CN103641311A - High-calcium and lightweight glass bottle formula - Google Patents
High-calcium and lightweight glass bottle formula Download PDFInfo
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- CN103641311A CN103641311A CN201310670404.7A CN201310670404A CN103641311A CN 103641311 A CN103641311 A CN 103641311A CN 201310670404 A CN201310670404 A CN 201310670404A CN 103641311 A CN103641311 A CN 103641311A
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- formula
- raw material
- glass
- calcium
- glass bottle
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Abstract
The invention discloses a high-calcium and lightweight glass bottle formula. The formula disclosed by the invention comprises 1) a raw material comprising the materials by weight percent: 70-75% of quartz sand SiO2, 12-16% of sodium carbonate NaCO3, 9-12% of calcite CaCO3, 2-3% of aluminum oxide Al2O3, 0.3-0.7% of sodium fluosilicate Na2SiF6, 0.4-0.8% of sodium nitrate NaNO3, 0.002-0.007% of zinc selenite ZnSeO3.2H2O, and 2) a clinker, namely glass slag which is 60% of weight of the raw material. A glass bottle prepared from the high-calcium and lightweight glass bottle formula disclosed by the invention is high in strength, good in color, good in brightness, high in utilization rate of waste glass, and high in yield of finished products.
Description
Technical field
The invention belongs to vial material prescription, especially solid waste glass is recycled melting and is made the formula technique field that vial adopts.
Background technology
At present, adopt the existing glass bottle of filling a prescription and producing that solid waste glass is recycled, easily occur bubble; Insufficient strength, maximum impact resistance is generally 0.5 to 0.6J; Finished product qualification rate is lower, and qualification rate is only 85% to 90%.This existing formula is,
1), raw material:
Quartz sand SiO
2, soda ash NaCO
3, calcite CaCO
3, Feldspar Powder Al
2o
3, fluorite CaF
2:, Sodium sulfate anhydrous.min(99) Na
2sO
4, SODIUMNITRATE NaNO
3, selenium-cobalt discoloring agent;
2), grog: glass dregs.
The accurate formula wherein the most often adopting is:
1), raw material:
Quartz sand SiO
2: 72.0%, soda ash NaCO
3: 14.8%, calcite CaCO
3: 9.8%, Feldspar Powder Al
2o
3: 3.0%, fluorite CaF
2: 0.8%, Sodium sulfate anhydrous.min(99) Na
2sO
4: 0.9%, SODIUMNITRATE NaNO
3: 0.6%, the weight of raw material before selenium-cobalt discoloring agent 8g/200KG();
2), grog: glass dregs is 40% of raw material weight.
The defect that above-mentioned existing solid waste glass is recycled the formula material existence of melting making vial employing is: the Feldspar Powder in existing formula belongs to mineral products, slag is a lot, using Feldspar Powder is mainly the aluminium element using wherein, owing to wherein containing iron, iron can affect the Forming Quality of vial and the intensity of vial;
Fluorite in existing formula, what mainly use is the fluorine element of its inside, for glass metal clarification.Fluorite belongs to mineral products, wherein certainly exists other element, can not use completely, and the element wherein having also can affect quality product, such as iron, magnesium elements;
Sodium sulfate anhydrous.min(99) in existing formula, life-time service can corrode kiln pond, reduces kiln pond work-ing life;
Selenium-cobalt discoloring agent in existing formula, cobalt wherein can affect the quality of vial;
Grog in existing actual formula adopts 40% glass dregs, also not very high to a kind of utilization ratio of scrap glass used in everyday.
The formula of above-mentioned prior art also makes the vial of making easily produce bubble, and impact resistance is also poor, and the qualification rate of finished product is not high yet.
Object of the present invention provides a kind of vial intensity of making high in order to overcome defect that above-mentioned prior art exists and weak point just, color, lightness are good, the high calcium that scrap glass utilization ratio is high, the qualification rate of finished product is high and light-weighted vial formula.
The object of the invention is to realize by following technical solution.
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 70～75%, soda ash NaCO
3: 12～16%, calcite CaCO
3: 9～12%, aluminium oxide Al
2o
3: 2～3%, Sodium Silicofluoride Na
2siF
6: 0.3～0.7%, SODIUMNITRATE NaNO
3: 0.4～0.8%, zincium selenious acid ZnSeO
3.2H
2o 0.002～0.007%;
2), grog: glass dregs is 60% of raw material weight.
Optimum formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 72.5%, soda ash NaCO
3: 13.8%, calcite CaCO
3: 10.296%, aluminium oxide Al
2o
3: 2.3%, Sodium Silicofluoride Na
2siF
6: 0.5%, SODIUMNITRATE NaNO
3: 0.6%, zincium selenious acid ZnSeO
3.2H
2o 0.004%;
2), grog: glass dregs is 60% of raw material weight.
The invention has the beneficial effects as follows, the vial intensity of making is high, and color, lightness are good, and scrap glass utilization ratio is high, the qualification rate of finished product is high.
The bottle that adopts formula of the present invention to produce, bottle is without bubble; Impact resistance can reach 0.7J to 1.0J, intensity enhancing; Finished product qualification rate reaches more than 97%.
The present invention changes aluminum oxide into by original Feldspar Powder: avoided bringing into of other slag, guaranteed glassy product quality.
The present invention changes Sodium Silicofluoride into by the fluorite of use originally, and the ratio of other raw material is adjusted, because its all the components is all operable (such as fluorine, silicon oxide, sodium oxide), has effectively controlled cost.And use, when glass melting, can play to glass metal the effect of clarification.
The present invention does not adopt Sodium sulfate anhydrous.min(99), so long as because life-time service can corrode kiln pond, reduces kiln pond work-ing life.
The present invention changes selenium-cobalt discoloring agent into zincium selenious acid, is mainly because wherein cobalt can affect the quality of vial.Make zincium selenious acid into, because it easily volatilizees, can guarantee the transparency of vial and avoid other color quality to affect quality product.
Grog of the present invention changes 60% into by 40% original glass dregs, and effectively a kind of effective utilization to scrap glass used in everyday, reduces costs, and has also protected environment.
The present invention also further by test of many times and analysis, has found out optimum formula on the basis of revising prior art formula, and this optimum formula has had very significant above-mentioned effect, becomes the preferred of a kind of the present invention's formula.
Embodiment
Embodiment mono-
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 70%, soda ash NaCO
3: 16%, calcite CaCO
3: 10.493%, aluminium oxide Al
2o
3: 2%, Sodium Silicofluoride Na
2siF
6: 0.7%, SODIUMNITRATE NaNO
3: 0.8%, zincium selenious acid ZnSeO
3.2H
2o 0.007%;
2), grog: glass dregs is 60% of raw material weight.
Embodiment bis-
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 75%, soda ash NaCO
3: 12%, calcite CaCO
3: 9.298%, aluminium oxide Al
2o
3: 3%, Sodium Silicofluoride Na
2siF
6: 0.3%, SODIUMNITRATE NaNO
3: 0.4%, zincium selenious acid ZnSeO
3.2H
2o 0.002%;
2), grog: glass dregs is 60% of raw material weight.
31 kinds of high calciums of embodiment and light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 72.5%, soda ash NaCO
3: 13.8%, calcite CaCO
3: 10.296%, aluminium oxide Al
2o
3: 2.3%, Sodium Silicofluoride Na
2siF
6: 0.5%, SODIUMNITRATE NaNO
3: 0.6%, zincium selenious acid ZnSeO
3.2H
2o 0.004%;
2), grog: glass dregs is 60% of raw material weight.
Embodiment tetra-
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 71%, soda ash NaCO
3: 14.094%, calcite CaCO
3: 12%, aluminium oxide Al
2o
3: 2%, Sodium Silicofluoride Na
2siF
6: 0.4%, SODIUMNITRATE NaNO
3: 0.5%, zincium selenious acid ZnSeO
3.2H
2o 0.006%;
2), grog: glass dregs is 60% of raw material weight.
Embodiment five
High calcium and a light-weighted vial formula, formula of the present invention is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 74%, soda ash NaCO
3: 13.197%, calcite CaCO
3: 9%, aluminium oxide Al
2o
3: 2.5%, Sodium Silicofluoride Na
2siF
6: 0.6%, SODIUMNITRATE NaNO
3: 0.7%, zincium selenious acid ZnSeO
3.2H
2o 0.003%;
2), grog: glass dregs is 60% of raw material weight.
Claims (2)
1. high calcium and a light-weighted vial formula, is characterized in that, filling a prescription is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 70～75%, soda ash NaCO
3: 12～16%, calcite CaCO
3: 9～12%, aluminium oxide Al
2o
3: 2～3%, Sodium Silicofluoride Na
2siF
6: 0.3～0.7%, SODIUMNITRATE NaNO
3: 0.4～0.8%, zincium selenious acid ZnSeO
3.2H
2o 0.002～0.007%;
2), grog: glass dregs is 60% of raw material weight.
2. a kind of high calcium according to claim 1 and light-weighted vial formula, is characterized in that, optimum formula is:
1), raw material: according to weight percent:
Quartz sand SiO
2: 72.5%, soda ash NaCO
3: 13.8%, calcite CaCO
3: 10.296%, aluminium oxide Al
2o
3: 2.3%, Sodium Silicofluoride Na
2siF
6: 0.5%, SODIUMNITRATE NaNO
3: 0.6%, zincium selenious acid ZnSeO
3.2H
2o 0.004%;
2), grog: glass dregs is 60% of raw material weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310670404.7A CN103641311A (en) | 2013-12-11 | 2013-12-11 | High-calcium and lightweight glass bottle formula |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310670404.7A CN103641311A (en) | 2013-12-11 | 2013-12-11 | High-calcium and lightweight glass bottle formula |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103641311A true CN103641311A (en) | 2014-03-19 |
Family
ID=50246648
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310670404.7A Pending CN103641311A (en) | 2013-12-11 | 2013-12-11 | High-calcium and lightweight glass bottle formula |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103641311A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105330145A (en) * | 2015-10-30 | 2016-02-17 | 太仓市双凤镇薄彩工艺品厂 | Formula of azure stone accessory |
| CN109534678A (en) * | 2019-01-22 | 2019-03-29 | 山东景耀玻璃集团有限公司 | A kind of low cost common white material glass and preparation method |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5718737A (en) * | 1995-03-03 | 1998-02-17 | International Cullet Exchange. Inc. | Method of recycling mixed colored cullet into amber, green, or flint glass |
| JPH10310446A (en) * | 1996-09-30 | 1998-11-24 | Fuoresuto:Kk | Production of glass product using fine powder of ohyaishi as starting material and glass product produced by same |
| CN1569712A (en) * | 2003-07-25 | 2005-01-26 | 阿城市大明玻璃制品有限公司 | Formulation for preparing high-class polyether bottle using varicolored cullet |
| CN102584017A (en) * | 2011-01-18 | 2012-07-18 | 武汉华夏玻璃制品有限公司 | Method for manufacturing beer bottles through broken glass |
| CN102584016A (en) * | 2011-01-18 | 2012-07-18 | 武汉华夏玻璃制品有限公司 | Method for manufacturing infusion bottles by using broken glass |
| CN102765882A (en) * | 2012-08-15 | 2012-11-07 | 黄炳炼 | Milk white glass wine bottle |
-
2013
- 2013-12-11 CN CN201310670404.7A patent/CN103641311A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5718737A (en) * | 1995-03-03 | 1998-02-17 | International Cullet Exchange. Inc. | Method of recycling mixed colored cullet into amber, green, or flint glass |
| JPH10310446A (en) * | 1996-09-30 | 1998-11-24 | Fuoresuto:Kk | Production of glass product using fine powder of ohyaishi as starting material and glass product produced by same |
| CN1569712A (en) * | 2003-07-25 | 2005-01-26 | 阿城市大明玻璃制品有限公司 | Formulation for preparing high-class polyether bottle using varicolored cullet |
| CN102584017A (en) * | 2011-01-18 | 2012-07-18 | 武汉华夏玻璃制品有限公司 | Method for manufacturing beer bottles through broken glass |
| CN102584016A (en) * | 2011-01-18 | 2012-07-18 | 武汉华夏玻璃制品有限公司 | Method for manufacturing infusion bottles by using broken glass |
| CN102765882A (en) * | 2012-08-15 | 2012-11-07 | 黄炳炼 | Milk white glass wine bottle |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105330145A (en) * | 2015-10-30 | 2016-02-17 | 太仓市双凤镇薄彩工艺品厂 | Formula of azure stone accessory |
| CN109534678A (en) * | 2019-01-22 | 2019-03-29 | 山东景耀玻璃集团有限公司 | A kind of low cost common white material glass and preparation method |
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| PB01 | Publication | ||
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140319 |