lot of producers utilize stainless steel slag and other raw material to prepare the products such as cement, concrete and pottery.For example, Japanese Patent (JPA51083623) discloses at stainless steel slag and has added other oxide compound, passes into carbonic acid gas under certain condition and prepares light weight concrete, although these products can utilize stainless steel slag, Cr
+ 6Often can ooze out from these goods, pollute, and be difficult to these products are recycled.
Therefore in order to address these problems, to have proposed a lot of methods and stoped Cr in stainless steel slag
+ 6Ooze out, Japanese Laid-Open Patent (JP-A) No. Hei-6-171993 for example) proposed, when toppling over the stainless steel slag of molten state, add aluminium ash and magnesium oxide-based industrial waste in the stainless steel slag and stop oozing out of chromium ion in slag.But because molten steel viscosity is too large, toppling process can not carry out fine as to mix, and the chromic oxide that therefore can not be completely fixed in slag stops Cr
+ 6Ooze out.In addition, the United States Patent (USP) (US 6,732,547 B1) of Japanese JFE Iron And Steel Company application is by Cr during a certain amount of sulfide of interpolation (S is less than 0.20%) stops stainless steel slag in the covering slag in stainless steel refining process
+ 6Ooze out.This method is to Cr
+ 6Ooze out good interception arranged, this stainless steel slag can be applied in preparation cement and the aspect such as pave the way, but this method has reduced the viscosity of slag, and molten steel is produced pollutes.In order at room temperature to reduce Cr
+ 6Seepage discharge, utilize ferrous sulfate to make Cr as reductive agent
+ 6Be reduced into Cr
+ 3To reduce the harm of environment.Japanese Patent JP-A-53028563 disclose a kind of utilize under sour environment calcium sulfite as reductive agent Cr
+ 6Be reduced into Cr
+ 3, then add oxyhydroxide and make Cr
+ 3Be transformed into the chromium hydroxide compound, add in cement at last being fixed to.This patent probably is reduced into Cr again not with the high-valued recycling of stainless steel slag under well-oxygenated environment
+ 6Cause serious environmental pressure.
For stainless steel slag being carried out green high-valued recycling, prepare as main raw material the attention that devitrified glass obtains people with it.Devitrified glass does not absorb water, and resistance to acids and bases is strong, and the chromium element serves as the crystallite nucleating agent, and good fixed action is arranged, and stops Cr
+ 6Pollution problem.In addition, the devitrified glass waste material can repeatedly melt down recycling.Chinese invention patent CN101838108A(application number: 201010154436.8 Shen Qing Publication dates: a kind of method of utilizing that 2010.09.22) discloses recovery of stainless steel tailings and flyash, by adding sodium carbonate and barium oxide, mix with stainless steel slag, flyash and quartz sand proportioning, adopt fusing, cast, annealing, coring, crystallization and processing to obtain devitrified glass.This application can be utilized stainless steel slag and the standby devitrified glass of coal ash for manufacturing, and owing to having added sodium carbonate and barium oxide industrial chemicals, production cost has improved.
The invention provides a kind of take stainless steel slag, dedusting ash of stainless steel, quartz sand, flyash, cullet solid waste as raw material, do not add other industrial chemicals, allocate the low-cost method for preparing devitrified glass by composition, not only various solid wastes is carried out the green composite cycling and reutilization, solved Cr in stainless steel slag and dedusting ash of stainless steel
+ 6Ooze out caused problem of environmental pollution.The devitrified glass of the present invention preparation has that cost is low, raw material sources are extensive, is fit to large-scale industrial production, and product can be widely used in building, decoration and industrial antisepsis field.
Summary of the invention
The present situation of utilizing for stainless steel slag and dedusting ash of stainless steel, the invention provides the method for stainless steel slag, dedusting ash of stainless steel, quartz sand, flyash, the utilization of cullet solid waste low cost green composite, make solid waste obtain low-cost high-efficiency increment recycling, stop Cr in stainless steel slag
+ 6Ooze out caused problem of environmental pollution.
Devitrified glass of the present invention not only makes stainless steel slag and dedusting ash of stainless steel can prepare devitrified glass by the composition adjustment, various solid wastes is carried out comprehensive cycling and reutilization, and having solved the caused problem of environmental pollution of heavy metal chromium, it comprises F, Cr simultaneously
2O
3, TiO
2, Fe
2O
3, one or more nucleating agent of S.
The technical solution adopted in the present invention is: take stainless steel slag as the basis, add dedusting ash of stainless steel, cullet, flyash, quartz sand and TiO
2In one or more be deployed into the devitrified glass of suitable component, wherein, the shared weight percent of stainless steel slag, dedusting ash of stainless steel, quartz sand, flyash and cullet is: stainless steel slag is 35 ~ 55%, quartz sand is 0 ~ 42%, flyash is 0 ~ 23%, dedusting ash of stainless steel is 0 ~ 15%, and cullet is 0 ~ 55%, TiO
2Be 0 ~ 5%.Table 1 has been listed the present invention's stainless steel slag, dedusting ash of stainless steel, flyash, cullet and quartz sand main component used.
Table 1 material composition compositing range (weight percent)
| Raw material type | Stainless steel slag | Dedusting ash of stainless steel | Flyash | Cullet | Quartz sand |
| SiO 2 | 18~24 | 20~25 | 55~58 | 73~77 | 97~99 |
| CaO | 32~40 | 38~43 | 4~7 | 10~13 | ― |
| MgO | 22~30 | 12~17 | 0~1 | ― | ― |
| Al 2O 3 | 4~8 | 4~6 | 15~30 | ― | ― |
| Cr 2O 3 | 0.4~3 | 10~14 | ― | ― | ― |
| TiO 2 | 0~1 | ― | 0~2 | ― | ― |
| Fe 2O 3 | 1~3 | 4~6 | 5~13 | ― | ― |
| Na 2O | ― | ― | ― | 10~15 | ― |
| F | 1~3 | ― | ― | ― | ― |
| Other | 0~2 | 0~2 | 1~4 | 1~3 | 1~3 |
Allocating by composition makes the devitrified glass component be: SiO
2Weight percent is 45 ~ 60%, the CaO weight percent is 20 ~ 28%, the MgO weight percent is 10 ~ 15%, Al
2O
3Weight percent is 2 ~ 9%, Na
2The O weight percent is 0 ~ 8%, Fe
2O
3Weight percent is 0.5 ~ 5%, Cr
2O
3Weight percent is 0.4 ~ 2.5%, the F weight percent is 0.5 ~ 1.5%, TiO
2Weight percent is 0.1 ~ 6%.
Another object of the present invention is to provide the above-mentioned preparation method of devitrified glass, and concrete technology is as follows:
(1) batching: the stainless steel slag weight percent is 35 ~ 55%; Addition material is one or more of quartz sand, flyash, dedusting ash of stainless steel, cullet, and the addition material weight percent is dedusting ash of stainless steel: 0 ~ 15%, and quartz sand: 0 ~ 42%, flyash: 0 ~ 23%, cullet: 0 ~ 55%, TiO
2: 0 ~ 5%;
(2) batch mixing: the devitrified glass raw material that proportioning is good mixes;
(3) melting: the heating raw materials to 1400 that mixes ~ 1600 ℃ is fused into glass solution and is incubated 1 ~ 3 hour;
(4) casting: the glass metal after melting is cast in 600 ~ 700 ℃ of stainless steel moulds is shaped;
(5) coring: the glass after being shaped is placed in process furnace, is heated to 650 ~ 900 ℃, coring 1 ~ 3 hour with the heat-up rate of 5 ~ 15 ℃/min;
(6) crystallization: the glass after coring is heated to 850 ~ 1100 ℃, crystallization 1 ~ 3 hour with the heat-up rate of 5 ~ 15 ℃/min;
(7) annealing: stove is chilled to 600 ℃ of annealing 1 ~ 2 hour, makes devitrified glass through polishing, polishing.
Devitrified glass composition range of the present invention is take weight percent as SiO
2Be that 45 ~ 60%, CaO is that 20 ~ 28%, MgO is 10 ~ 15%, Al
2O
3Be 2 ~ 9%, Na
2O is 0 ~ 8%, Fe
2O
3Be 0.5 ~ 5%, Cr
2O
3Be that 0.4 ~ 2.5%, F is 0.1 ~ 1.5%, TiO
2Be 0.1 ~ 6%.
It is that raw material prepares devitrified glass that the present invention adopts stainless steel slag, dedusting ash of stainless steel, quartz sand, flyash, cullet solid waste, not only various solid wastes is carried out the high value cycling and reutilization of low cost, and solved the problem of environmental pollution of heavy metal chromium.The devitrified glass of the present invention's preparation can be widely used in building, decoration and industrial antisepsis.
Embodiment
According to the raw material of table 1, the required devitrified glass composition of proportioning obtains devitrified glass through melting, casting, coring, crystallization, annealing and post-treatment operation.Below be further described with the preparation of the right devitrified glass of embodiment, will help the present invention is better understood.Protection domain of the present invention is not subjected to the restriction of these embodiment, and protection scope of the present invention is determined by claims.
Embodiment 1
(1) batching: raw material is by weight ratio: stainless steel slag: 55%, and quartz sand: 42%; Flyash: 3%;
(2) batch mixing: the devitrified glass raw material for preparing is mixed;
(3) melting: the heating raw materials to 1600 that mixes ℃ is fused into glass solution and is incubated 1 hour;
(4) casting: the glass metal after melting is cast in 700 ℃ of stainless steel moulds is shaped;
(5) coring: the glass after being shaped is placed in process furnace, is heated to 900 ℃, coring 3 hours with the heat-up rate of 15 ℃/min;
(6) crystallization: the glass after coring is heated to 1100 ℃, crystallization 3 hours with the heat-up rate of 15 ℃/min;
(7) annealing: stove is chilled to 600 ℃ of annealing 2 hours, makes devitrified glass through polishing, polishing.
The prepared devitrified glass chemical constitution of above-mentioned technique is (weight percent): SiO
2: 60%; CaO:25.5%; MgO:10%; Al
2O
3: 2%; Fe
2O
3: 0.5%; Cr
2O
3: 0.4%; F:1.5%; TiO
2: 0.1%;
Embodiment 2
(1) batching: raw material is by weight ratio: stainless steel slag: 35%, and dedusting ash of stainless steel: 15%; Cullet: 50%;
(2) batch mixing: the devitrified glass raw material for preparing is mixed;
(3) melting: the heating raw materials to 1400 that mixes ℃ is fused into glass solution and is incubated 3 hours;
(4) casting: the glass metal after melting is cast in 600 ℃ of stainless steel moulds is shaped;
(5) coring: the glass after being shaped is placed in process furnace, is heated to 650 ℃, coring 2 hours with the heat-up rate of 5 ℃/min;
(6) crystallization: the glass after coring is heated to 850 ℃, crystallization 2 hours with the heat-up rate of 5 ℃/min;
(7) annealing: stove is chilled to 600 ℃ of annealing 1 hour, makes devitrified glass through polishing, polishing.
The prepared devitrified glass chemical constitution of above-mentioned technique is (weight percent): SiO
2: 45%; CaO:28%; MgO:11.9%; Al
2O
3: 3%; Na
2O:7.5%; Fe
2O
3: 1.5%; Cr
2O
3: 2.5%; F:0.5%; TiO
2: 0.1%.
Embodiment 3
(1) batching: raw material is by weight ratio: stainless steel slag: 40%, and dedusting ash of stainless steel: 10%; Quartz sand: 12%; Flyash: 23%; TiO
2: 5%;
(2) batch mixing: the devitrified glass raw material for preparing is mixed;
(3) melting: the heating raw materials to 1500 that mixes ℃ is fused into glass solution and is incubated 2 hours;
(4) casting: the glass metal after melting is cast in 650 ℃ of stainless steel moulds is shaped;
(5) coring: the glass after being shaped is placed in process furnace, is heated to 650 ℃, coring 1 hour with the heat-up rate of 10 ℃/min;
(6) crystallization: the glass after coring is heated to 950 ℃, crystallization 1 hour with the heat-up rate of 10 ℃/min;
(7) annealing: stove is chilled to 600 ℃ of annealing 1.5 hours, makes devitrified glass through polishing, polishing.
The prepared devitrified glass chemical constitution of above-mentioned technique is (weight percent): SiO
2: 45%; CaO:20%; MgO:12%; Al
2O
3: 9%; Fe
2O
3: 5%; Cr
2O
3: 1.3%; F:0.7%; TiO
2: 6%.
Embodiment 4
(1) batching: raw material is by weight ratio: stainless steel slag: 55%, and dedusting ash of stainless steel: 15%; Quartz sand: 15%; Flyash: 15%;
(2) batch mixing: the devitrified glass raw material for preparing is mixed;
(3) melting: the heating raw materials to 1550 that mixes ℃ is fused into glass solution and is incubated 2 hours;
(4) casting: the glass metal after melting is cast in 680 ℃ of stainless steel moulds is shaped;
(5) coring: the glass after being shaped is placed in process furnace, is heated to 840 ℃, coring 2 hours with the heat-up rate of 12 ℃/min;
(6) crystallization: the glass after coring is heated to 1000 ℃, crystallization 2 hours with the heat-up rate of 12 ℃/min;
(7) annealing: stove is chilled to 600 ℃ of annealing 2 hours, makes devitrified glass through polishing, polishing.
The prepared devitrified glass chemical constitution of above-mentioned technique is (weight percent): SiO
2: 50%; CaO:23.5%; MgO:15%; Al
2O
3: 5%; Fe
2O
3: 2%; Cr
2O
3: 2.5%; F:1%; TiO
2: 1%.
Embodiment 5
(1) batching: raw material is by weight ratio: stainless steel slag: 50%, and dedusting ash of stainless steel: 8%; Quartz sand: 20%; Flyash: 10%; Cullet: 10%; TiO
2: 2%;
(2) batch mixing: the devitrified glass raw material for preparing is mixed;
(3) melting: the heating raw materials to 1450 that mixes ℃ is fused into glass solution and is incubated 1.5 hours;
(4) casting: the glass metal after melting is cast in 660 ℃ of stainless steel moulds is shaped;
(5) coring: the glass after being shaped is placed in process furnace, is heated to 800 ℃, coring 2 hours with the heat-up rate of 7.5 ℃/min;
(6) crystallization: the glass after coring is heated to 900 ℃, crystallization 2 hours with the heat-up rate of 7.5 ℃/min;
(7) annealing: stove is chilled to 600 ℃ of annealing 1.5 hours, makes devitrified glass through polishing, polishing.
The prepared devitrified glass chemical constitution of above-mentioned technique is (weight percent): SiO
2: 52%; CaO:23%; MgO:12.4%; Al
2O
3: 4%; Na
2O:3%; Fe
2O
3: 1.5%; Cr
2O
3: 1%; F:0.6%; TiO
2: 2.5%.
Embodiment 6
(1) batching: raw material is by weight ratio: stainless steel slag: 35%, and dedusting ash of stainless steel: 5%; Flyash: 4%; Cullet: 55%, TiO
2: 1%;
(2) batch mixing: the devitrified glass raw material for preparing is mixed;
(3) melting: the heating raw materials to 1480 that mixes ℃ is fused into glass solution and is incubated 2.5 hours;
(4) casting: the glass metal after melting is cast in 620 ℃ of stainless steel moulds is shaped;
(5) coring: the glass after being shaped is placed in process furnace, is heated to 700 ℃, coring 1.5 hours with the heat-up rate of 9 ℃/min;
(6) crystallization: the glass after coring is heated to 1050 ℃, crystallization 1.5 hours with the heat-up rate of 8 ℃/min;
(7) annealing: stove is chilled to 600 ℃ of annealing 1.5 hours, makes devitrified glass through polishing, polishing.
The prepared devitrified glass chemical constitution of above-mentioned technique is (weight percent): SiO
2: 55%; CaO:21%; MgO:8%; Al
2O
3: 3.8%; Na
2O:8%; Fe
2O
3: 1.5%; Cr
2O
3: 0.7%; F:0.5%; TiO
2: 1.5%.
Claims (2)
1. a devitrified glass, is characterized in that, the composition of this devitrified glass is: take stainless steel slag as major ingredient, with dedusting ash of stainless steel, quartz sand, flyash, cullet, TiO
2Be auxiliary material; Wherein, the shared weight percent of each component is: stainless steel slag is 35 ~ 55%, and dedusting ash of stainless steel is≤15% and greater than 0, and quartz sand is≤42% and greater than 0, and flyash is≤23% and greater than 0, and cullet is≤55% and greater than 0, TiO
2For≤5% and greater than 0; Allocating component by composition is: SiO
2Weight percent is 45 ~ 60%, the CaO weight percent is 20 ~ 28%, the MgO weight percent is 10 ~ 15%, Al
2O
3Weight percent is 2 ~ 9%, Na
2The O weight percent is 0 ~ 8%, Fe
2O
3Weight percent is 0.5 ~ 5%, Cr
2O
3Weight percent is 0.4 ~ 2.5%, the F weight percent is 0.5 ~ 1.5%, TiO
2Weight percent is 0.1 ~ 6%.
2. the preparation method of devitrified glass according to claim 1, it is levied and is, specifically comprises the following steps:
(1) batching: the stainless steel slag weight percent is 35 ~ 55%; Addition material is dedusting ash of stainless steel, quartz sand, flyash, cullet and TiO
2, the addition material weight percent amount is that dedusting ash of stainless steel is≤15% and greater than 0, and quartz sand is≤42% and greater than 0, and flyash is≤23% and greater than 0, and cullet is≤55% and greater than 0, TiO
2For≤5% and greater than 0;
(2) batch mixing: the devitrified glass raw material that proportioning is good mixes;
(3) melting: the heating raw materials to 1400 that mixes ~ 1600 ℃ is fused into glass melt and is incubated 1 ~ 3 hour;
(4) casting: glass melt is cast in 600 ~ 700 ℃ of stainless steel moulds is shaped;
(5) coring: the glass after being shaped is placed in process furnace, is heated to 650 ~ 900 ℃, coring 1 ~ 3 hour with the heat-up rate of 5 ~ 15 ℃/min;
(6) crystallization: the glass after coring is heated to 850 ~ 1100 ℃, crystallization 1 ~ 3 hour with the heat-up rate of 5 ~ 15 ℃/min;
(7) annealing: stove is chilled to 600 ℃ of annealing 1 ~ 2 hour, makes devitrified glass through polishing, polishing.
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055724A (en) * | 1991-04-26 | 1991-10-30 | 连云港市特种灯泡厂 | Method for making nucleatede glass marble from phosphoric tailings |
| CN101020968A (en) * | 2006-12-29 | 2007-08-22 | 金川集团有限公司 | Process of comprehensively utilizing high temperature nickel smelting slag |
| CN101914639A (en) * | 2010-09-08 | 2010-12-15 | 北京科技大学 | Method for recycling iron on line from iron-containing industrial slag and preparing glass ceramics frit |
-
2011
- 2011-05-10 CN CN 201110119884 patent/CN102211874B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1055724A (en) * | 1991-04-26 | 1991-10-30 | 连云港市特种灯泡厂 | Method for making nucleatede glass marble from phosphoric tailings |
| CN101020968A (en) * | 2006-12-29 | 2007-08-22 | 金川集团有限公司 | Process of comprehensively utilizing high temperature nickel smelting slag |
| CN101914639A (en) * | 2010-09-08 | 2010-12-15 | 北京科技大学 | Method for recycling iron on line from iron-containing industrial slag and preparing glass ceramics frit |
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