CN102224821A - Bactericide composition containing effective Epoxiconazole ingredients - Google Patents
Bactericide composition containing effective Epoxiconazole ingredients Download PDFInfo
- Publication number
- CN102224821A CN102224821A CN2011101061973A CN201110106197A CN102224821A CN 102224821 A CN102224821 A CN 102224821A CN 2011101061973 A CN2011101061973 A CN 2011101061973A CN 201110106197 A CN201110106197 A CN 201110106197A CN 102224821 A CN102224821 A CN 102224821A
- Authority
- CN
- China
- Prior art keywords
- ring azoles
- fluorine ring
- bactericide
- active ingredient
- polyoxin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 28
- 239000003899 bactericide agent Substances 0.000 title abstract description 25
- 230000000844 anti-bacterial effect Effects 0.000 title abstract description 24
- ZMYFCFLJBGAQRS-IRXDYDNUSA-N (2R,3S)-epoxiconazole Chemical compound C1=CC(F)=CC=C1[C@@]1(CN2N=CN=C2)[C@H](C=2C(=CC=CC=2)Cl)O1 ZMYFCFLJBGAQRS-IRXDYDNUSA-N 0.000 title abstract 6
- 239000005767 Epoxiconazole Substances 0.000 title abstract 6
- 239000004615 ingredient Substances 0.000 title abstract 3
- 229930182764 Polyoxin Natural products 0.000 claims abstract description 23
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 claims abstract description 23
- 239000000839 emulsion Substances 0.000 claims abstract description 6
- -1 fluorine ring azoles Chemical class 0.000 claims description 75
- 239000004480 active ingredient Substances 0.000 claims description 25
- 239000000843 powder Substances 0.000 claims description 15
- 238000009736 wetting Methods 0.000 claims description 15
- 230000003641 microbiacidal effect Effects 0.000 claims description 14
- 229940124561 microbicide Drugs 0.000 claims description 14
- 239000002855 microbicide agent Substances 0.000 claims description 14
- 239000000375 suspending agent Substances 0.000 claims description 3
- 238000009825 accumulation Methods 0.000 claims description 2
- 239000004562 water dispersible granule Substances 0.000 claims description 2
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 abstract description 29
- 239000003795 chemical substances by application Substances 0.000 abstract description 24
- 238000000034 method Methods 0.000 abstract description 18
- 241000221785 Erysiphales Species 0.000 abstract description 17
- 230000000694 effects Effects 0.000 abstract description 17
- 239000005842 Thiophanate-methyl Substances 0.000 abstract description 16
- TWFZGCMQGLPBSX-UHFFFAOYSA-N Carbendazim Natural products C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 abstract description 15
- 239000005802 Mancozeb Substances 0.000 abstract description 15
- 239000011717 all-trans-retinol Substances 0.000 abstract description 15
- 235000019169 all-trans-retinol Nutrition 0.000 abstract description 15
- 239000006013 carbendazim Substances 0.000 abstract description 15
- QGHREAKMXXNCOA-UHFFFAOYSA-N thiophanate-methyl Chemical group COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC QGHREAKMXXNCOA-UHFFFAOYSA-N 0.000 abstract description 15
- JNPZQRQPIHJYNM-UHFFFAOYSA-N carbendazim Chemical compound C1=C[CH]C2=NC(NC(=O)OC)=NC2=C1 JNPZQRQPIHJYNM-UHFFFAOYSA-N 0.000 abstract description 14
- 241000918585 Pythium aphanidermatum Species 0.000 abstract description 13
- 239000012895 dilution Substances 0.000 abstract description 7
- 238000010790 dilution Methods 0.000 abstract description 7
- 230000002265 prevention Effects 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000003814 drug Substances 0.000 description 21
- 230000003449 preventive effect Effects 0.000 description 16
- AMHNZOICSMBGDH-UHFFFAOYSA-L zineb Chemical compound [Zn+2].[S-]C(=S)NCCNC([S-])=S AMHNZOICSMBGDH-UHFFFAOYSA-L 0.000 description 14
- 201000010099 disease Diseases 0.000 description 6
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 6
- 238000005507 spraying Methods 0.000 description 6
- 238000013016 damping Methods 0.000 description 5
- 230000000855 fungicidal effect Effects 0.000 description 5
- 239000000417 fungicide Substances 0.000 description 5
- 239000005995 Aluminium silicate Substances 0.000 description 4
- 235000012211 aluminium silicate Nutrition 0.000 description 4
- YDEXUEFDPVHGHE-GGMCWBHBSA-L disodium;(2r)-3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Na+].[Na+].COC1=CC=CC(C[C@H](CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O YDEXUEFDPVHGHE-GGMCWBHBSA-L 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical group O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 4
- 230000002195 synergetic effect Effects 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical compound C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 235000013339 cereals Nutrition 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 231100000053 low toxicity Toxicity 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009885 systemic effect Effects 0.000 description 2
- 230000001225 therapeutic effect Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 206010059866 Drug resistance Diseases 0.000 description 1
- 241000238631 Hexapoda Species 0.000 description 1
- 206010034133 Pathogen resistance Diseases 0.000 description 1
- 241000233679 Peronosporaceae Species 0.000 description 1
- 241001454747 Streptomyces aureus Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000008485 antagonism Effects 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 230000004992 fission Effects 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 231100000636 lethal dose Toxicity 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- 230000011278 mitosis Effects 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012216 screening Methods 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 230000001018 virulence Effects 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a bactericide composition containing the effective Epoxiconazole ingredients, which comprises the effective ingredients, namely Epoxiconazole A and a bactericide B, wherein the bactericide B comprises one or two or more of thiophanatemethyl, carbendazim, mancozeb, zineb, trioneb and polyoxin; and the Epoxiconazole A and the bactericide B are mixed based on the mass ratio of (50-1): (1-50). The invention is characterized in that the bactericide composition is a binary bactericide composition, and can prevent and treat damping off and powdery mildew which are difficult to prevent and treat in the agriculture, the field prevention and treatment effects on the damping off and the powdery mildew are respectively 90.4% and 95.2% 72 hours after the bactericide composition is diluted according to a dilution factor (2000-3000) and sprayed, and the field prevention and treatment effects on the damping off and powdery mildew are respectively 30.8% and 21.2% 72 hours after the bactericide composition is prepared into an EW (emulsion in water) by adopting 45% Epoxiconazole single agent based on the same method. It is not difficult to see that the control efficiency of the blended composition is 3-4 times better compared with that of any of Epoxiconazole A and bactericide B.
Description
The application is for dividing an application, and original application is Zhang Shaowu application " a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles ", and the application number of original application is: 200710018860.8, and original application day is 2007.10.15.
Technical field
The present invention relates to the agriculture chemicals fungicide composition, being specifically related to is a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles.
Technical background
Existing agriculture chemicals fungicide is to form with single agent kind and additive combination mostly, and there is the relatively poor defective of prevention and elimination of disease and pests effect in this single agent kind, narrates the shortcoming of single agent kind below respectively:
Thiophanate-methyl: being a kind of common bactericide, belonging to benzimidazole, is a kind of broad spectrum activity systemic fungicide, can prevent and treat the various crop disease.Have interior suction, prevention and therapeutic action.In addition, prevent and treat disease drug resistance in recent years separately and strengthen, cause preventive effect to descend.
Carbendazim: also being a kind of common bactericide, belonging to benzimidazole, is a kind of high-efficiency low-toxicity, systemic fungicide.Its main mechanism is to disturb the formation of spindle in the mitosis of bacterium, thereby influences the fission process of bacterium.Single use preventive effect is not obvious.
Mancozeb: be a kind of common protectiveness that has than wide spectrum, can effectively prevent and treat damping off that various crop causes and powdery mildew etc.
Zineb: belong to the broad spectrum protection organosulfureous fungicide, can effectively prevent and treat damping off, powdery mildew and anthracnose that various crop such as vegetables, peanut, wheat class cause.
Carbatene: be a kind of non-internal-absorting bactericide, be used for leaf surface treatment and play the effect of protection sterilizing disease-preventing.Important germ such as ring spot, the downy mildew etc. of control on the agricultural.Facts have proved that this composition not only control efficiency is good, and free from environmental pollution.
Polyoxin: be the metabolite that streptomyces aureus produces, belong to the broad-spectrum antibiotics series bactericidal agent, have interior preferably absorption.Be a kind of efficient, the safety pesticide of low toxicity non-environmental-pollution, owing to belong to biologic product, and simple the use, preventive effect is slow.
Damping off and powdery mildew are diseases more common on the various crop, and especially in zone, the north, the annual generation usually caused the crushing disaster of crop.In some serious zone, crop strengthens conventional pesticide composition resistance, use separately to be difficult to control, and effect is very poor, has a strong impact on the good harvest of grain.
Go up the germ that produces resistance for control agricultural, a kind of way is to release the new component that new and existing kind do not have cross resistance.But the development cost height of new active ingredient, the construction cycle is long, and all produces the speed of resistance forever less than insect.
Summary of the invention
The purpose of this invention is to provide a kind of composition of different cultivars that adopts and be mixed, produce synergistic effect, make field control effect significantly be better than a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles of two kinds of single agent.
In order to prevent and treat more refractory damping off and powdery mildew on the agricultural, technical solution of the present invention is achieved in that a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles, its outstanding substantive distinguishing features and obvious improvement is to be made up of the fluorine ring azoles A and the bactericide B of active ingredient, its described bactericide B component is meant in thiophanate-methyl, carbendazim, mancozeb, zineb, Carbatene or the polyoxin any one or two or more combination, and fluorine ring azoles A and bactericide B press mass ratio 50～1: between 1～50.Carried out mutual composite efficiency raising scheme with fluorine ring azoles A and different types of B composition, damping off on the various crop and powdery mildew etc. have been carried out Toxicity Determination and used the prescription screening with different proportionings.Be that any one is combined as active ingredient with fluorine ring azoles A and B thiophanate-methyl, carbendazim, mancozeb, zineb, Carbatene or polyoxin, can prevent and treat agricultural and go up the damping off of difficult control and powdery mildew etc.
Fluorine ring azoles: be seldom common in the market a kind of bactericide, a series of cereal crop disease and damping off, powdery mildew etc. are had good preventive and therapeutic effect.It not only has good protection, treats and roots out activity, and inhales and stronger residual activity in having.
Test medicine provides for former pharmaceutical factory man.This experiment adopts growth rate method to carry out, and be mixed into contrast with equivalent aqua sterilisa and medium, calculate virulence equation and lethal concentration of 50 LC50 with method of least squares, calculate the toxicity index of medicament and the co-toxicity coefficient of using with (CTC method) according to the abundant method of Sun Yun, two kinds of different proportioning synergies of medicament are antagonism than it (SR) SR＜0.5,0.5≤SR≤1.5 are summation action, SR＞1.5 are synergistic effect.Therefore, identical for mechanism of action, the composition of different cultivars is mixed, and is a kind of selection of the best.If reasonable proportioning is arranged, usually can produce synergistic effect.Make field control effect significantly be better than the effect of two kinds of single agent.Show the result of 1+1＞2.Its beneficial effect sees Table 1, table 2.
Table 1 different blended pairing damping off experimental data
| Handle | ?LC50(PPM) | Co-toxicity coefficient |
| Fluorine ring azoles 10+ thiophanate-methyl 35 | ?13.82 | 513.8 |
| Fluorine ring azoles 30+ thiophanate-methyl 30 | ?15.01 | 481.5 |
| Fluorine ring azoles 40+ carbendazim 10 | ?12.55 | 550.8 |
| Fluorine ring azoles 10+ carbendazim 35 | ?11.55 | 598.5 |
| Fluorine ring azoles 8+ mancozeb 40 | ?12.82 | 470.2 |
| Fluorine ring azoles 45+ mancozeb 5 | ?14.01 | 509.1 |
| Fluorine ring azoles 10+ zineb 40 | ?12.82 | 670.2 |
| Fluorine ring azoles 30+ zineb 10 | ?15.01 | 549.1 |
| Fluorine ring azoles 40+ Carbatene 15 | ?13.82 | 570.2 |
| Fluorine ring azoles 15+ Carbatene 30 | ?11.01 | 619.1 |
| Fluorine ring azoles 30+ polyoxin 20 | ?14.82 | 446.2 |
| Fluorine ring azoles 15+ polyoxin 35 | ?15.01 | 559.1 |
| Fluorine ring azoles | ?35.42 | ---- |
| Thiophanate-methyl | ?55.44 | ---- |
| Carbendazim | ?49.20 | ---- |
| Mancozeb | ?45.14 | ---- |
| Zineb | 55.60 | ---- |
| Carbatene | 60.70 | ---- |
| Polyoxin | 50.76 | ---- |
Table 2 different blended pairing powdery mildew experimental data
| Handle | ?LC50(PPM) | Co-toxicity coefficient |
| Fluorine ring azoles 10+ thiophanate-methyl 45 | ?11.83 | 693.8 |
| Fluorine ring azoles 30+ thiophanate-methyl 30 | ?14.01 | 500.9 |
| Fluorine ring azoles 30+ carbendazim 15 | ?11.82 | 567.4 |
| Fluorine ring azoles 15+ carbendazim 15 | ?14.01 | 609.5 |
| Fluorine ring azoles 25+ mancozeb 30 | ?12.22 | 570.2 |
| Fluorine ring azoles 10+ mancozeb 45 | ?15.01 | 509.1 |
| Fluorine ring azoles 10+ zineb 45 | ?12.82 | 590.2 |
| Fluorine ring azoles 40+ zineb 10 | ?14.01 | 649.1 |
| Fluorine ring azoles 10+ Carbatene 15 | ?12.82 | 670.2 |
| Fluorine ring azoles 35+ Carbatene 8 | ?15.01 | 550.1 |
| Fluorine ring azoles 10+ polyoxin 45 | ?13.82 | 775.2 |
| Fluorine ring azoles 25+ polyoxin 35 | ?15.01 | 559.1 |
| Fluorine ring azoles | ?45.24 | ---- |
| Thiophanate-methyl | ?50.24 | ---- |
| Carbatene | ?63.63 | ---- |
| Polyoxin | ?50.54 | ---- |
| Carbatene | ?68.20 | ---- |
| Polyoxin | ?50.47 | ---- |
| Carbatene | 65.98 | ---- |
As can be seen from the table, wherein any one combination of fluorine ring azoles and thiophanate-methyl, carbendazim, mancozeb, zineb, Carbatene or polyoxin.Damping off, the powdery mildew of difficult control on the agricultural there is clearly synergistic effect.
Specific embodiments
Following examples specify content of the present invention, but the present invention is not limited to following examples.Each component percentage composition or proportioning are all in weight ratio among the embodiment.
Fluorine ring azoles A and bactericide B by active ingredient form, its described bactericide B component is meant in thiophanate-methyl, carbendazim, mancozeb, zineb, Carbatene or the polyoxin any one or two or more combination, and fluorine ring azoles A and bactericide B press mass ratio 50～1: between 1～50.
Described a kind of microbicide compositions that contains the active ingredient of Carbatene, described by the fluorine ring azoles A of quality than active ingredient: the part by weight of bactericide B is 45: 5～10: 40.
Described by the fluorine ring azoles A of quality than active ingredient: the part by weight of bactericide B is 40: 10～15: 35.
Described by the fluorine ring azoles A of quality than active ingredient: the part by weight of bactericide B is 35: 15～20: 30.
Described a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles can be made different application forms, and its application forms can be suspending agent or aqueous dispersion pulvis or aqueous emulsion or wetting powder.
Described a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles, any one accumulation content by weight percentage is between 1～99% in thiophanate-methyl, carbendazim, mancozeb, zineb, Carbatene or the polyoxin among fluorine ring azoles A and the bactericide B.
Embodiment 1: fluorine ring azoles+thiophanate-methyl
Press fluorine ring azoles weight proportion (unless stated otherwise, all refer to percentage by weight) 10%, thiophanate-methyl 10%, white carbon 5%, sodium lignin sulfonate 10%, filler is a kaolin, make water dispersible granules, this prescription is by 1000～1500 times of dilution sprayings, and 72 hours field control effect damping offs are 90.4% behind the medicine, powdery mildew is 92.8%; If adopt 10% fluorine ring azoles list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 30.4%, 23.8% behind the medicine; If adopt 10% thiophanate-methyl list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 38.4%, 33.8% behind the medicine.Be mixed and single agent use comparison by above-mentioned, be understood that its gained control efficiency differs 2～3 times.
Embodiment 2: fluorine ring azoles+carbendazim
Press fluorine ring azoles weight proportion (unless stated otherwise, all referring to percentage by weight) 25%, carbendazim 30%, white carbon 4%, sodium lignin sulfonate 5%, filler is a kaolin, makes wetting powder.This prescription is by 1000～2000 times of dilution sprayings, and 72 hours field control effect damping offs are 93.6% behind the medicine, powdery mildew is 92.8%; If adopt 25% fluorine ring azoles list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 30.4%, 23.8% behind the medicine; If adopt 30% carbendazim list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 18.4%, 23.8% behind the medicine, are mixed and single agent is used relatively by above-mentioned, are understood that its gained control efficiency differs 3～4 times.
Embodiment 3: fluorine ring azoles+mancozeb
Press fluorine ring azoles weight proportion (unless stated otherwise, all referring to percentage by weight) 45%, mancozeb 10%, xanthans 0.2%, glycerine 6%, agricultural newborn 601# and be 3%, water is that surplus is made suspending agent.This prescription is by 1000～2500 times of dilution sprayings, and 72 hours field control effect damping offs are 91.7% behind the medicine; If adopt 45% fluorine ring azoles list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 19.3%, 20.6% behind the medicine; If adopt 10% mancozeb list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 10.3%, 29.8% behind the medicine, are mixed and single agent is used relatively by above-mentioned, are understood that its gained control efficiency differs 3～8 times.
Embodiment 4: fluorine ring azoles+zineb
Press fluorine ring azoles weight proportion (unless stated otherwise, all referring to percentage by weight) 15%, zineb 20%, sodium lignin sulfonate 7%, 10%, filler is a kaolin, makes wetting powder.This prescription is by 1000～1500 times of dilution sprayings, and 72 hours field control effect damping offs are 93.2% behind the medicine, powdery mildew is 94.8%; If adopt 15% fluorine ring azoles list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 23.6%, 32.8% behind the medicine; If adopt 20% zineb list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 14.2%, 39.8% behind the medicine, are mixed and single agent is used relatively by above-mentioned, are understood that its gained control efficiency differs 2～3 times.
Embodiment 5: fluorine ring azoles+Carbatene
Press fluorine ring azoles weight proportion (unless stated otherwise, all referring to percentage by weight) 40%, Carbatene 20%, sodium lignin sulfonate 5%, white carbon 15%, filler is a kaolin, makes wetting powder.This prescription is by 2000～2500 times of dilution sprayings, and 72 hours field control effect damping offs are 91.7% behind the medicine, powdery mildew is 93.7%; If adopt 40% fluorine ring azoles list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 20.8%, 29.2% behind the medicine; If adopt 20% Carbatene list agent to be made into wetting powder according to using with quadrat method, 72 hours preventive effects are respectively 10.2%, 23.4% behind the medicine, are mixed and single agent is used relatively by above-mentioned, are understood that its gained control efficiency differs 4～8 times.
Embodiment 6: fluorine ring azoles+polyoxin
Press fluorine ring azoles weight proportion (unless stated otherwise, all referring to percentage by weight) 45%, polyoxin 10%, agricultural newborn 500#10%, agricultural newborn 601#8%, dimethylbenzene is 10%, and water is surplus, makes aqueous emulsion.This prescription is by 2000～3000 times of dilution sprayings, and 72 hours field control effects are that damping off is 90.4% behind the medicine, and powdery mildew is 95.2%; If adopt 45% fluorine ring azoles list agent to be made into aqueous emulsion according to using with quadrat method, 72 hours preventive effects are respectively 30.8%, 21.2% behind the medicine; If adopt 10% polyoxin list agent to be made into aqueous emulsion according to using with quadrat method, 72 hours preventive effects are respectively 23.1%, 24.3% behind the medicine, are mixed and single agent is used relatively by above-mentioned, are understood that its gained control efficiency differs 3～4 times.
Claims (6)
1. a microbicide compositions that contains the active ingredient of fluorine ring azoles is characterized in that active ingredient comprises fluorine ring azoles and polyoxin, and fluorine ring azoles and polyoxin are pressed mass ratio 50～1: between 1～50.
2. a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles according to claim 1, it is characterized in that the fluorine ring azoles of described active ingredient by mass percentage: the weight percent of polyoxin is 45～5: 10～40.
3. a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles according to claim 1, it is characterized in that the fluorine ring azoles of described active ingredient by mass percentage: the weight percent of polyoxin is 40～10: 15～35.
4. a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles according to claim 1, it is characterized in that the fluorine ring azoles of described active ingredient by mass percentage: the weight percent of polyoxin is 35～15: 20～30.
5. a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles according to claim 1 is characterized in that making different application forms, and its application forms can be suspending agent or water dispersible granules or aqueous emulsion or wetting powder.
6. a kind of microbicide compositions that contains the active ingredient of fluorine ring azoles according to claim 1 is characterized in that fluorine ring azoles and polyoxin; Accumulation content by weight percentage is between 1% to 99%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110106197 CN102224821B (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing effective Epoxiconazole ingredients |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201110106197 CN102224821B (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing effective Epoxiconazole ingredients |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2007100188608A Division CN101171919B (en) | 2007-10-15 | 2007-10-15 | Bactericide agent composition containing active ingredient of epoxiconazole |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102224821A true CN102224821A (en) | 2011-10-26 |
| CN102224821B CN102224821B (en) | 2013-10-09 |
Family
ID=44805862
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201110106197 Expired - Fee Related CN102224821B (en) | 2007-10-15 | 2007-10-15 | Bactericide composition containing effective Epoxiconazole ingredients |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN102224821B (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1023832B1 (en) * | 1999-01-29 | 2004-11-17 | Basf Aktiengesellschaft | Aqueous suspension concentrate |
| CN1874680A (en) * | 2003-10-31 | 2006-12-06 | 石原产业株式会社 | Bactericide composition and method for controlling plant disease |
-
2007
- 2007-10-15 CN CN 201110106197 patent/CN102224821B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1023832B1 (en) * | 1999-01-29 | 2004-11-17 | Basf Aktiengesellschaft | Aqueous suspension concentrate |
| CN1874680A (en) * | 2003-10-31 | 2006-12-06 | 石原产业株式会社 | Bactericide composition and method for controlling plant disease |
Non-Patent Citations (1)
| Title |
|---|
| 代玉华等: "红塔区草莓主要病虫害防治技术探讨", 《云南农业科技》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102224821B (en) | 2013-10-09 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101171919B (en) | Bactericide agent composition containing active ingredient of epoxiconazole | |
| CN101171921B (en) | Bactericide agent composition containing active ingredient of metiram | |
| CN104322558A (en) | Sterilization composition and applications thereof | |
| CN102860307B (en) | Compound pesticide containing validamycin and cyprosulfamide and application of compound pesticide | |
| CN101755837B (en) | Fungicidal composition containing bromothalonil and prochloraz manganese | |
| CN101194620B (en) | Bactericide agent composition containing tebuconazole | |
| CN102224821B (en) | Bactericide composition containing effective Epoxiconazole ingredients | |
| CN106135252A (en) | A kind of containing Boscalid and the bactericidal composition of prochloraz-manganese chloride complex and application | |
| CN102204553A (en) | Antibacterial composition containing epoxiconazole active component | |
| CN102204558A (en) | Bactericide composite containing epoxiconazole used as active ingredient | |
| CN106577680A (en) | Bactericide and application thereof | |
| CN102550563B (en) | Sterilization composition comprising boscalid and flutolanil | |
| CN107396926A (en) | It is a kind of to increase composition containing the antibacterial of DCPTA and methoxy acrylic | |
| CN102308822B (en) | Bactericide composition containing active ingredients of metiram | |
| CN102308821B (en) | Bactericide composition containing metiram active ingredient | |
| CN108651482A (en) | A kind of composition pesticide containing bronopol and benziothiazolinone | |
| CN102308820B (en) | Bactericide composition containing metiram active ingredient | |
| CN105941440A (en) | Sterilization composition containing Bixafen and zineb and application thereof | |
| CN106973924A (en) | Composition pesticide containing captan and fluazinam | |
| CN105211063B (en) | A kind of bactericidal composition containing dimoxystrobin and antibioticses | |
| CN102308818B (en) | Germicide composition containing active ingredient of polyram | |
| CN107087609A (en) | Microbicide compositions containing anthraquinone analog compound and S-Ethyl ethylthio sulfonate | |
| CN105918323A (en) | Bactericidal composition containing carabrone and isopyrazam | |
| CN105994294A (en) | Bactericidal composition containing bixafen and propiconazole and application thereof | |
| CN104686539A (en) | Sterilization compound with metconazole and folpet and purposes of sterilization compound |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20161221 Address after: 715500 Pucheng County of Shaanxi Province agricultural base industrial park Patentee after: Shaanxi Meibang Pesticides Co., Ltd. Address before: 715500 Pucheng City, Shaanxi province grain street, No. 23 Patentee before: Zhang Shaowu |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20131009 Termination date: 20171015 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |