CN102421766B - 提高铼助催化的环氧化催化剂的效率的方法以及使用它们的环氧化方法 - Google Patents

提高铼助催化的环氧化催化剂的效率的方法以及使用它们的环氧化方法 Download PDF

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CN102421766B
CN102421766B CN201080017690.1A CN201080017690A CN102421766B CN 102421766 B CN102421766 B CN 102421766B CN 201080017690 A CN201080017690 A CN 201080017690A CN 102421766 B CN102421766 B CN 102421766B
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catalyst
temperature
epoxidation
feed
concentration
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CN102421766A (zh
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刘正宇
张丽萍
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Dow Technology Investments LLC
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Dow Technology Investments LLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D301/00—Preparation of oxiranes
    • C07D301/02—Synthesis of the oxirane ring
    • C07D301/03—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds
    • C07D301/04—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen
    • C07D301/08—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase
    • C07D301/10—Synthesis of the oxirane ring by oxidation of unsaturated compounds, or of mixtures of unsaturated and saturated compounds with air or molecular oxygen in the gaseous phase with catalysts containing silver or gold
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/40—Special temperature treatment, i.e. other than just for template removal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
    • B01J2523/70—Constitutive chemical elements of heterogeneous catalysts of Group VII (VIIB) of the Periodic Table
    • B01J2523/74—Rhenium

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Epoxy Compounds (AREA)
  • Catalysts (AREA)
CN201080017690.1A 2009-04-21 2010-04-05 提高铼助催化的环氧化催化剂的效率的方法以及使用它们的环氧化方法 Active CN102421766B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US17120709P 2009-04-21 2009-04-21
US61/171,207 2009-04-21
PCT/US2010/029948 WO2010123675A1 (en) 2009-04-21 2010-04-05 Methods for enhancing the efficiency of rhenium-promoted epoxidation catalysts and epoxidation methods utilizing these

Publications (2)

Publication Number Publication Date
CN102421766A CN102421766A (zh) 2012-04-18
CN102421766B true CN102421766B (zh) 2015-03-25

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CN201080017690.1A Active CN102421766B (zh) 2009-04-21 2010-04-05 提高铼助催化的环氧化催化剂的效率的方法以及使用它们的环氧化方法

Country Status (9)

Country Link
US (1) US8084632B2 (cg-RX-API-DMAC7.html)
EP (1) EP2421839B1 (cg-RX-API-DMAC7.html)
JP (1) JP5584284B2 (cg-RX-API-DMAC7.html)
KR (1) KR101704079B1 (cg-RX-API-DMAC7.html)
CN (1) CN102421766B (cg-RX-API-DMAC7.html)
CA (1) CA2759390C (cg-RX-API-DMAC7.html)
SG (1) SG175762A1 (cg-RX-API-DMAC7.html)
TW (2) TWI625165B (cg-RX-API-DMAC7.html)
WO (1) WO2010123675A1 (cg-RX-API-DMAC7.html)

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CN102458651B (zh) * 2009-04-21 2015-06-10 陶氏技术投资有限公司 铼助催化的环氧化催化剂及其制造和使用方法
US8742147B2 (en) 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8742146B2 (en) * 2010-12-08 2014-06-03 Shell Oil Company Process for improving the selectivity of an EO catalyst
US8884037B2 (en) 2010-12-10 2014-11-11 Dow Technology Investments Llc Method of reducing the value of an alkylene oxide production parameter in a process of making an alkylene oxide using a high efficiency catalyst
WO2012082389A1 (en) 2010-12-15 2012-06-21 Dow Technology Investments Llc Method of starting-up a process of producing an alkylene oxide using a high-efficiency catalyst
RU2606504C2 (ru) * 2011-04-29 2017-01-10 Шелл Интернэшнл Рисерч Маатсхаппий Б.В. Способ повышения селективности катализатора эпоксидирования
CN108707125A (zh) 2011-10-18 2018-10-26 哈桑·伊萨·阿拉哈迈迪 具有添加缓和剂的环氧化方法
CN104080778B (zh) 2011-12-09 2016-08-24 陶氏技术投资有限责任公司 在利用高效催化剂制造环氧烷的工艺中保持环氧烷生产参数值的方法
KR102155068B1 (ko) 2012-12-31 2020-09-11 사이언티픽 디자인 컴파니 인코포레이티드 고 선택성 산화에틸렌 촉매를 위한 스타트-업 공정
KR102155073B1 (ko) * 2013-01-11 2020-09-11 사이언티픽 디자인 컴파니 인코포레이티드 후-컨디셔닝 단계를 이용하는 에폭시화 공정
CN108025978B (zh) 2015-06-02 2021-08-27 科学设计有限公司 具有增强的孔结构的多孔体
CN106311234B (zh) * 2015-07-02 2018-11-30 中国石油化工股份有限公司 复合型银催化剂的制备方法、该催化剂及其应用
US10449520B2 (en) 2017-05-15 2019-10-22 Scientific Design Company, Inc. Porous bodies with enhanced crush strength
CN110357836B (zh) * 2018-03-26 2021-04-13 中国石油化工股份有限公司 一种环氧乙烷生产方法

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Publication number Publication date
US20100267973A1 (en) 2010-10-21
JP5584284B2 (ja) 2014-09-03
TW201601837A (zh) 2016-01-16
JP2012524656A (ja) 2012-10-18
KR101704079B1 (ko) 2017-02-07
WO2010123675A1 (en) 2010-10-28
TWI625165B (zh) 2018-06-01
EP2421839A1 (en) 2012-02-29
KR20120006551A (ko) 2012-01-18
CN102421766A (zh) 2012-04-18
CA2759390C (en) 2017-08-22
TWI504440B (zh) 2015-10-21
EP2421839B1 (en) 2014-05-07
TW201041652A (en) 2010-12-01
SG175762A1 (en) 2011-12-29
US8084632B2 (en) 2011-12-27
CA2759390A1 (en) 2010-10-28

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