CN102187876B - 用含硫化合物对土壤或基质进行农药处理 - Google Patents
用含硫化合物对土壤或基质进行农药处理 Download PDFInfo
- Publication number
- CN102187876B CN102187876B CN201110072792.XA CN201110072792A CN102187876B CN 102187876 B CN102187876 B CN 102187876B CN 201110072792 A CN201110072792 A CN 201110072792A CN 102187876 B CN102187876 B CN 102187876B
- Authority
- CN
- China
- Prior art keywords
- soil
- dmds
- compound
- effect
- sulphur compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002689 soil Substances 0.000 title claims abstract description 41
- 239000000575 pesticide Substances 0.000 title claims abstract description 6
- 239000000758 substrate Substances 0.000 title claims abstract description 6
- 238000011282 treatment Methods 0.000 title abstract description 18
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical class [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title abstract description 6
- WQOXQRCZOLPYPM-UHFFFAOYSA-N dimethyl disulfide Chemical compound CSSC WQOXQRCZOLPYPM-UHFFFAOYSA-N 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 31
- -1 sulphur compound Chemical class 0.000 claims abstract description 15
- 239000005864 Sulphur Substances 0.000 claims abstract description 9
- 241000244206 Nematoda Species 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 241000894006 Bacteria Species 0.000 claims description 7
- 239000004530 micro-emulsion Substances 0.000 claims description 7
- 239000000243 solution Substances 0.000 claims description 6
- 230000000361 pesticidal effect Effects 0.000 claims description 5
- 239000007864 aqueous solution Substances 0.000 claims description 3
- UOORRWUZONOOLO-OWOJBTEDSA-N (E)-1,3-dichloropropene Chemical group ClC\C=C\Cl UOORRWUZONOOLO-OWOJBTEDSA-N 0.000 claims description 2
- LFHISGNCFUNFFM-UHFFFAOYSA-N chloropicrin Chemical compound [O-][N+](=O)C(Cl)(Cl)Cl LFHISGNCFUNFFM-UHFFFAOYSA-N 0.000 claims description 2
- HZBLLTXMVMMHRJ-UHFFFAOYSA-L disodium;sulfidosulfanylmethanedithioate Chemical compound [Na+].[Na+].[S-]SC([S-])=S HZBLLTXMVMMHRJ-UHFFFAOYSA-L 0.000 claims description 2
- 239000003960 organic solvent Substances 0.000 claims description 2
- 230000000885 phytotoxic effect Effects 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 30
- 150000001875 compounds Chemical class 0.000 abstract description 25
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 abstract description 14
- 229910052783 alkali metal Inorganic materials 0.000 abstract description 5
- 150000001340 alkali metals Chemical group 0.000 abstract description 5
- 125000003342 alkenyl group Chemical group 0.000 abstract description 4
- 229940102396 methyl bromide Drugs 0.000 abstract description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 abstract 1
- 229910052739 hydrogen Inorganic materials 0.000 abstract 1
- 239000001257 hydrogen Substances 0.000 abstract 1
- 238000002347 injection Methods 0.000 abstract 1
- 239000007924 injection Substances 0.000 abstract 1
- 231100000760 phototoxic Toxicity 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000007789 gas Substances 0.000 description 19
- 239000000047 product Substances 0.000 description 18
- 241000233866 Fungi Species 0.000 description 16
- 235000013339 cereals Nutrition 0.000 description 15
- 230000004083 survival effect Effects 0.000 description 14
- ALVPFGSHPUPROW-UHFFFAOYSA-N di-n-propyl disulfide Natural products CCCSSCCC ALVPFGSHPUPROW-UHFFFAOYSA-N 0.000 description 11
- 241001558929 Sclerotium <basidiomycota> Species 0.000 description 10
- 239000004094 surface-active agent Substances 0.000 description 10
- 241000196324 Embryophyta Species 0.000 description 9
- JDLKFOPOAOFWQN-VIFPVBQESA-N Allicin Natural products C=CCS[S@](=O)CC=C JDLKFOPOAOFWQN-VIFPVBQESA-N 0.000 description 8
- 241000238631 Hexapoda Species 0.000 description 8
- JDLKFOPOAOFWQN-UHFFFAOYSA-N allicin Chemical compound C=CCSS(=O)CC=C JDLKFOPOAOFWQN-UHFFFAOYSA-N 0.000 description 8
- 235000010081 allicin Nutrition 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 241001530056 Athelia rolfsii Species 0.000 description 7
- 230000006378 damage Effects 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 239000011159 matrix material Substances 0.000 description 7
- 244000005700 microbiome Species 0.000 description 7
- 231100000572 poisoning Toxicity 0.000 description 7
- 230000000607 poisoning effect Effects 0.000 description 7
- 238000012360 testing method Methods 0.000 description 7
- 241001149949 Phytophthora cactorum Species 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 244000144987 brood Species 0.000 description 6
- 239000002316 fumigant Substances 0.000 description 6
- 230000000855 fungicidal effect Effects 0.000 description 6
- 230000000749 insecticidal effect Effects 0.000 description 6
- 239000002609 medium Substances 0.000 description 6
- 244000000010 microbial pathogen Species 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 241000234282 Allium Species 0.000 description 5
- KHBQMWCZKVMBLN-UHFFFAOYSA-N Benzenesulfonamide Chemical compound NS(=O)(=O)C1=CC=CC=C1 KHBQMWCZKVMBLN-UHFFFAOYSA-N 0.000 description 5
- 240000008415 Lactuca sativa Species 0.000 description 5
- 235000003228 Lactuca sativa Nutrition 0.000 description 5
- 241000813090 Rhizoctonia solani Species 0.000 description 5
- 230000000843 anti-fungal effect Effects 0.000 description 5
- 229940121375 antifungal agent Drugs 0.000 description 5
- 231100000225 lethality Toxicity 0.000 description 5
- 230000001954 sterilising effect Effects 0.000 description 5
- 150000008111 thiosulfinates Chemical class 0.000 description 5
- 229920001817 Agar Polymers 0.000 description 4
- LGDSHSYDSCRFAB-UHFFFAOYSA-N Methyl isothiocyanate Chemical compound CN=C=S LGDSHSYDSCRFAB-UHFFFAOYSA-N 0.000 description 4
- 235000019484 Rapeseed oil Nutrition 0.000 description 4
- 240000003768 Solanum lycopersicum Species 0.000 description 4
- 239000008272 agar Substances 0.000 description 4
- 230000000844 anti-bacterial effect Effects 0.000 description 4
- 230000004071 biological effect Effects 0.000 description 4
- 235000013601 eggs Nutrition 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 150000004702 methyl esters Chemical class 0.000 description 4
- 230000001717 pathogenic effect Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- 238000004659 sterilization and disinfection Methods 0.000 description 4
- BIHPYCDDPGNWQO-UHFFFAOYSA-N 5-iai Chemical compound C1=C(I)C=C2CC(N)CC2=C1 BIHPYCDDPGNWQO-UHFFFAOYSA-N 0.000 description 3
- 235000016623 Fragaria vesca Nutrition 0.000 description 3
- 240000009088 Fragaria x ananassa Species 0.000 description 3
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 3
- 239000003905 agrochemical Substances 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 230000001580 bacterial effect Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 230000002708 enhancing effect Effects 0.000 description 3
- 238000007046 ethoxylation reaction Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- 230000001069 nematicidal effect Effects 0.000 description 3
- 239000005645 nematicide Substances 0.000 description 3
- 244000052769 pathogen Species 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 240000004160 Capsicum annuum Species 0.000 description 2
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 2
- 244000241257 Cucumis melo Species 0.000 description 2
- 235000009847 Cucumis melo var cantalupensis Nutrition 0.000 description 2
- 240000008067 Cucumis sativus Species 0.000 description 2
- 235000010799 Cucumis sativus var sativus Nutrition 0.000 description 2
- 239000005644 Dazomet Substances 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 240000005979 Hordeum vulgare Species 0.000 description 2
- 235000007340 Hordeum vulgare Nutrition 0.000 description 2
- 241000256602 Isoptera Species 0.000 description 2
- 241000243784 Meloidogyne arenaria Species 0.000 description 2
- 206010033799 Paralysis Diseases 0.000 description 2
- 241001361634 Rhizoctonia Species 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- OKJPEAGHQZHRQV-UHFFFAOYSA-N Triiodomethane Natural products IC(I)I OKJPEAGHQZHRQV-UHFFFAOYSA-N 0.000 description 2
- 241000607479 Yersinia pestis Species 0.000 description 2
- 150000001447 alkali salts Chemical class 0.000 description 2
- 125000002877 alkyl aryl group Chemical group 0.000 description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000009395 breeding Methods 0.000 description 2
- 230000001488 breeding effect Effects 0.000 description 2
- 239000006227 byproduct Substances 0.000 description 2
- 150000001721 carbon Chemical group 0.000 description 2
- QAYICIQNSGETAS-UHFFFAOYSA-N dazomet Chemical compound CN1CSC(=S)N(C)C1 QAYICIQNSGETAS-UHFFFAOYSA-N 0.000 description 2
- 238000003795 desorption Methods 0.000 description 2
- PFRGXCVKLLPLIP-UHFFFAOYSA-N diallyl disulfide Chemical compound C=CCSSCC=C PFRGXCVKLLPLIP-UHFFFAOYSA-N 0.000 description 2
- 150000001993 dienes Chemical class 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 235000013399 edible fruits Nutrition 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 238000010413 gardening Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 230000012447 hatching Effects 0.000 description 2
- 238000000338 in vitro Methods 0.000 description 2
- 239000002917 insecticide Substances 0.000 description 2
- INQOMBQAUSQDDS-UHFFFAOYSA-N iodomethane Chemical compound IC INQOMBQAUSQDDS-UHFFFAOYSA-N 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 230000003151 ovacidal effect Effects 0.000 description 2
- 229910052760 oxygen Inorganic materials 0.000 description 2
- 239000001301 oxygen Substances 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- AGGIJOLULBJGTQ-UHFFFAOYSA-N sulfoacetic acid Chemical compound OC(=O)CS(O)(=O)=O AGGIJOLULBJGTQ-UHFFFAOYSA-N 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 235000013311 vegetables Nutrition 0.000 description 2
- ZAIDIVBQUMFXEC-UHFFFAOYSA-N 1,1-dichloroprop-1-ene Chemical group CC=C(Cl)Cl ZAIDIVBQUMFXEC-UHFFFAOYSA-N 0.000 description 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 206010011732 Cyst Diseases 0.000 description 1
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 1
- 244000166124 Eucalyptus globulus Species 0.000 description 1
- 241000255777 Lepidoptera Species 0.000 description 1
- 241000243786 Meloidogyne incognita Species 0.000 description 1
- 241000243785 Meloidogyne javanica Species 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- 229910019093 NaOCl Inorganic materials 0.000 description 1
- 241001597008 Nomeidae Species 0.000 description 1
- 241000233614 Phytophthora Species 0.000 description 1
- NCXMLFZGDNKEPB-UHFFFAOYSA-N Pimaricin Natural products OC1C(N)C(O)C(C)OC1OC1C=CC=CC=CC=CCC(C)OC(=O)C=CC2OC2CC(O)CC(O)(CC(O)C2C(O)=O)OC2C1 NCXMLFZGDNKEPB-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 241000576755 Sclerotia Species 0.000 description 1
- 241000221696 Sclerotinia sclerotiorum Species 0.000 description 1
- 241001518615 Sclerotium cepivorum Species 0.000 description 1
- 244000062793 Sorghum vulgare Species 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical class OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 240000008042 Zea mays Species 0.000 description 1
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 1
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000001476 alcoholic effect Effects 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005210 alkyl ammonium group Chemical group 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 239000002280 amphoteric surfactant Substances 0.000 description 1
- AVKUERGKIZMTKX-NJBDSQKTSA-N ampicillin Chemical compound C1([C@@H](N)C(=O)N[C@H]2[C@H]3SC([C@@H](N3C2=O)C(O)=O)(C)C)=CC=CC=C1 AVKUERGKIZMTKX-NJBDSQKTSA-N 0.000 description 1
- 229960000723 ampicillin Drugs 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 150000007860 aryl ester derivatives Chemical class 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- RIOXQFHNBCKOKP-UHFFFAOYSA-N benomyl Chemical compound C1=CC=C2N(C(=O)NCCCC)C(NC(=O)OC)=NC2=C1 RIOXQFHNBCKOKP-UHFFFAOYSA-N 0.000 description 1
- MITFXPHMIHQXPI-UHFFFAOYSA-N benzoxaprofen Natural products N=1C2=CC(C(C(O)=O)C)=CC=C2OC=1C1=CC=C(Cl)C=C1 MITFXPHMIHQXPI-UHFFFAOYSA-N 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- JQXXHWHPUNPDRT-BQVAUQFYSA-N chembl1523493 Chemical compound O([C@](C1=O)(C)O\C=C/[C@@H]([C@H]([C@@H](OC(C)=O)[C@H](C)[C@H](O)[C@H](C)[C@@H](O)[C@@H](C)/C=C\C=C(C)/C(=O)NC=2C(O)=C3C(O)=C4C)C)OC)C4=C1C3=C(O)C=2C=NN1CCN(C)CC1 JQXXHWHPUNPDRT-BQVAUQFYSA-N 0.000 description 1
- 229960005091 chloramphenicol Drugs 0.000 description 1
- WIIZWVCIJKGZOK-RKDXNWHRSA-N chloramphenicol Chemical compound ClC(Cl)C(=O)N[C@H](CO)[C@H](O)C1=CC=C([N+]([O-])=O)C=C1 WIIZWVCIJKGZOK-RKDXNWHRSA-N 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 239000002361 compost Substances 0.000 description 1
- 235000005822 corn Nutrition 0.000 description 1
- 208000031513 cyst Diseases 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 229960001760 dimethyl sulfoxide Drugs 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000005059 dormancy Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 150000002194 fatty esters Chemical class 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 238000004362 fungal culture Methods 0.000 description 1
- 238000004817 gas chromatography Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- 235000012974 gum Nutrition 0.000 description 1
- 229920000591 gum Polymers 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000002054 inoculum Substances 0.000 description 1
- 239000000543 intermediate Substances 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000001418 larval effect Effects 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 238000003760 magnetic stirring Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000019713 millet Nutrition 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000011490 mineral wool Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229960003255 natamycin Drugs 0.000 description 1
- NCXMLFZGDNKEPB-FFPOYIOWSA-N natamycin Chemical compound O[C@H]1[C@@H](N)[C@H](O)[C@@H](C)O[C@H]1O[C@H]1/C=C/C=C/C=C/C=C/C[C@@H](C)OC(=O)/C=C/[C@H]2O[C@@H]2C[C@H](O)C[C@](O)(C[C@H](O)[C@H]2C(O)=O)O[C@H]2C1 NCXMLFZGDNKEPB-FFPOYIOWSA-N 0.000 description 1
- 239000006199 nebulizer Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001021 polysulfide Polymers 0.000 description 1
- 239000005077 polysulfide Substances 0.000 description 1
- 150000008117 polysulfides Polymers 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000003254 radicals Chemical class 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000000241 respiratory effect Effects 0.000 description 1
- 229960001225 rifampicin Drugs 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000006152 selective media Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 238000010561 standard procedure Methods 0.000 description 1
- 239000008223 sterile water Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-O sulfonium Chemical compound [SH3+] RWSOTUBLDIXVET-UHFFFAOYSA-O 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- 229910021642 ultra pure water Inorganic materials 0.000 description 1
- 239000012498 ultrapure water Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom not containing sulfur-to-oxygen bonds, e.g. polysulfides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N31/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic oxygen or sulfur compounds
- A01N31/02—Acyclic compounds
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/04—Sulfonic acids; Derivatives thereof
- A01N41/08—Sulfonic acid halides; alpha-Hydroxy-sulfonic acids; Amino-sulfonic acids; Thiosulfonic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N41/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom
- A01N41/02—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a sulfur atom bound to a hetero atom containing a sulfur-to-oxygen double bond
- A01N41/10—Sulfones; Sulfoxides
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Dentistry (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Agronomy & Crop Science (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0103674A FR2822022B1 (fr) | 2001-03-19 | 2001-03-19 | Traitement pesticide des sols agricoles avec des composes soufres |
| FR01/03674 | 2001-03-19 |
Related Parent Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN028095510A Division CN1507321B (zh) | 2001-03-19 | 2002-03-04 | 用含硫化合物对土壤或基质进行农药处理 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN102187876A CN102187876A (zh) | 2011-09-21 |
| CN102187876B true CN102187876B (zh) | 2015-05-27 |
Family
ID=8861268
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201110072792.XA Expired - Lifetime CN102187876B (zh) | 2001-03-19 | 2002-03-04 | 用含硫化合物对土壤或基质进行农药处理 |
| CN028095510A Expired - Lifetime CN1507321B (zh) | 2001-03-19 | 2002-03-04 | 用含硫化合物对土壤或基质进行农药处理 |
Family Applications After (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN028095510A Expired - Lifetime CN1507321B (zh) | 2001-03-19 | 2002-03-04 | 用含硫化合物对土壤或基质进行农药处理 |
Country Status (18)
| Country | Link |
|---|---|
| US (2) | US20040087665A1 (https=) |
| EP (1) | EP1370137B1 (https=) |
| JP (1) | JP5036953B2 (https=) |
| CN (2) | CN102187876B (https=) |
| AP (1) | AP1898A (https=) |
| AT (1) | ATE517547T1 (https=) |
| AU (1) | AU2002249309B2 (https=) |
| BR (1) | BR0208278B1 (https=) |
| CY (1) | CY1112569T1 (https=) |
| DK (1) | DK1370137T3 (https=) |
| ES (1) | ES2369658T3 (https=) |
| FR (1) | FR2822022B1 (https=) |
| IL (2) | IL157998A0 (https=) |
| MA (1) | MA26109A1 (https=) |
| MX (1) | MXPA03008531A (https=) |
| PT (1) | PT1370137E (https=) |
| WO (1) | WO2002074083A1 (https=) |
| ZA (1) | ZA200307311B (https=) |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IL140948A0 (en) * | 2001-01-17 | 2002-02-10 | Yeda Res & Dev | Method for soil sterilization from pathogens |
| EP1501358A2 (en) * | 2002-04-25 | 2005-02-02 | Yeda Research and Development Co. Ltd. | Use of allicin as insect repellent and insecticide in agricultural crops |
| ES2388432T3 (es) * | 2003-03-05 | 2012-10-15 | Kanesho Soil Treatment Bvba | Composiciones para controlar organismos perjudiciales para las plantas |
| US8865200B2 (en) | 2004-07-09 | 2014-10-21 | Laboratoire Hra Pharma | Sustained release compositions containing progesterone receptor modulators |
| AU2006344450A1 (en) * | 2005-10-14 | 2007-12-21 | Genaro Casas Jassan | Natural pesticide |
| CN101491242B (zh) * | 2008-01-24 | 2012-03-28 | 中国农业科学院植物保护研究所 | 二甲基二硫作为土壤熏蒸剂的应用技术 |
| WO2009137803A2 (en) * | 2008-05-09 | 2009-11-12 | Rentech, Inc. | Ft naphtha and ft diesel as solvents or carriers for pesticides and/or herbicides |
| EP2326173A4 (en) * | 2008-08-25 | 2013-04-10 | Univ Florida | METHOD AND COMPOSITIONS FOR THE TREATMENT AND PREVENTION OF CITRAL DISEASE HLB |
| MX2011004092A (es) * | 2008-10-17 | 2011-07-28 | Valent Biosciences Corp | Composiciones de cinamaldehiido-alacina y su metodo de uso. |
| US9161532B2 (en) | 2008-10-17 | 2015-10-20 | Valent Biosciences Corporation | Cinnamaldehyde-allicin formulations and methods of their use |
| CN101606533B (zh) * | 2009-07-27 | 2012-05-02 | 山东美罗福农化有限公司 | 一种土壤熏蒸剂组合物及其应用 |
| FR2979521B1 (fr) | 2011-09-01 | 2013-08-23 | Arkema France | Film photocatalytique pour la fumigation des sols |
| CA2856196C (en) | 2011-12-06 | 2020-09-01 | Masco Corporation Of Indiana | Ozone distribution in a faucet |
| US20130178364A1 (en) * | 2012-01-05 | 2013-07-11 | John Stephen Godbehere | Odor mitigating fumigant composition |
| MA37469A1 (fr) | 2012-04-30 | 2016-04-29 | Dow Agrosciences Llc | Véhicules d'administration d'une composition de pesticide |
| JP2014183806A (ja) * | 2013-03-25 | 2014-10-02 | C I Kasei Co Ltd | 土壌燻蒸用フィルム |
| CN104365600B (zh) * | 2014-09-30 | 2016-09-14 | 北京格林泰姆科技有限公司 | 二甲基二硫乳油、其制备方法以及水乳剂和胶囊 |
| FR3028148B1 (fr) * | 2014-11-10 | 2017-05-19 | Arkema France | Film autoadhesif pour la fumigation des sols |
| CN104604860A (zh) * | 2015-01-28 | 2015-05-13 | 中国农业科学院植物保护研究所 | 一种二甲基二硫颗粒剂及其制备方法 |
| CN104826150B (zh) * | 2015-04-17 | 2017-07-11 | 文山苗乡三七科技有限公司 | 一种三七连作土壤的消毒方法 |
| WO2017112795A1 (en) | 2015-12-21 | 2017-06-29 | Delta Faucet Company | Fluid delivery system including a disinfectant device |
| US11439151B2 (en) | 2017-10-20 | 2022-09-13 | Biosafe Systems Llc | Process for treating an agricultural medium |
| BR112020017642A2 (pt) | 2018-03-01 | 2020-12-22 | Arkema Inc. | Tratamento de solo usando peróxido |
| FR3100105B1 (fr) * | 2019-08-30 | 2023-12-08 | Arkema France | Formulation fumigante pour application en goutte a goutte |
| EP4125362A1 (en) * | 2020-03-24 | 2023-02-08 | Taminco BV | Methods of reducing fusarium contamination |
| CN112021311B (zh) * | 2020-08-18 | 2022-01-04 | 云南农业大学 | 硫醚类化合物烯丙基丙基二硫醚抑制疫霉菌的新用途 |
| CN113893363A (zh) * | 2021-10-14 | 2022-01-07 | 中国农业科学院植物保护研究所 | 一种防治土传病害的联合土壤消毒方法 |
| GB2623555A (en) * | 2022-10-20 | 2024-04-24 | Ecospray Ltd | An Improved Biopesticide |
| CN117884463B (zh) * | 2024-01-18 | 2024-08-30 | 上海久澄环境工程有限公司 | 一种常温解吸法处理土壤中二乙基硫醚、二乙基二硫醚 |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB249830A (en) * | 1925-03-24 | 1927-08-16 | Chem Fab Auf Actien | Process for the prevention of injury to crops by soil nematodes |
| US2917429A (en) * | 1956-08-17 | 1959-12-15 | Collier Carbon & Chemical Co | Method of destroying nematodes employing dimethyl polysulfides |
| US3586723A (en) * | 1968-12-11 | 1971-06-22 | Westvaco Corp | Preparation of dialkyl disulfides |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5858322B2 (ja) * | 1980-10-28 | 1983-12-24 | 勲 堀内 | 植物の病害防除方法 |
| US5013350A (en) * | 1981-10-27 | 1991-05-07 | Union Oil Company Of California | Stabilized thiocarbonate solutions |
| JPH01207204A (ja) * | 1988-02-12 | 1989-08-21 | Mitsubishi Kasei Corp | 殺線虫剤 |
| FR2779615A1 (fr) * | 1997-10-27 | 1999-12-17 | Gilles Gerard Norbert Joly | Obtention et application d'un produit pesticide a base d'odeurs de plantes du genre allium |
| JP3406210B2 (ja) * | 1997-12-19 | 2003-05-12 | 三井化学株式会社 | 土壌燻蒸組成物 |
| JPH11222410A (ja) * | 1998-02-03 | 1999-08-17 | Riken Health Kk | 植物の枯損防除及び活性化剤 |
| US6593299B1 (en) * | 1999-04-21 | 2003-07-15 | University Of Florida Research Foundation, Inc. | Compositions and methods for controlling pests |
| US6923937B2 (en) * | 2000-12-13 | 2005-08-02 | Trical, Inc. | Emulsified soil biocides used in drip irrigation systems |
-
2001
- 2001-03-19 FR FR0103674A patent/FR2822022B1/fr not_active Expired - Lifetime
-
2002
- 2002-03-04 CN CN201110072792.XA patent/CN102187876B/zh not_active Expired - Lifetime
- 2002-03-04 PT PT02718237T patent/PT1370137E/pt unknown
- 2002-03-04 US US10/472,083 patent/US20040087665A1/en not_active Abandoned
- 2002-03-04 WO PCT/FR2002/000768 patent/WO2002074083A1/fr not_active Ceased
- 2002-03-04 JP JP2002572806A patent/JP5036953B2/ja not_active Expired - Lifetime
- 2002-03-04 AT AT02718237T patent/ATE517547T1/de active
- 2002-03-04 AP APAP/P/2003/002889A patent/AP1898A/en active
- 2002-03-04 DK DK02718237.7T patent/DK1370137T3/da active
- 2002-03-04 BR BRPI0208278-0A patent/BR0208278B1/pt active IP Right Grant
- 2002-03-04 AU AU2002249309A patent/AU2002249309B2/en not_active Expired
- 2002-03-04 EP EP02718237A patent/EP1370137B1/fr not_active Expired - Lifetime
- 2002-03-04 MX MXPA03008531A patent/MXPA03008531A/es active IP Right Grant
- 2002-03-04 IL IL15799802A patent/IL157998A0/xx active IP Right Grant
- 2002-03-04 CN CN028095510A patent/CN1507321B/zh not_active Expired - Lifetime
- 2002-03-04 ES ES02718237T patent/ES2369658T3/es not_active Expired - Lifetime
-
2003
- 2003-09-18 ZA ZA200307311A patent/ZA200307311B/en unknown
- 2003-09-18 IL IL157998A patent/IL157998A/en unknown
- 2003-10-15 MA MA27362A patent/MA26109A1/fr unknown
-
2011
- 2011-06-20 US US13/164,584 patent/US8663669B2/en not_active Expired - Fee Related
- 2011-10-26 CY CY20111101015T patent/CY1112569T1/el unknown
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB249830A (en) * | 1925-03-24 | 1927-08-16 | Chem Fab Auf Actien | Process for the prevention of injury to crops by soil nematodes |
| US2917429A (en) * | 1956-08-17 | 1959-12-15 | Collier Carbon & Chemical Co | Method of destroying nematodes employing dimethyl polysulfides |
| US3586723A (en) * | 1968-12-11 | 1971-06-22 | Westvaco Corp | Preparation of dialkyl disulfides |
Also Published As
| Publication number | Publication date |
|---|---|
| CY1112569T1 (el) | 2016-02-10 |
| IL157998A0 (en) | 2004-03-28 |
| AP1898A (en) | 2008-10-10 |
| CN1507321A (zh) | 2004-06-23 |
| US20120021032A1 (en) | 2012-01-26 |
| JP2004529120A (ja) | 2004-09-24 |
| US8663669B2 (en) | 2014-03-04 |
| CN102187876A (zh) | 2011-09-21 |
| AP2003002889A0 (en) | 2003-12-31 |
| ATE517547T1 (de) | 2011-08-15 |
| US20040087665A1 (en) | 2004-05-06 |
| AU2002249309B2 (en) | 2008-04-03 |
| JP5036953B2 (ja) | 2012-09-26 |
| ZA200307311B (en) | 2004-09-20 |
| MA26109A1 (fr) | 2004-04-01 |
| CN1507321B (zh) | 2011-05-11 |
| EP1370137A1 (fr) | 2003-12-17 |
| IL157998A (en) | 2008-06-05 |
| FR2822022A1 (fr) | 2002-09-20 |
| MXPA03008531A (es) | 2004-06-30 |
| BR0208278B1 (pt) | 2012-12-25 |
| EP1370137B1 (fr) | 2011-07-27 |
| DK1370137T3 (da) | 2011-10-31 |
| FR2822022B1 (fr) | 2005-11-04 |
| BR0208278A (pt) | 2004-03-09 |
| WO2002074083A1 (fr) | 2002-09-26 |
| ES2369658T3 (es) | 2011-12-02 |
| PT1370137E (pt) | 2011-10-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102187876B (zh) | 用含硫化合物对土壤或基质进行农药处理 | |
| US6124275A (en) | Methods and compositions for controlling a pest population | |
| AU1104300A (en) | A natural and safe alternative to fungicides, bacteriocides, nematicides and insecticides for plant protection and against household pests | |
| CN114431256B (zh) | 一种含有除虫菊素与球孢白僵菌的复配组合物及其应用 | |
| US20090186761A1 (en) | Use of bio-derived surfactants for mitigating damage to plants from pests | |
| US20260053144A1 (en) | Pest control kit and method | |
| MX2011004092A (es) | Composiciones de cinamaldehiido-alacina y su metodo de uso. | |
| US5518993A (en) | Pesticidal compositions containing ethoxylated fatty amines for increasing the effectiveness of endothal and salts thereof | |
| CA2334523A1 (en) | Use of at least one acid from the citric acid cycle combined with glycerine as a pesticide | |
| AU2004201268A1 (en) | A natural and safe alternative to fungicides, bacteriocides, nematicides and insecticides for plant protection and against household pests | |
| CN111374129A (zh) | 一种含1-辛烯-3-醇的杀线虫药剂及其制备方法和应用 | |
| CN114831140B (zh) | 西藏亚菊提取物在制备除草剂和/或杀虫剂中的应用 | |
| RU2841206C2 (ru) | Набор и способ борьбы с вредителями | |
| JP4471264B2 (ja) | 混合燻蒸剤 | |
| WO1999062334A1 (en) | Methods for controlling a pest population | |
| JP3465854B2 (ja) | 殺屋内塵性ダニ剤 | |
| CN104255776A (zh) | 一次性卫生除害处理制剂 | |
| AU4109399A (en) | Pesticidal compositions containing ethoxylated fatty amines for increasing the effectiveness of endothall and salts thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: French Cologne Applicant after: ARKEMA FRANCE Address before: French pitot Applicant before: ARKEMA Address after: French pitot Applicant after: ARKEMA Address before: French Maputo Applicant before: ATOFINA |
|
| COR | Change of bibliographic data |
Free format text: CORRECT: APPLICANT; FROM: ATO PHENA S.A. TO: ATOFINA Free format text: CORRECT: APPLICANT; FROM: ATOFINA TO: ARKEMA |
|
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CX01 | Expiry of patent term | ||
| CX01 | Expiry of patent term |
Granted publication date: 20150527 |