CN111925118A - Preparation formula for producing high-whiteness glass by recycling printed cullet - Google Patents

Preparation formula for producing high-whiteness glass by recycling printed cullet Download PDF

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Publication number
CN111925118A
CN111925118A CN202010605462.1A CN202010605462A CN111925118A CN 111925118 A CN111925118 A CN 111925118A CN 202010605462 A CN202010605462 A CN 202010605462A CN 111925118 A CN111925118 A CN 111925118A
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CN
China
Prior art keywords
glass
cullet
printing
printed
sorting
Prior art date
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Pending
Application number
CN202010605462.1A
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Chinese (zh)
Inventor
陈北
付俊华
张飞妮
卓丽真
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Fujian Huaxing Glass Co ltd
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Fujian Huaxing Glass Co ltd
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Filing date
Publication date
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Priority to CN202010605462.1A priority Critical patent/CN111925118A/en
Publication of CN111925118A publication Critical patent/CN111925118A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/002Use of waste materials, e.g. slags
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/02Pretreated ingredients
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C1/00Ingredients generally applicable to manufacture of glasses, glazes, or vitreous enamels
    • C03C1/02Pretreated ingredients
    • C03C1/026Pelletisation or prereacting of powdered raw materials
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00Compositions for glass with special properties
    • C03C4/02Compositions for glass with special properties for coloured glass

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a preparation formula for producing high-white glass by recycling printing cullet, which comprises quartz powder, calcite, feldspar, soda ash and printing cullet, wherein the processing flow of the printing cullet comprises collection, iron removal, sorting, cleaning, crushing, water filtration and classified stacking, and the printing glass is collected and uniformly recovered through a collection device; carrying out iron removal operation on the collected printed glass through an electromagnet; sorting and classifying the printed glass subjected to iron removal in sorting equipment; conveying the sorted printed glass into a crusher for crushing operation; cleaning the printing cullet through water filtering operation; the screened printing cullet is sorted and stacked according to the sorting and stacking carried out by the previous sorting equipment, wherein the percentage of each component is 30% -50% of quartz powder, 10% -15% of calcite, 10% -20% of feldspar, 10% -20% of soda ash and 10% -20% of printing cullet. The invention has the advantages of improving the proportion of the printing cullet, reducing the formula cost and reducing the energy consumption of melting glass.

Description

Preparation formula for producing high-whiteness glass by recycling printed cullet
Technical Field
The invention relates to the technical field of high-white glass production, in particular to a preparation formula for producing high-white glass by recycling printed cullet.
Background
The high-white glass is ultra-transparent low-iron glass, also called low-iron glass and high-transparency glass. It is a high-quality, multifunctional, novel and high-grade glass variety, its light transmittance can be up to above 91.5%, and it has the characteristics of crystal clear, high-grade and elegant. The high-whiteness glass has excellent physical, mechanical and optical properties. Various further processing is carried out like other high quality float glass. Compared with the prior art, the ultra-white glass has excellent quality and product performance, so that the ultra-white glass has wide application space and bright market prospect.
By analyzing the processed components of the printed glass bottle and combining the requirements on the components of sodium, calcium, silicon and the like in the existing formula, the using amount of other raw materials is adjusted, so that the sodium, calcium, silicon and the like in the full analysis of the finished glass can generate the glass.
The utilization rate of the existing printing cullet is low, and a large amount of printing cullet is wasted, so that a large amount of resources are wasted, and the cost is increased.
Disclosure of Invention
The invention aims to provide a preparation formula for recycling printed cullet to produce high-whiteness glass, which has the advantages of improving the proportion of the printed cullet, reducing the formula cost and the energy consumption of melting glass, and solves the problems of low utilization rate of the printed cullet, waste of a large amount of printed cullet, resource waste and cost increase.
In order to achieve the purpose, the invention provides the following technical scheme: a preparation formula for producing high-white glass by recycling printing cullet comprises 30-50% of quartz powder, 10-15% of calcite, 10-20% of feldspar, 10-20% of soda and 10-20% of printing cullet.
As a further scheme of the invention, the processing flow of the printing cullet comprises collection, iron removal, sorting, cleaning, crushing, water filtration and classified stacking, and the printing glass is collected and uniformly recovered by a collection device; carrying out iron removal operation on the collected printed glass through an electromagnet to adsorb and take away iron substances in the printed glass; sorting and classifying the printed glass subjected to iron removal in sorting equipment, and performing classification treatment on the printed glass with different sizes; conveying the sorted printed glass into a crusher for crushing operation, and crushing the printed glass into printed cullet; cleaning the printing cullet through water filtering operation; and sorting and stacking the filtered printing cullet according to the sorting and sorting performed by the previous sorting equipment.
As a further scheme of the invention, the high-white glass with low hardness is prepared, wherein the percentage of each component is 50% of quartz powder, 10% of calcite, 10% of feldspar, 20% of soda and 10% of printing cullet, the calculated corresponding materials are crushed, the reagent is added, and then the materials are uniformly mixed by a stirrer.
As a further scheme of the invention, the medium-hardness high-white glass is prepared, wherein the components comprise 40% of quartz powder, 15% of calcite, 15% of feldspar, 15% of soda and 15% of printing cullet, the calculated corresponding materials are crushed, the reagent is added, and then the materials are uniformly mixed by a stirrer.
As a further scheme of the invention, the high-white glass with high hardness is prepared, wherein the high-white glass comprises 30% of quartz powder, 15% of calcite, 20% of feldspar, 15% of soda ash and 20% of printing cullet in percentage by weight, the calculated corresponding materials are crushed, the reagent is added, and then the materials are uniformly mixed by a stirrer.
Compared with the prior art, the invention has the following beneficial effects: by analyzing the processed components of the printed cullet and combining the requirements on components such as soda-lime-silica and the like in the existing formula, the using amount of other raw materials is adjusted, so that the soda-lime-silica and the like in the full analysis of the finished glass product can generate glass, and the formula and the processing technology can greatly improve the use of the printed cullet in the colleagues meeting the quality requirements of glass bottles. The using ratio of the printed glass is greatly adjusted to 20 percent from the original 5 percent. The formula cost and the energy consumption of melting glass can be reduced, and the phenomena of brittleness, unstable color and the like of glass produced after a large amount of printed glass is applied are improved.
Detailed Description
The technical solutions in the embodiments of the present invention are clearly and completely described below, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all embodiments. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
In the description of the present invention, it is to be noted that, unless otherwise explicitly specified or limited, the terms "mounted," "disposed," "connected," and the like are to be construed broadly, such as "connected," which may be fixedly connected, detachably connected, or integrally connected; can be mechanically or electrically connected; they may be connected directly or indirectly through intervening media, or they may be interconnected between two elements. The specific meanings of the above terms in the present invention can be understood in specific cases to those skilled in the art.
Example 1
The embodiment provided by the invention comprises the following steps: a preparation formula for producing high-white glass by recycling printing cullet comprises 30-50% of quartz powder, 10-15% of calcite, 10-20% of feldspar, 10-20% of soda and 10-20% of printing cullet, and workers correspondingly adjust the ratio of the components in the formula according to different indexes. During glass processing, corresponding additive agents, such as coloring agents, decolorants, clarifiers and opacifiers, are commonly used. Colorant: certain metal oxides are capable of dissolving directly in a glass solution to color the glass. For example, cobalt oxide can be blue, nickel oxide can be brown, manganese oxide can be purple, and the like. Decoloring agent: the impurities in the raw materials can bring the color and luster to the glass, and the common cobalt oxide, sodium carbonate and the like as decolorants can show complementary color with the original color in the glass, so that the glass becomes colorless. A clarifying agent: the fining agent can reduce the viscosity of the glass solution, so that the chemical reaction generates bubbles and the fining is easy. Commonly used clarifiers are: sodium sulfate, ammonium salt, white arsenic, manganese dioxide, etc. An opacifying agent: the opacifying agent is capable of rendering the glass milky translucent. The commonly used opacifier is sodium fluosilicate, tin phosphide, cryolite and the like. They can form particles of 0.1 to 1.0 μm, making the glass opacified. And adding by workers according to actual production requirements.
Example 2
The embodiment provided by the invention comprises the following steps: a preparation formula for producing high-white glass by recycling printing cullet comprises quartz powder, calcite, feldspar, soda ash and printing cullet, and is used for preparing low-hardness colored glass, wherein the components comprise 50% of quartz powder, 10% of calcite, 10% of feldspar, 20% of soda ash and 10% of printing cullet. The printed glass is collected and uniformly recovered by the collecting device, and a large amount of printed glass is placed in the collecting box; the electromagnet extends into the collecting box, generates magnetic force after being electrified, moves back and forth in the collecting box, and carries out iron removal operation on the collected printed glass through the electromagnet to adsorb and take away iron substances in the printed glass; sorting and classifying the printed glass subjected to iron removal in sorting equipment, classifying the printed glass with different sizes into small, medium and large types, and respectively carrying out subsequent operation; conveying the classified printed glass into a crusher for crushing operation, crushing the printed glass into printed cullet, and classifying the crushed printed glass according to the previous small, medium and large sizes; cleaning the printing cullet through water filtering operation; and sorting and stacking the filtered printing cullet according to the sorting and sorting performed by the previous sorting equipment. Crushing the calculated corresponding materials, adding a coloring agent, enabling cobalt oxide to be blue, nickel oxide to be brown and manganese oxide to be purple, selecting by workers according to production requirements, uniformly mixing by using a stirrer, conveying the mixed materials into a furnace, and producing glass by high-temperature calcination.
Example 3
The embodiment provided by the invention comprises the following steps: a preparation formula for producing high-white glass by recycling printing cullet comprises quartz powder, calcite, feldspar, soda ash and printing cullet, and is used for manufacturing medium-hardness white glass, wherein the components comprise 40% of quartz powder, 15% of calcite, 15% of feldspar, 15% of soda ash and 15% of printing cullet. The printed glass is collected and uniformly recovered by the collecting device, and a large amount of printed glass is placed in the collecting box; the electromagnet extends into the collecting box, generates magnetic force after being electrified, moves back and forth in the collecting box, and carries out iron removal operation on the collected printed glass through the electromagnet to adsorb and take away iron substances in the printed glass; sorting and classifying the printed glass subjected to iron removal in sorting equipment, classifying the printed glass with different sizes into small, medium and large types, and respectively carrying out subsequent operation; conveying the classified printed glass into a crusher for crushing operation, crushing the printed glass into printed cullet, and classifying the crushed printed glass according to the previous small, medium and large sizes; cleaning the printing cullet through water filtering operation; and sorting and stacking the filtered printing cullet according to the sorting and sorting performed by the previous sorting equipment. The calculated corresponding materials are crushed, a decoloring agent is added, and cobalt oxide, sodium carbonate and the like are used as the decoloring agent, so that the color can be complemented with the original color in the glass, the glass is colorless, the materials are automatically selected by workers according to production requirements, then the materials are uniformly mixed by a stirrer, the mixed materials are conveyed into a furnace, and the glass is produced by high-temperature calcination.
Example 4
The embodiment provided by the invention comprises the following steps: a preparation formula for producing high-white glass by recycling printing cullet comprises quartz powder, calcite, feldspar, soda ash and printing cullet, and is used for manufacturing high-hardness translucent glass, wherein the quartz powder accounts for 30%, the calcite accounts for 15%, the feldspar accounts for 20%, the soda ash accounts for 15%, and the printing cullet accounts for 20%. The printed glass is collected and uniformly recovered by the collecting device, and a large amount of printed glass is placed in the collecting box; the electromagnet extends into the collecting box, generates magnetic force after being electrified, moves back and forth in the collecting box, and carries out iron removal operation on the collected printed glass through the electromagnet to adsorb and take away iron substances in the printed glass; sorting and classifying the printed glass subjected to iron removal in sorting equipment, classifying the printed glass with different sizes into small, medium and large types, and respectively carrying out subsequent operation; conveying the classified printed glass into a crusher for crushing operation, crushing the printed glass into printed cullet, and classifying the crushed printed glass according to the previous small, medium and large sizes; cleaning the printing cullet through water filtering operation; and sorting and stacking the filtered printing cullet according to the sorting and sorting performed by the previous sorting equipment. Crushing the calculated corresponding materials, adding an opacifier, sodium fluosilicate, tin phosphide and cryolite as the opacifier to enable the glass to become milky semitransparent bodies, selecting the milky semitransparent bodies by workers according to production requirements, uniformly mixing the milky semitransparent bodies by using a stirrer, conveying the mixed materials into a furnace, and calcining the mixed materials at high temperature to produce the glass.
The formula provided by the invention can greatly improve the use of the printed cullet in colleagues meeting various quality requirements of glass bottles. The using ratio of the printed glass is greatly adjusted to 20 percent from the original 5 percent. Can reduce the formula cost and the energy consumption of melting glass.
It will be evident to those skilled in the art that the invention is not limited to the details of the foregoing illustrative embodiments, and that the present invention may be embodied in other specific forms without departing from the spirit or essential attributes thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description, and all changes which come within the meaning and range of equivalency of the claims are therefore intended to be embraced therein.

Claims (5)

1. A preparation formula for producing high-white glass by recycling printing cullet comprises 30-50% of quartz powder, 10-15% of calcite, 10-20% of feldspar, 10-20% of soda and 10-20% of printing cullet.
2. The preparation formula for producing high-whiteness glass by recycling printed cullet according to claim 1, wherein the preparation formula comprises the following components in percentage by weight: the processing flow of the printing cullet comprises collection, iron removal, sorting, cleaning, crushing, water filtration and classified stacking, and the printing cullet is collected and uniformly recovered through a collection device; carrying out iron removal operation on the collected printed glass through an electromagnet to adsorb and take away iron substances in the printed glass; sorting and classifying the printed glass subjected to iron removal in sorting equipment, and performing classification treatment on the printed glass with different sizes; conveying the sorted printed glass into a crusher for crushing operation, and crushing the printed glass into printed cullet; cleaning the printing cullet through water filtering operation; and sorting and stacking the filtered printing cullet according to the sorting and sorting performed by the previous sorting equipment.
3. The preparation formula for producing high-whiteness glass by recycling printed cullet according to claim 1, wherein the preparation formula comprises the following components in percentage by weight: the method comprises the steps of preparing low-hardness high-white glass, wherein the high-white glass comprises 50% of quartz powder, 10% of calcite, 10% of feldspar, 20% of soda ash and 10% of printing cullet in percentage by weight, crushing the calculated corresponding materials, adding a reagent, and uniformly mixing by using a stirrer.
4. The preparation formula for producing high-whiteness glass by recycling printed cullet according to claim 1, wherein the preparation formula comprises the following components in percentage by weight: the method comprises the steps of preparing medium-hardness high-white glass, wherein the quartz powder accounts for 40%, the calcite accounts for 15%, the feldspar accounts for 15%, the soda ash accounts for 15%, and the printing cullet accounts for 15%, crushing the calculated corresponding materials, adding a reagent, and uniformly mixing by using a stirrer.
5. The preparation formula for producing high-whiteness glass by recycling printed cullet according to claim 1, wherein the preparation formula comprises the following components in percentage by weight: the high-hardness high-white glass is prepared by preparing high-hardness high-white glass, wherein the components comprise 30% of quartz powder, 15% of calcite, 20% of feldspar, 15% of soda ash and 20% of printing cullet in percentage by weight, crushing the calculated corresponding materials, adding a reagent, and uniformly mixing by using a stirrer.
CN202010605462.1A 2020-06-29 2020-06-29 Preparation formula for producing high-whiteness glass by recycling printed cullet Pending CN111925118A (en)

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CN202010605462.1A CN111925118A (en) 2020-06-29 2020-06-29 Preparation formula for producing high-whiteness glass by recycling printed cullet

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Application Number Priority Date Filing Date Title
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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101759364A (en) * 2008-12-02 2010-06-30 山东省药用玻璃股份有限公司 Manufacturing method of medical high white material molded glass bottle
CN102584016A (en) * 2011-01-18 2012-07-18 武汉华夏玻璃制品有限公司 Method for manufacturing infusion bottles by using broken glass
FR3051788A1 (en) * 2016-05-30 2017-12-01 Sgd Parfumerie France INTERMEDIATE COMPOSITION FOR WHITE GLASS, PROCESS FOR PRODUCING SUCH COMPOSITION AND METHOD FOR PRODUCING WHITE GLASS ARTICLE
CN109047294A (en) * 2018-09-11 2018-12-21 福建长城华兴玻璃有限公司 A kind of vial waste material milling process
US20200002215A1 (en) * 2018-01-23 2020-01-02 Xaris Holdings, LLC Amorphous Silica Products and Methods of Producing Amorphous Silica Products

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101759364A (en) * 2008-12-02 2010-06-30 山东省药用玻璃股份有限公司 Manufacturing method of medical high white material molded glass bottle
CN102584016A (en) * 2011-01-18 2012-07-18 武汉华夏玻璃制品有限公司 Method for manufacturing infusion bottles by using broken glass
FR3051788A1 (en) * 2016-05-30 2017-12-01 Sgd Parfumerie France INTERMEDIATE COMPOSITION FOR WHITE GLASS, PROCESS FOR PRODUCING SUCH COMPOSITION AND METHOD FOR PRODUCING WHITE GLASS ARTICLE
US20200002215A1 (en) * 2018-01-23 2020-01-02 Xaris Holdings, LLC Amorphous Silica Products and Methods of Producing Amorphous Silica Products
CN109047294A (en) * 2018-09-11 2018-12-21 福建长城华兴玻璃有限公司 A kind of vial waste material milling process

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Application publication date: 20201113

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