CN108069606A - A kind of method that beer bottle is prepared using cullet - Google Patents

A kind of method that beer bottle is prepared using cullet Download PDF

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Publication number
CN108069606A
CN108069606A CN201610989647.0A CN201610989647A CN108069606A CN 108069606 A CN108069606 A CN 108069606A CN 201610989647 A CN201610989647 A CN 201610989647A CN 108069606 A CN108069606 A CN 108069606A
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CN
China
Prior art keywords
kilograms
cullet
beer bottle
powder
preparing
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Pending
Application number
CN201610989647.0A
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Chinese (zh)
Inventor
刘书刚
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Individual
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Individual
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Priority to CN201610989647.0A priority Critical patent/CN108069606A/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/004Refining agents
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/04Opacifiers, e.g. fluorides or phosphates; Pigments
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/02Compositions for glass with special properties for coloured glass

Abstract

A kind of method that beer bottle is prepared using cullet adds powder in every 1000 kilograms of cullet, wherein when preparing white beer bottle, the composition and its weight of the powder are:0.5 1.5 kilograms of 55 57 kilograms of quartz sand, 15 19 kilograms of soda ash, 15 19 kilograms of calcite, 36 kilograms of dolomite, 68 kilograms of feldspar, 35 kilograms of saltcake, 57 kilograms of fluorite, 12 kilograms of sodium nitrate or ceria;When preparing green beer bottle, the composition and its weight of the powder are:53 57 kilograms of quartz sand, 17 21 kilograms of soda ash, 7 10 kilograms of calcite, 35 kilograms of dolomite, 46 kilograms of feldspar, 46 kilograms of saltcake, 57 kilograms of fluorite, 0.5 1.5 kilograms of chromite ore fine;When preparing brown beer bottle, the composition and its weight of the powder are:52 56 kilograms of quartz sand, 17 20 kilograms of soda ash, 12 15 kilograms of calcite, 35 kilograms of dolomite, 46 kilograms of feldspar, 57 kilograms of saltcake, 57 kilograms of fluorite, 0.3 1.0 kilograms of carbon dust.The present invention can improve cullet utilization rate, ensure glass quality, can be suitable for the manufacture of beer bottle.

Description

A kind of method that beer bottle is prepared using cullet
Technical field
The present invention relates to the manufacturings of vial, are specifically a kind of method that beer bottle is prepared using cullet.
Background technology
How the largely discarded cullet generated in the daily production and living of people effectively recycle, be it is current domestic or even One of global glass worker problem urgently to be resolved hurrily.The prior art mainly uses the recycling of waste and old (or discarded) glass The quality index such as glass impurities are required with relatively low glass in low-grade horizontal drawing plate glass, mosaic glass etc..And for quality The high glass kind of index request, such as float glass do not add discarded glass generally as raw material.《The recycling of scrap glass is again It utilizes》(Jiang Wenjiu《Shanghai building materials》3rd phase in 2003) disclose applicable cases of the prior art to discarded cullet, disclosure Content quotation in this.
Cullet can reduce energy consumption and production costs as a kind of reclaimed materials, save resources of production, reduce environment The generation of discarded object reduces environmental pollution.But due to the waste and old cullet broad categories on present society, and color, composition All it is not quite similar.If these Resolving probiems cannot cannot be produced qualified beer bottle.
In addition the beer bottle brittleness merely using the production of waste and old cullet is higher, and intensity is low, while pressure-resistant and shock resistance is not It is qualified.So it is existing with waste and old cullet production beer bottle formula in, the content of waste and old cullet all below 70%, This is also the main reason for causing product cost higher.
The content of the invention
The present invention provides a kind of method that beer bottle is prepared using cullet, can improve cullet utilization rate, ensures glass Quality, such as shock resistance, compressive resistance can be suitable for the manufacture of beer bottle;Simultaneously have economize on resources, reduce into Originally the advantages that, reducing environmental pollution.
A kind of method that beer bottle is prepared using cullet adds powder in every 1000 kilograms of cullet, wherein
When preparing white beer bottle, the composition and its weight of the powder are:55-57 kilograms of quartz sand, 15-19 kilograms of soda ash, 15-19 kilograms of calcite, 3-6 kilograms of dolomite, 6-8 kilograms of feldspar, 3-5 kilograms of saltcake, 5-7 kilograms of fluorite, sodium nitrate 1-2 thousand Gram or 0.5-1.5 kilograms of ceria;
When preparing green beer bottle, the composition and its weight of the powder are:53-57 kilograms of quartz sand, 17-21 kilograms of soda ash, 7-10 kilograms of calcite, 3-5 kilograms of dolomite, 4-6 kilograms of feldspar, 4-6 kilograms of saltcake, 5-7 kilograms of fluorite, chromite ore fine 0.5- 1.5 kilogram;
When preparing brown beer bottle, the composition and its weight of the powder are:52-56 kilograms of quartz sand, 17-20 kilograms of soda ash, 12-15 kilograms of calcite, 3-5 kilograms of dolomite, 4-6 kilograms of feldspar, 5-7 kilograms of saltcake, 5-7 kilograms of fluorite, carbon dust 0.3-1.0 Kilogram.
The preparation method of beer bottle of the present invention and general beer bottle preparation method are essentially identical, compared with other prior arts, the present invention Advantageous effect be:
1) present invention adds in the powder (quartz sand, feldspar) of suitable SiO2, Al2O3 composition in cullet, and glass is adjusted Chemical composition improves the physical and chemical indexes such as beer bottle shock resistance and compressive resistance.
2) suitable powder containing R2O oxides (R represents Na or K), such as feldspar, soda ash are added in into glass dregs Deng on the one hand accelerating the fusing of glass, supplemented with the volatilization loss of cullet R2O in remelting, keep glass composition Ingredient stability.
3) present invention adds the fining agent Na2SO4 slightly more than conventional amount used, fluxing agent fluorite etc. in cullet, can be with The viscosity of glass is reduced, improves the clarifying speed of glass, strengthens glass metal homogenizing quality, bubble is enable to exclude rapidly, glass reason It is more excellent to change index, so as to prevent the problem of glass is difficult to clarify, bubble is difficult to escape occur when largely using cullet, improves The utilization rate of cullet.The content of the cullet of the present invention can reach 90-92%, so may be such that the production cost of beer bottle It substantially reduces.
4) suitable decolorising agent such as sodium nitrate or addition ceria (CeO2) etc. are added in when prepared by white beer bottle, Glass metal atmosphere is in oxidisability in melting furnaces;Green beer bottle adds in suitable Cr2O3 when preparing and glass is coloured, and addition is suitable The sodium sulphate of amount adjusts glass metal atmosphere in its melting furnaces and is in neutrality;Glass with Na2SO4 and carbon dust when prepared by brown beer bottle Color, it is in reproducibility to adjust glass metal atmosphere in its melting furnaces.Color, composition can be so solved in waste and old cullet well all not to the utmost The problem of identical, to produce qualified beer bottle.
Specific embodiment
The technical solution in the present invention is clearly and completely described with reference to specific embodiment.
1) white beer bottle is prepared:
Embodiment 1:
By 55-57 kilograms of quartz sand, 15-19 kilograms of soda ash, 15-19 kilograms of calcite, 3-6 kilograms of dolomite, feldspar 6-8 thousand Gram, 3-5 kilograms of saltcake, 5-7 kilograms of fluorite, 1-2 kilograms of sodium nitrate (or 0.5-1.5 kilograms of ceria), add in close material machine mix Uniformly powder is made in conjunction, and the uniformity of powder is made to reach >=95%, adds the cullet for meeting and preparing white beer bottle requirement It 1000 kilograms, is sufficiently mixed again with powder, moisture≤8% of mixture;Then it is made according to the processing technology of vial white Color beer bottle.
1000 kilograms of cullet for wherein preparing white beer bottle are flat including the general white glasses of 70-100% and 0-30% whites Glass sheet, the granularity of cullet is 10-40 millimeters, cullet water content≤5%.
Embodiment 2:
By 57 kilograms of quartz sand, 17 kilograms of soda ash, 17 kilograms of calcite, 4 kilograms of dolomite, 7 kilograms of feldspar, 5 kilograms of saltcake, firefly 6 kilograms of stone, 1.5 kilograms of sodium nitrate add in and close material machine and be uniformly mixed powder is made, and the uniformity of powder is made to reach >=95%, then 1000 kilograms of cullet for meeting white beer bottle requirement are added in, are sufficiently mixed again with powder, moisture≤8% of mixture; Then white beer bottle is made according to the processing technology of vial.
1000 kilograms of cullet for wherein preparing white beer bottle are flat including the general white glasses of 70-100% and 0-30% whites Glass sheet, the granularity of cullet is 10-40 millimeters, cullet water content≤5%.
2) green beer bottle is prepared:
Embodiment 1:
By 53-57 kilograms of quartz sand, 17-21 kilograms of soda ash, 7-10 kilograms of calcite, 3-5 kilograms of dolomite, 4-6 kilograms of feldspar, 4-6 kilograms of saltcake, 5-7 kilograms of fluorite, 0.5-1.5 kilograms of chromite ore fine, addition conjunction material machine, which is uniformly mixed, is made powder, makes the uniformity Reach >=95%, add 1000 kilograms of cullet for meeting green beer bottle requirement, be sufficiently mixed again with powder, mixture Moisture≤8%;Then green beer bottle is made according to the processing technology of vial.
Wherein preparing 1000 kilograms of cullet of green beer bottle includes 0-100% green glasses and other variegated glass, The granularity of cullet is 10-40 millimeters, cullet water content≤5%.
Embodiment 2:
By 55 kilograms of quartz sand, 19 kilograms of soda ash, 9 kilograms of calcite, 4 kilograms of dolomite, 5 kilograms of feldspar, 6 kilograms of saltcake, firefly 6 kilograms of stone, 1 kilogram of chromite ore fine, addition conjunction material machine are uniformly mixed and powder are made, and the uniformity is made to reach >=95%, adds and meets 1000 kilograms of the cullet of green beer bottle requirement, are sufficiently mixed, the CN102584017A specifications of mixture with powder again Moisture≤8% of page 43/3 5;Then green beer bottle is made according to the processing technology of vial.
Wherein preparing 1000 kilograms of cullet of green beer bottle includes 0-100% green glasses and other variegated glass, The granularity of cullet is 10-40 millimeters, cullet water content≤5%.
3) brown beer bottle is prepared:
Embodiment 1:
By 52-56 kilograms of quartz sand, 17-20 kilograms of soda ash, 12-15 kilograms of calcite, 3-5 kilograms of dolomite, feldspar 4-6 thousand Gram, 5-7 kilograms of saltcake, 5-7 kilograms of fluorite, 0.3-1.0 kilograms of carbon dust, add in and close material machine and be uniformly mixed powder is made, make uniformly Degree reaches >=95%, adds 1000 kilograms of cullet for meeting brown beer bottle requirement, is sufficiently mixed again with powder, mixes Moisture≤8% of material;Then brown beer bottle is made according to the processing technology of vial.
Wherein preparing 1000 kilograms of cullet of brown beer bottle includes 50-100% brown glass and the variegated glass of 0-50% Glass, the granularity of cullet is 10-40 millimeters, cullet water content≤5%.
Embodiment 2:
By 54 kilograms of quartz sand, 18 kilograms of soda ash, 14 kilograms of calcite, 4 kilograms of dolomite, 5 kilograms of feldspar, 5 kilograms of saltcake, firefly 6 kilograms of stone, 0.8 kilogram of carbon dust, addition conjunction material machine, which is uniformly mixed, is made powder, and the uniformity is made to reach >=95%, adds and meets 1000 kilograms of the cullet of brown beer bottle requirement, are sufficiently mixed, moisture≤8% of mixture with powder again;Then according to Brown beer bottle is made in the processing technology of vial.
Wherein prepare that 1000 kilograms of cullet of brown beer bottle include 50-100% brown glass and 0-50% is miscellaneous Color glass, the granularity of cullet is 10-40 millimeters, cullet water content≤5%.
During using cullet, granule size, dosage, Adding Way, the rational melting system of cullet are determined, to have Profit ensures that the quick of glass is melted and is homogenized.The granularity of cullet of the present invention is designed as 10-40 millimeters.The grain of cullet Degree cannot be too small, more much bigger than powder, and otherwise, the soda ash in raw material can first be reacted with cullet, and quartz sand raw material is caused to melt Change difficulty, entire melting process slack-off will degenerate, and desired design effect is not achieved.
The above description is merely a specific embodiment, but protection scope of the present invention is not limited thereto, any Belong to those skilled in the art in the technical scope disclosed by the present invention, the change or replacement that can be readily occurred in all should It is included within the scope of the present invention.Therefore, protection scope of the present invention should be subject to the protection scope in claims.

Claims (6)

  1. A kind of 1. method that beer bottle is prepared using cullet, it is characterised in that:Powder is added in every 1000 kilograms of cullet, Wherein
    When preparing white beer bottle, the composition and its weight of the powder are:55-57 kilograms of quartz sand, 15-19 kilograms of soda ash, 15-19 kilograms of calcite, 3-6 kilograms of dolomite, 6-8 kilograms of feldspar, 3-5 kilograms of saltcake, 5-7 kilograms of fluorite, sodium nitrate 1-2 thousand Gram or 0.5-1.5 kilograms of ceria;
    When preparing green beer bottle, the composition and its weight of the powder are:53-57 kilograms of quartz sand, 17-21 kilograms of soda ash, 7-10 kilograms of calcite, 3-5 kilograms of dolomite, 4-6 kilograms of feldspar, 4-6 kilograms of saltcake, 5-7 kilograms of fluorite, chromite ore fine 0.5- 1.5 kilogram;When preparing brown beer bottle, the composition and its weight of the powder are:52-56 kilograms of quartz sand, soda ash 17-20 thousand Gram, 12-15 kilograms of calcite, 3-5 kilograms of dolomite, 4-6 kilograms of feldspar, 5-7 kilograms of saltcake, 5-7 kilograms of fluorite, carbon dust 0.3- 1.0 kilogram.
  2. 2. the method for preparing beer bottle using cullet as described in claim 1, it is characterised in that:Prepare white beer bottle 1000 kilograms of cullet include the general white glasses of 70-100% and 0-30% white plate glass.
  3. 3. the method for preparing beer bottle using cullet as described in claim 1, it is characterised in that:Prepare green beer bottle 1000 kilograms of cullet include 0-100% green glasses and other variegated glass.
  4. 4. the method for preparing beer bottle using cullet as described in claim 1, it is characterised in that:Prepare brown beer bottle 1000 kilograms of cullet include 50-100% brown glass and the variegated glass of 0-50%.
  5. 5. the method for preparing beer bottle using cullet as described in claim 1, it is characterised in that:The uniformity of the powder >=95%, cullet water content≤5%, cullet are sufficiently mixed moisture≤8% of rear mixture with powder.
  6. 6. the method for preparing beer bottle using cullet as described in claim 1, it is characterised in that:The granularity of cullet is 10-40 millimeters.
CN201610989647.0A 2016-11-10 2016-11-10 A kind of method that beer bottle is prepared using cullet Pending CN108069606A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610989647.0A CN108069606A (en) 2016-11-10 2016-11-10 A kind of method that beer bottle is prepared using cullet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610989647.0A CN108069606A (en) 2016-11-10 2016-11-10 A kind of method that beer bottle is prepared using cullet

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CN108069606A true CN108069606A (en) 2018-05-25

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108423988A (en) * 2018-05-28 2018-08-21 江苏宝恒新材料科技有限公司 A method of using giving up, domestic glass produces repeat glass
CN109942183A (en) * 2019-02-22 2019-06-28 信义环保特种玻璃(江门)有限公司 Improve the method for the partially yellow phenomenon of the general white glass color of float glass process
US20210340047A1 (en) * 2020-05-04 2021-11-04 Bormioli Luigi S.P.A. Method for producing a glass container

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108423988A (en) * 2018-05-28 2018-08-21 江苏宝恒新材料科技有限公司 A method of using giving up, domestic glass produces repeat glass
CN109942183A (en) * 2019-02-22 2019-06-28 信义环保特种玻璃(江门)有限公司 Improve the method for the partially yellow phenomenon of the general white glass color of float glass process
CN109942183B (en) * 2019-02-22 2022-02-18 信义环保特种玻璃(江门)有限公司 Method for improving yellow color phenomenon of float white glass
US20210340047A1 (en) * 2020-05-04 2021-11-04 Bormioli Luigi S.P.A. Method for producing a glass container

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Application publication date: 20180525