CN102067851B - Antibacterial composition containing polyoxin and methoxyacrylate compound - Google Patents
Antibacterial composition containing polyoxin and methoxyacrylate compound Download PDFInfo
- Publication number
- CN102067851B CN102067851B CN201110022960.4A CN201110022960A CN102067851B CN 102067851 B CN102067851 B CN 102067851B CN 201110022960 A CN201110022960 A CN 201110022960A CN 102067851 B CN102067851 B CN 102067851B
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- CN
- China
- Prior art keywords
- polyoxin
- active ingredient
- bactericide
- kresoxim
- enestroburin
- Prior art date
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- 229930182764 Polyoxin Natural products 0.000 title claims abstract description 153
- YEBIHIICWDDQOL-YBHNRIQQSA-N polyoxin Polymers O[C@@H]1[C@H](O)[C@@H](C(C=O)N)O[C@H]1N1C(=O)NC(=O)C(C(O)=O)=C1 YEBIHIICWDDQOL-YBHNRIQQSA-N 0.000 title claims abstract description 146
- 239000000203 mixture Substances 0.000 title claims abstract description 60
- 230000000844 anti-bacterial effect Effects 0.000 title claims abstract description 29
- -1 methoxyacrylate compound Chemical class 0.000 title abstract description 26
- 201000010099 disease Diseases 0.000 claims abstract description 19
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 claims abstract description 19
- 241000221785 Erysiphales Species 0.000 claims abstract description 11
- 241000233679 Peronosporaceae Species 0.000 claims abstract description 11
- 240000007594 Oryza sativa Species 0.000 claims abstract description 4
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 4
- 235000009566 rice Nutrition 0.000 claims abstract description 4
- 239000004480 active ingredient Substances 0.000 claims abstract 7
- 239000005784 Fluoxastrobin Substances 0.000 claims description 23
- UFEODZBUAFNAEU-NLRVBDNBSA-N fluoxastrobin Chemical group C=1C=CC=C(OC=2C(=C(OC=3C(=CC=CC=3)Cl)N=CN=2)F)C=1C(=N/OC)\C1=NOCCO1 UFEODZBUAFNAEU-NLRVBDNBSA-N 0.000 claims description 23
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 claims description 6
- 206010039509 Scab Diseases 0.000 claims description 3
- 239000012752 auxiliary agent Substances 0.000 claims description 3
- 230000035613 defoliation Effects 0.000 claims description 2
- 235000013339 cereals Nutrition 0.000 claims 1
- 235000013399 edible fruits Nutrition 0.000 claims 1
- 235000013311 vegetables Nutrition 0.000 claims 1
- 239000005869 Pyraclostrobin Substances 0.000 abstract description 32
- VMNULHCTRPXWFJ-UJSVPXBISA-N enoxastrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1CO\N=C(/C)\C=C\C1=CC=C(Cl)C=C1 VMNULHCTRPXWFJ-UJSVPXBISA-N 0.000 abstract description 32
- HZRSNVGNWUDEFX-UHFFFAOYSA-N pyraclostrobin Chemical compound COC(=O)N(OC)C1=CC=CC=C1COC1=NN(C=2C=CC(Cl)=CC=2)C=C1 HZRSNVGNWUDEFX-UHFFFAOYSA-N 0.000 abstract description 32
- 239000005800 Kresoxim-methyl Substances 0.000 abstract description 28
- ZOTBXTZVPHCKPN-HTXNQAPBSA-N kresoxim-methyl Chemical compound CO\N=C(\C(=O)OC)C1=CC=CC=C1COC1=CC=CC=C1C ZOTBXTZVPHCKPN-HTXNQAPBSA-N 0.000 abstract description 28
- 230000002195 synergetic effect Effects 0.000 abstract description 22
- 239000000575 pesticide Substances 0.000 abstract description 13
- 239000005730 Azoxystrobin Substances 0.000 abstract description 8
- 239000003899 bactericide agent Substances 0.000 abstract description 7
- WFDXOXNFNRHQEC-GHRIWEEISA-N azoxystrobin Chemical compound CO\C=C(\C(=O)OC)C1=CC=CC=C1OC1=CC(OC=2C(=CC=CC=2)C#N)=NC=N1 WFDXOXNFNRHQEC-GHRIWEEISA-N 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 5
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- 238000001228 spectrum Methods 0.000 abstract description 2
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- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 7
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- 239000005995 Aluminium silicate Substances 0.000 description 6
- 235000012211 aluminium silicate Nutrition 0.000 description 6
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 6
- 229910052921 ammonium sulfate Inorganic materials 0.000 description 6
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 6
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- 150000004996 alkyl benzenes Chemical class 0.000 description 4
- 229940077388 benzenesulfonate Drugs 0.000 description 4
- 239000011230 binding agent Substances 0.000 description 4
- 239000011575 calcium Substances 0.000 description 4
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- 235000020232 peanut Nutrition 0.000 description 4
- PYODKQIVQIVELM-UHFFFAOYSA-M sodium;2,3-bis(2-methylpropyl)naphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(S([O-])(=O)=O)=C(CC(C)C)C(CC(C)C)=CC2=C1 PYODKQIVQIVELM-UHFFFAOYSA-M 0.000 description 4
- 241000255789 Bombyx mori Species 0.000 description 3
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 235000007688 Lycopersicon esculentum Nutrition 0.000 description 3
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 description 3
- 240000003768 Solanum lycopersicum Species 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- 230000008485 antagonism Effects 0.000 description 3
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- 229910052625 palygorskite Inorganic materials 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 159000000000 sodium salts Chemical class 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 239000004094 surface-active agent Substances 0.000 description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 230000009471 action Effects 0.000 description 2
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- 239000000126 substance Substances 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- UHPMCKVQTMMPCG-UHFFFAOYSA-N 5,8-dihydroxy-2-methoxy-6-methyl-7-(2-oxopropyl)naphthalene-1,4-dione Chemical compound CC1=C(CC(C)=O)C(O)=C2C(=O)C(OC)=CC(=O)C2=C1O UHPMCKVQTMMPCG-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 241000223602 Alternaria alternata Species 0.000 description 1
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 1
- 229920001353 Dextrin Polymers 0.000 description 1
- 239000004375 Dextrin Substances 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 235000016623 Fragaria vesca Nutrition 0.000 description 1
- 240000009088 Fragaria x ananassa Species 0.000 description 1
- 235000011363 Fragaria x ananassa Nutrition 0.000 description 1
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- 241000223218 Fusarium Species 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 206010027146 Melanoderma Diseases 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
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- 244000131316 Panax pseudoginseng Species 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 235000014443 Pyrus communis Nutrition 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 238000012271 agricultural production Methods 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 229940088710 antibiotic agent Drugs 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
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- 238000011161 development Methods 0.000 description 1
- 235000019425 dextrin Nutrition 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
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- 239000000463 material Substances 0.000 description 1
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- KFSLWBXXFJQRDL-UHFFFAOYSA-N peroxyacetic acid Substances CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 1
- 239000000825 pharmaceutical preparation Substances 0.000 description 1
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- 229920005646 polycarboxylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 description 1
- 108090000765 processed proteins & peptides Proteins 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 239000002718 pyrimidine nucleoside Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
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- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses an antibacterial composition containing polyoxin and a methoxyacrylate compound, in particular to an antibacterial composition containing an active ingredient A and an active ingredient B. The active ingredient A is polyoxin, the active ingredient B may be an azoxystrobin bactericide, a kresoxim-methyl bactericide, an (E)-2-[2-(2,5-dimethylphenoxymethyl)-phenyl]-3-methoxymethylmethoxyacrylate bactericide, a pyraclostrobin bactericide or an enestroburin bactericide, the weight part ratio of the active ingredient A to the active ingredient B is 1:72-72:1. The antibacterial composition can prevent and control various diseases in crops, has an obvious synergetic effect, enlarges an antibacterial spectrum, and has high activity for diseases such as downy mildew, epidemic diseases, anthracnose, powdery mildew, alternaria leaf spot, leafspot, cladosporium cucumerinum and rice blast; and the composition helps to reduce pesticide dose and the residual pesticide on crops and relieve environment pollution.
Description
Technical field
The invention belongs to technical field of pesticide, relate to a kind of binary mixture bactericidal composition that contains polyoxin and methoxy acrylic ester compounds.
Background technology
Polyoxin (polyoxin), molecular formula: C17H25N5O14, chemical name peptide pyrimidine nucleoside.
Structural formula:
Polyoxin broad-spectrum antibiotics class, in having preferably, inhale conduction, its mechanism of action is to disturb the chitinous biosynthesis of bacterial cell wall, after germ tube contacts medicament with mycelium, expand part, break, overflow cell inclusion, and can not normal development, cause death, suppress in addition germ and produce spore and scab expansion effect, this medicine does not have toxicity to animal, and plant is not had to poisoning.Main controlling object has wheat powdery mildew, Alternaria alternate, cucumber downy mildew, cucurbits fusarium wilt, black fleck disease of ginseng, rice sheath blight disease, alternaria leaf spot of apple, strawberry and work grape grey mould, the multiple fungal diseases such as forest spike top and Pear black spot.
Yet in the real process of agricultural production, preventing and treating the problem that disease the most easily produces is the drug-fast generation of germ.Different cultivars composition carries out composite, is to prevent and treat the very common method of resistance germ.Heterogeneity is carried out composite, according to practical application effect, judge certain composite be synergy, add and or antagonism.In most cases, the composite effect of agricultural chemicals is all additive effect, really has the seldom composite of synergistic effect, especially synergistic effect very obviously, synergy ratio very high composite just still less.Through inventor's research, discovery can produce good synergistic effect by polyoxin and kresoxim-methyl, ZJ0712, pyraclostrobin and Enestroburin after composite, and not yet open about polyoxin and the composite relevant report of methoxy acrylic ester compounds Fluoxastrobin, kresoxim-methyl, ZJ0712, pyraclostrobin and Enestroburin.
Summary of the invention
A kind of bactericidal composition that contains polyoxin and methoxy acrylic ester compounds, comprise effective active component, auxiliary agent and filler, it is characterized in that: A, B ratio of weight and number are 1: 72～72: 1, active component A is selected from polyoxin, and active component B is Fluoxastrobin, kresoxim-methyl, ZJ0712, pyraclostrobin, Enestroburin.
Described a kind of bactericidal composition that contains polyoxin and methoxy acrylic ester compounds, is characterized in that: the ratio of weight and number of A, two kinds of active components of B is 1: 18～18: 1.
The described bactericidal composition containing polyoxin, is characterized in that: the ratio of weight and number of polyoxin and Fluoxastrobin is 1: 9～9: 1.
The described bactericidal composition containing polyoxin, is characterized in that: the ratio of weight and number of polyoxin and kresoxim-methyl is 1: 9～9: 1.
The described bactericidal composition containing polyoxin, is characterized in that: the ratio of weight and number of polyoxin and ZJ0712 is 1: 9～9: 1.
The described bactericidal composition containing polyoxin, is characterized in that: the ratio of weight and number of polyoxin and pyraclostrobin is 1: 9～9: 1.
The described bactericidal composition containing polyoxin, is characterized in that: the ratio of weight and number of polyoxin and Enestroburin is 1: 9～9: 1.
The ratio of weight and number of A, two kinds of active components of B is 1: 72～72: 1.Conventionally in composition, active weight percentage is gross weight 1～90%, is preferably 5%～85%.According to different preparation types, active component content scope is different.Conventionally, solid pharmaceutical preparation contains 5～85% active substance by weight, is preferably 10～80%.
In bactericidal composition of the present invention, at least contain a kind of surfactant, the dispersion of active component in water while being beneficial to use.Surface-active contents is 5～30% of total formulation weight amount, and surplus is solid or liquid diluent.
The selected surfactant of bactericidal composition of the present invention is known in those skilled in the art: can be selected from one or more in dispersant, wetting agent, binding agent.According to different dosage form, in preparation, can also contain disintegrant known in those skilled in the art etc.
Described dispersant is selected from alkylnaphthalene sulfonate, two (alkyl) naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product, aryl phenol polyoxyethylene succinate sulfonate, octylphenol polyethylene oxyethylene group ether sulfate, polycarboxylate, lignosulfonates, the phonetic formaldehyde condensation products sulphate of alkylphenol-polyethenoxy, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol-polyethenoxy is phonetic, aliphatic amine polyoxyethylene is phonetic, polyoxyethylene carboxylate, one or more during ester polyoxyethylene is phonetic.
Described wetting agent is selected from: one or more in lauryl sodium sulfate, neopelex, Nekal BX, wetting and penetrating agent F, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride.
Described binding agent is selected from: one or more in gum Arabic, xanthans, sodium phosphate trimer, phenolic resins, sodium alginate, white dextrin, methylcellulose, PAA, polyvinylpyrrolidone, crospolyvinylpyrrolidone, polyethylene glycol, polyvinyl alcohol.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Composition of the present invention can be by user before use through dilution or directly use.Its preparation can be prepared by common processing method, after being about to active substance and mixing with liquid flux or solid carrier, then adds surfactant as one or more in dispersant, stabilizing agent, wetting agent, adhesive etc.
Bactericidal composition of the present invention, can be processed into acceptable formulation on any agricultural chemicals on demand.Wherein preferred dosage form is wetting powder, water dispersible granules.
When making wetting powder, composition comprises following constituent content: polyoxin 1～72%, active component B 1～72%, dispersant 5～10%, wetting agent 2～10%, filler add to 100%.
Active component polyoxin, active component B, dispersant, wetting agent, filler are mixed, in mixed cylinder, mix, after airslide disintegrating mill is pulverized, mix again, can be made into the wetting powder product of the present composition.
When making water dispersible granules, composition comprises following constituent content: active component polyoxin 1～72%, active component B 1～72%, dispersant 3～12%, wetting agent 1～8%, disintegrant 1～10%, binding agent 1～8%, filler add to 100%.
Active component polyoxin, active component B, dispersant, wetting agent, disintegrant, filler etc. are obtained to the particle diameter needing through air-flow crushing together, then add other auxiliary agents such as binding agent, obtain the materials of granulating.By item quantitatively send in fluidized bed granulation dryer through granulation and dry after, make the water dispersible granules product of the present composition.
The invention has the advantages that:
(1) polyoxin and methoxy acrylic bactericide composite after, there is notable synergistic and lasting effect;
(2) expanded fungicidal spectrum, the diseases such as downy mildew, epidemic disease, gray mold, powdery mildew, anthracnose, spot defoliation, leaf spot, scab, rust, rice blast have all been had to greater activity;
(3) the present invention not with an organic solvent, is difficult for producing poisoning, is convenient to transportation and storage;
(4) reduce the dosage of agricultural chemicals, reduced the residual quantity of agricultural chemicals on crop, alleviated environmental pollution.
Embodiment
Below in conjunction with embodiment, to further instruction of the present invention, the portion rate in embodiment is ratio of weight and number, but the present invention is not limited thereto.
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.
Application Example one
Example 1 60% polyoxin kresoxim-methyl wetting powder
Polyoxin 10%, kresoxim-methyl 50%, polyoxyethylene carboxylate 5%, Nekal BX 5%, bentonite add to 100%, and mixture carries out air-flow crushing, make 60% polyoxin kresoxim-methyl wetting powder.
Example 2 80% polyoxin kresoxim-methyl wetting powders
Polyoxin 30%, kresoxim-methyl 50%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 5%, lauryl sodium sulfate 4%, kaolin add to 100%, and mixture carries out air-flow crushing, make 80% polyoxin kresoxim-methyl wetting powder.
Example 3 50% polyoxin water dispersion granules agent of Kresoxim
Polyoxin 5%, kresoxim-methyl 45%, soapberry powder 5%, alkyl benzene sulfonate calcium salt 5%, ammonium sulfate 1%, bentonite add to 100%, mix and make 50% polyoxin water dispersion granules agent of Kresoxim.
Example 4 70% polyoxin water dispersion granules agent of Kresoxim
Polyoxin 15%, kresoxim-methyl 55%, wetting and penetrating agent F 4%, lignosulfonates 5%, urea 0.8%, bentonite add to 100%, mix and make 70% polyoxin water dispersion granules agent of Kresoxim.
Example 5 55% polyoxin ZJ0712 wetting powders
Polyoxin 5%, ZJ0712 50%, lignosulfonates 6%, wetting and penetrating agent F5%, kaolin add to 100%, and mixture carries out air-flow crushing, make 55% polyoxin ZJ0712 wetting powder.
Example 6 35% polyoxin ZJ0712 wetting powders
Polyoxin 30%, ZJ0712 5%, alkyl benzene sulfonate calcium salt 5%, spaonin powder 4%, white carbon add to 100%, and mixture carries out air-flow crushing, make 35% polyoxin ZJ0712 wetting powder.
Example 7 40% polyoxin ZJ0712 water dispersible granules
Polyoxin 30%, ZJ0712 10%, alkylphenol-polyethenoxy are phonetic 6%, lauryl sodium sulfate 5%, aluminium chloride 0.5%, bentonite 15%, diatomite add to 100%, mix and make 40% polyoxin ZJ0712 water dispersible granules.
Example 8 25% polyoxin ZJ0712 water dispersible granules
Polyoxin 5%, ZJ0712 20%, polyoxyethylene carboxylate 4%, silkworm excrement 5%, urea 0.2%, bentonite 10%, kaolin add to 100%, mix and make 25% polyoxin ZJ0712 water dispersible granules.
Example 9 60% polyoxin pyraclostrobin wetting powders
Polyoxin 20%, pyraclostrobin 40%, aryl phenol polyoxyethylene succinate sulfonate 8%, wetting and penetrating agent F 5%, attapulgite add to 100%, and mixture carries out air-flow crushing, make 60% polyoxin pyraclostrobin wetting powder.
Example 10 80% polyoxin pyraclostrobin wetting powders
Polyoxin 25%, pyraclostrobin 55%, lignosulfonates 7%, spaonin powder 5%, white carbon add to 100%, and mixture carries out air-flow crushing, make 80% polyoxin pyraclostrobin wetting powder.
Example 11 50% polyoxin pyraclostrobin water dispersible granules
Polyoxin 15%, pyraclostrobin 35%, naphthalene sulfonic acid-formaldehyde condensation product 6%, soapberry powder 4%, aluminium chloride 1%, bentonite add to 100%, mix and make 50% polyoxin pyraclostrobin water dispersible granules.
Example 12 15% polyoxin pyraclostrobin water dispersible granules
Polyoxin 5%, pyraclostrobin 10%, lignosulfonates 3%, Nekal BX 5%, ammonium sulfate 1%, bentonite add to 100%, mix and make 15% polyoxin pyraclostrobin water dispersible granules.
Example 13 45% polyoxin Enestroburin wetting powders
Polyoxin 15%, Enestroburin 30%, alkyl benzene sulfonate calcium salt 7%, silkworm excrement 5%, diatomite add to 100%, and mixture carries out air-flow crushing, make 45% polyoxin Enestroburin wetting powder.
Example 14 80% polyoxin Enestroburin wetting powders
Polyoxin 20%, Enestroburin 60%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 8%, soapberry powder 6%, white carbon add to 100%, and mixture carries out air-flow crushing, make 80% polyoxin Enestroburin wetting powder.
Example 15 36% polyoxin Enestroburin water dispersible granules
Polyoxin 6%, Enestroburin 30%, lignosulfonates 6%, wetting and penetrating agent F5%, ammonium sulfate 1.2%, bentonite add to 100%, mix and make 36% polyoxin Enestroburin water dispersible granules.
Example 16 5% polyoxin Enestroburin water dispersible granules
Polyoxin 2%, Enestroburin 3%, alkylnaphthalene sulfonate 6%, spaonin powder 4%, ammonium sulfate 1%, bentonite 10%, kaolin add to 100%, mix and make 5% polyoxin Enestroburin water dispersible granules.
Example 17 60% polyoxin Fluoxastrobin wetting powders
Polyoxin 10%, Fluoxastrobin 50%, aryl phenol polyoxyethylene succinate sulfonate 6%, wetting and penetrating agent F 5%, attapulgite add to 100%, and mixture carries out air-flow crushing, make 60% polyoxin Fluoxastrobin wetting powder.
Example 18 80% polyoxin Fluoxastrobin wetting powders
Polyoxin 8%, Fluoxastrobin 72%, lignosulfonates 4%, spaonin powder 5%, kaolin add to 100%, and mixture carries out air-flow crushing, make 80% polyoxin Fluoxastrobin wetting powder.
Example 19 50% polyoxin azoxystrobin water dispersible granules
Polyoxin 10%, Fluoxastrobin 40%, naphthalene sulfonic acid-formaldehyde condensation product 6%, soapberry powder 4%, aluminium chloride 0.8%, bentonite add to 100%, mix and make 50% polyoxin azoxystrobin water dispersible granule.
Example 20 60% polyoxin azoxystrobin water dispersible granules
Polyoxin 15%, Fluoxastrobin 45%, lignosulfonates 4%, Nekal BX 5%, ammonium sulfate 1%, bentonite add to 100%, mix and make 60% polyoxin azoxystrobin water dispersible granule.
The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.The embodiment of the present invention is the method that adopts Toxicity Determination and field trial to combine.First pass through Toxicity Determination, synergy ratio (SR) after clear and definite two kinds of medicaments are composite by a certain percentage, SR < 0.5 is antagonism, 0.5≤SR≤1.5 are summation action, SR > 1.5 is synergistic effect, on this basis, then carry out field trial.
The composite Toxicity Determination to target of polyoxin and active component B (B is selected from a kind of of Fluoxastrobin, kresoxim-methyl, ZJ0712, pyraclostrobin, Enestroburin).
After the effective inhibition concentration scope of each medicament is determined in prerun, each medicament is established respectively 5 dosage by active constituent content and is processed, and establishes clear water contrast.With reference to < < farm-chemical indoor determination test rule bactericide > >, carry out, adopt mycelial growth rate method to measure the virulence of medicament to target fungus.After 72h, by right-angled intersection method, measure colony diameter, calculate and respectively process net growth, mycelial growth inhibition rate.
Net growth (mm)=measurement colony diameter-5
Mycelial growth inhibition rate is converted into probit value (y), and liquor strength (μ g/mL) converts logarithm value (x) to, with method of least squares, tries to achieve virulence regression equation (y=a+bx), and calculates thus the EC of every kind of medicament
50value.According to Wadley method, calculate the different proportioning synergy ratio (SR) of two medicaments, SR < 0.5 is antagonism simultaneously, and 0.5≤SR≤1.5 are summation action, and SR > 1.5 is synergistic effect.Computing formula is as follows:
Wherein: a, b are respectively active component polyoxin and B (Fluoxastrobin, kresoxim-methyl, ZJ0712, pyraclostrobin, Enestroburin) shared ratio in combination;
A is polyoxin;
B is a kind of in Fluoxastrobin, kresoxim-methyl, ZJ0712, pyraclostrobin, Enestroburin.
Implementation of an application example two:
Polyoxin and azoxystrobin compound are to graw mold of tomato Toxicity Determination
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining polyoxin, the former medicine of Fluoxastrobin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 1 polyoxin, Fluoxastrobin and the composite toxicity test analysis of results table to graw mold of tomato thereof
As shown in Table 1, polyoxin, the EC of Fluoxastrobin to graw mold of tomato
50be respectively 1.24mg/L and 1.89mg/L.Polyoxin compares at 72: 1 to 1: 72 o'clock with Fluoxastrobin, synergy ratio SR is all greater than 1.5, illustrate that polyoxin and kresoxim-methyl were mixed in scope and all show synergistic effect at 72: 1 to 1: 72, especially when the two proportioning is during at 18: 1 to 1: 18, synergistic effect is more obviously outstanding, wherein when polyoxin and Fluoxastrobin weight ratio are 1: 1, synergy ratio SR is maximum, and synergistic effect is the most obvious.
Implementation of an application example three polyoxins and kresoxim-methyl are composite to apple mildew Toxicity Determination
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining polyoxin, the former medicine of kresoxim-methyl and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 2 polyoxin, kresoxim-methyl and the composite toxicity test analysis of results table to apple mildew thereof
As shown in Table 2, polyoxin, the EC of kresoxim-methyl to apple mildew
50be respectively 1.51mg/L and 1.66mg/L.The virulence of kresoxim-methyl is higher than the virulence of polyoxin.Polyoxin and kresoxim-methyl proportioning were at 72: 1 to 1: 72 o'clock, synergy ratio SR is all greater than 1.5, illustrate that polyoxin and kresoxim-methyl were mixed in scope and all show synergistic effect at 72: 1 to 1: 72, especially when the two proportioning is during at 18: 1 to 1: 18, synergistic effect is more obviously outstanding, wherein when polyoxin and kresoxim-methyl weight ratio are 1: 1, synergy ratio SR is maximum, and synergistic effect is the most obvious.
Implementation of an application example four polyoxins and ZJ0712 are composite to powdery mildew of cucumber Toxicity Determination.
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining polyoxin, the former medicine of ZJ0712 and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 3 polyoxin, ZJ0712 and the composite toxicity test analysis of results table to powdery mildew of cucumber thereof
As shown in Table 3, polyoxin, the EC of ZJ0712 to powdery mildew of cucumber
50be respectively 1.35mg/L and 0.14mg/L.The virulence of ZJ0712 is higher than the virulence of polyoxin.Polyoxin and ZJ0712 proportioning were at 72: 1 to 1: 72 o'clock, synergy ratio SR is all greater than 1.5, illustrate that polyoxin and ZJ0712 were mixed in scope and all show synergistic effect at 72: 1 to 1: 72, especially when the two proportioning is during at 18: 1 to 1: 6, synergistic effect is more obviously outstanding, wherein when polyoxin and ZJ0712 weight ratio are 3: 1, synergy ratio SR is maximum, and synergistic effect is the most obvious.
Implementation of an application example five
Polyoxin and pyraclostrobin are composite to sigatoka Toxicity Determination.
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining polyoxin, the former medicine of pyraclostrobin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 4 polyoxin, pyraclostrobin and the composite toxicity test analysis of results table to sigatoka thereof
As shown in Table 4, polyoxin, the EC of pyraclostrobin to sigatoka
50be respectively 1.67mg/L and 1.69mg/L.The virulence of pyraclostrobin is higher than the virulence of polyoxin.Polyoxin and pyraclostrobin proportioning were at 72: 1 to 1: 72 o'clock, synergy ratio SR is all greater than 1.5, illustrate that polyoxin and pyraclostrobin were mixed in scope and all show synergistic effect at 72: 1 to 1: 72, especially when the two proportioning is during at 18: 1 to 1: 18, synergistic effect is more obviously outstanding, wherein when polyoxin and pyraclostrobin weight ratio are 1: 1, synergy ratio SR is maximum, and synergistic effect is the most obvious.
Implementation of an application example six:
Polyoxin and Enestroburin are composite to downy mildew of garpe Toxicity Determination.
Test medicine provides by Shaanxi Mei Bang agricultural chemicals Co., Ltd.
Experimental scheme: effective inhibition concentration scope of determining polyoxin, the former medicine of Enestroburin and the two different proportioning mixture through preliminary experiment.
Toxicity test result
Table 5 polyoxin, Enestroburin and the composite toxicity test analysis of results table to downy mildew of garpe thereof
As shown in Table 5, polyoxin, the EC of Enestroburin to downy mildew of garpe
50be respectively 1.77mg/L and 1.35mg/L.The virulence of Enestroburin is higher than the virulence of polyoxin.Polyoxin compares at 72: 1 to 1: 72 o'clock with Enestroburin, synergy ratio SR is all greater than 1.5, illustrate that polyoxin and Enestroburin were mixed in scope and all show synergistic effect at 72: 1 to 1: 72, especially when the two proportioning is during at 18: 1 to 1: 18, synergistic effect is more obviously outstanding, wherein when polyoxin and Enestroburin weight ratio are 1: 1, synergy ratio SR is maximum, and synergistic effect is the most obvious.
Application Example seven polyoxins and kresoxim-methyl and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Liquan County, Xianyang, Shanxi province city, and test medicine is researched and developed, provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 10% polyoxin wetting powder (commercial), 50% water dispersion granules agent of Kresoxim (commercial).
Investigation apple mildew disease index before medicine, in their early stage dispenser, dispenser for the second time after 7 days, dispenser is 3 times altogether, within after dispenser 7 days, 14 days for the third time, investigates disease indexs and calculates preventive effect.Experimental result is as follows:
Table 6 polyoxin, kresoxim-methyl and the composite apple mildew test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 6, after polyoxin and kresoxim-methyl are composite, can effectively prevent and treat apple mildew, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example eight polyoxins and ZJ0712 and the composite powdery mildew of cucumber test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in suburb, Rizhao City, Shandong Province, and test medicine is researched and developed, provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 10% polyoxin wetting powder (commercial), 10% ZJ0712 suspending agent (commercial).
The investigation powdery mildew of cucumber state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after dispenser 7 days, 14 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 7 polyoxin, ZJ0712 and the composite powdery mildew of cucumber test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 7, after polyoxin and ZJ0712 are composite, can effectively prevent and treat powdery mildew of cucumber, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example nine polyoxins and pyraclostrobin and the composite leaf spot of peanut test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Wei Qiu township, Yan Feng county, Henan Province, and test medicine is provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 10% polyoxin wetting powder (commercial), 25% pyraclostrobin missible oil (commercial).
The investigation leaf spot of peanut state of an illness before medicine, in the dispenser for the first time of state of an illness initial stage, once, dispenser is 2 times altogether in dispenser in every 7 days.Within after dispenser 7 days, 14 days for the second time, investigate respectively disease index and calculate preventive effect.Experimental result is as follows:
Table 8 polyoxin, pyraclostrobin and the composite leaf spot of peanut test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 8, after polyoxin and pyraclostrobin are composite, can effectively prevent and treat leaf spot of peanut, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example ten polyoxins and Enestroburin and the composite downy mildew of garpe test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Weinan City Pucheng County, Shaanxi Province, and test medicine is researched and developed, provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 10% polyoxin wetting powder (commercial), 25% Enestroburin missible oil (commercial).
Investigation downy mildew of garpe disease index before medicine, in their early stage dispenser, dispenser for the second time after 7 days, dispenser is 3 times altogether, within after dispenser 7 days, 14 days for the second time, investigates disease indexs and calculates preventive effect.Experimental result is as follows:
Table 9 polyoxin, Enestroburin and the composite downy mildew of garpe test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 9, after polyoxin and Enestroburin are composite, can effectively prevent and treat downy mildew of garpe, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Application Example 11 polyoxins and Fluoxastrobin and the composite wheat rust test of pesticide effectiveness of preventing and treating thereof
This experimental establishment is in Dancheng County, Henan Province, and test medicine is researched and developed, provided by Shaanxi Mei Bang agricultural chemicals Co., Ltd, contrast medicament 10% polyoxin wetting powder (commercial), 50% azoxystrobin water dispersible granule (commercial).
Investigation wheat rust disease index before medicine, in their early stage dispenser, dispenser for the second time after 10 days, dispenser is 2 times altogether, within after dispenser 7 days, 14 days for the second time, investigates disease indexs and calculates preventive effect.Experimental result is as follows:
Table 10 polyoxin, Fluoxastrobin and the composite wheat rust test of pesticide effectiveness of preventing and treating thereof
As can be seen from Table 10, after polyoxin and azoxystrobin compound, can effectively prevent and treat wheat rust, control efficiency is all better than the preventive effect of single dose.In test scope of medication, target crop is had no adverse effects.
Claims (6)
1. containing a bactericidal composition for polyoxin and methoxy acrylic, comprise effective active component, auxiliary agent, it is characterized in that: active ingredient is A and B, A, B ratio of weight and number are 1:72～72:1, and described A is polyoxin, and B is Fluoxastrobin.
2. according to the bactericidal composition described in claim l, it is characterized in that: the ratio of weight and number of A, two kinds of active components of B is 1:18～18:1.
3. bactericidal composition according to claim 2, is characterized in that: the ratio of weight and number of polyoxin and Fluoxastrobin is 1:9～9:1.
4. according to the bactericidal composition described in claim l, it is characterized in that: wherein effective active composition accounts for 5%～80% of gross weight.
5. according to the bactericidal composition described in claim l, be used for preventing and treating the application of the disease on vegetables, fruit tree and cereal crop.
6. application according to claim 5, is characterized in that: described disease comprises downy mildew, epidemic disease, gray mold, powdery mildew, anthracnose, spot defoliation, leaf spot, scab, rust, rice blast.
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| CN102239862A (en) * | 2011-05-27 | 2011-11-16 | 江苏省绿盾植保农药实验有限公司 | Compound bactericide of azoxystrobin and polyoxin |
| CN103621562B (en) * | 2012-08-23 | 2015-09-09 | 陕西美邦农药有限公司 | A kind of bactericidal composition |
| CN105211063B (en) * | 2012-09-13 | 2018-01-16 | 冀梦菲 | A kind of bactericidal composition containing dimoxystrobin and antibioticses |
| CN104351254B (en) * | 2014-10-30 | 2016-09-14 | 陕西麦可罗生物科技有限公司 | A kind of containing Nikemycin with the bactericidal composition of Fluoxastrobin |
| CN106857545A (en) * | 2017-04-23 | 2017-06-20 | 佛山市瑞生通科技有限公司 | A kind of bactericidal composition of the mycin of second containing fen and Enestroburin |
| CN106857546A (en) * | 2017-04-28 | 2017-06-20 | 佛山市瑞生通科技有限公司 | Bactericidal composition and its application containing trifloxystrobin and fen second mycin |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007104677A1 (en) * | 2006-03-14 | 2007-09-20 | Basf Se | Method of inducing tolerance of plants against bacterioses |
| CN101233855A (en) * | 2008-01-17 | 2008-08-06 | 张少武 | Bactericide agent composition containing polyoxin having synergistic interaction and uses thereof |
| CN101253864A (en) * | 2008-03-28 | 2008-09-03 | 中国农业大学 | Bactericial composition containing maneb zincium and methoxyl group acrylic ester series bactericidal agent |
| CN101379984A (en) * | 2008-07-04 | 2009-03-11 | 张少武 | Bactericidal composition containing azoxystrobin and carbendazim and use thereof |
| CN101653131A (en) * | 2009-07-31 | 2010-02-24 | 深圳诺普信农化股份有限公司 | Bactericidal composition containing azoxystrobin |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4423612A1 (en) * | 1994-07-06 | 1996-01-11 | Basf Ag | 2 - [(Dihydro) pyrazolyl-3'-oxymethylene] anilides, process for their preparation and their use |
| CN101248793B (en) * | 2008-03-12 | 2011-06-15 | 王英姿 | Bactericial composition containing pyrazole aether bacterium ester and multiple anti-teichomycin and uses thereof |
-
2011
- 2011-01-20 CN CN201110022960.4A patent/CN102067851B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007104677A1 (en) * | 2006-03-14 | 2007-09-20 | Basf Se | Method of inducing tolerance of plants against bacterioses |
| CN101233855A (en) * | 2008-01-17 | 2008-08-06 | 张少武 | Bactericide agent composition containing polyoxin having synergistic interaction and uses thereof |
| CN101253864A (en) * | 2008-03-28 | 2008-09-03 | 中国农业大学 | Bactericial composition containing maneb zincium and methoxyl group acrylic ester series bactericidal agent |
| CN101379984A (en) * | 2008-07-04 | 2009-03-11 | 张少武 | Bactericidal composition containing azoxystrobin and carbendazim and use thereof |
| CN101653131A (en) * | 2009-07-31 | 2010-02-24 | 深圳诺普信农化股份有限公司 | Bactericidal composition containing azoxystrobin |
Non-Patent Citations (2)
| Title |
|---|
| 刘长令 等.广谱高效杀菌剂嘧菌酯.《世界农药》.2002,第24卷(第1期),参见第46-49页. |
| 广谱高效杀菌剂嘧菌酯;刘长令 等;《世界农药》;20020225;第24卷(第1期);参见第46-49页 * |
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