CN108069603A - A kind of production method of brown glass and brown glass beer bottle - Google Patents

A kind of production method of brown glass and brown glass beer bottle Download PDF

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Publication number
CN108069603A
CN108069603A CN201610988224.7A CN201610988224A CN108069603A CN 108069603 A CN108069603 A CN 108069603A CN 201610988224 A CN201610988224 A CN 201610988224A CN 108069603 A CN108069603 A CN 108069603A
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China
Prior art keywords
glass
temperature
brown
brown glass
sent
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CN201610988224.7A
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Chinese (zh)
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梁泽超
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Individual
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Individual
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Priority to CN201610988224.7A priority Critical patent/CN108069603A/en
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B5/00Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
    • C03B5/16Special features of the melting process; Auxiliary means specially adapted for glass-melting furnaces
    • C03B5/235Heating the glass
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/02Compositions for glass with special properties for coloured glass
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P40/00Technologies relating to the processing of minerals
    • Y02P40/50Glass production, e.g. reusing waste heat during processing or shaping

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Glass Compositions (AREA)

Abstract

The invention discloses the production method of a kind of brown glass and brown glass beer bottle, this method belongs to glass manufacturing area;Product of the present invention is using real estate quartz sand, sodium carbonate, dolomite, calcite, fluorite, lepidolite, chromite ore fine, nickel oxide, purchase brown cullet as raw material, using blender, high-temperature melting furnace, forming machine, annelaing pot as equipment, by processes such as the blending of mixture, high-temperature fusion, formed product, annealing come finished product;This method has the series of advantages such as simple for process, raw material sources are convenient, production cost is low, pollution-free, suitable industrialized production.

Description

A kind of production method of brown glass and brown glass beer bottle
Technical field
The invention belongs to glass manufacturing area more particularly to the producers of a kind of brown glass and brown glass beer bottle Method.
Background technology
Glass is a kind of transparent or semitransparent solid matter, the formation contiguous network structure in melting, in cooling procedure Viscosity gradually increases and hardens and non crystallized silicates nonmetallic materials, and the main ingredient of simple glass is silica, Be widely used in building, for every wind light transmission, also can be used for manufacturing various glasswares, be with the addition of suitable raw material it Afterwards, a variety of colors can be made, belong to mixture.Glass is usually divided into nonoxide glass and oxide glass by main component Glass, nonoxide glass mainly have chalcogenide glass and halide glass, and output is seldom;Oxide glass is divided into as glassy silicate Glass, borate glass, phosphate glass etc., silicate glass refer to the simple glass that basis is silica, simple glass Hard texture and it is crisp, be a kind of colourless transparent material, and various composition can be added green, brown, light ink color, cobalt blue is made Color etc., simple glass is thermally treated to can be made into tempered glass, and elasticity, impact resistance, thermal stability have better than simple glass The transparency of the higher new tempered glass of mechanical strength will be higher by 4-5 times of simple glass, limpid charming just as crystal, It also has higher hardness and high-temperature stability simultaneously.Silica in glass, alkali metal, alkali-metal-oxide content Difference, and can be made into:1. quartz glass, for dioxide-containing silica between 98%-99.9%, the thermal expansion coefficient of glass is low, resistance to High temperature, chemical stability is good, saturating ultraviolet light and infrared light, and glass melting temperature is high, viscosity is big, and shaping is more difficult, is chiefly used in semiconductor, electricity In the technologies and optical instrument such as light source, optical commucication, laser;2. soda-lime glass, with dioxide-containing silica between 55%-65%, Calcium oxide also containing 15% sodium oxide molybdena and 15%, low production cost is easily molded, and yield accounts for the 90% of practical glass, Glass bottle and jar, plate glass, vessel, light bulb etc. can be produced;3. lead silicate glass, main component has silica and oxidation Lead has unique high index of refraction and high volume resistance, has good wellability with metal, available for manufacture light bulb, vacuum tube Stem, crystal ware, flint optical glass etc..Lead glass containing a large amount of lead oxide can stop X-ray and gamma-rays;4. Alumina silicate glass:Using silica and alundum (Al2O3) as main component, softening transform temperature is high;
6. borosilicate glass, steady with good heat resistance and chemistry using silica and diboron trioxide as main component Qualitative, melting temperature is low, is a kind of novel optical glass.Product of the present invention be it is a kind of using real estate quartz sand and brown cullet as The brown glass of main material production and brown glass beer bottle, its essence should belong to the coloured sodium calcium in simple glass Glass, soda-lime glass abbreviation soda-lime glass are for primary raw material, through 1500-1600 DEG C with quartz sand, soda ash, lime stone, feldspar etc. High-temperature fusion, shaping and amorphous non-crystalline solid material prepared by through being quickly cooled down, chemical composition is sufficiently complex, main To be silica, sodium oxide molybdena and calcium oxide, in addition also a small amount of alundum (Al2O3), magnesia, potassium oxide etc., usual because containing There is more impurity component often to carry light green color.Soda-lime glass is of low cost, widely used, thus building, daily glass product, Bottle etc. is widely used.Production product of the present invention with real estate quartz sand, sodium carbonate, dolomite, calcite, fluorite, Lepidolite, chromite ore fine, nickel oxide, purchase brown cullet are raw material, using blender, high-temperature melting furnace, forming machine, annelaing pot as Equipment, by processes such as the high-temperature fusions, formed product, annealing of mixture come finished product, this method has simple for process, former The series of advantages such as material source is convenient, production cost is low, pollution-free, suitable industrialized production.
The content of the invention
Present invention mainly solves the problem of be to provide one kind using this real estate quartz sand and brown cullet as primary raw material, work The method that industry metaplasia produces brown glass and brown glass beer bottle, this method is with real estate quartz sand, sodium carbonate, dolomite, Fang Xie Stone, fluorite, lepidolite, chromite ore fine, nickel oxide, purchase brown cullet are raw material, with blender, high-temperature melting furnace, forming machine, Annelaing pot is equipment, by processes such as the high-temperature fusions, formed product, annealing of mixture come finished product.What the present invention used Raw material weight proportioning of soup processed is:Real estate quartz sand 30%-32%, sodium carbonate 9%-11%, dolomite 4%, calcite 2%, fluorite 1%, lepidolite 0.8%th, chromite ore fine 0.6%, nickel oxide 0.6%, purchase brown cullet 50%.The present invention can come real by the following technical programs It is existing:
A kind of method of industrialized production brown glass and brown glass beer bottle, it is characterized in that being made of following steps:
(1)By the real estate quartz sand of formula ratio, sodium carbonate, dolomite, calcite, fluorite, lepidolite, chromite ore fine, nickel oxide, receipts It is uniform to purchase the blending of brown cullet.
(2)Melting furnace is fed the mixture into, 550 DEG C of the coal gas obtained with coal burning by gas transmission equipmen is sent into and is melted Change stove, sealing combustion makes the temperature of mixture reach 1530 DEG C -1540 DEG C, when keeping this temperature 18-24 small, reaches mixture To molten condition, brown glass molten mass is obtained.
(3)Glass melt is sent into forming machine, glass plate, the beer bottle of certain specification is made.
(4)Annelaing pot is sent into conveyer when glass plate or vial are naturally cooling to 600 DEG C or so, first adjusts annelaing pot
Interior temperature maintains 20 minutes to 550 DEG C or so;Temperature is adjusted to 400 DEG C or so again, is maintained 20 minutes;Then progressively Cooling, cooled the temperature to 150 DEG C in 60 minutes, and annealing at this time finishes, and brown glass plate or vial are sent into air, Room temperature is naturally cooled in air, obtains finished product.
Above-mentioned steps(2)Described in melting furnace in fusion temperature be about 1535 DEG C.
Above-mentioned steps(4)Described in annealing time be 100 minutes.
The beneficial effects of the invention are as follows:A kind of method for producing brown glass and brown glass beer bottle in batches is provided, This method have simple for process, raw material sources are convenient, production cost is low, it is pollution-free, be suitble to industrialized production etc. a series of excellent Point;Product glass plate can be used as plate glass, and beer bottle is used for into dress beer.Specific embodiment
With reference to specific embodiment, the present invention is described in further detail.
Embodiment 1
Real estate quartz sand that total amount is 30% will be accounted for, sodium carbonate that total amount is 10% is accounted for, accounts for dolomite that total amount is 4%, accounts for total amount and is 2% calcite accounts for fluorite that total amount is 1%, accounts for lepidolite that total amount is 0.8%, account for chromite ore fine that total amount is 0.6%, account for total amount Nickel oxide for 0.6%, to account for the purchase brown cullet blending that total amount is 50% uniform;Melting furnace is fed the mixture into, using coal 550 DEG C of the coal gas that charcoal burning obtains is sent into melting furnace by gas transmission equipmen, and sealing combustion makes the temperature of mixture reach 1530 DEG C -1540 DEG C, when keeping this temperature 18-24 small, mixture is made to reach molten condition, obtains brown glass molten mass;By glass Molten mass is sent into forming machine, and glass plate, the beer bottle of certain specification is made;Glass plate or vial are naturally cooling to 600 DEG C Annelaing pot is sent into conveyer during left and right, the temperature in annelaing pot is first adjusted to be maintained 20 minutes to 550 DEG C or so;Again temperature tune To 400 DEG C or so, maintain 20 minutes;Then progressively cool down, 150 DEG C were cooled the temperature in 60 minutes, annealing at this time finishes, will Brown glass plate or vial are sent into air, are naturally cooled to room temperature in air, are obtained finished product.
Embodiment 2
Real estate quartz sand that total amount is 31% will be accounted for, sodium carbonate that total amount is 10% is accounted for, accounts for dolomite that total amount is 4%, accounts for total amount and is 2% calcite accounts for fluorite that total amount is 1%, accounts for lepidolite that total amount is 0.8%, account for chromite ore fine that total amount is 0.6%, account for total amount Nickel oxide for 0.6%, to account for the purchase brown cullet blending that total amount is 50% uniform;Feed the mixture into melting furnace,
550 DEG C of the coal gas obtained with coal burning is sent into melting furnace by gas transmission equipmen, sealing combustion makes the temperature of mixture Degree reaches 1530 DEG C -1540 DEG C, when keeping this temperature 18-24 small, mixture is made to reach molten condition, obtains brown glass melting Body;Glass melt is sent into forming machine, glass plate, the beer bottle of certain specification is made;Glass plate or vial are dropped naturally Temperature is sent into annelaing pot at 600 DEG C or so with conveyer, and the temperature in annelaing pot is first adjusted to be maintained 20 minutes to 550 DEG C or so;Again Temperature is adjusted to 400 DEG C or so, is maintained 20 minutes;Then progressively cool down, 150 DEG C were cooled the temperature in 60 minutes, is moved back at this time Fire finishes, and brown glass plate or vial are sent into air, room temperature is naturally cooled in air, obtains finished product.
Embodiment 3
Real estate quartz sand that total amount is 32% will be accounted for, sodium carbonate that total amount is 9% is accounted for, accounts for dolomite that total amount is 4%, accounts for total amount and is 2% calcite accounts for fluorite that total amount is 1%, accounts for lepidolite that total amount is 0.8%, account for chromite ore fine that total amount is 0.6%, account for total amount Nickel oxide for 0.6%, to account for the purchase brown cullet blending that total amount is 50% uniform;Feed the mixture into melting furnace,
550 DEG C of the coal gas obtained with coal burning is sent into melting furnace by gas transmission equipmen, sealing combustion makes the temperature of mixture Degree reaches
To 1530 DEG C -1540 DEG C, when keeping this temperature 18-24 small, mixture is made to reach molten condition, obtain brown glass melting Body;Glass melt is sent into forming machine, glass plate, the beer bottle of certain specification is made;Glass plate or vial are dropped naturally Temperature is sent into annelaing pot at 600 DEG C or so with conveyer, and the temperature in annelaing pot is first adjusted to be maintained 20 minutes to 550 DEG C or so;Again Temperature is adjusted to 400 DEG C or so, is maintained 20 minutes;Then progressively cool down, 150 DEG C were cooled the temperature in 60 minutes, is moved back at this time Fire finishes, and brown glass plate or vial are sent into air, room temperature is naturally cooled in air, obtains finished product.

Claims (3)

1. the production method of a kind of brown glass and brown glass beer bottle, composition of raw materials count by weight percentage, including: Real estate quartz sand 30%-32%, sodium carbonate 9%-11%, dolomite 4%, calcite 2%, fluorite 1%, lepidolite 0.8%, chromite ore fine 0.6%th, nickel oxide 0.6%, purchase brown cullet 50%, it is characterized in that:Step(1)By real estate quartz sand, the carbonic acid of formula ratio Sodium, dolomite, calcite, fluorite, lepidolite, chromite ore fine, nickel oxide, the cullet blending of purchase brown are uniform;Step(2)It will be mixed Close material be sent into melting furnace, 550 DEG C of the coal gas obtained with coal burning by gas transmission equipmen be sent into melting furnace, sealing combustion, The temperature of mixture is made to reach 1530 DEG C -1540 DEG C, when keeping this temperature 18-24 small, mixture is made to reach molten condition, is obtained Brown glass molten mass;Step(3)Glass melt is sent into forming machine, glass plate, the beer bottle of certain specification is made;Step (4)Annelaing pot is sent into conveyer when glass plate or vial are naturally cooling to 600 DEG C or so, first adjusts the temperature in annelaing pot It to 550 DEG C or so, maintains 20 minutes, then temperature is adjusted to 400 DEG C or so, maintain 20 minutes, then progressively cool down, at 60 minutes 150 DEG C are inside cooled the temperature to, annealing at this time finishes, and brown glass plate or vial are sent into air, naturally cold in air But to room temperature, finished product is obtained.
2. the production method of a kind of brown glass according to claim 1 and brown glass beer bottle, step(2)Feature It is:Fusion temperature in the melting furnace is 1535 DEG C.
3. the production method of a kind of brown glass according to claim 1 and brown glass beer bottle, step(4)Feature It is:The annealing time is 100 minutes altogether.
CN201610988224.7A 2016-11-10 2016-11-10 A kind of production method of brown glass and brown glass beer bottle Pending CN108069603A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610988224.7A CN108069603A (en) 2016-11-10 2016-11-10 A kind of production method of brown glass and brown glass beer bottle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610988224.7A CN108069603A (en) 2016-11-10 2016-11-10 A kind of production method of brown glass and brown glass beer bottle

Publications (1)

Publication Number Publication Date
CN108069603A true CN108069603A (en) 2018-05-25

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110577361A (en) * 2019-10-21 2019-12-17 徐州宏华玻璃科技有限公司 formula and production method of purple true-color glass
CN110577360A (en) * 2019-10-21 2019-12-17 徐州宏华玻璃科技有限公司 formula and manufacturing process of brown glass
CN112299713A (en) * 2020-11-13 2021-02-02 郑州市华源玻璃制品有限公司 Production process of beer bottle

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110577361A (en) * 2019-10-21 2019-12-17 徐州宏华玻璃科技有限公司 formula and production method of purple true-color glass
CN110577360A (en) * 2019-10-21 2019-12-17 徐州宏华玻璃科技有限公司 formula and manufacturing process of brown glass
CN112299713A (en) * 2020-11-13 2021-02-02 郑州市华源玻璃制品有限公司 Production process of beer bottle

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Application publication date: 20180525

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