CN102428931B - Bacteriocidal composition containing Boscalid and triazole bactericide - Google Patents
Bacteriocidal composition containing Boscalid and triazole bactericide Download PDFInfo
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Abstract
The invention relates to a bacteriocidal composition and an application thereof. The bacteriocidal composition is characterized by comprising Boscalid (A) and at least one (B) selected from the following active components of a triazole bactericide: difenoconazole, propiconazole, tebuconazole, hexaconazole, flutriafol, epoxiconazole, tetraconazole, flusilazole, myclobutanil, cyproconazole, triazolone and diniconazole, wherein the mass ratio of A to B is (1:50)-(50:1). The composition can be applied to preventing and treating diseases of crops such as cereal crops, melons, fruits, vegetables and the like.
Description
(1) technical field
The present invention relates to a kind of bactericidal composition and uses thereof, particularly, the present invention relates to a kind of Boscalid and at least a triazole bactericidal agent that is selected from of containing as the bactericidal composition of active component, and this bactericidal composition is used for the purposes of controlling plant diseases.
(2) background technology
Boscalid
English common name: Boscalid
Chemical name: 2-chloro-N-(4-chlordiphenyl-2-yl) vitamin PP
Structural formula:
Boscalid is in recent years Novel tobacco amide-type systemic fungicide newly developed, fungicidal spectrum is wider, almost all types of fungal diseases there is activity, very effective to preventing and treating powdery mildew, gray mold, stalk break and various rots etc., and the resistance bacterium to other medicaments is also effective, is mainly used in comprising the control of the diseases such as rape, grape, fruit tree, vegetables and field crop.Because its distinctive mechanism of action be difficult for to produce cross resistance, to crop safety and favourable toxicity data and ecological effect, be the Novel tobacco acid amide fungicides of significant in addition.
Although Boscalid has above-mentioned advantage, because cost is too high, at present domestic almost not application.
(3) summary of the invention
One of purpose of the present invention is to overcome above-mentioned deficiency, but the low delaying drug resistance development of a kind of applied widely, effective, cost is provided contain Boscalid and a kind of triazole bactericidal agent that is selected from as the bactericidal composition of active component.
Two of purpose of the present invention is to provide a kind of Boscalid and at least a purposes that is selected from the bactericidal composition of triazole bactericidal agent of containing.
The object of the present invention is achieved like this:
A kind of bactericidal composition that contains Boscalid, described composition contains active ingredient and is (A) Boscalid and at least a being selected from (B) triazole bactericidal agent: Difenoconazole, propiconazole, Tebuconazole, own azoles alcohol, Flutriafol, epoxiconazole, tetraconazole, Flusilazole, nitrile bacterium azoles, Cyproconazole, triazolone, alkene azoles alcohol, the weight ratio of described A and B is 1～50: 50～1.
The preferred weight ratio of described A and B is 3～40: 2～40.
Described combination dosage form is any one formulation that allows on the agricultural chemicals.Such as wetting powder, water dispersible granules, suspending agent, aqueous emulsion, missible oil or the agent of kind clothing etc.
When concrete the application, described A and the mass percent of B component in above-mentioned formulation are 5～90%.
A kind of purposes that contains the bactericidal composition of Boscalid is used for the control of control cereal crop or gourd, fruit and vegetable class plant disease.The for example control of the multiple cereal crop disease on paddy rice, the wheat, for example rice blast, banded sclerotial blight, false smut, glume blight, wheat rust, powdery mildew, full rot, wheat scab, barley leaf blotch, leaf rust, Gerlachia oryaae, triticale powdery mildew, leaf rust, corn northern and southern leaf blight, head smut etc., preferred, bactericidal composition of the present invention is used for preventing and treating rice sheath blight disease, leaf rust of barley, triticale leaf rust, wheat scab and the corn northern leaf blight.Gourd, fruit and vegetable class plant disease is such as cucumber downy mildew, alternaria leaf spot of apple, ring rot of apple, pear scab, Chinese cabbage rot, downy mildew of garpe, capsicum epidemic disease, watermelon anthrax, citrus scab, tomato late blight etc., preferably, bactericidal composition of the present invention is used for control tomato late blight, pear scab.
Compared with prior art, the invention has the beneficial effects as follows:
(1) present composition synergistic effect of doing well in certain ratio range, the bactericidal effect of composition have had than single dose and have significantly improved, and have reduced simultaneously agricultural chemicals using dosage and cost, have reduced residually, have also alleviated the harmful effect to environment;
(2) mechanism of action of two kinds of active components is different among the present invention, and the application of composition can delay or overcome the resistance of pathogen, prolongs the service life of product;
(3) present composition is applicable to prevent and treat the cereal crop disease, also can be used in addition the control of other crop pest
(4) embodiment
Clearer in order to be purpose of the present invention, technical scheme and advantage, the present invention describes with following instantiation, but the present invention is not limited to these examples.
The present composition is take Boscalid and a kind of active component of triazole bactericidal agent that is selected from as active ingredient, find through the indoor bioassay test, antagonistic drug venereal disease evil had obvious synergistic function after both were composite, specifically was illustrated with following biologicall test example.
The example 1 of measuring in kind: Boscalid and the composite toxicity test to Rhizoctonia solani Kuhn of own azoles alcohol
1, subjects: rice sheath blight disease [Latin formal name used at school: Thanatephorus cucumeris (Frank) Donk.]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.5-2006 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.5-2006 ", according to Sun﹠amp; The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect.
5, results and analysis
The toxicity test that makes up Rhizoctonia solani Kuhn that is mixed of Boscalid, own azoles alcohol and the two different proportion thereof the results are shown in Table 1, in the table 1 " pyridine: oneself " be writing a Chinese character in simplified form of " Boscalid: own azoles alcohol ".
Table 1 Boscalid and own azoles alcohol are mixed to the toxicity test result of Rhizoctonia solani Kuhn
Indoor biometrics is the result show: Boscalid and own azoles alcohol are mixed with 1: 1,1: 3,1: 5,1: 7,3: 1,5: 1 and 7: 1 ratios, it shows addition or synergistic effect to Rhizoctonia solani Kuhn, and is wherein the most obvious with the ratio mixed synergies of 1: 1,1: 3,1: 5 and 3: 1.
The example 2 of measuring in kind: the composite toxicity test to the leaf rust of barley bacterium of Boscalid and Difenoconazole
1, subjects: leaf rust of barley bacterium [Latin formal name used at school: Puccinia hordei Otth.]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.15-2008 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.15-2008 ", according to Sun﹠amp; The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect.
5, results and analysis
The toxicity test that makes up the leaf rust of barley bacterium that is mixed of Boscalid, Difenoconazole and the two different proportion thereof the results are shown in Table 2, and " pyridine: benzene " is writing a Chinese character in simplified form of " Boscalid: Difenoconazole " in the table 2.
Table 2 Boscalid and Difenoconazole are mixed to the toxicity test result of leaf rust of barley bacterium
Indoor biometrics is the result show: Boscalid and Difenoconazole are mixed with 1: 1,1: 2,1: 5,1: 8,2: 1,5: 1 and 8: 1 ratios, it shows addition or synergistic effect to leaf rust of barley, and is wherein the most obvious with the ratio mixed synergies of 1: 1,1: 2,2: 1 and 5: 1.
The example 3 of measuring in kind: the composite toxicity test to triticale leaf rust bacterium of Boscalid and Flutriafol
1, subjects: triticale leaf rust bacterium [Latin formal name used at school: ccinia recondita=P.Recondita Roberge ex Desmaz.f.tritici]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.15-2008 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.15-2008 ", according to Sun﹠amp; The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect.
5, results and analysis
The toxicity test that makes up triticale leaf rust bacterium that is mixed of Boscalid, Flutriafol and the two different proportion thereof the results are shown in Table 3, and " pyridine: powder " is writing a Chinese character in simplified form of " Boscalid: Flutriafol " in the table 3.
Table 3 Boscalid and Flutriafol are mixed to the toxicity test result of triticale leaf rust bacterium
Indoor biometrics is the result show: Boscalid and Flutriafol are mixed with 1: 1,1: 2,1: 4,1: 8,2: 1,4: 1 and 8: 1 ratios, it shows addition or synergistic effect to triticale leaf rust bacterium, and is wherein the most obvious with the ratio mixed synergies of 1: 1,2: 1 and 2: 1.
The example 4 of measuring in kind: the composite toxicity test to fusarium graminearum of Boscalid and Cyproconazole
1, subjects: fusarium graminearum [Latin formal name used at school: FusaHum graminearum Sehw.]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", according to Sun﹠amp; The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect.
5, results and analysis
The toxicity test that makes up fusarium graminearum that is mixed of Boscalid, Cyproconazole and the two different proportion thereof the results are shown in Table 4, and " pyridine: ring " is writing a Chinese character in simplified form of " Boscalid: Cyproconazole " in the table 4.
Table 4 Boscalid and Cyproconazole are mixed to the toxicity test result of fusarium graminearum
Indoor biometrics is the result show: Boscalid and Cyproconazole are mixed with 1: 1,1: 3,1: 5,1: 7,3: 1,5: 1 and 7: 1 ratios, it shows addition or synergistic effect to fusarium graminearum, and is wherein the most obvious with the ratio mixed synergies of 1: 1,1: 3,1: 5 and 3: 1.
The example 5 of measuring in kind: the composite toxicity test to Exserohilum turcicum of Boscalid and epoxiconazole
1, subjects: the corn northern leaf blight [Latin formal name used at school: Exserohilum turcicum (Pass.)) Leonard et Suggs]
2, test method: with reference to " pesticide bioassay test rule NY/T 1464.15-2007 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1464.15-2007 ", according to Sun﹠amp; The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect.
5, results and analysis
The toxicity test that makes up Exserohilum turcicum that is mixed of Boscalid, epoxiconazole and the two different proportion thereof the results are shown in Table 5, and " pyridine: fluorine " is writing a Chinese character in simplified form of " Boscalid: epoxiconazole " in the table 5.
Table 5 Boscalid and epoxiconazole are mixed to the toxicity test result of Exserohilum turcicum
Indoor biometrics is the result show: Boscalid and epoxiconazole are mixed with 1: 1,1: 3,1: 5,1: 9,3: 1,5: 1 and 9: 1 ratios, it shows addition or synergistic effect to Exserohilum turcicum, and is wherein the most obvious with the ratio mixed synergies of 1: 1,1: 3,1: 5 and 3: 1.
The example 6 of measuring in kind: the composite toxicity test to the tomato late blight bacterium of Boscalid and Flusilazole
1, subjects: tomato late blight bacterium [Latin formal name used at school: Phytophthora infestans (Mont.) deBary.]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.Calculate mycelial growth inhibition rate (%) according to test data, obtain virulence regression equation formula, correlation coefficient (r), EC
50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", according to Sun﹠amp; The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80＜CTC＜120 are summation action, and CTC 〉=120 are synergistic effect.
5, results and analysis
The toxicity test that makes up the tomato late blight bacterium that is mixed of Boscalid, Flusilazole and the two different proportion thereof the results are shown in Table 5, and " pyridine: silicon " is writing a Chinese character in simplified form of " Boscalid: Flusilazole " in the table 5.
Table 5 Boscalid and Flusilazole are mixed to the toxicity test result of tomato late blight bacterium
Indoor biometrics is the result show: Boscalid and epoxiconazole are mixed with 1: 1,1: 3,1: 5,1: 9,3: 1,5: 1 and 9: 1 ratios, it shows addition or synergistic effect to the tomato late blight bacterium, and is wherein the most obvious with the ratio mixed synergies of 1: 1,1: 3,3: 1 and 5: 1.
The present composition can be with known auxiliary agent and assistant agent, with known method preparation and be fit to upper any one formulation used of agricultural, wherein reasonable formulation has missible oil, water dispersible granules, aqueous emulsion, suspending agent, the agent of kind clothing and wetting powder, and these known auxiliary agents, assistant agent have dispersant, diffusant, defoamer, wetting agent, disintegrant, filler etc.
Below describe with instantiation.
Embodiment 1:
Boscalid 10g, own azoles alcohol 30g, cyclohexanone 15g, phenethyl phenol polyethenoxy ether 3g, castor oil are added to 100g, be mixed to even liquid phase, make the present composition 40% missible oil.
Embodiment 2:
Boscalid 30g, Difenoconazole 10g, sodium methylene bis-naphthalene sulfonate 5g, sodium lignin sulfonate 8g, urea 3g, polyvinyl alcohol 1.5g, bentonite are added to 100g, through air-flow crushing, granulation, make the present composition 40% water dispersible granules.
Embodiment 3:
With Boscalid 10g, Flutriafol 20g, dodecyl sodium sulfate 5g, polyoxyethylene nonylphenol ether 3g, naphthalene sulfonic acid-formaldehyde condensation product 2g, xanthans 0.2g, propane diols 5g, suitable quantity of water, mixing is through wet grinding, homogenizing makes the present composition 30% suspending agent.
Embodiment 4:
Boscalid 20g, Cyproconazole 20g, dispersing agent NNO 4.5g, sodium lignin sulfonate 3g, white carbon 5g, kaolin are added to 100g, mix making the present composition 40% wetting powder through air-flow crushing.
Embodiment 5:
With Boscalid 5g, epoxiconazole 15g, pyrrolidones 20g, alkylaryl formaldehyde resin APEO 10g, alkylphenol polyoxyethylene phosphate 1g, ethylene glycol 4g and suitable quantity of water, the preparation oil phase, the preparation water, under high shear, add in the oil phase with the even aqueous phase of oil phase or with water, shear and make the present composition 20% aqueous emulsion.
Embodiment 6:
Boscalid 30g, epoxiconazole 45g, sodium alkyl sulfate 8g, alkyl naphthalene sulfonic acid formaldehyde condensation products 3g, glauber salt 3g, polyvinyl alcohol 1.5g, bentonite are added to 100g, through air-flow crushing, granulation, make the present composition 75% water dispersible granules.
Embodiment 7:
With Boscalid 30g, Flusilazole 10g, dodecyl sodium sulfonate calcium 5g, polyoxyethylene nonylphenol ether 3g, naphthalene sulfonic acid-formaldehyde condensation product 2g, xanthans 0.1g, ethylene glycol 5g, organic silicone 0.3g, suitable quantity of water, mixing is through wet grinding, homogenizing makes the present composition 40% suspending agent.
Claims (3)
1. a bactericidal composition is for the purposes of preventing and treating leaf rust of barley, and it is characterized in that: the active ingredient of described composition is comprised of Boscalid and Difenoconazole, and the weight ratio of the two is 1: 1,1: 2,1: 5,2: 1,5: 1 or 8: 1.
2. purposes according to claim 1, it is characterized in that: described combination dosage form is wetting powder, water dispersible granules, suspending agent, aqueous emulsion or missible oil.
3. purposes according to claim 2, it is characterized in that: the mass percent of the active ingredient of described bactericidal composition in formulation is 5～90%.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| GB2552695A (en) * | 2016-08-04 | 2018-02-07 | Rotam Agrochem Int Co Ltd | A synergistic fungicidal composition |
| WO2019123186A1 (en) * | 2017-12-20 | 2019-06-27 | Upl Ltd | Co-crystals of boscalid and triazoles |
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| CN103416425B (en) * | 2012-05-22 | 2016-02-17 | 陕西韦尔奇作物保护有限公司 | A kind of bactericidal composition containing tiadinil and triazole type |
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| CN106135225A (en) * | 2015-04-13 | 2016-11-23 | 南京华洲药业有限公司 | A kind of bactericidal composition containing Boscalid and Difenoconazole and application thereof |
| CN106135223A (en) * | 2015-04-13 | 2016-11-23 | 南京华洲药业有限公司 | A kind of containing Boscalid and the bactericidal composition of prothioconazoles and application |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| TW431861B (en) * | 1997-12-18 | 2001-05-01 | Basf Ag | Fungicidal mixtures based on amide compounds and azoles |
| CN100444731C (en) * | 2007-07-19 | 2008-12-24 | 安徽华星化工股份有限公司 | Germicide composition |
| US8349877B2 (en) * | 2007-09-26 | 2013-01-08 | Basf Se | Ternary fungicidal compositions comprising boscalid and chlorothalonil |
| CN101617671B (en) * | 2009-08-01 | 2012-05-02 | 深圳诺普信农化股份有限公司 | Combination sterilization composition |
| CN102334480A (en) * | 2010-07-23 | 2012-02-01 | 青岛奥迪斯生物科技有限公司 | Sterilizing composition containing boscalid and epoxiconazole |
| CN102217604B (en) * | 2011-04-16 | 2013-11-06 | 陕西汤普森生物科技有限公司 | Bactericidal composition containing boscalid and triazole compounds |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2552695A (en) * | 2016-08-04 | 2018-02-07 | Rotam Agrochem Int Co Ltd | A synergistic fungicidal composition |
| WO2019123186A1 (en) * | 2017-12-20 | 2019-06-27 | Upl Ltd | Co-crystals of boscalid and triazoles |
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