CN102550600B - Sterilization composition containing fluazinam and sulphur - Google Patents

Sterilization composition containing fluazinam and sulphur Download PDF

Info

Publication number
CN102550600B
CN102550600B CN2011104369469A CN201110436946A CN102550600B CN 102550600 B CN102550600 B CN 102550600B CN 2011104369469 A CN2011104369469 A CN 2011104369469A CN 201110436946 A CN201110436946 A CN 201110436946A CN 102550600 B CN102550600 B CN 102550600B
Authority
CN
China
Prior art keywords
sulphur
fluazinam
bactericidal composition
weight ratio
mixed
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN2011104369469A
Other languages
Chinese (zh)
Other versions
CN102550600A (en
Inventor
缪金凤
汪静莉
宋亚华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGYIN SULI CHEMICAL CO., LTD.
Original Assignee
JIANGYIN SULI CHEMICAL CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGYIN SULI CHEMICAL CO Ltd filed Critical JIANGYIN SULI CHEMICAL CO Ltd
Priority to CN2011104369469A priority Critical patent/CN102550600B/en
Publication of CN102550600A publication Critical patent/CN102550600A/en
Application granted granted Critical
Publication of CN102550600B publication Critical patent/CN102550600B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention relates to a sterilization composition containing fluazinam and sulphur and application thereof. The composition contains fluazinam and sulphur, wherein the weight ratio between the fluazinam and the sulphur is 1-40: 1-60. The composition can be applied to disease control of cereal crops, melons or vegetables. The composition is wide in application scope, good in effect, low in cost, small in residue and safe for human, livestock, the environment and the like.

Description

A kind of bactericidal composition that contains fluazinam and sulphur
(1) technical field
The present invention relates to a kind of bactericidal composition and uses thereof, relate in particular to a kind of bactericidal composition that contains fluazinam and sulphur, be mainly used in the control of cereal crop disease.
(2) background technology
Fluazinam (Fluazinam) is the phenyl amines wide-spectrum bactericide, and its mechanism of action is that mitochondrial oxidation phosphorus is extremely dissolved coupling agent, by the inhibition spore, gives sprouting, mycelia breakthrough, growth and sporulation and suppresses infecting of pathogen.The fluazinam applicable crops is wide in grape, apple, pears, oranges and tangerines, wheat, soybean, potato, tomato, cucumber, paddy rice, tea, lawn etc., to interlink spore genus, Botrytis, Phytophthora, Plasmopara, Sclerotinia and Venturia bacterium are very effective, as gray mold of cucumber, rot, downy mildew, anthracnose, powdery mildew, stem's pestilence of rotting, tomato late blight, apple scab, leaf spot, Pear black spot, rust, paddy rice slightly pain is sick, banded sclerotial blight, the oat hat lures disease, grape grey mould, downy mildew, citrus scab, gray mold, potato late blight, the lawn spot disease.Botrytis cinerea to anti-benzimidazole type and dicarboximide class biocide agent also has good result.Resistance of rainwater washing against, the lasting period is long.Except bactericidal activity, fluazinam also has certain acaricidal activity, engraves mite, kamisawa tetranychus etc. as citrus red mite, China pink.
Though fluazinam has above-mentioned advantage, because cost is higher, application is very limited at home at present.
The sulphur application is very extensive, in agricultural production, also can be used for the control of corps diseases, its mechanism of action is respiration inhibitor, acts on electron transfer process between germ helium reduction system cytochrome b and c, capture electronics, disturb normal " oxidation-reduction ".Have protection and therapeutic action, but there is no systemic activity.Can be used for wheat, beet, vegetables such as cucumber, eggplant etc., fruit tree such as apple, Lee, peach, grape, oranges and tangerines, the control of the crop pests such as matrimony vine.Controlling object is for preventing and treating wheat powdery mildew, rust, smut, head blight, cucurbits powdery mildew, and apple is bright, pears, peach scab, grape powdery mildew etc., except having bactericidal activity, sulphur also has acaricidal action, as be used to preventing and treating phyllocoptruta oleivora etc.
Absorption protective fungicide in the sulphur right and wrong, do not have result for the treatment of, not absorption in tool.
(3) summary of the invention
One of purpose of the present invention is to overcome above-mentioned deficiency, and a kind of applied widely, effective, cost is low, the lasting period is long bactericidal composition that contains fluazinam and sulphur is provided.
Two of purpose of the present invention is to provide a kind of purposes that contains the bactericidal composition of fluazinam and sulphur.
The object of the present invention is achieved like this:
A kind of bactericidal composition that contains fluazinam and sulphur, described composition contains fluazinam and sulphur, and the weight ratio of described fluazinam and sulphur is 1~40: 1~60.
The preferred weight ratio of described fluazinam and sulphur is 5~30: 10~45.
Described combination dosage form is any one formulation allowed on agricultural chemicals.Such as wetting powder, water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent etc.
Described fluazinam and the sulphur mass percent in above-mentioned formulation is 5~90%.
A kind of purposes that contains the bactericidal composition of fluazinam and sulphur, for the control as the cereal crop disease.
The present composition can be used for rice sheath blight disease, rice blast, false smut, paddy rice sheath maize ear rot, paddy rice glume blight, wheat powdery mildew, wheat rust, wheat scab, take-all, the corn northern leaf blight, maize head smut, the corn loose kernel smut, corn smut, barley leaf blotch, net blotch of barley, leaf rust of barley, the triticale rust, the Chinese sorghum stripe disease, the Chinese sorghum spot disease, Chinese sorghum smut, the millet downy mildew, millet blast, rice sheath blight disease, oat sheath maize ear rot, the Oat Red leaf disease, the Grain Production of Amaranthus fusarium wilt, Grain Production of Amaranthus anthracnose, broomcorn millet is checked the control of the cereal crop diseases such as head smut.Be preferred for the control of rice blast, net blotch of barley, jowar smut, wheat scab, corn smut.
Compared with prior art, the invention has the beneficial effects as follows:
(1) present composition synergistic effect of doing well in certain ratio range, the bactericidal effect of composition has had and has significantly improved than single dose, has reduced simultaneously agricultural chemicals using dosage and cost, has reduced residually, has also alleviated the harmful effect to environment;
(2) the mechanism of action difference of two kinds of active components in the present invention, the application of composition can delay or overcome the resistance of pathogen, extends the service life of product;
(3) present composition is good to the cereal crop diseases control, in addition, also can be used for the control of its corps diseases.
(4) embodiment
Clearer in order to be purpose of the present invention, technical scheme and advantage, the present invention describes with following instantiation, but the present invention is not limited to these examples.
The present composition be take fluazinam and sulphur and is active ingredient, finds through the indoor bioassay test, and after both were composite, antagonistic drug venereal disease evil had obvious synergistic function, specifically with following biologicall test example, was illustrated.
The example of measuring in kind: fluazinam and the sulfur compounded toxicity test to rice blast fungus
1, subjects: rice blast fungus [Latin formal name used at school: Phyricularia grisea (Cooke) Sacc.]
2, test method: with reference to " pesticide bioassay test rule NY/T1156.8-2007 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.According to test data, calculate mycelial growth inhibition rate (%), obtain virulence regression equation formula, correlation coefficient (r), EC 50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T1156.8-2007 ", according to Sun& The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80<CTC<120 are summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The toxicity test combined rice blast fungus that is mixed of fluazinam, sulphur and the two different proportion thereof the results are shown in Table 1, and in table 1, " fluorine: sulphur " is writing a Chinese character in simplified form of " fluazinam: sulphur ".
Table 1 fluazinam and sulphur are mixed to the toxicity test result of rice blast fungus
Figure BSA00000642517200041
The indoor biometrics result shows, fluazinam and sulphur are mixed with the ratio of 1: 11,1: 7,1: 3,1: 1,3: 1,7: 1 and 9: 1, it shows addition or synergistic effect to rice blast fungus, wherein better with the synergistic effect of 1: 5,1: 3 and 3: 1.
The example 2 of measuring in kind: fluazinam and the sulfur compounded toxicity test to the net blotch of barley bacterium
1, subjects: net blotch of barley bacterium [Latin formal name used at school: Pyrenophorateres Sacc.) Drechsler]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.According to test data, calculate mycelial growth inhibition rate (%), obtain virulence regression equation formula, correlation coefficient (r), EC 50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", according to Sun& The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80<CTC<120 are summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The toxicity test combined the net blotch of barley bacterium that is mixed of fluazinam, sulphur and the two different proportion thereof the results are shown in Table 2, and in table 2, " fluorine: sulphur " is writing a Chinese character in simplified form of " fluazinam: sulphur ".
Table 2 fluazinam and sulphur are mixed to the toxicity test result of net blotch of barley bacterium
Figure BSA00000642517200051
The indoor biometrics result shows: fluazinam and sulphur are mixed with 1: 1,1: 4,1: 8,1: 15,4: 1,8: 1 and 15: 1 ratios, it all shows synergistic effect to the net blotch of barley bacterium, wherein the most obvious with the ratio mixed synergies of 1: 1,1: 4,4: 1,8: 1 and 15: 1.Consider, fluazinam and sulphur are composite to net blotch of barley bacterium best results with 1: 4~15: 1.
The example 3 of measuring in kind: fluazinam and the sulfur compounded toxicity test to the jowar black tassel bacteria
1, subjects: jowar black tassel bacteria [Latin formal name used at school: Sorghum bicolor (L.) Moench]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.According to test data, calculate mycelial growth inhibition rate (%), obtain virulence regression equation formula, correlation coefficient (r), EC 50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", according to Sun& The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80<CTC<120 are summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The toxicity test combined the jowar black tassel bacteria that is mixed of fluazinam, sulphur and the two different proportion thereof the results are shown in Table 3, and in table 3, " fluorine: sulphur " is writing a Chinese character in simplified form of " fluazinam: sulphur ".
Table 3 fluazinam and sulphur are mixed to the toxicity test result of jowar black tassel bacteria
Figure BSA00000642517200061
The indoor biometrics result shows: fluazinam and sulphur are mixed with 1: 1,1: 4,1: 8,1: 12,4: 1,8: 1 and 12: 1 ratios, it shows addition or synergistic effect to the jowar black tassel bacteria, wherein the most obvious with the ratio mixed synergies of 1: 1,1: 4,1: 8,1: 15 and 4: 1.Consider, fluazinam and sulphur are composite better to highlighted black tassel bacteria effect with 1: 15~4: 1.
The example 4 of measuring in kind: fluazinam and the sulfur compounded toxicity test to fusarium graminearum
1, subjects: fusarium graminearum [Latin formal name used at school: FusaHum graminearum Sehw.]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.According to test data, calculate mycelial growth inhibition rate (%), obtain virulence regression equation formula, correlation coefficient (r), EC 50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", according to Sun& The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80<CTC<120 are summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The toxicity test combined fusarium graminearum that is mixed of fluazinam, sulphur and the two different proportion thereof the results are shown in Table 4, and in table 4, " fluorine: sulphur " is writing a Chinese character in simplified form of " fluazinam: sulphur ".
Table 4 fluazinam and sulphur are mixed to the toxicity test result of fusarium graminearum
Figure BSA00000642517200071
The indoor biometrics result shows: fluazinam and sulphur are mixed with 1: 1,1: 3,1: 5,1: 10,3: 1,5: 1 and 10: 1 ratios, it all shows synergistic effect to fusarium graminearum, wherein the most obvious with the ratio mixed synergies of 1: 1,1: 3,3: 1,5: 1 and 10: 1.Consider, fluazinam and sulphur are composite better to the fusarium graminearum effect with 1: 3~10: 1.
The example 5 of measuring in kind: fluazinam and the sulfur compounded toxicity test to Ustilago maydis
1, subjects: corn smut [Latin formal name used at school: Ustilago maydis (DC.) Corda]
2, test method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", adopt the pastille medium therapy.
3, data statistic analysis: analyze with the SAS6.12 statistical software.According to test data, calculate mycelial growth inhibition rate (%), obtain virulence regression equation formula, correlation coefficient (r), EC 50And co-toxicity coefficient.
4, evaluation method: with reference to " pesticide bioassay test rule NY/T 1156.2-2006 ", according to Sun& The co-toxicity coefficient method (CTC) of Johnson (1960) is estimated the synergistic effect of pharmacy mix, and namely CTC≤80 are antagonism, and 80<CTC<120 are summation action, and CTC >=120 are synergistic effect.
5, results and analysis
The toxicity test combined Ustilago maydis that is mixed of fluazinam, sulphur and the two different proportion thereof the results are shown in Table 5, and in table 5, " fluorine: sulphur " is writing a Chinese character in simplified form of " fluazinam: sulphur ".
Table 5 fluazinam and sulphur are mixed to the toxicity test result of Ustilago maydis
The indoor biometrics result shows: fluazinam and sulphur are mixed with 1: 1,1: 3,1: 5,1: 9,3: 1,5: 1 and 9: 1 ratios, it shows addition or synergistic effect to Ustilago maydis, wherein the most obvious with the ratio mixed synergies of 1: 1,1: 3,3: 1 and 5: 1.Consider, fluazinam and sulphur are composite better to the Ustilago maydis effect with 1: 3~5: 1.
The present composition can be with known auxiliary agent and assistant agent, be and be applicable to upper any one formulation used of agricultural with known method preparation, wherein reasonable formulation has missible oil, water dispersible granules, aqueous emulsion, suspending agent and wetting powder, and these known auxiliary agents, assistant agent have dispersant, diffusant, defoamer, wetting agent, disintegrant, filler etc.
Below with instantiation, describe.
Embodiment 1:
Fluazinam 10g, sulphur 30g, pyrrolidones 5g, agriculture breast 600# (styryl phenyl APEO) 4g, diesel oil are added to 100g, after solid material is pulverized respectively, then each component is mixed to even liquid phase, make the present composition 40% missible oil.
Embodiment 2:
By fluazinam 10g, sulphur 50g, sodium methylene bis-naphthalene sulfonate) 4.5g, sodium lignin sulfonate 3g, kaolin adds to 100g, and first solid constituent is separately pulverized, mixed, then, through air-flow crushing, granulation, make the present composition 60% water dispersible granules.
Embodiment 3:
By fluazinam 30g, sulphur 6g, dodecyl sodium sulfate 5g, polyoxyethylene nonylphenol ether 3g, dispersing agent NNO 2g, xanthans 0.2g propane diols 5g, suitable quantity of water, after first solid constituent separately being pulverized, is mixed, through wet grinding, homogenizing, make the present composition 36% suspending agent again.
Embodiment 4:
Fluazinam 20g, sulphur 20g, dispersing agent NNO 4.5g, sodium lignin sulfonate 3g, white carbon 5g, kaolin are added to 100g, mix through air-flow crushing, make the present composition 40% wetting powder.
Embodiment 5:
By fluazinam 5g, sulphur 5g, cyclohexanone 6g, alkylaryl formaldehyde resin APEO 10g, alkylphenol polyoxyethylene phosphate 1g, propane diols 3g and suitable quantity of water, first solid material is separately pulverized, mixed, prepare again oil phase, the preparation water, under high shear, to in the even water of oil phase or by water, add in oil phase, shear and make the present composition 10% aqueous emulsion.

Claims (8)

1. bactericidal composition that contains fluazinam and sulphur, it is characterized in that: the active component of described composition is fluazinam and sulphur, the weight ratio of described fluazinam and sulphur is 1~40: 1~60.
2. bactericidal composition according to claim 1, it is characterized in that: the weight ratio of described fluazinam and sulphur is 5~30: 10~45.
3. bactericidal composition according to claim 1 and 2, it is characterized in that: the weight ratio of described fluazinam and sulphur is 1: 11,1: 9,1: 7,1: 5,1: 3,1: 1,3: 1,5: 1,7: 1 or 9: 1.
4. according to the arbitrary described bactericidal composition of claim 1 or 2, it is characterized in that: described combination dosage form is any one formulation allowed on agricultural chemicals.
5. bactericidal composition according to claim 4, it is characterized in that: described combination dosage form is wetting powder, water dispersible granules, suspending agent, aqueous emulsion, missible oil or seed coat agent.
6. bactericidal composition according to claim 5, it is characterized in that: described fluazinam and the sulphur mass percent in formulation is 5~90%.
7. claim 1 or 2 bactericidal composition are for preventing and treating the purposes of cereal crop disease.
8. purposes according to claim 7, wherein the cereal crop disease is rice blast, net blotch of barley, jowar smut, wheat scab, corn smut.
CN2011104369469A 2011-12-23 2011-12-23 Sterilization composition containing fluazinam and sulphur Active CN102550600B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2011104369469A CN102550600B (en) 2011-12-23 2011-12-23 Sterilization composition containing fluazinam and sulphur

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2011104369469A CN102550600B (en) 2011-12-23 2011-12-23 Sterilization composition containing fluazinam and sulphur

Publications (2)

Publication Number Publication Date
CN102550600A CN102550600A (en) 2012-07-11
CN102550600B true CN102550600B (en) 2013-11-27

Family

ID=46398251

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2011104369469A Active CN102550600B (en) 2011-12-23 2011-12-23 Sterilization composition containing fluazinam and sulphur

Country Status (1)

Country Link
CN (1) CN102550600B (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104970042A (en) * 2015-07-21 2015-10-14 宁波三江益农作物保护有限公司 Acaricidal and antibacterial composition
CN112772655A (en) * 2021-01-11 2021-05-11 中国烟草总公司郑州烟草研究院 Nano sulfur compound medicament and application thereof
WO2023175613A1 (en) * 2022-03-14 2023-09-21 Adama Makhteshim Ltd. Fungicidal mixture composition comprising sulphur

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101984825A (en) * 2010-07-15 2011-03-16 江阴苏利科技有限公司 Fluazinam and fosetyl-aluminium-containing sterilization composition and application thereof
CN101984820A (en) * 2010-07-15 2011-03-16 江阴苏利科技有限公司 Fluazinam and propiconazol-containing sterilization composition and application thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101984825A (en) * 2010-07-15 2011-03-16 江阴苏利科技有限公司 Fluazinam and fosetyl-aluminium-containing sterilization composition and application thereof
CN101984820A (en) * 2010-07-15 2011-03-16 江阴苏利科技有限公司 Fluazinam and propiconazol-containing sterilization composition and application thereof

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
国内杀菌剂混剂概况及展望;朱伟刚等;《浙江化工》;20011231;第32卷(第2期);52-54 *
朱伟刚等.国内杀菌剂混剂概况及展望.《浙江化工》.2001,第32卷(第2期),52-54.

Also Published As

Publication number Publication date
CN102550600A (en) 2012-07-11

Similar Documents

Publication Publication Date Title
CN102428931B (en) Bacteriocidal composition containing Boscalid and triazole bactericide
CN102415392A (en) Germicide composition containing boscalid and cymoxanil
CN102550600B (en) Sterilization composition containing fluazinam and sulphur
CN102308831B (en) The bactericidal composition of a kind of pyraclostrobin-containing and dicarboxyl carboximide class
CN103719099A (en) Sterilization composite containing cyazofamid and tetraconazole
CN101984825A (en) Fluazinam and fosetyl-aluminium-containing sterilization composition and application thereof
CN101984817B (en) Bactericidal composition containing azoxystrobin and fluazinam and use thereof
CN101984821B (en) Bactericidal composition containing fluazinam and tebuconazole and application thereof
CN102428955B (en) Bactericidal composition containing boscalid and fosetyl-aluminium
CN108651473A (en) The effectively fertilizer granules of prevention soil-borne disease and plant disease
CN102550563B (en) Sterilization composition comprising boscalid and flutolanil
CN110495456A (en) A kind of bactericidal composition
CN102524256A (en) Pesticide composition containing flutolanil and chlorothalonil
CN103385244A (en) Bactericidal composition comprising fluxapyroxad and thiocarbamate
CN101984820B (en) Fluazinam and propiconazol-containing sterilization composition and application thereof
CN101984824A (en) Sterilizing composition containing azoxystrobin and zineb and application thereof
CN101984816A (en) Bactericidal composition containing azoxystrobin and flutolanil and use thereof
CN103719090A (en) Sterilization composition containing cyazofamid and cyprosulfamide as well as use of sterilization composition
CN104621157B (en) A kind of bactericidal composition containing cyprodinil and iprovalicarb and application thereof
CN102524282B (en) Bactericidal composition containing prochloraz and flutolanil
CN102349522B (en) Synergy sterilizing composition containing tetraconazole and tricyclazole
CN103563934B (en) Bactericidal composition containing thifluzamide and amobam and application thereof
CN103719100A (en) Sterilization composite containing cyazofamid and flutriafol
CN108244115A (en) A kind of propargite and the acaricidal complex composition of vinyl cyanide
CN103719091A (en) Sterilization composite containing cyazofamid and fludioxonil

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: JIANGYIN SULI CHEMICALS CO., LTD.

Free format text: FORMER OWNER: JIANGYIN SULI FINE CHEMICAL CO., LTD.

Effective date: 20130313

C41 Transfer of patent application or patent right or utility model
TA01 Transfer of patent application right

Effective date of registration: 20130313

Address after: 214444 lubrication Road 7, Li Town, Jiangsu, Jiangyin

Applicant after: JIANGYIN SULI CHEMICAL CO., LTD.

Address before: 214444 lubrication Road 7, Li Town, Jiangsu, Jiangyin

Applicant before: Jingyin Suli Chemical Co., Ltd.

C14 Grant of patent or utility model
GR01 Patent grant