CN102549032B - 具有低的橡胶交联的冲击-改性的单亚乙烯基芳族聚合物 - Google Patents

具有低的橡胶交联的冲击-改性的单亚乙烯基芳族聚合物 Download PDF

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Publication number
CN102549032B
CN102549032B CN201080044865.8A CN201080044865A CN102549032B CN 102549032 B CN102549032 B CN 102549032B CN 201080044865 A CN201080044865 A CN 201080044865A CN 102549032 B CN102549032 B CN 102549032B
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Prior art keywords
rubber
polymer
ocli
modified
monovinylidene aromatic
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Expired - Fee Related
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CN201080044865.8A
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English (en)
Chinese (zh)
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CN102549032A (zh
Inventor
G·C·E·包奎特
F·斯利杰科曼
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Trinseo Europe GmbH
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Styron Europe GmbH
Trinseo Europe GmbH
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F257/00—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00
    • C08F257/02—Macromolecular compounds obtained by polymerising monomers on to polymers of aromatic monomers as defined in group C08F12/00 on to polymers of styrene or alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
CN201080044865.8A 2009-10-07 2010-10-06 具有低的橡胶交联的冲击-改性的单亚乙烯基芳族聚合物 Expired - Fee Related CN102549032B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP09172468.2 2009-10-07
EP09172468A EP2308906A1 (en) 2009-10-07 2009-10-07 Impact-modified monovinylidene aromatic polymer having low rubber crosslinking
PCT/EP2010/006112 WO2011042178A1 (en) 2009-10-07 2010-10-06 Impact-modified monovinylidene aromatic polymer having low rubber crosslinking

Publications (2)

Publication Number Publication Date
CN102549032A CN102549032A (zh) 2012-07-04
CN102549032B true CN102549032B (zh) 2016-07-06

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Country Status (7)

Country Link
US (1) US9447219B2 (cg-RX-API-DMAC7.html)
EP (2) EP2308906A1 (cg-RX-API-DMAC7.html)
JP (3) JP2013507458A (cg-RX-API-DMAC7.html)
KR (1) KR101758401B1 (cg-RX-API-DMAC7.html)
CN (1) CN102549032B (cg-RX-API-DMAC7.html)
TW (1) TWI499601B (cg-RX-API-DMAC7.html)
WO (1) WO2011042178A1 (cg-RX-API-DMAC7.html)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2308906A1 (en) 2009-10-07 2011-04-13 Styron Europe GmbH Impact-modified monovinylidene aromatic polymer having low rubber crosslinking
EP2961781B1 (en) 2013-02-26 2017-08-02 Trinseo Europe GmbH High impact polystryene having high modulus and resistance to environmental stress cracking
DE202019002164U1 (de) 2019-05-17 2019-06-21 Heraeus Nexensos Gmbh Verbesserter Hochtemperaturchip

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US6437043B1 (en) * 2001-09-13 2002-08-20 Fina Technology, Inc. Process and apparatus for continuous manufacture of elastomer-modified monovinylaromatic compounds
CN1466601A (zh) * 2001-07-30 2004-01-07 LG��ѧ��ʽ���� 丙烯腈-丁二烯-苯乙烯(abs)热塑性透明树脂
CN1556818A (zh) * 2001-07-24 2004-12-22 ͨ�õ�����˾ 改进的聚合方法
CN1727375A (zh) * 2004-12-27 2006-02-01 上海华谊本体聚合技术开发有限公司 一种制备高抗冲abs聚合物混合体的连续本体聚合工艺
CN101307121A (zh) * 2008-07-08 2008-11-19 郑勇 抗冲击高分子聚合物、高分子聚合物的制备方法、及高分子聚合物应用

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DE2525019B1 (de) 1975-06-05 1975-12-04 Basf Ag Schlagfeste thermoplastische Formmassen mit erhoehter Spannungsrissbestaendigkeit
US4572819A (en) 1983-08-24 1986-02-25 The Dow Chemical Company Apparatus for anionic polymerization wherein the molecular weight of the polymer is closely controlled
US4585825A (en) 1983-09-30 1986-04-29 The Dow Chemical Company Monovinylidene aromatic polymer resins having added amounts of high molecular weight polymer
US4666987A (en) 1985-02-22 1987-05-19 The Dow Chemical Company In-mold polymerization of vinyl aromatic compound
US5286792A (en) 1990-09-04 1994-02-15 Monsanto Company ABS with novel morphology
ES2171390T3 (es) * 1990-09-04 2002-09-16 Bayer Antwerpen Nv Polimeros de abs de brillo elevado producidos por un procedimiento continuo.
JP3254054B2 (ja) * 1993-08-17 2002-02-04 旭化成株式会社 ゴム変性ビニル芳香族樹脂組成物及びその製法
JP3362266B2 (ja) * 1993-11-29 2003-01-07 新日鐵化学株式会社 ゴム変性スチレン系樹脂組成物
DE4431732A1 (de) * 1994-09-06 1996-03-07 Basf Ag Transparente, schlagzähe Formmassen mit hoher Spannungsrißbeständigkeit und matter Oberfläche
AU4162796A (en) * 1994-11-30 1996-06-19 Chevron Chemical Company Styrenic polymer resins achieving improved gloss and impact resistance
TW418232B (en) * 1996-11-12 2001-01-11 Ube Industries Impact-resistant polystyrene resin composition
US6187862B1 (en) * 1998-05-01 2001-02-13 Bayer Corporation Weatherable resinous composition having improved opacity and impact strength
US6380304B1 (en) * 1999-09-30 2002-04-30 The Dow Chemical Company Mass polymerized rubber-modified monovinylidene aromatic copolymer compositions
JP2002020566A (ja) * 2000-07-11 2002-01-23 Kanegafuchi Chem Ind Co Ltd 透明、耐衝撃性熱可塑性樹脂組成物
JP2002275210A (ja) * 2000-10-24 2002-09-25 Mitsui Chemicals Inc 耐油性ゴム変性ポリスチレン組成物
DE60315132T2 (de) * 2002-01-30 2007-11-15 Idemitsu Kosan Co. Ltd. Thermoplastharzzusammensetzung, polycarbonatharzzusammensetzung und formkörper daraus
JP4553842B2 (ja) * 2003-06-12 2010-09-29 株式会社カネカ ゴム変性スチレン系樹脂組成物
DE10354379A1 (de) * 2003-11-20 2005-06-23 Röhm GmbH & Co. KG Formmasse, enthaltend ein Mattierungsmittel
JP4916091B2 (ja) * 2004-02-23 2012-04-11 テクノポリマー株式会社 ゴム変性熱可塑性樹脂およびその組成物
US7312277B2 (en) * 2004-04-21 2007-12-25 Dow Global Technologies Inc. Mass polymerized rubber-modified monovinylidene aromatic copolymer composition
DE102005047463A1 (de) * 2005-09-30 2007-04-05 Basf Ag Thermoplastische Formmassen mit verbesserten optischen Eigenschaften
WO2008134131A1 (en) * 2007-04-25 2008-11-06 Dow Global Technologies Inc. Process for the production of a (co) polymer composition by mediated free radical chain growth polymerization
EP2308906A1 (en) 2009-10-07 2011-04-13 Styron Europe GmbH Impact-modified monovinylidene aromatic polymer having low rubber crosslinking

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1556818A (zh) * 2001-07-24 2004-12-22 ͨ�õ�����˾ 改进的聚合方法
CN1466601A (zh) * 2001-07-30 2004-01-07 LG��ѧ��ʽ���� 丙烯腈-丁二烯-苯乙烯(abs)热塑性透明树脂
US6437043B1 (en) * 2001-09-13 2002-08-20 Fina Technology, Inc. Process and apparatus for continuous manufacture of elastomer-modified monovinylaromatic compounds
CN1727375A (zh) * 2004-12-27 2006-02-01 上海华谊本体聚合技术开发有限公司 一种制备高抗冲abs聚合物混合体的连续本体聚合工艺
CN101307121A (zh) * 2008-07-08 2008-11-19 郑勇 抗冲击高分子聚合物、高分子聚合物的制备方法、及高分子聚合物应用

Also Published As

Publication number Publication date
KR20120093184A (ko) 2012-08-22
WO2011042178A1 (en) 2011-04-14
JP6254637B2 (ja) 2017-12-27
JP2013507458A (ja) 2013-03-04
EP2308906A1 (en) 2011-04-13
CN102549032A (zh) 2012-07-04
US9447219B2 (en) 2016-09-20
KR101758401B1 (ko) 2017-07-14
US20120202949A1 (en) 2012-08-09
JP2016145367A (ja) 2016-08-12
TW201130867A (en) 2011-09-16
EP2486069A1 (en) 2012-08-15
TWI499601B (zh) 2015-09-11
JP6353148B2 (ja) 2018-07-04
JP2018012843A (ja) 2018-01-25

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