CN102285762A - Method for producing green glass and beer bottles - Google Patents
Method for producing green glass and beer bottles Download PDFInfo
- Publication number
- CN102285762A CN102285762A CN2010102169088A CN201010216908A CN102285762A CN 102285762 A CN102285762 A CN 102285762A CN 2010102169088 A CN2010102169088 A CN 2010102169088A CN 201010216908 A CN201010216908 A CN 201010216908A CN 102285762 A CN102285762 A CN 102285762A
- Authority
- CN
- China
- Prior art keywords
- glass
- temperature
- green glass
- sent
- green
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Landscapes
- Glass Compositions (AREA)
Abstract
The invention discloses a method for producing green glass and beer bottles by taking quartz sand and cullet as raw materials. The green glass produced by the method disclosed by the invention is glass with large yield, wide application range and low cost, the raw materials for producing the green glass comprise the quartz sand, soda ash, dolomite, calcite, fluorite, lepidolite, chromium ore powder and cullet. The proper quantity of lepidolite is added during glass melting such that the glass is green, and the flat green glass and the beer bottles are produced through a series of processes. The method for producing the green glass and the beer bottles, disclosed by the invention, has the advantages of simple process, low production cost, no pollution and applicability in industrial production.
Description
Technical field
The invention belongs to glass manufacturing area, be specifically related to the production method of a kind of green glass and Beer Bottle.
Background technology
Glass is divided into nonoxide glass and oxide glass by main component usually.Nonoxide glass mainly contains chalcogenide glass and halide glass, and turnout seldom.Oxide glass is divided into silicate glass, borate glass, phosphate glass etc. again.Silicate glass refers to that basal component is the simple glass of SiO2, and the quality of simple glass is hard and crisp, is a kind of colourless transparent material, and can add various one-tenth and assign to make green, dark brown, light ink look, cobalt blue glass etc.Simple glass can be made into toughened glass through thermal treatment, its elasticity, shock-resistance, thermostability are better than simple glass, having higher physical strength. the transparency of novel toughened glass will exceed simple glass 4-5 doubly, limpid charming just as crystal, it also has higher hardness and high-temperature stability simultaneously, it is wide in variety, and purposes is wide.Usually press the different content of SiO2 in the glass and basic metal, alkaline earth metal oxide, be divided into again: 1. silica glass: SiO2 content is between 98%-99.9%, this thermal expansion coefficient of glass is low, high temperature resistant, chemical stability is good, saturating UV-light and infrared light, and glass melting temperature height, viscosity are big, moulding is difficult, is used in technology such as semi-conductor, electric light source, optical commucication, laser and the opticinstrument more; 2. soda-lime glass: between SiO2 content 55%-65%, also contain 15% Na2O and 16% CaO, it is with low cost, easy-formation, and suitable for mass production, its output accounts for 90% of practical glass.Can produce glass bottle and jar, sheet glass, vessel, bulb etc.3. lead silicate glass: main component has SiO2 and PbO, has unique high refractive index and high volume resistance, with metal good wetting property is arranged, and can be used for making bulb, valve tube stem stem, crystal glass vessel, flint optical glass etc.The lead glass that contains a large amount of PbO can stop X ray and gamma-rays.4. alumina silicate glass: with SiO2 and Al2O3 is main component, and softening transform temperature height is used to make discharge bulb, high temp glass thermometer, chemical combustion pipe and glass fibre etc.5. borosilicate glass: with B2O3 is main component, have good thermotolerance and chemical stability, melt temperature is low, can resist the sodium vapor corrosion, the borate glass specific refractory power height, the chromatic dispersion that contain rare earth element are low, be a kind of novel optical glass, in order to make cooking apparatus, Laboratory Instruments, metal sealing glass etc.Phosphate glass is main component with P2O5, and specific refractory power is low, chromatic dispersion is low, is used for opticinstrument.Product of the present invention be a kind of be the green glass and the Beer Bottle of main material production with real estate quartz sand and glass cullet.Its essence should belong to the coloured soda-lime glass in the simple glass.In the process of founding, add an amount of lithionite and be green, make green sheet glass or Beer Bottle by a series of technology by glass.Produce that this product technology is simple, production cost is low, and is pollution-free, be fit to suitability for industrialized production.
Summary of the invention
It is main raw material with this real estate quartz sand and green glass cullet that the problem that the present invention mainly solves provides a kind of, the method for suitability for industrialized production green glass and Beer Bottle.The composition of raw materials amount that the present invention uses is: real estate quartz sand 28%-35% (contain SiO2 and be not less than 85%); Soda ash (Na2CO3) 7%-9% (content is 97%) is produced in Huaian; Rhombspar 3.5%-4.5% (containing MgO 20%, CaO 30%) is produced in the Ganyu; Calcite 1.5%-2% (containing CaO 48%, MgO 2%) is produced in Zhenjiang; Anhui is produced fluorite 1%-1.2% and (is contained CaFe260%; Lithionite 0.75%-0.85% (containing Li2O 3.4%, Al2O321%, SiO254%) is produced in Guangxi; Chromite ore fine 0.5%-0.6% (containing Cr2O3 is 30%) is produced in Wafangdian, Dalian; Purchase green glass cullet 48%-58%.
The present invention can be achieved through the following technical solutions:
The method of a kind of suitability for industrialized production green glass and Beer Bottle is characterized in that being made of following steps:
(1) quartz sand, soda ash, rhombspar, calcite, fluorite, lithionite, chromite ore fine, the green glass cullet with formula ratio stir after mixing.
(2) compound is sent into smelting furnace, 550 ℃ the coal gas that obtains with coal burning is sent into smelting furnace by gas transmission equipment, sealing combustion, make the temperature of compound reach 1520 ℃-1560 ℃, keep this temperature 18-24 hour, and made compound reach molten state, obtain the green glass molten mass.
(3) glass melt is sent into shaper, make the sheet glass or the vial of certain specification.
(4) sheet glass or vial are sent into annealing box with transfer roller, about first temperature adjustment degree to 500 ℃, kept 20 minutes; Again temperature is transferred to about 450 ℃, kept 20 minutes; Progressively cooling cooled the temperature in 1 hour about 150 ℃ then, and this moment, annealing finished, and green glass plate or vial are sent in the air, naturally cooled to normal temperature in air, obtained finished product.
Gas temperature described in the above-mentioned steps (2) is 550 ℃, and the temperature of fusion in the smelting furnace is about between 1520 ℃-1560 ℃.
The present invention compared with prior art has the following advantages:
(1) produce green glass plate or vial, production technique is simple, production cost is low, and is pollution-free.
(2) be suitable for industrialized mass production, the quality product height.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in further detail.
Embodiment one
Quartz sand 28%, soda ash 7%, rhombspar 3.5%, calcite 1.5%, fluorite 1%, lithionite 0.75%, chromite ore fine 0.5%, green glass cullet 58% are stirred after mixing, compound is sent into smelting furnace, 550 ℃ the coal gas that obtains with coal burning is sent into smelting furnace by gas transmission equipment, sealing combustion, make the temperature of compound reach 1520 ℃-1560 ℃, keep this temperature 18-24 hour, and made compound reach molten state, obtain green soda-lime glass molten mass.Glass melt is sent into shaper, make certain specification sheet glass or vial.Sheet glass or vial are sent into annealing box with transfer roller, about first temperature adjustment degree to 500 ℃, kept 20 minutes; Again temperature is transferred to about 450 ℃, kept 20 minutes; Progressively cooling cooled the temperature in 1 hour about 150 ℃ then, and this moment, annealing finished, and green glass plate or vial are sent in the air, naturally cooled to normal temperature in air, obtained product.
Embodiment two
Quartz sand 31%, soda ash 8%, rhombspar 4%, calcite 1.75%, fluorite 1.1%, lithionite 0.8%, chromite ore fine 0.55%, green glass cullet 53% are stirred after mixing.Compound is sent into smelting furnace, 550 ℃ the coal gas that obtains with coal burning is sent into smelting furnace by gas transmission equipment, sealing combustion, make the temperature of compound reach 1520 ℃-1560 ℃, keep this temperature 18-24 hour, and made compound reach molten state, obtain green soda-lime glass molten mass.Glass melt is sent into shaper, make certain specification sheet glass or vial.Sheet glass or vial are sent into annealing box with transfer roller, about first temperature adjustment degree to 500 ℃, kept 20 minutes; Again temperature is transferred to about 450 ℃, kept 20 minutes; Progressively cooling cooled the temperature in 1 hour about 150 ℃ then, and this moment, annealing finished, and green glass plate or vial are sent in the air, naturally cooled to normal temperature in air, obtained product.
Embodiment three
Quartz sand 35%, soda ash 9%, rhombspar 4.5%, calcite 2%, fluorite 1.2%, lithionite 0.85%, chromite ore fine 0.6%, green glass cullet 48% are stirred after mixing.Compound is sent into smelting furnace, 550 ℃ the coal gas that obtains with coal burning is sent into smelting furnace by gas transmission equipment, sealing combustion, make the temperature of compound reach 1520 ℃-1560 ℃, keep this temperature 18-24 hour, and made compound reach molten state, obtain green soda-lime glass molten mass.Glass melt is sent into shaper, make certain specification sheet glass or vial.Sheet glass or vial are sent into annealing box with transfer roller, about first temperature adjustment degree to 500 ℃, kept 20 minutes; Again temperature is transferred to about 450 ℃, kept 20 minutes; Progressively cooling cooled the temperature in 1 hour about 150 ℃ then, and this moment, annealing finished, and green glass plate or vial are sent in the air, naturally cooled to normal temperature in air, obtained product.
Embodiment four
Quartz sand 33%, soda ash 8.5%, rhombspar 4.25%, calcite 1.75%, fluorite 1.15%, lithionite 0.85%, chromite ore fine 0.5%, green glass cullet 50% are stirred after mixing.Compound is sent into smelting furnace, 550 ℃ the coal gas that obtains with coal burning is sent into smelting furnace by gas transmission equipment, sealing combustion, make the temperature of compound reach 1520 ℃-1560 ℃, keep this temperature 18-24 hour, and made compound reach molten state, obtain green soda-lime glass molten mass.Glass melt is sent into shaper, make certain specification sheet glass or vial.Sheet glass or vial are sent into annealing box with transfer roller, about first temperature adjustment degree to 500 ℃, kept 20 minutes; Again temperature is transferred to about 450 ℃, kept 20 minutes; Progressively cooling cooled the temperature in 1 hour about 150 ℃ then, and this moment, annealing finished, and green glass plate or vial are sent in the air, naturally cooled to normal temperature in air, obtained product.
Claims (5)
1. the production method of green glass and Beer Bottle is characterized in that: with real estate quartz sand 28%-35% (contain SiO2 and be not less than 85%); Soda ash (Na2CO3) 7%-9% (content is 97%) is produced in Huaian; Rhombspar 3.5%-4.5% (containing MgO 2O%, CaO 30%) is produced in the Ganyu; Calcite 1.5%-2% (containing CaO 48%, MgO 2%) is produced in Zhenjiang; Anhui is produced fluorite 1%-1.2% and (is contained CaFe260%; Lithionite 0.75%-0.85% (containing Li2O 3.4%, Al2O3 21%, SiO2 54%) is produced in Guangxi; Chromite ore fine 0.5%-0.6% (containing Cr2O3 is 30%) is produced in Wafangdian, Dalian; Purchasing green glass cullet 48%-58% is raw material, obtains finished product by following steps.
2. the production method of a kind of green glass according to claim 1 and Beer Bottle, the feature of its first step is: quartz sand, soda ash, rhombspar, calcite, fluorite, lithionite, chromite ore fine, the green glass cullet of formula ratio are stirred after mixing.
3. the production method of a kind of green glass according to claim 1 and Beer Bottle, the feature in its second step is: compound is sent into smelting furnace, 550 ℃ the coal gas that obtains with coal burning is sent into smelting furnace by gas transmission equipment, it is 1520 ℃-1560 ℃ that sealing combustion makes the temperature of compound, kept this temperature 18-24 hour, make compound reach molten state, obtain the green glass molten mass.
4. the production method of a kind of green glass according to claim 1 and Beer Bottle, the feature in its 3rd step is: glass melt is sent into shaper, make the sheet glass or the vial of certain specification.
5. the production method of a kind of green glass according to claim 1 and Beer Bottle, the feature in its 4th step is: sheet glass or vial are sent into annealing box with transfer roller, and first temperature adjustment degree transfers to about 500 ℃, keeps 20 minutes; Again temperature is transferred to about 450 ℃, kept 20 minutes; Progressively cooling cooled the temperature in 1 hour about 150 ℃ then, and this moment, annealing finished, and green glass plate or vial are sent in the air, naturally cooled to normal temperature in air, obtained finished product.
It is 550 ℃ that aforesaid right requires the gas temperature described in (3), and the temperature of fusion in the smelting furnace is between 1520 ℃-1560 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102169088A CN102285762A (en) | 2010-06-18 | 2010-06-18 | Method for producing green glass and beer bottles |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102169088A CN102285762A (en) | 2010-06-18 | 2010-06-18 | Method for producing green glass and beer bottles |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN102285762A true CN102285762A (en) | 2011-12-21 |
Family
ID=45332544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2010102169088A Withdrawn CN102285762A (en) | 2010-06-18 | 2010-06-18 | Method for producing green glass and beer bottles |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102285762A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964063A (en) * | 2012-11-28 | 2013-03-13 | 江苏蓝色玻璃集团有限公司 | Semi-opaque material skyblue winebottle and technology for producing same |
| CN103043909A (en) * | 2012-12-29 | 2013-04-17 | 青岛崂山玻璃有限公司 | Fabrication method of beer bottle |
| CN104176937A (en) * | 2013-05-27 | 2014-12-03 | 朱晓明 | Manufacturing method for colored microcrystalline glass |
| CN104692662A (en) * | 2015-02-28 | 2015-06-10 | 山东景耀玻璃集团有限公司 | Special formula for lightweight glass packaging material |
| CN108455845A (en) * | 2018-02-08 | 2018-08-28 | 合肥利裕泰玻璃制品有限公司 | A kind of high hardness wear-resisting glass and preparation method thereof |
-
2010
- 2010-06-18 CN CN2010102169088A patent/CN102285762A/en not_active Withdrawn
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102964063A (en) * | 2012-11-28 | 2013-03-13 | 江苏蓝色玻璃集团有限公司 | Semi-opaque material skyblue winebottle and technology for producing same |
| CN102964063B (en) * | 2012-11-28 | 2017-05-17 | 江苏蓝色玻璃集团有限公司 | Semi-opaque material skyblue winebottle and technology for producing same |
| CN103043909A (en) * | 2012-12-29 | 2013-04-17 | 青岛崂山玻璃有限公司 | Fabrication method of beer bottle |
| CN103043909B (en) * | 2012-12-29 | 2016-02-10 | 青岛崂山玻璃有限公司 | A kind of preparation method of Beer Bottle |
| CN104176937A (en) * | 2013-05-27 | 2014-12-03 | 朱晓明 | Manufacturing method for colored microcrystalline glass |
| CN104692662A (en) * | 2015-02-28 | 2015-06-10 | 山东景耀玻璃集团有限公司 | Special formula for lightweight glass packaging material |
| CN108455845A (en) * | 2018-02-08 | 2018-08-28 | 合肥利裕泰玻璃制品有限公司 | A kind of high hardness wear-resisting glass and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP6973959B2 (en) | Chemically strengthenable glass plate | |
| JP2021120344A (en) | Chemically temperable glass sheet | |
| US10294141B2 (en) | Chemically temperable glass sheet | |
| CN103539351A (en) | Production method of brown glass and brown glass beer bottles | |
| CN104024170A (en) | Glass | |
| CA2797415A1 (en) | Glass substrates for high temperature applications | |
| CN110028240B (en) | Aluminosilicate glass and preparation method thereof | |
| CN102285762A (en) | Method for producing green glass and beer bottles | |
| CN106517772A (en) | Low-refractive glass applied to drawing formation preparation of optical fiber faceplate and preparation method thereof | |
| CN101016195A (en) | High transmittivity glass for solar energy and preparing process thereof | |
| CN108863047A (en) | A kind of CIGS thin film based on 3D printing technique glass plate used for solar batteries and its processing technology | |
| CN108069603A (en) | A kind of production method of brown glass and brown glass beer bottle | |
| CN101723585A (en) | Borosilicate glass with high chemical stability and application thereof | |
| Meechoowas et al. | Alternative soda-lime glass batch to reduce energy consumption | |
| CN105967505A (en) | Formula of quartz glass plates and preparation technology thereof | |
| CN103241952A (en) | Method for producing aluminosilicate water gauge surface glass | |
| CN109851218A (en) | A kind of optical fiber image inverter veiling glare heat absorbing glass and preparation method thereof | |
| CN103241954A (en) | Method for producing a green glass beer bottle | |
| CN103011594A (en) | Method for producing brown flat glass | |
| CN102690055A (en) | Aluminosilicate glass for plasma display based on float process | |
| CN108947238B (en) | Light guide plate glass, preparation method and application thereof | |
| JP2018505117A (en) | Chemically temperable glass plate | |
| CN107879601A (en) | The preparation method of float glass | |
| EP3759058B1 (en) | Glass composition with nickel to reduce energy consumption during its melting step | |
| JPH01286936A (en) | Amber-colored borosilicate glass |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C04 | Withdrawal of patent application after publication (patent law 2001) | ||
| WW01 | Invention patent application withdrawn after publication |
Open date: 20111221 |