CN104176935B - Crystal-jade ceramic milk glass - Google Patents
Crystal-jade ceramic milk glass Download PDFInfo
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- CN104176935B CN104176935B CN201410403920.8A CN201410403920A CN104176935B CN 104176935 B CN104176935 B CN 104176935B CN 201410403920 A CN201410403920 A CN 201410403920A CN 104176935 B CN104176935 B CN 104176935B
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Abstract
The invention discloses a crystal-jade ceramic milk glass which is prepared by melting the following raw materials in parts by weight: 55-65 parts of quartz sand, 4-7 parts of commercial alumina, 1.2-2.4 parts of spodumene, 0.1-0.3 part of potassium nitrate, 10-14 parts of sodium carbonate, 3-6 parts of dolomite, 5-8 parts of sodium borate pentahydrate, 1-2 parts of barium carbonate, 0-0.5 part of calcite, 2-5 parts of sodium fluosilicate, 1-2 parts of zinc oxide, 1-2 parts of colorant, 3-6 parts of opacifier regulator and 1-2 parts of clarifier. The dolomite and multiple additives are used instead of magnesium oxide and for reducing the consumption of fluorides, thereby lowering the raw material cost on the premise of ensuring the milky effect, reducing the environmental pollution, being more beneficial to lowering the melting temperature, accelerating the melting process and lowering energy consumption.
Description
Technical field
The present invention relates to the formulatory arts of pottery opal glass, particularly relate to a kind of brilliant beautiful matter pottery opal glass.
Background technology
Emulsion opal glass is containing the opaque of a large amount of dispersed particles or translucent opal glass and the general designation of coloured glass.Adding opacifiers in preparing glass charge and carry out high-temperature fusion, when temperature reduces, opacifiers isolates from frit because dissolubility reduces, and to disperse the biggest particle shape to be present in solid glass, forms the emulsion opal glass of various fineness.
For the opaque effect of reinforcing glass, most emulsion opal glass all adds magnesium oxide and fluoride.Although fluoride has certain opaque effect, but environment can be caused serious pollution by the use of a large amount of fluoride, and the cost of magnesium oxide is high, and chemical stability is low, apt to deteriorate, affects the quality stability that emulsion opal glass produces.
Summary of the invention
The technical problem that present invention mainly solves is to provide a kind of brilliant beautiful matter pottery opal glass, and fluoride consumption is few, pollutes few, and opaque effect is good, it is not necessary to magnesium oxide, low cost, and quality stability is high.
For solving above-mentioned technical problem, the technical scheme that the present invention uses is: provides a kind of brilliant beautiful matter pottery opal glass, prepares: quartz sand 55 ~ 65 parts, commercial alumina 4 ~ 7 parts, spodumene 1.2 ~ 2.4 parts, potassium nitrate 0.1 ~ 0.3 part, soda 10 ~ 14 parts, dolomite 3 ~ 6 parts, borax pentahydrate 5 ~ 8 parts, brium carbonate 1 ~ 2 part, 0 ~ 0.5 part of calcite, prodan 2 ~ 5 parts, zinc oxide 1 ~ 2 part, coloring agent 1 ~ 2 part, opacifiers regulator 3 ~ 6 parts and clarifier 1 ~ 2 part after the raw materials melt by following parts by weight.
In a preferred embodiment of the present invention, the temperature range of described raw materials melt is 1380 ~ 1450 DEG C.
In a preferred embodiment of the present invention, described clarifier is cerium oxide.
In a preferred embodiment of the present invention, described coloring agent is titanium dioxide.
In a preferred embodiment of the present invention, described milkiness regulator is calcium phosphate.
The invention has the beneficial effects as follows: a kind of brilliant beautiful matter pottery opal glass that the present invention points out, have employed dolomite and multiple additives to substitute magnesium oxide and to reduce the consumption of fluoride, the cost of raw material is reduced on the basis of ensureing opaque effect, decrease the pollution of environment, it is more beneficial for reducing glass melting temperature, accelerate the process founded, reduce energy consumption.
Detailed description of the invention
Technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described embodiment is only a part of embodiment of the present invention rather than whole embodiments.Based on the embodiment in the present invention, all other embodiments that those of ordinary skill in the art are obtained under not making creative work premise, broadly fall into the scope of protection of the invention.
The embodiment of the present invention includes:
A kind of brilliant beautiful matter pottery opal glass, prepare after raw materials melt by following parts by weight: quartz sand 55 ~ 65 parts, commercial alumina 4 ~ 7 parts, spodumene 1.2 ~ 2.4 parts, potassium nitrate 0.1 ~ 0.3 part, soda 10 ~ 14 parts, dolomite 3 ~ 6 parts, borax pentahydrate 5 ~ 8 parts, brium carbonate 1 ~ 2 part, 0 ~ 0.5 part of calcite, prodan 2 ~ 5 parts, zinc oxide 1 ~ 2 part, coloring agent 1 ~ 2 part, opacifiers regulator 3 ~ 6 parts and clarifier 1 ~ 2 part, the emulsion opal glass goods made, outward appearance is milky white as pottery, but it is sparkling and crystal-clear as beautiful, homogeneous, the most aobvious top grade.
The formula excellent in design of a kind of brilliant beautiful matter pottery opal glass that the present invention points out, produces low-temperature eutectic thing, lowers glass melting temperature when the introducing of dolomite makes to found, shorten melting process, such that it is able to reduce the energy consumption produced, energy-saving and emission-reduction, the temperature range of described raw materials melt is 1380 ~ 1450 DEG C.
Further, described clarifier is cerium oxide, and cerium oxide can strengthen the effect of milkiness, and can improve melted efficiency, the bubble produced when removing raw materials melt.
Further, described coloring agent is titanium dioxide.The whiteness of titanium dioxide is high, covering power is big, and low raw-material cost, the dispersibility in melting process is preferable.
In a preferred embodiment of the present invention, described milkiness regulator is calcium phosphate, and calcium phosphate according to actual needs, can regulate the effect of milkiness.
In sum, a kind of brilliant beautiful matter pottery opal glass that the present invention points out, opaque effect is outstanding, and fluoride consumption is few, pollutes little, non-oxidation magnesium, and the cost of material is low, and can shorten the time founded, and reduces melted temperature, reduces energy consumption.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every equivalent structure utilizing description of the invention content to be made or equivalence flow process conversion; or directly or indirectly it is used in other relevant technical field, the most in like manner it is included in the scope of patent protection of the present invention.
Claims (2)
1. a brilliant beautiful matter pottery opal glass, it is characterized in that, prepare after raw materials melt by following parts by weight: quartz sand 55 ~ 65 parts, commercial alumina 4 ~ 7 parts, spodumene 1.2 ~ 2.4 parts, potassium nitrate 0.1 ~ 0.3 part, soda 10 ~ 14 parts, dolomite 3 ~ 6 parts, borax pentahydrate 5 ~ 8 parts, brium carbonate 1 ~ 2 part, 0 ~ 0.5 part of calcite, prodan 2 ~ 5 parts, zinc oxide 1 ~ 2 part, coloring agent 1 ~ 2 part, milkiness regulator 3 ~ 6 parts and clarifier 1 ~ 2 part, described milkiness regulator is calcium phosphate, described clarifier is cerium oxide, and described coloring agent is titanium dioxide.
Brilliant beautiful matter pottery opal glass the most according to claim 1, it is characterised in that the temperature range of described raw materials melt is 1380 ~ 1400 DEG C.
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CN201410403920.8A CN104176935B (en) | 2014-08-18 | 2014-08-18 | Crystal-jade ceramic milk glass |
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CN201410403920.8A CN104176935B (en) | 2014-08-18 | 2014-08-18 | Crystal-jade ceramic milk glass |
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CN104176935A CN104176935A (en) | 2014-12-03 |
CN104176935B true CN104176935B (en) | 2017-01-11 |
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Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN105776859B (en) * | 2016-01-30 | 2018-05-18 | 淄博市淄川振华玻璃制品有限公司 | The preparation method of chicken gizzard stone coloured glaze |
CN107777881A (en) * | 2016-08-30 | 2018-03-09 | 江苏杰龙晶瓷科技有限公司 | A kind of method that milky white heat resistant glass is produced using lepidolite as raw material |
CN110451808A (en) * | 2019-08-19 | 2019-11-15 | 淮阴工学院 | A method of improving fluoride opal glass whiteness |
CN111977978A (en) * | 2020-09-09 | 2020-11-24 | 沂南三汇玻璃有限公司 | Jade-sapphire-blue-imitated glass and preparation method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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JPS61158840A (en) * | 1984-12-31 | 1986-07-18 | Masao Yoshizawa | Crystallized glass molded article and production thereof |
CN101717191A (en) * | 2009-11-13 | 2010-06-02 | 中国家用电器研究院 | Opal glass suitable for full electrofusion forming and preparation process thereof |
CN102199002B (en) * | 2011-01-22 | 2013-01-02 | 广东三圆微晶玻璃科技有限公司 | Jade crystal glass ceramic |
CN102531397B (en) * | 2012-01-11 | 2014-12-17 | 温州市汇顺达工贸有限公司 | Milky white glass ceramic suitable for all electric melting and preparation process for milky white glass ceramic |
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Effective date of registration: 20181126 Address after: 223800 Longjin Road 999, Sucheng Economic Development Zone, Suqian City, Jiangsu Province Patentee after: Jiangsu Bao Heng new Mstar Technology Ltd Address before: 223814 North of Longjin Road, Jiangsu Sucheng Economic Development Zone, Suqian City, Jiangsu Province Patentee before: JIANGSU JIELONG GLASSWARE TECHNOLOGY CO., LTD. |
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