CN108455845A - A kind of high hardness wear-resisting glass and preparation method thereof - Google Patents
A kind of high hardness wear-resisting glass and preparation method thereof Download PDFInfo
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- CN108455845A CN108455845A CN201810125660.0A CN201810125660A CN108455845A CN 108455845 A CN108455845 A CN 108455845A CN 201810125660 A CN201810125660 A CN 201810125660A CN 108455845 A CN108455845 A CN 108455845A
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C4/00—Compositions for glass with special properties
- C03C4/02—Compositions for glass with special properties for coloured glass
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C1/00—Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
- C03C1/04—Opacifiers, e.g. fluorides or phosphates; Pigments
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of high hardness wear-resisting glasses and preparation method thereof, are made of the component comprising the above parts by weight：24 32 parts of quartz sand, 18 26 parts of soda ash, 10 15 parts of nano silicon dioxide, 5 12 parts of mica powder, 49 parts of nano oxidized graphite, 38 parts of molybdenum disulfide, 26 parts of sodium metasilicate, 0.6 2.4 parts of zinc borate, 27 parts of silicon nitride, 48 parts of calcium oxide, 0.8 1.6 parts of adhesive, 0.4 1.2 parts of grinding aid, 0.3 0.8 parts of colorant.Technical solution provided by the present invention can effectively overcome the made glass hardness of the prior art low, the defect of wear-resisting property difference, and simple for process, be suitable for industrialized production.
Description
Technical field
The present invention relates to glass manufacturing technology fields, and in particular to a kind of high hardness wear-resisting glass and its preparation side
Method.
Background technology
Glass is although penetrating good-looking, but not easy to maintain, cautious must place, the cup of tangible all materials
In, glass is only most healthy, and glass is free of toxic chemical substance, when people are drunk water or Other Drinks with glass
When, it is not necessary to worry that harmful chemical substance can be drunk into belly, and surface is smooth, it is easy to clean, so people like very much
Joyous glass.
For a kind of crack preventing glass of acquisition and its preparation side in patent application CN106242279A disclosed in China
Method, using including giving a tongue-lashing in vain, silicon carbide, decolorising agent, grinding aid, corrosion inhibiter, adhesive, silica, sodium carbonate and talcum powder stir
It mixes and is mixed to prepare powder；Heating is carried out to the powder again, glass molten slurry is made, it is then that the glass molten slurry is mechanical-moulded, most
The crack preventing glass is made in after annealing, and the made glass of the invention has certain crack preventing performance.Disclosed in China
For a kind of crystal quartz glass of acquisition and preparation method thereof in patent application CN103922580A, using nano silica fume, nitre
Sour potassium, zirconium silicate, calcite, sodium fluoride, anhydrous sodium sulphate, sodium nitrate, kyanite, rare earth oxide, nanometer arsenic powder, nano-cobalt powder,
Cellulose, phosphotungstic acid are raw material, and glass shape glossiness obtained and reflecting effect are good, in beautiful color.
Although the made glass of the prior art has certain crack preventing performance, in beautiful color, made glass hardness
It is low, it is easily broken, wear-resisting property is poor, and scar can be left by encountering object with high hardness and colliding.
Invention content
In order to solve above-mentioned the deficiencies in the prior art, a kind of high hardness wear-resisting glass of present invention offer and its preparation side
Method.
In order to solve the above-mentioned technical problem, the present invention adopts the following technical scheme that：
A kind of high hardness wear-resisting glass, is made of the component comprising the above parts by weight：24-32 parts of quartz sand, soda ash 18-26
Part, 10-15 parts of nano silicon dioxide, 5-12 parts of mica powder, graphite 4-9 parts nano oxidized, 3-8 parts of molybdenum disulfide, sodium metasilicate 2-6
Part, 0.4-1.2 parts of grinding aid, 0.6-2.4 parts of zinc borate, 2-7 parts of silicon nitride, 4-8 parts of calcium oxide, 0.8-1.6 parts of adhesive
0.3-0.8 parts of toner.
Preferably, being made of the component comprising the above parts by weight：28 parts of quartz sand, 22 parts of soda ash, nano silicon dioxide
12.5 parts, 8.5 parts of mica powder, 6.5 parts of nano oxidized graphite, 5.5 parts of molybdenum disulfide, 4 parts of sodium metasilicate, 2 parts of zinc borate, silicon nitride
4.5 parts, 6 parts of calcium oxide, 1.2 parts of adhesive, 0.8 part of grinding aid, 0.5 part of colorant.
Preferably, the adhesive is selected from one or more of polyvinyl alcohol, phenolic resin, butadiene-styrene rubber.
Preferably, the grinding aid is selected from one or more of sodium acetate, aluminum sulfate and calcium formate.
Preferably, the colorant is selected from one or more of titanium dioxide, zinc oxide and lithopone.
The present invention also provides a kind of preparation methods of high hardness wear-resisting glass, include the following steps：
（1）Each component is weighed by regulation number；
（2）By quartz sand, soda ash, nano silicon dioxide, mica powder, nano oxidized graphite, molybdenum disulfide, sodium metasilicate, zinc borate,
Silicon nitride, calcium oxide mixing, carry out vibration mixing or ball milling mixing；
（3）The raw material of ball milling is sent into 1200-1300 DEG C of crucible and is melted to obtain glass metal, is then sequentially added
Adhesive, grinding aid, colorant, and 2-4h is melted at 1400-1450 DEG C after crucible cover is covered, obtain glass melt body；
（4）Glass melt body is sent into molding machine, extrusion forming is made the different glass of specification, is then naturally cooling to harden
It is sent into annealing furnace annealing 1-2h afterwards；
（5）Glass after annealing is sent into tempering in tempering case, high hardness wear-resisting glass is obtained after the completion of tempering.
Preferably, the vibration mixing is that raw material is put into vibration tank to vibrate 20-40min, vibration top tank structure is poly-
Tetrafluoroethene, vibration frequency 45Hz, amplitude 5mm, vibration force 12000N, power 0.80kW.
Preferably, the ball milling condition is that raw material is placed in wet-milling 30-40min on ball mill, wet grinding media is
Alcohol, drum's speed of rotation 350-400r/min, ball material mass ratio are 10：1.
Preferably, step（4）In, annealing temperature fall off rate is 5-15 DEG C/min.
Compared with prior art, the present invention has following advantageous effect：
（1）The high hardness wear-resisting glass obtained of the present invention, by the way that quartz sand, soda ash, nano silicon dioxide, mica is added
Powder, nano oxidized graphite, molybdenum disulfide, sodium metasilicate, zinc borate, silicon nitride, calcium oxide so that glass obtained has relatively strong
Hardness and preferable wear-resisting property；
（2）Raw material is ground into powder by the present invention in the way of vibration mixing or ball milling mixing, so that glass is made
Quality is more uniform, and flatness is high, and further improves the hardness and wear-resisting property of glass；
（3）High hardness wear-resisting glass processing method produced by the present invention is simple, and glass obtained has good process
Performance remains to keep color constant, is not in yellowing phenomenon after longer usage time；
（4）The present invention high hardness wear-resisting glass, preparation method is simple, and preparation process is nontoxic, have it is at low cost,
It is simple for process, it is suitable for industrialized production.
Specific implementation mode
Present invention will be further explained below with reference to specific examples.These embodiments are merely to illustrate the present invention and do not have to
In limiting the scope of the invention.
Embodiment 1
A kind of high hardness wear-resisting glass of the present embodiment, is made of the component comprising the above parts by weight：24 parts of quartz sand, soda ash
18 parts, 10 parts of nano silicon dioxide, 5 parts of mica powder, 4 parts of nano oxidized graphite, 3 parts of molybdenum disulfide, 2 parts of sodium metasilicate, zinc borate
0.6 part, 2 parts of silicon nitride, 4 parts of calcium oxide, 0.8 part of adhesive, 0.4 part of grinding aid, 0.3 part of colorant.
The adhesive of the present embodiment is selected from one or more of polyvinyl alcohol, phenolic resin, butadiene-styrene rubber.
The grinding aid of the present embodiment is selected from one or more of sodium acetate, aluminum sulfate and calcium formate.
The colorant of the present embodiment is selected from one or more of titanium dioxide, zinc oxide and lithopone.
The present invention also provides a kind of preparation methods of high hardness wear-resisting glass, include the following steps：
（1）Each component is weighed by regulation number；
（2）By quartz sand, soda ash, nano silicon dioxide, mica powder, nano oxidized graphite, molybdenum disulfide, sodium metasilicate, zinc borate,
Silicon nitride, calcium oxide mixing, carry out vibration mixing or ball milling mixing；
（3）It will be melted to obtain glass metal in crucible that the raw material of ball milling is sent DEG C, then sequentially add adhesive, grinding aid
Agent, colorant, and 2h is melted at 1400 DEG C after crucible cover is covered, obtain glass melt body；
（4）Glass melt body is sent into molding machine, extrusion forming is made the different glass of specification, is then naturally cooling to harden
It is sent into annealing furnace annealing 1h afterwards；
（5）Glass after annealing is sent into tempering in tempering case, high hardness wear-resisting glass is obtained after the completion of tempering.
The vibration mixing of the present embodiment is that raw material is put into vibration tank to vibrate 20min, and vibration top tank structure is polytetrafluoroethyl-ne
Alkene, vibration frequency 45Hz, amplitude 5mm, vibration force 12000N, power 0.80kW.
The ball milling condition of the present embodiment is that raw material is placed in wet-milling 30min on ball mill, and wet grinding media is alcohol, ball
Mill speed is 350r/min, and ball material mass ratio is 10：1.
The step of the present embodiment（4）In, annealing temperature fall off rate is 5 DEG C/min.
Embodiment 2
A kind of high hardness wear-resisting glass, is made of the component comprising the above parts by weight：32 parts of quartz sand, soda ash 26 part, nanometer
5 parts of silica 1,12 parts of mica powder, 9 parts of nano oxidized graphite, 8 parts of molybdenum disulfide, 6 parts of sodium metasilicate, 2.4 parts of zinc borate, nitrogen
7 parts of SiClx, 8 parts of calcium oxide, 1.6 parts of adhesive, 1.2 parts of grinding aid, 0.8 part of colorant.
The adhesive of the present embodiment is selected from one or more of polyvinyl alcohol, phenolic resin, butadiene-styrene rubber.
The grinding aid of the present embodiment is selected from one or more of sodium acetate, aluminum sulfate and calcium formate.
The colorant of the present embodiment is selected from one or more of titanium dioxide, zinc oxide and lithopone.
The present invention also provides a kind of preparation methods of high hardness wear-resisting glass, include the following steps：
（1）Each component is weighed by regulation number；
（2）By quartz sand, soda ash, nano silicon dioxide, mica powder, nano oxidized graphite, 5.5 parts of molybdenum disulfide, sodium metasilicate, boron
Sour zinc, silicon nitride, calcium oxide mixing, carry out vibration mixing or ball milling mixing；
（3）The raw material of ball milling is sent into 1300 DEG C of crucible and is melted to obtain glass metal, then sequentially adds gluing
Agent, grinding aid, colorant, and 4h is melted at 1450 DEG C after crucible cover is covered, obtain glass melt body；
（4）Glass melt body is sent into molding machine, extrusion forming is made the different glass of specification, is then naturally cooling to harden
It is sent into annealing furnace annealing 2h afterwards；
（5）Glass after annealing is sent into tempering in tempering case, high hardness wear-resisting glass is obtained after the completion of tempering.
The vibration mixing of the present embodiment is that raw material is put into vibration tank to vibrate 40min, and vibration top tank structure is polytetrafluoroethyl-ne
Alkene, vibration frequency 45Hz, amplitude 5mm, vibration force 12000N, power 0.80kW.
The ball milling condition of the present embodiment is that raw material is placed in wet-milling 40min on ball mill, and wet grinding media is alcohol, ball
Mill speed is 400r/min, and ball material mass ratio is 10：1.
The step of the present embodiment（4）In, annealing temperature fall off rate is 15 DEG C/min.
Embodiment 3
A kind of high hardness wear-resisting glass, is made of the component comprising the above parts by weight：28 parts of quartz sand, soda ash 22 part, nanometer
2.5 parts of silica 1,8.5 parts of mica powder, 6.5 parts of nano oxidized graphite, 5.5 parts of molybdenum disulfide, 4 parts of sodium metasilicate, zinc borate 2
Part, 4.5 parts of silicon nitride, 6 parts of calcium oxide, 1.2 parts of adhesive, 0.8 part of grinding aid, 0.5 part of colorant.
The adhesive of the present embodiment is selected from one or more of polyvinyl alcohol, phenolic resin, butadiene-styrene rubber.
The grinding aid of the present embodiment is selected from one or more of sodium acetate, aluminum sulfate and calcium formate.
The colorant of the present embodiment is selected from one or more of titanium dioxide, zinc oxide and lithopone.
The present invention also provides a kind of preparation methods of high hardness wear-resisting glass, include the following steps：
（1）Each component is weighed by regulation number；
（2）By quartz sand, soda ash, nano silicon dioxide, mica powder, nano oxidized graphite, 5.5 parts of molybdenum disulfide, sodium metasilicate, boron
Sour zinc, silicon nitride, calcium oxide mixing, carry out vibration mixing or ball milling mixing；
（3）The raw material of ball milling is sent into 1250 DEG C of crucible and is melted to obtain glass metal, then sequentially adds gluing
Agent, grinding aid, colorant, and 3h is melted at 1475 DEG C after crucible cover is covered, obtain glass melt body；
（4）Glass melt body is sent into molding machine, extrusion forming is made the different glass of specification, is then naturally cooling to harden
It is sent into annealing furnace annealing 1.5h afterwards；
（5）Glass after annealing is sent into tempering in tempering case, high hardness wear-resisting glass is obtained after the completion of tempering.
The vibration mixing of the present embodiment is that raw material is put into vibration tank to vibrate 30min, and vibration top tank structure is polytetrafluoroethyl-ne
Alkene, vibration frequency 45Hz, amplitude 5mm, vibration force 12000N, power 0.80kW.
The ball milling condition of the present embodiment is that raw material is placed in wet-milling 35min on ball mill, and wet grinding media is alcohol, ball
Mill speed is 375r/min, and ball material mass ratio is 10：1.
The step of the present embodiment（4）In, annealing temperature fall off rate is 10 DEG C/min.
The above is only a preferred embodiment of the present invention, protection scope of the present invention is not limited merely to above-mentioned implementation
Example, all technical solutions belonged under thinking of the present invention all belong to the scope of protection of the present invention.It should be pointed out that for the art
Those of ordinary skill for, several improvements and modifications without departing from the principles of the present invention, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (9)
1. a kind of high hardness wear-resisting glass, it is characterised in that：It is made of the component comprising the above parts by weight：Quartz sand 24-32
Part, 18-26 parts of soda ash, 10-15 parts of nano silicon dioxide, 5-12 parts of mica powder, graphite 4-9 parts nano oxidized, molybdenum disulfide 3-8
Part, 2-6 parts of sodium metasilicate, 0.6-2.4 parts of zinc borate, 2-7 parts of silicon nitride, 4-8 parts of calcium oxide, 0.8-1.6 parts of adhesive, grinding aid
0.4-1.2 parts, 0.3-0.8 parts of colorant.
2. high hardness wear-resisting glass according to claim 1, it is characterised in that：By the component system for including the above parts by weight
At：28 parts of quartz sand, 22 parts of soda ash, 12.5 parts of nano silicon dioxide, 8.5 parts of mica powder, 6.5 parts of nano oxidized graphite, two sulphur
Change 5.5 parts of molybdenum, 4 parts of sodium metasilicate, 2 parts of zinc borate, 4.5 parts of silicon nitride, 6 parts of calcium oxide, 1.2 parts of adhesive, 0.8 part of grinding aid,
0.5 part of colorant.
3. high hardness wear-resisting glass according to claim 1, it is characterised in that：The adhesive be selected from polyvinyl alcohol,
One or more of phenolic resin, butadiene-styrene rubber.
4. high hardness wear-resisting glass according to claim 1, it is characterised in that：The grinding aid is selected from sodium acetate, sulphur
One or more of sour aluminium and calcium formate.
5. high hardness wear-resisting glass according to claim 1, it is characterised in that：The colorant is selected from titanium dioxide, oxygen
Change one or more of zinc and lithopone.
6. a kind of preparation method according to claim 1-5 any one of them high hardness wear-resisting glasses, it is characterised in that：Packet
Include following steps：
（1）Each component is weighed by regulation number；
（2）By quartz sand, soda ash, nano silicon dioxide, mica powder, nano oxidized graphite, molybdenum disulfide, sodium metasilicate, zinc borate,
Silicon nitride, calcium oxide mixing, carry out vibration mixing or ball milling mixing；
（3）The raw material of ball milling is sent into 1200-1300 DEG C of crucible and is melted to obtain glass metal, is then sequentially added
Adhesive, grinding aid, colorant, and 2-4h is melted at 1400-1450 DEG C after crucible cover is covered, obtain glass melt body；
（4）Glass melt body is sent into molding machine, extrusion forming is made the different glass of specification, is then naturally cooling to harden
It is sent into annealing furnace annealing 1-2h afterwards；
（5）Glass after annealing is sent into tempering in tempering case, high hardness wear-resisting glass is obtained after the completion of tempering.
7. high hardness wear-resisting glass according to claim 6, it is characterised in that：The vibration mixing is to throw raw material
Enter to vibrate tank vibration 20-40min, vibration top tank structure is polytetrafluoroethylene (PTFE), and vibration frequency 45Hz, amplitude 5mm, vibration force is
12000N, power 0.80kW.
8. high hardness wear-resisting glass according to claim 6, it is characterised in that：The ball milling condition is by raw material
It is placed in wet-milling 30-40min on ball mill, wet grinding media is alcohol, drum's speed of rotation 350-400r/min, and ball material mass ratio is
10：1.
9. high hardness wear-resisting glass according to claim 4, it is characterised in that：Step（4）In, reduction of speed under annealing temperature
Rate is 5-15 DEG C/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810125660.0A CN108455845A (en) | 2018-02-08 | 2018-02-08 | A kind of high hardness wear-resisting glass and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810125660.0A CN108455845A (en) | 2018-02-08 | 2018-02-08 | A kind of high hardness wear-resisting glass and preparation method thereof |
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| CN108455845A true CN108455845A (en) | 2018-08-28 |
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| CN201810125660.0A Withdrawn CN108455845A (en) | 2018-02-08 | 2018-02-08 | A kind of high hardness wear-resisting glass and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109095780A (en) * | 2018-09-30 | 2018-12-28 | 江苏耀兴安全玻璃有限公司 | A kind of abrasion-resistance glass and preparation method thereof |
| CN111087171A (en) * | 2019-11-22 | 2020-05-01 | 石家庄泰图建材有限公司 | Glass color sheet and preparation method thereof |
| CN114409255A (en) * | 2022-02-10 | 2022-04-29 | 淄博泰康轻工制品有限公司 | Breakage-proof glass cup |
| CN114956558A (en) * | 2022-06-29 | 2022-08-30 | 江苏中盈玻璃科技有限公司 | High-strength wear-resistant glass product and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102285762A (en) * | 2010-06-18 | 2011-12-21 | 孙守富 | Method for producing green glass and beer bottles |
| CN105417951A (en) * | 2015-12-03 | 2016-03-23 | 李嘉 | Preparation method of high temperature resistant yellow glass |
| CN107265848A (en) * | 2017-06-12 | 2017-10-20 | 和县晶晶玻璃制品有限公司 | A kind of production technology of high hardness wear-resisting glass |
-
2018
- 2018-02-08 CN CN201810125660.0A patent/CN108455845A/en not_active Withdrawn
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102285762A (en) * | 2010-06-18 | 2011-12-21 | 孙守富 | Method for producing green glass and beer bottles |
| CN105417951A (en) * | 2015-12-03 | 2016-03-23 | 李嘉 | Preparation method of high temperature resistant yellow glass |
| CN107265848A (en) * | 2017-06-12 | 2017-10-20 | 和县晶晶玻璃制品有限公司 | A kind of production technology of high hardness wear-resisting glass |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109095780A (en) * | 2018-09-30 | 2018-12-28 | 江苏耀兴安全玻璃有限公司 | A kind of abrasion-resistance glass and preparation method thereof |
| CN111087171A (en) * | 2019-11-22 | 2020-05-01 | 石家庄泰图建材有限公司 | Glass color sheet and preparation method thereof |
| CN114409255A (en) * | 2022-02-10 | 2022-04-29 | 淄博泰康轻工制品有限公司 | Breakage-proof glass cup |
| CN114409255B (en) * | 2022-02-10 | 2024-07-02 | 济宁市兖州区国运玻璃制品有限公司 | Breakage-proof glass cup |
| CN114956558A (en) * | 2022-06-29 | 2022-08-30 | 江苏中盈玻璃科技有限公司 | High-strength wear-resistant glass product and preparation method thereof |
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Application publication date: 20180828 |
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