CN102497921B - 固体无机组合物、其制备方法及其在烟道气中的用途 - Google Patents

固体无机组合物、其制备方法及其在烟道气中的用途 Download PDF

Info

Publication number
CN102497921B
CN102497921B CN201080031507.3A CN201080031507A CN102497921B CN 102497921 B CN102497921 B CN 102497921B CN 201080031507 A CN201080031507 A CN 201080031507A CN 102497921 B CN102497921 B CN 102497921B
Authority
CN
China
Prior art keywords
inorganic compound
halide salt
composition
weight
doped
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201080031507.3A
Other languages
English (en)
Chinese (zh)
Other versions
CN102497921A (zh
Inventor
A·布拉施尔
J-P·皮拉德
A·洛代
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Lhoist Recherche et Developpement SA
Universite de Liege
Original Assignee
Lhoist Recherche et Developpement SA
Universite de Liege
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Lhoist Recherche et Developpement SA, Universite de Liege filed Critical Lhoist Recherche et Developpement SA
Publication of CN102497921A publication Critical patent/CN102497921A/zh
Application granted granted Critical
Publication of CN102497921B publication Critical patent/CN102497921B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/64—Heavy metals or compounds thereof, e.g. mercury
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/46—Removing components of defined structure
    • B01D53/68—Halogens or halogen compounds
    • B01D53/70—Organic halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/0203—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04
    • B01J20/0274—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of metals not provided for in B01J20/04 characterised by the type of anion
    • B01J20/0288—Halides of compounds other than those provided for in B01J20/046
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/04—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium
    • B01J20/046—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising compounds of alkali metals, alkaline earth metals or magnesium containing halogens, e.g. halides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/12—Naturally occurring clays or bleaching earth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28059—Surface area, e.g. B.E.T specific surface area being less than 100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28057—Surface area, e.g. B.E.T specific surface area
    • B01J20/28061—Surface area, e.g. B.E.T specific surface area being in the range 100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
    • B01J20/28054—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J20/28069—Pore volume, e.g. total pore volume, mesopore volume, micropore volume
    • B01J20/28071—Pore volume, e.g. total pore volume, mesopore volume, micropore volume being less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/3078—Thermal treatment, e.g. calcining or pyrolizing
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3202—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the carrier, support or substrate used for impregnation or coating
    • B01J20/3204—Inorganic carriers, supports or substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30—Processes for preparing, regenerating, or reactivating
    • B01J20/32—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating
    • B01J20/3231—Impregnating or coating ; Solid sorbent compositions obtained from processes involving impregnating or coating characterised by the coating or impregnating layer
    • B01J20/3234—Inorganic material layers
    • B01J20/3236—Inorganic material layers containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/16—Clays or other mineral silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/63—Pore volume
    • B01J35/633—Pore volume less than 0.5 ml/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/70—Catalysts, in general, characterised by their form or physical properties characterised by their crystalline properties, e.g. semi-crystalline
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/106—Silica or silicates
    • B01D2253/11—Clays
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10—Inorganic adsorbents
    • B01D2253/116—Molecular sieves other than zeolites
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/304—Linear dimensions, e.g. particle shape, diameter
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/306—Surface area, e.g. BET-specific surface
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/30—Physical properties of adsorbents
    • B01D2253/302—Dimensions
    • B01D2253/311—Porosity, e.g. pore volume
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/20—Halogens or halogen compounds
    • B01D2257/206—Organic halogen compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/60—Heavy metals or heavy metal compounds
    • B01D2257/602—Mercury or mercury compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Environmental & Geological Engineering (AREA)
  • General Chemical & Material Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Treating Waste Gases (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
CN201080031507.3A 2009-07-13 2010-07-13 固体无机组合物、其制备方法及其在烟道气中的用途 Expired - Fee Related CN102497921B (zh)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
BE2009/0427 2009-07-13
BE200900427 2009-07-13
US33225410P 2010-05-07 2010-05-07
US61/332,254 2010-05-07
PCT/EP2010/060075 WO2011006898A1 (fr) 2009-07-13 2010-07-13 Composition solide minerale, son procede de preparation et son utilisation en abattement de dioxines et metaux lourds des gaz de fumees

Publications (2)

Publication Number Publication Date
CN102497921A CN102497921A (zh) 2012-06-13
CN102497921B true CN102497921B (zh) 2015-08-19

Family

ID=41719070

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201080031507.3A Expired - Fee Related CN102497921B (zh) 2009-07-13 2010-07-13 固体无机组合物、其制备方法及其在烟道气中的用途

Country Status (17)

Country Link
US (1) US20120134903A1 (https=)
EP (1) EP2454007B1 (https=)
JP (1) JP5722888B2 (https=)
KR (1) KR20120085718A (https=)
CN (1) CN102497921B (https=)
AU (1) AU2010272573A1 (https=)
BE (1) BE1019420A5 (https=)
CA (1) CA2767282A1 (https=)
FR (1) FR2949979A1 (https=)
IL (1) IL217480A0 (https=)
MX (1) MX2012000590A (https=)
NZ (1) NZ598097A (https=)
PL (1) PL2454007T3 (https=)
RU (1) RU2543210C2 (https=)
SG (1) SG177490A1 (https=)
UA (1) UA108615C2 (https=)
WO (1) WO2011006898A1 (https=)

Families Citing this family (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102814180B (zh) * 2012-06-07 2017-12-22 盐城工学院 用于烟气中单质汞氧化凹凸棒土载体催化剂及其制备方法
US20130330257A1 (en) 2012-06-11 2013-12-12 Calgon Carbon Corporation Sorbents for removal of mercury
US9751043B1 (en) 2014-09-05 2017-09-05 Mississippi Lime Company Systems and method for removal of acid gas in a circulating dry scrubber
US10155227B2 (en) 2012-08-24 2018-12-18 Mississippi Lime Company Systems and method for removal of acid gas in a circulating dry scrubber
CN104918886B (zh) * 2012-11-13 2018-08-10 巴斯夫欧洲公司 沸石材料的制备和在将氧合物转化成烯烃的方法中的用途
US10221094B1 (en) 2013-03-04 2019-03-05 Mississippi Lime Company Method of manufacturing hydrated lime
US9963386B1 (en) 2013-03-04 2018-05-08 Mississippi Lime Company Method of manufacturing hydrated lime
JP6616928B2 (ja) * 2013-06-19 2019-12-04 カルゴン カーボン コーポレーション 活性炭からの重金属浸出の軽減方法
CN103381337B (zh) * 2013-06-26 2016-01-20 广东电网公司电力科学研究院 一种用于湿法烟气脱汞的催化氧化添加剂及其制备方法
US10668480B1 (en) 2014-09-05 2020-06-02 Mississippi Lime Company Systems and method for removal of acid gas in a circulating dry scrubber
CA2995357C (en) 2015-08-11 2023-12-19 Calgon Carbon Corporation Enhanced sorbent formulation for removal of mercury from flue gas
CN105435735A (zh) * 2015-11-19 2016-03-30 兰州坤仑环保科技有限公司 一种水体重金属离子凹凸棒吸附剂
CN105944554A (zh) * 2016-06-08 2016-09-21 黄立维 一种去除有害气体的方法及装置
US11148149B2 (en) 2017-12-29 2021-10-19 Mississippi Lime Company Hydrated lime with reduced resistivity and method of manufacture
US11365150B1 (en) 2018-07-18 2022-06-21 Mississippi Lime Company Lime hydrate with improved reactivity via additives
CN111389219B (zh) * 2020-03-27 2021-11-02 浙江浙能技术研究院有限公司 一种用于燃煤锅炉启停阶段的喷氨控制方法
CN120054434B (zh) * 2025-03-12 2025-09-30 广州鑫材科技有限公司 一种硅基吸附剂及其在生活垃圾焚烧废气处置中的应用

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01155930A (ja) * 1987-12-11 1989-06-19 Onoda Cement Co Ltd 複合乾燥剤
DE19824237A1 (de) * 1998-05-29 1999-12-02 Walhalla Kalk Entwicklungs Und Reagentien für die Reinigung von Abgasen
JP2000140627A (ja) * 1998-11-10 2000-05-23 Takuma Co Ltd ダイオキシン除去材、ダイオキシン除去方法、及び、ダイオキシン除去材の再生方法
JP2001031107A (ja) * 1999-07-21 2001-02-06 Kurin Kasei Kk ダイオキシン対策用ごみ袋
WO2006099291A2 (en) * 2005-03-14 2006-09-21 Praxair Technology, Inc. Adsorbents for mercury removal from flue gas
CN1929897A (zh) * 2004-03-15 2007-03-14 勒瓦研究开发股份有限公司 减少烟道气中重金属的方法
CN101175550A (zh) * 2005-03-17 2008-05-07 Noxⅱ国际有限公司 降低煤燃烧过程中汞的排放量

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1481646A (fr) 1966-05-31 1967-05-19 Union Carbide Corp Compositions adsorbantes siliceuses et leur procédé de préparation
JPS4953591A (https=) * 1972-09-29 1974-05-24
JPS59160534A (ja) * 1983-03-03 1984-09-11 Takeda Chem Ind Ltd 水銀蒸気吸着剤および水銀蒸気含有気体の処理方法
JPS5910343A (ja) * 1982-07-08 1984-01-19 Takeda Chem Ind Ltd 水銀蒸気吸着剤
ES8704428A1 (es) 1986-02-11 1987-04-16 Consejo Superior Investigacion Procedimiento de fabricacion de un adsorbente azufrado, util para retener vapores de metal, como mercurio.
RU2035993C1 (ru) * 1993-09-30 1995-05-27 Александр Ефимович Горенбейн Способ получения сорбентов для очистки газов от ртути
JPH09208336A (ja) * 1996-01-30 1997-08-12 Ootake Seramu Kk 塩基性多孔体及びその製造法
ES2136496B1 (es) 1996-06-18 2000-10-01 Consejo Superior Investigacion Procedimiento de sulfuracion de silicatos naturales para retener vapores de metales.
JP2001276606A (ja) 2000-03-31 2001-10-09 Hitachi Zosen Corp 排ガス中の有機系有害物除去用吸着剤および同有害物の除去方法
JP3790890B2 (ja) 2001-07-19 2006-06-28 日立造船株式会社 塩素化芳香族化合物の生成抑制剤および生成抑制方法
RU2200053C1 (ru) * 2001-11-27 2003-03-10 Рынейский Вадим Анатольевич Установка для очистки дымовых газов
DE10228459A1 (de) * 2002-06-26 2004-01-15 Iko Minerals Gmbh Verfahren zur Herstellung eines silikatischen Adsorbermaterials
US8652235B2 (en) * 2004-08-30 2014-02-18 Energy & Environmental Research Center Foundation Sorbents for the oxidation and removal of mercury
US8906823B2 (en) * 2007-09-24 2014-12-09 Basf Corporation Pollutant emission control sorbents and methods of manufacture and use
FR2947736B1 (fr) * 2009-07-13 2015-09-18 Lhoist Rech & Dev Sa Composition solide minerale, son procede de preparation et son utilisation en abattement de metaux lourds des gaz de fumees

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01155930A (ja) * 1987-12-11 1989-06-19 Onoda Cement Co Ltd 複合乾燥剤
DE19824237A1 (de) * 1998-05-29 1999-12-02 Walhalla Kalk Entwicklungs Und Reagentien für die Reinigung von Abgasen
JP2000140627A (ja) * 1998-11-10 2000-05-23 Takuma Co Ltd ダイオキシン除去材、ダイオキシン除去方法、及び、ダイオキシン除去材の再生方法
JP2001031107A (ja) * 1999-07-21 2001-02-06 Kurin Kasei Kk ダイオキシン対策用ごみ袋
CN1929897A (zh) * 2004-03-15 2007-03-14 勒瓦研究开发股份有限公司 减少烟道气中重金属的方法
WO2006099291A2 (en) * 2005-03-14 2006-09-21 Praxair Technology, Inc. Adsorbents for mercury removal from flue gas
CN101175550A (zh) * 2005-03-17 2008-05-07 Noxⅱ国际有限公司 降低煤燃烧过程中汞的排放量

Also Published As

Publication number Publication date
EP2454007B1 (fr) 2017-08-02
EP2454007A1 (fr) 2012-05-23
AU2010272573A1 (en) 2012-02-23
JP2012532754A (ja) 2012-12-20
KR20120085718A (ko) 2012-08-01
RU2012104806A (ru) 2013-09-27
IL217480A0 (en) 2012-02-29
SG177490A1 (en) 2012-02-28
CA2767282A1 (fr) 2011-01-20
UA108615C2 (uk) 2015-05-25
CN102497921A (zh) 2012-06-13
FR2949979A1 (fr) 2011-03-18
PL2454007T3 (pl) 2018-01-31
JP5722888B2 (ja) 2015-05-27
US20120134903A1 (en) 2012-05-31
WO2011006898A1 (fr) 2011-01-20
RU2543210C2 (ru) 2015-02-27
MX2012000590A (es) 2012-06-01
BE1019420A5 (fr) 2012-07-03
NZ598097A (en) 2013-08-30

Similar Documents

Publication Publication Date Title
CN102497921B (zh) 固体无机组合物、其制备方法及其在烟道气中的用途
US7704920B2 (en) Pollutant emission control sorbents and methods of manufacture
US7578869B2 (en) Methods of manufacturing bentonite pollution control sorbents
CA2522258C (en) Sorbents and methods for the removal of mercury from combustion gases
US8728974B2 (en) Pollutant emission control sorbents and methods of manufacture and use
JP6545616B2 (ja) 水銀を除去する吸着剤
CN101132856B (zh) 沉淀二氧化硅的聚集体，其制备方法和其在气体过滤中作为过滤器介质的用途
JP2018507776A (ja) 吸着剤ポリマー複合材料を用いた排気ガス精製システムおよび方法
JP2013505832A (ja) 燃焼排ガスから水銀を取り除く吸着剤
US20120103907A1 (en) Manganese based sorbent for removal of mercury species from fluids
CN104394960B (zh) 净化液体的介质，其制备方法及其应用
JP5689878B2 (ja) 固体無機組成物、その作製方法および煙道ガス中の重金属を減少させるためのその使用
CN107073395A (zh) 净化流体的方法
MXPA06010638A (es) Procedimiento para reducir metales pesados de los gases de humos.
Rafeen et al. Tackling elemental mercury removal from the wet-gas phase by enhancing the performance of redox-active copper-based adsorbents utilising an operando pre-heating system
RU2574541C2 (ru) Твердая минеральная композиция, способ ее получения и ее применение для снижения содержания тяжелых металлов в отходящем газе
KR20120062703A (ko) 연도 가스에서 중금속을 감소시키기 위한 고체 무기 조성물, 이의 제조방법 및 이의 용도
MX2012000589A (es) Composicion mineral solida, procedimiento de fabricacion y uso de la misma para reducir los metales pesados de los gases de combustion.

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20150819

Termination date: 20200713

CF01 Termination of patent right due to non-payment of annual fee