CN102092864A - 锅炉给水用有机除氧剂 - Google Patents
锅炉给水用有机除氧剂 Download PDFInfo
- Publication number
- CN102092864A CN102092864A CN 201110000457 CN201110000457A CN102092864A CN 102092864 A CN102092864 A CN 102092864A CN 201110000457 CN201110000457 CN 201110000457 CN 201110000457 A CN201110000457 A CN 201110000457A CN 102092864 A CN102092864 A CN 102092864A
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- CN
- China
- Prior art keywords
- water
- organic
- alkyl
- deoxidant
- amine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 31
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims abstract description 12
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 12
- 150000001412 amines Chemical class 0.000 claims abstract description 9
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 125000001072 heteroaryl group Chemical group 0.000 claims abstract description 6
- 125000000896 monocarboxylic acid group Chemical group 0.000 claims abstract description 6
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims abstract description 5
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000003118 aryl group Chemical group 0.000 claims abstract description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229940123973 Oxygen scavenger Drugs 0.000 claims description 22
- 125000000753 cycloalkyl group Chemical group 0.000 claims description 6
- 229960004418 trolamine Drugs 0.000 claims description 4
- CNPURSDMOWDNOQ-UHFFFAOYSA-N 4-methoxy-7h-pyrrolo[2,3-d]pyrimidin-2-amine Chemical compound COC1=NC(N)=NC2=C1C=CN2 CNPURSDMOWDNOQ-UHFFFAOYSA-N 0.000 claims description 2
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract description 15
- 229910052760 oxygen Inorganic materials 0.000 abstract description 15
- 239000001301 oxygen Substances 0.000 abstract description 15
- 235000011114 ammonium hydroxide Nutrition 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- PAFZNILMFXTMIY-UHFFFAOYSA-N cyclohexylamine Chemical group NC1CCCCC1 PAFZNILMFXTMIY-UHFFFAOYSA-N 0.000 abstract description 3
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 abstract 1
- 125000004432 carbon atom Chemical group C* 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 125000001424 substituent group Chemical group 0.000 abstract 1
- 150000002429 hydrazines Chemical class 0.000 description 8
- 238000002161 passivation Methods 0.000 description 8
- 239000000047 product Substances 0.000 description 7
- 229910004298 SiO 2 Inorganic materials 0.000 description 6
- 238000010612 desalination reaction Methods 0.000 description 6
- 238000001914 filtration Methods 0.000 description 6
- 239000012467 final product Substances 0.000 description 6
- 239000008236 heating water Substances 0.000 description 6
- 238000005342 ion exchange Methods 0.000 description 6
- 239000012528 membrane Substances 0.000 description 6
- 230000001681 protective effect Effects 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 5
- 238000005260 corrosion Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- REYJJPSVUYRZGE-UHFFFAOYSA-N Octadecylamine Chemical compound CCCCCCCCCCCCCCCCCCN REYJJPSVUYRZGE-UHFFFAOYSA-N 0.000 description 4
- -1 copper complex ion Chemical class 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 3
- 150000002780 morpholines Chemical class 0.000 description 3
- FJLUATLTXUNBOT-UHFFFAOYSA-N 1-Hexadecylamine Chemical compound CCCCCCCCCCCCCCCCN FJLUATLTXUNBOT-UHFFFAOYSA-N 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- DJEQZVQFEPKLOY-UHFFFAOYSA-N N,N-dimethylbutylamine Chemical compound CCCCN(C)C DJEQZVQFEPKLOY-UHFFFAOYSA-N 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- 239000010949 copper Substances 0.000 description 2
- 238000006392 deoxygenation reaction Methods 0.000 description 2
- 125000000717 hydrazino group Chemical group [H]N([*])N([H])[H] 0.000 description 2
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OOIVKYXECPNCMF-UHFFFAOYSA-N 1-(chloromethyl)-1-phenylhydrazine Chemical compound ClCN(N)C1=CC=CC=C1 OOIVKYXECPNCMF-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- DWAQJAXMDSEUJJ-UHFFFAOYSA-M Sodium bisulfite Chemical compound [Na+].OS([O-])=O DWAQJAXMDSEUJJ-UHFFFAOYSA-M 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical class NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 235000014655 lactic acid Nutrition 0.000 description 1
- 239000004310 lactic acid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000010137 moulding (plastic) Methods 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- QVGXLLKOCUKJST-BJUDXGSMSA-N oxygen-15 atom Chemical compound [15O] QVGXLLKOCUKJST-BJUDXGSMSA-N 0.000 description 1
- 229960000624 procarbazine Drugs 0.000 description 1
- 235000010267 sodium hydrogen sulphite Nutrition 0.000 description 1
- 159000000000 sodium salts Chemical class 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 1
Landscapes
- Preventing Corrosion Or Incrustation Of Metals (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110000457A CN102092864B (zh) | 2011-01-04 | 2011-01-04 | 锅炉给水用有机除氧剂 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201110000457A CN102092864B (zh) | 2011-01-04 | 2011-01-04 | 锅炉给水用有机除氧剂 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN102092864A true CN102092864A (zh) | 2011-06-15 |
CN102092864B CN102092864B (zh) | 2012-09-19 |
Family
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201110000457A Active CN102092864B (zh) | 2011-01-04 | 2011-01-04 | 锅炉给水用有机除氧剂 |
Country Status (1)
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CN (1) | CN102092864B (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102815797A (zh) * | 2012-07-12 | 2012-12-12 | 天津市瑞德赛恩新材料开发有限公司 | 一种多功能锅炉给水系统保护剂及其制备方法 |
CN106015837A (zh) * | 2016-05-31 | 2016-10-12 | 无锡锡能锅炉有限公司 | 一种煤粉锅炉回收水管路用复水剂 |
CN106167305A (zh) * | 2015-11-25 | 2016-11-30 | 天津市奔晟新材料科技开发有限公司 | 锅炉及冷凝水系统的中和胺保护剂 |
CN107324476A (zh) * | 2017-07-21 | 2017-11-07 | 沈阳追梦蓝环保科技有限公司 | 一种复合型除盐水pH调节剂及其制备方法 |
CN107324557A (zh) * | 2017-08-08 | 2017-11-07 | 杭州航民热电有限公司 | 一种锅炉给水的水处理方法 |
CN107352610A (zh) * | 2017-07-11 | 2017-11-17 | 沈阳追梦蓝环保科技有限公司 | 一种复合型锅炉给水用除氧缓蚀剂及其制备方法 |
CN113562855A (zh) * | 2021-08-03 | 2021-10-29 | 浙江砉润科技有限公司 | 一种环保高效汽包锅炉用炉水调节剂 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5904857A (en) * | 1997-04-17 | 1999-05-18 | Nalco Chemical Company | 4-alkyl and aryl semicarbazides as oxygen scavengers |
CN101716450A (zh) * | 2009-12-18 | 2010-06-02 | 哈尔滨工业大学 | 一种除氧复合药剂/uv联用的除氧方法 |
-
2011
- 2011-01-04 CN CN201110000457A patent/CN102092864B/zh active Active
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5904857A (en) * | 1997-04-17 | 1999-05-18 | Nalco Chemical Company | 4-alkyl and aryl semicarbazides as oxygen scavengers |
CN101716450A (zh) * | 2009-12-18 | 2010-06-02 | 哈尔滨工业大学 | 一种除氧复合药剂/uv联用的除氧方法 |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102815797A (zh) * | 2012-07-12 | 2012-12-12 | 天津市瑞德赛恩新材料开发有限公司 | 一种多功能锅炉给水系统保护剂及其制备方法 |
CN106167305A (zh) * | 2015-11-25 | 2016-11-30 | 天津市奔晟新材料科技开发有限公司 | 锅炉及冷凝水系统的中和胺保护剂 |
CN106015837A (zh) * | 2016-05-31 | 2016-10-12 | 无锡锡能锅炉有限公司 | 一种煤粉锅炉回收水管路用复水剂 |
CN107352610A (zh) * | 2017-07-11 | 2017-11-17 | 沈阳追梦蓝环保科技有限公司 | 一种复合型锅炉给水用除氧缓蚀剂及其制备方法 |
CN107324476A (zh) * | 2017-07-21 | 2017-11-07 | 沈阳追梦蓝环保科技有限公司 | 一种复合型除盐水pH调节剂及其制备方法 |
CN107324557A (zh) * | 2017-08-08 | 2017-11-07 | 杭州航民热电有限公司 | 一种锅炉给水的水处理方法 |
CN113562855A (zh) * | 2021-08-03 | 2021-10-29 | 浙江砉润科技有限公司 | 一种环保高效汽包锅炉用炉水调节剂 |
Also Published As
Publication number | Publication date |
---|---|
CN102092864B (zh) | 2012-09-19 |
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C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
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TR01 | Transfer of patent right |
Effective date of registration: 20160801 Address after: 113004, building 5, Longfeng Road South, Dongzhou District, Fushun, Liaoning Patentee after: Liaoning low carbon Chemical Co., Ltd. Address before: 213003, No. 185, front street, Tianning District, Jiangsu, Changzhou Patentee before: Wang Zhongxian Patentee before: Shen Hongxin |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20190415 Address after: 110000 Block 806, Jialong Center B, No. 6 Tiancheng Street, Hunnan District, Shenyang City, Liaoning Province Patentee after: Wang Zhongxian Address before: 113004 Building 5, Longfeng South Road, Dongzhou District, Fushun City, Liaoning Province Patentee before: Liaoning low carbon Chemical Co., Ltd. |
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TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20220209 Address after: 100043 room 336, floor 3, building 1, Gucheng North Road comprehensive commercial building, Shijingshan District, Beijing Patentee after: Beijing Low Carbon Technology Co.,Ltd. Address before: 110000 Block 806, Jialong Center B, No. 6 Tiancheng Street, Hunnan District, Shenyang City, Liaoning Province Patentee before: Wang Zhongxian |