CN102442871A - 以贝壳和扇贝裙边为原料的复合氨基酸螯合钙的制备方法 - Google Patents
以贝壳和扇贝裙边为原料的复合氨基酸螯合钙的制备方法 Download PDFInfo
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- CN102442871A CN102442871A CN2010105121023A CN201010512102A CN102442871A CN 102442871 A CN102442871 A CN 102442871A CN 2010105121023 A CN2010105121023 A CN 2010105121023A CN 201010512102 A CN201010512102 A CN 201010512102A CN 102442871 A CN102442871 A CN 102442871A
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- amino acid
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- calcium
- shell
- scallop
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- -1 compound amino acid Chemical class 0.000 title claims abstract description 38
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 title claims abstract description 34
- 229910052791 calcium Inorganic materials 0.000 title claims abstract description 33
- 239000011575 calcium Substances 0.000 title claims abstract description 33
- 235000020637 scallop Nutrition 0.000 title claims abstract description 25
- 241000237509 Patinopecten sp. Species 0.000 title claims abstract description 24
- 239000002994 raw material Substances 0.000 title claims abstract description 8
- 238000002360 preparation method Methods 0.000 title claims 6
- 238000000034 method Methods 0.000 claims abstract description 16
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims abstract description 12
- 238000006243 chemical reaction Methods 0.000 claims abstract description 12
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims abstract description 10
- 230000009920 chelation Effects 0.000 claims abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 235000015170 shellfish Nutrition 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 229910000019 calcium carbonate Inorganic materials 0.000 claims abstract description 4
- 238000001556 precipitation Methods 0.000 claims abstract description 3
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 6
- 239000000047 product Substances 0.000 claims description 6
- 238000001953 recrystallisation Methods 0.000 claims description 6
- 239000001110 calcium chloride Substances 0.000 claims description 5
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 5
- 239000013522 chelant Substances 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000002699 waste material Substances 0.000 claims description 5
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000012043 crude product Substances 0.000 claims description 4
- 238000007670 refining Methods 0.000 claims description 4
- 238000003786 synthesis reaction Methods 0.000 claims description 4
- 238000000967 suction filtration Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 2
- 229960000935 dehydrated alcohol Drugs 0.000 claims 1
- 238000000926 separation method Methods 0.000 claims 1
- 239000004365 Protease Substances 0.000 abstract description 4
- 230000007071 enzymatic hydrolysis Effects 0.000 abstract description 4
- 238000006047 enzymatic hydrolysis reaction Methods 0.000 abstract description 4
- 108090000145 Bacillolysin Proteins 0.000 abstract description 3
- 108091005507 Neutral proteases Proteins 0.000 abstract description 3
- 102000035092 Neutral proteases Human genes 0.000 abstract description 3
- 108090000526 Papain Proteins 0.000 abstract description 3
- 229940055729 papain Drugs 0.000 abstract description 3
- 235000019834 papain Nutrition 0.000 abstract description 3
- 108091005508 Acid proteases Proteins 0.000 abstract description 2
- 238000004321 preservation Methods 0.000 abstract description 2
- 241000237503 Pectinidae Species 0.000 abstract 1
- 239000000463 material Substances 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 238000002791 soaking Methods 0.000 abstract 1
- 230000002194 synthesizing effect Effects 0.000 abstract 1
- 229960005069 calcium Drugs 0.000 description 18
- 239000008399 tap water Substances 0.000 description 4
- 235000020679 tap water Nutrition 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 241000237502 Ostreidae Species 0.000 description 3
- 235000013305 food Nutrition 0.000 description 3
- 235000020636 oyster Nutrition 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000003463 adsorbent Substances 0.000 description 2
- 238000009360 aquaculture Methods 0.000 description 2
- 244000144974 aquaculture Species 0.000 description 2
- 229960003563 calcium carbonate Drugs 0.000 description 2
- 206010006956 Calcium deficiency Diseases 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- 108091005804 Peptidases Proteins 0.000 description 1
- 102100037486 Reverse transcriptase/ribonuclease H Human genes 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- VSGNNIFQASZAOI-UHFFFAOYSA-L calcium acetate Chemical compound [Ca+2].CC([O-])=O.CC([O-])=O VSGNNIFQASZAOI-UHFFFAOYSA-L 0.000 description 1
- 239000001639 calcium acetate Substances 0.000 description 1
- 229960005147 calcium acetate Drugs 0.000 description 1
- 235000011092 calcium acetate Nutrition 0.000 description 1
- 235000010216 calcium carbonate Nutrition 0.000 description 1
- 239000004227 calcium gluconate Substances 0.000 description 1
- 229960004494 calcium gluconate Drugs 0.000 description 1
- 235000013927 calcium gluconate Nutrition 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 229960002401 calcium lactate Drugs 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- 239000001506 calcium phosphate Substances 0.000 description 1
- 229910000389 calcium phosphate Inorganic materials 0.000 description 1
- 229960001714 calcium phosphate Drugs 0.000 description 1
- 235000011010 calcium phosphates Nutrition 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 229940069978 calcium supplement Drugs 0.000 description 1
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 229940088598 enzyme Drugs 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 230000002779 inactivation Effects 0.000 description 1
- 231100000053 low toxicity Toxicity 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008520 organization Effects 0.000 description 1
- 235000019419 proteases Nutrition 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- QORWJWZARLRLPR-UHFFFAOYSA-H tricalcium bis(phosphate) Chemical compound [Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O QORWJWZARLRLPR-UHFFFAOYSA-H 0.000 description 1
Landscapes
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Meat, Egg Or Seafood Products (AREA)
- Medicines Containing Material From Animals Or Micro-Organisms (AREA)
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| CN2010105121023A CN102442871A (zh) | 2010-10-12 | 2010-10-12 | 以贝壳和扇贝裙边为原料的复合氨基酸螯合钙的制备方法 |
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| CN2010105121023A CN102442871A (zh) | 2010-10-12 | 2010-10-12 | 以贝壳和扇贝裙边为原料的复合氨基酸螯合钙的制备方法 |
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| Publication Number | Publication Date |
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| CN102442871A true CN102442871A (zh) | 2012-05-09 |
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| CN2010105121023A Pending CN102442871A (zh) | 2010-10-12 | 2010-10-12 | 以贝壳和扇贝裙边为原料的复合氨基酸螯合钙的制备方法 |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103710403A (zh) * | 2013-12-09 | 2014-04-09 | 广东环西生物科技股份有限公司 | 复合氨基酸螯合钙高效清洁生产工艺 |
| CN104905256A (zh) * | 2015-05-21 | 2015-09-16 | 北海富安源生物科技有限公司 | 一种以牡蛎为原料制备的复合氨基酸钙 |
| CN105433300A (zh) * | 2015-12-29 | 2016-03-30 | 广西钦州市绿源天然食品加工有限公司 | 一种牡蛎壳生产活性钙的加工方法 |
| CN105567775A (zh) * | 2016-03-03 | 2016-05-11 | 集美大学 | 鱼胶原肽螯合钙的生产方法 |
| CN108477619A (zh) * | 2018-03-16 | 2018-09-04 | 青岛大学 | 一种复合氨基酸螯合钙的制备方法 |
| CN110256267A (zh) * | 2019-07-08 | 2019-09-20 | 中国海洋大学 | 一种以太平洋牡蛎壳为钙源的l-天冬氨酸螯合钙制备方法 |
| CN114190469A (zh) * | 2021-12-27 | 2022-03-18 | 南通励成生物工程有限公司 | 一种水解乳清蛋白复合氨基酸螯合物及其制备方法与应用 |
| CN117586067A (zh) * | 2023-12-07 | 2024-02-23 | 峨眉山市龙腾生物科技有限公司 | 一种氨基酸螯合有机肥及其生产工艺 |
| CN119898874A (zh) * | 2025-03-31 | 2025-04-29 | 中国林业科学研究院林产化学工业研究所 | 一种梯度螯合-自由基活化协同的桉木化机浆废水复合混凝剂及其制备方法 |
Citations (5)
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|---|---|---|---|---|
| CN1348008A (zh) * | 2001-10-15 | 2002-05-08 | 彭城职业大学 | 复合l－氨基酸钙生产方法 |
| CN101449737A (zh) * | 2008-12-23 | 2009-06-10 | 青岛大学 | 一种扇贝纯边氨基酸营养粉的制备方法 |
| CN101602685A (zh) * | 2009-06-30 | 2009-12-16 | 青岛大学 | 以贝类加工废弃物为钙源的谷氨酸螯合钙合成方法 |
| JP2010068757A (ja) * | 2008-09-19 | 2010-04-02 | Suzuki Farm:Kk | 卵殻をアミノ酸卵殻カルシウムにする方法 |
| CN101747222A (zh) * | 2009-12-25 | 2010-06-23 | 河北农业大学 | 甘氨酸螯合牡蛎钙水相合成方法及高钙酱油的制备 |
-
2010
- 2010-10-12 CN CN2010105121023A patent/CN102442871A/zh active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1348008A (zh) * | 2001-10-15 | 2002-05-08 | 彭城职业大学 | 复合l－氨基酸钙生产方法 |
| JP2010068757A (ja) * | 2008-09-19 | 2010-04-02 | Suzuki Farm:Kk | 卵殻をアミノ酸卵殻カルシウムにする方法 |
| CN101449737A (zh) * | 2008-12-23 | 2009-06-10 | 青岛大学 | 一种扇贝纯边氨基酸营养粉的制备方法 |
| CN101602685A (zh) * | 2009-06-30 | 2009-12-16 | 青岛大学 | 以贝类加工废弃物为钙源的谷氨酸螯合钙合成方法 |
| CN101747222A (zh) * | 2009-12-25 | 2010-06-23 | 河北农业大学 | 甘氨酸螯合牡蛎钙水相合成方法及高钙酱油的制备 |
Non-Patent Citations (3)
| Title |
|---|
| 王家明等: "以牡蛎壳为钙源的谷氨酸螯合钙制备工艺研究", 《中国海洋药物杂志》 * |
| 郑清等: "利用文蛤壳制备复合氨基酸螯合钙", 《安徽化工》 * |
| 魏玉西等: "扇贝裙边氨基酸营养粉的制备工艺研究", 《渔业科学进展》 * |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103710403A (zh) * | 2013-12-09 | 2014-04-09 | 广东环西生物科技股份有限公司 | 复合氨基酸螯合钙高效清洁生产工艺 |
| CN103710403B (zh) * | 2013-12-09 | 2016-05-04 | 广东环西生物科技股份有限公司 | 复合氨基酸螯合钙高效清洁生产工艺 |
| CN104905256A (zh) * | 2015-05-21 | 2015-09-16 | 北海富安源生物科技有限公司 | 一种以牡蛎为原料制备的复合氨基酸钙 |
| CN105433300A (zh) * | 2015-12-29 | 2016-03-30 | 广西钦州市绿源天然食品加工有限公司 | 一种牡蛎壳生产活性钙的加工方法 |
| CN105567775A (zh) * | 2016-03-03 | 2016-05-11 | 集美大学 | 鱼胶原肽螯合钙的生产方法 |
| CN108477619A (zh) * | 2018-03-16 | 2018-09-04 | 青岛大学 | 一种复合氨基酸螯合钙的制备方法 |
| CN110256267A (zh) * | 2019-07-08 | 2019-09-20 | 中国海洋大学 | 一种以太平洋牡蛎壳为钙源的l-天冬氨酸螯合钙制备方法 |
| CN114190469A (zh) * | 2021-12-27 | 2022-03-18 | 南通励成生物工程有限公司 | 一种水解乳清蛋白复合氨基酸螯合物及其制备方法与应用 |
| CN114190469B (zh) * | 2021-12-27 | 2024-03-15 | 南通励成生物工程有限公司 | 一种水解乳清蛋白复合氨基酸螯合物及其制备方法与应用 |
| CN117586067A (zh) * | 2023-12-07 | 2024-02-23 | 峨眉山市龙腾生物科技有限公司 | 一种氨基酸螯合有机肥及其生产工艺 |
| CN119898874A (zh) * | 2025-03-31 | 2025-04-29 | 中国林业科学研究院林产化学工业研究所 | 一种梯度螯合-自由基活化协同的桉木化机浆废水复合混凝剂及其制备方法 |
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Application publication date: 20120509 |