CN101999349A - D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren - Google Patents
D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren Download PDFInfo
- Publication number
- CN101999349A CN101999349A CN201010599201XA CN201010599201A CN101999349A CN 101999349 A CN101999349 A CN 101999349A CN 201010599201X A CN201010599201X A CN 201010599201XA CN 201010599201 A CN201010599201 A CN 201010599201A CN 101999349 A CN101999349 A CN 101999349A
- Authority
- CN
- China
- Prior art keywords
- ant
- nest
- citrene
- oil
- killing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a d-limonene-containing mixed oil agent for killing solenopsis invicta buren and a method for killing the solenopsis invicta buren. The d-limonene-containing mixed oil agent consists of 80 to 90 percent of d-limonene and 10 to 20 percent of edible vegetable oil in percentage by volume. The method for killing the solenopsis invicta buren comprises the step of placing a carrier adsorbing the d-limonene-containing mixed oil agent into solenopsis invicta buren nests, wherein the using amount of the d-limonene-containing mixed oil agent in each nest is 10 to 50 ml. In the d-limonene-containing mixed oil agent and the method for killing the solenopsis invicta buren, the high volatility of the d-limonene can permeate the nests and wax protective layers of all the individual body surfaces of the solenopsis invicta buren in the nests can be damaged through high permeability of the d-limonene, so the blockage of the spiracles of the solenopsis invicta buren can cause asphyxiation and death of the solenopsis invicta buren; the edible vegetable oil has unique oil odor, so the number of solenopsis invicta buren escaping from the nests caused by the repelling reaction to the d-limonene can be reduced; the d-limonene-containing mixed oil agent enters the nests quickly by a cave administration method, so that all the individuals including the queen ant in each nest can be killed quickly and the aim of killing the solenopsis invicta buren nests is fulfilled.
Description
Technical field:
The invention belongs to the insect control field, be specifically related to the miscible oil that contains the d-citrene of a kind of red fire ant extremely and use the method that this contains the miscible oil killing red ant of d-citrene.
Background technology:
Red fire ant is a kind of very harmful and be listed in the world one of tool invasion property and destructive 100 kinds of pests to human and livestock health, agricultural production, ecotope and communal facility.Red fire ant stings when stinging human body, repeatedly injects rapidly the venom that contains the high concentration toxin in skin, causes pain as the violent calcination, causes red swelling of the skin and produces the purulence bubble, and allergy sufferers high fever can occur, feels sick, chest pain, shock even death.Red fire ant originates in South America Parana basin, and the '20s invasion in last century U.S. causes serious harm, is diffused into a plurality of countries such as West Indian Ocean Isle, New Zealand and Puerto Rico subsequently.Though external tag or with the multiple measure prevention and control such as period poison bait of insect growth regulator, IGR preparation, red fire ant still spreads in many countries at present through adopting decades with chemical agent.U.S.'s scholarly forecast, the wide geographic area in middle Mexico, Central America, close on surrounding area, Mediterranean, the Caspian Sea and Black Sea in the neighbourhood, many countries and regions such as most area, Africa, India, the southeast, Asia, Middle East, Japan south, Korea S south all are that the potential invasion of red fire ant is regional.Red fire ant is by the anthropochory that may bring in diffusion and the world economy and trade naturally, worldwide extensively invasion, and the mankind face the serious threat that red fire ant endangers.
Found red fire ant in 2003 in China Taiwan, subsequently in Hong Kong, the part area of provinces and regions such as Macao, Guangdong, Guangxi, Hunan and Fujian takes place in succession, and is diffusion and spreads situation, the national Ministry of Agriculture has classified it as quarantine property insect.Xue Dayong etc. (2005) adopt the parameter of U.S.'s fitting of distribution, utilize CLIMEX and GARP2 kind methods analyst result to show respectively, China south China, East China, Central China and southwest totally 25 provinces and cities and North China some areas, the north in addition can to arrive the area, Hebei will be that the potential invasion of red fire ant is regional.The greenhouse culture of global warming and crop provides suitable existence and procreation condition for red fire ant, and therefore, red fire ant is also spread the area to the north of prediction distribution circle.China's scholarly forecast is not eradicated if do not adopt an effective measure, and can cause 1280.4 hundred million yuans economic loss at following 35 years.Red fire ant can't be calculated especially to the loss that environmental disruption causes.To this, the Ministry of Agriculture had worked out " national red fire ant epidemic situation is eradicated plan " (farming is done farming [2005] No. 51) in 2005.The characteristics that, diffusion fast according to the red fire ant reproduction speed spread rapidly, be difficult to eradicate after invade successfully are very difficult processes in the target of China realization elimination red fire ant.
Though brought into play strong effect with chemical insecticide prevention and control red fire ant both at home and abroad, long-term a large amount of chemical insecticides that use certainly will pollute soil and water resource, then the mankind are caused potential very big harm after pollutant enters food chain.Along with the improvement of the progress of society, expanding economy and people's life, human food hygiene and Environmental security consciousness improve gradually, and people urgently wish with nuisanceless, of low pollution and the effective traditional pest control with insecticide medicament of the anti-control products replacement of insect.
At present the d-citrene that is applied to food industry and chemical engineering industry is mixed with low toxic pesticide in extensive use aspect sanitary insect pest and the agricultural insect pests control as pesticide synergistic agent and agricultural chemicals both at home and abroad, and quick-acting with it, toxicity is low, residual characteristics such as low and chemical pesticide match in excellence or beauty.In recent years China has reported chemical agent for preventing and curing lepidopterous, coleoptera, Hymenoptera, Homoptera and the Diptera pest research of doing synergist preparation with the d-citrene, and Yuan Zhenguo (on 03 10th, 2004) has invented the insects such as Lepidoptera cabbage caterpillar, prodenia litura, diamond-back moth, aphid that are used to prevent and treat crops with the d-citrene bio-synergistic insecticide of d-citrene, pyrethroid, emulsifier and solvent preparation; Li Jianlin (on 02 13rd, 2008) has invented a kind of highly effective environment-friendly type biological insecticide that combines with d-citrene, nimbin, emulsifier and solvent, can any environment field close and the fruit and vegetable food of immediate access on use; Mention in He Cuijuan, song letter (2008) " application and the DEVELOPMENT PROSPECT of d one citrene bio-synergistic insecticide in the agricultural production " literary composition, the indoor and outdoor of brassicaceous vegetable insect aphid (Lipaphis erysimi), cabbage caterpillar (Pieris rapae), diamond-back moth (Plutella xylostella), beet armyworm (Laphygma exigua) larva and camphor tree camphor tree nest snout moth's larva in Lepidoptera, the Homoptera is tested the control efficiency that all reaches more than 85% with d-citrene bio-synergistic insecticide development product " 37% feels happy missible oil "; Or the like.
The external method that once adopted suds to make surfactant and d-citrene and water mixed liquid perfusion ant nest is handled single anthill, or with d-citrene, turpentine oil, pyrethroid etc. and water mixed perfusion anthill, irritate nest no matter adopt which kind of intermixture, all emphasize to fill with whole ant nest, guarantee that whole ant nest is saturated by soup fully.Above method weak point be dosage big, waste time and energy, cost is high, particularly place far away is more inconvenient in dried up source.
Summary of the invention:
The purpose of this invention is to provide the miscible oil that contains the d-citrene of a kind of red fire ant extremely and use the method that this contains the miscible oil killing red ant of d-citrene, utilize this miscible oil that contains the d-citrene according to method killing red ant of the present invention, have simple to operation, dosage is few, the advantage that cost is low, and, be the method for the killing red ant of a kind of environmental protection, highly effective and safe to ecological environment security.
The miscible oil that contains the d-citrene that kills red fire ant of the present invention is characterized in that, by total volume fraction 100%, is made up of d-citrene 80%～90% and edible vegetable oil 10%～20%.
The described miscible oil that contains the d-citrene by total volume fraction 100%, is preferably: described d-citrene is 90%, and edible vegetable oil is 10%.
Described edible vegetable oil is preferably peanut oil, rapeseed oil, sesame oil, sunflower seed oil or soybean oil.
Application of the present invention contains the method for the miscible oil killing red ant of d-citrene, it is characterized in that, may further comprise the steps: the carrier that will be adsorbed with the miscible oil of the described d-of the containing citrene of claim 1 is put into the red fire ant ant nest, and the every nest consumption that contains the miscible oil of d-citrene is 10～50ml.
Described carrier is preferably sponge.
Preferably, the method of described killing red ant is: in red fire ant anthill center, get into the cave vertically downward at the bottom of nest, the sponge block that will be adsorbed with the miscible oil that contains the d-citrene then drops in the cave, the sealing hole, the every nest consumption that contains the miscible oil of d-citrene is 10～50ml.By this mode dispenser, than being easier to operation, less to the red fire ant disturbance in the ant nest, control efficiency is good.
Described in red fire ant anthill center, the iron staff with Φ 3～6cm of getting into the cave vertically downward at the bottom of the nest preferably produces the cave at the bottom of being inserted to nest in the anthill center under vertical.
The miscible oil that contains the d-citrene that kills red fire ant of the present invention is preparation like this, content by the each component of the miscible oil that contains the d-citrene, measure d-citrene and edible vegetable oil respectively, with both mixing and stirring, promptly obtain the miscible oil that contains the d-citrene that kills red fire ant of the present invention then.
The inventor finds through experiment, if use in the input cave of the sponge block that only is adsorbed with the d-citrene, seal the hole then, the d-citrene also can volatilize, in nest, fully fill the air, but the effect of control is not fine, can not reach the purpose of killing red ant ant nest, in the 2m of some ant nest scope, new ant nest is arranged again.After experiment finds that this is that when the d-citrene volatilized, some red fire ant may be fled from ant nest rapidly, sets up new ant nest, thereby has influenced control efficiency because the d-citrene has repellent action to red fire ant.The inventor forms the miscible oil that contains the d-citrene by d-citrene and edible vegetable oil are matched, reduce the repellent reaction of red fire ant by the unique salted cake fried in sesame oil smell of edible vegetable oil, thereby improve the insect killing effect of d-citrene red fire ant to the d-citrene.
The present invention puts into the red fire ant ant nest with the miscible oil that contains the d-citrene of 10～50ml by absorption carrier; the miscible oil that contains the d-citrene fully fills the air in nest with its good volatile performance; and destroy the wax protective layer of all individual body surfaces of red fire ant in nest with its powerful permeance property; causing red fire ant ventilation hole obstruction to cause to be choked to death dies; thereby kill all individualities that comprise queen in the nest fast, reach the purpose of killing red ant ant nest.Compare with the method for the water mixed liquid perfusion ant nest of other materials with d-citrene of the prior art, the present invention need not to fill whole ant nest, but utilize the volatility of killing the red fire ant miscible oil to fill the air whole ant nest, kill red fire ant, therefore the present invention have simple to operation, time saving and energy saving, drug dose is few, cost is low, the nest obvious results advantage of all can using and go out throughout the year, this method is the innovation of adopting on the d-citrene killing red ant method.
Active ingredient d-citrene in the miscible oil that contains the d-citrene that the present invention adopts is a kind of degreasing solvent that can be degraded fully by biology, be the nontoxic fully natural green environment-friendly products of food-grade, regarded as the solvent of GRAS (safety) level and be widely used in pharmaceutical industry by Food and Drug Administration (FDA), and batching edible vegetable oil is the daily edible oil and fat of people, unique salted cake fried in sesame oil smell can reduce the repellent reaction of red fire ant to the d-citrene, thereby improves the insect killing effect of d-citrene to red fire ant.The miscible oil that contains the d-citrene that the present invention adopts is the medicament of the killing red ant ant nest of a kind of environmental protection to ecological environment security, highly effective and safe.Therefore the present invention can be applicable in the strategic objective of eradicating red fire ant.
Embodiment:
Below be to further specify to of the present invention, rather than limitation of the present invention.
One, preparation contains the miscible oil of d-citrene
Content by the miscible oil each component that contains the d-citrene is measured d-citrene and edible vegetable oil respectively, then both is mixed, and stirs.
Wherein, by total volume fraction 100%, contain the miscible oil of d-citrene, form for I number by d-citrene 80% and peanut oil 20%; Contain the miscible oil of d-citrene II number, form by d-citrene 85% and peanut oil 15%; Contain the miscible oil of d-citrene III number, form by d-citrene 90% and peanut oil 10%.
Experiment place: sub-district 1
1. sponge being cut into specification is 3 * 3 * 3cm fritter, and each sponge block splashes into I, the II of 10ml or the miscible oil that contains the d-citrene III number.Compare with same method with pure d-citrene and edible vegetable oil.
2. to the ripe movable ant nest of the red fire ant of anthill Φ 20～40cm, at the bottom of being inserted to nest in the anthill center under vertical with the iron staff of Φ 3cm, fill in from extracting in the cave that stays behind the iron staff with 1～5 in the sponge that tweezers will adsorb 10ml I, II or contain the miscible oil of d-citrene for III number, the quantity of sponge block is determined according to the size of ant nest, seal the hole with earth then, 15 repetitions are established in each test.The ant nest of contrast vertically bores down in nest in the anthill center with iron staff equally and bores a hole until the bottom of nest, after extracting iron staff out, throw in the sponge block that contains edible vegetable oil or contain pure d-citrene of experimental group equivalent respectively in contrast, seal with earth then, 15 repetitions are established in each contrast.
3. dispensing back the 7th day excavates to throw in spud and is adsorbed with I, II or contains the miscible oil of d-citrene for III number and the ant nest inspection of the sponge block of pure d-citrene, the method for digging nest: at first dig the edge of anthill, check whether also have dead worker ant; Excavate the ant nest center again, dig the ant nest bottom always, carefully search dead ant corpse (comprising queen) while digging; Check at last whether whether anthill has new ant nest in the 2m on every side, cause the red fire ant transfer to judge the d-citrene.
Insert in the contrast nest of throwing in the sponge block that is adsorbed with edible vegetable oil with iron wire, check red fire ant survival condition in the nest.
4. test back was dug the nest check result on the 7th day and is:
Every nest is thrown in 15 nests that are adsorbed with 1～5 of the miscible oil sponge block that contains the d-citrene for 10ml I number, have in the 2 nest nests small number of activity worker ant is arranged, worker ant activity more than 200 is arranged around the table of mound, movable red fire ant is not seen in 13 nests and anthill edge, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest rate of going down is 86.6%.
Every nest is thrown in 15 nests that are adsorbed with 1～5 of the miscible oil sponge block that contains the d-citrene for 10ml II number, have in the 1 nest nest small number of activity worker ant is arranged, worker ant activity more than 200 is arranged around the table of mound, movable red fire ant is not seen in 14 nests and anthill edge, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest rate of going down is 93.3%.
Every nest is thrown in 15 nests that are adsorbed with 1～5 of the miscible oil sponge block that contains the d-citrene for 10mlIII number, movable red fire ant is not seen in 15 nests and anthill edge, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest rate of going down is 100%.
Above-mentioned input is adsorbed with I, II and contains for III number in the peripheral 2m of anthill of test ant nest of miscible oil of d-citrene and there is no new red fire ant ant nest.
Every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with the pure d-citrene of 10ml, do not see movable red fire ant inside and outside 12 ant nests, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, the anthill edge of all the other 3 ant nests has than the multi-activity worker ant, in the peripheral 2m of anthill 1～2 tiny anthill is arranged.
The red fire ant that every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with 10ml peanut oil is movable normal.
Embodiment 2:
Experiment place: sub-district 2
This is identical with embodiment 1 for the present embodiment subbase, and the place difference of experiment just experimentizes in the place of present embodiment according to the method for embodiment 1.The test back was dug the nest check result on the 7th day and is:
Every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with the miscible oil that contains the d-citrene for 10ml I number, have in the 1 nest nest small number of activity worker ant is arranged, worker ant activity more than 200 is arranged around the table of mound, movable red fire ant is not seen in 14 nests and anthill edge, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest rate of going down is 93.3%.
Every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with the miscible oil that contains the d-citrene for 10ml II number, have in the 1 nest nest small number of activity worker ant is arranged, worker ant activity more than 200 is arranged around the table of mound, movable red fire ant is not seen in 14 nests and anthill edge, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest rate of going down is 93.3%.
Every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with the miscible oil that contains the d-citrene for 10ml III number, have in the 1 nest nest small number of activity worker ant is arranged, worker ant activity more than 200 is arranged around the table of mound, movable red fire ant is not seen in 14 nests and anthill edge, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest rate of going down is 93.3%.
Above-mentioned input is adsorbed with I, II and contains for III number in the peripheral 2m of anthill of test ant nest of miscible oil of d-citrene and there is no new red fire ant ant nest.
Every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with the pure d-citrene of 10ml, do not see movable red fire ant inside and outside 13 ant nests, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, the anthill edge of all the other 2 ant nests has than the multi-activity worker ant, in the peripheral 2m of anthill 1 tiny anthill is arranged respectively.
The red fire ant that every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with 10ml peanut oil is movable normal.
Embodiment 3:
Experiment place: sub-district 3
This is identical with embodiment 1 for the present embodiment subbase, and the place difference of experiment just experimentizes in the place of present embodiment according to the method for embodiment 1.The test back was dug the nest check result on the 7th day and is:
Every nest is thrown in 15 nests of 1～5 of sponge block of the miscible oil that I number of being adsorbed with 10ml contain the d-citrene, have in the 1 nest nest small number of activity worker ant is arranged, worker ant activity more than 200 is arranged around the table of mound, movable red fire ant is not seen in 14 nests and anthill edge, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest rate of going down is 93.3%.
Every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with the miscible oil that contains the d-citrene for 10ml II number, have in the 1 nest nest small number of activity worker ant is arranged, worker ant activity more than 200 is arranged around the table of mound, movable red fire ant is not seen in 14 nests and anthill edge, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest rate of going down is 93.3%.
Every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with the miscible oil that contains the d-citrene for 10ml III number, movable red fire ant is not seen in 15 nests and anthill edge, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, and the ant nest rate of going down is 100%.
Above-mentioned input is adsorbed with I, II and contains for III number in the peripheral 2m of anthill of test ant nest of miscible oil of d-citrene and there is no new red fire ant ant nest.
In 15 nests that the sponge block of the pure d-citrene of every nest input absorption 10ml is 1～5, do not see movable red fire ant inside and outside 13 ant nests, the interior ant corpse (comprise worker ant, pupa, wing breeding ants, queen and ovum are arranged) of nest is the mildew bacterium, the anthill edge of all the other 2 ant nests has than the multi-activity worker ant, in the peripheral 2m of anthill 1 and 2 tiny anthill is arranged respectively.
The red fire ant that every nest is thrown in 15 nests of 1～5 of the sponge block that is adsorbed with 10ml peanut oil is movable normal.
The result of three embodiment is as shown in table 1:
Table 1: the effect that contains the miscible oil killing red ant ant nest of d-citrene
More than the ripe movable ant nest of red fire ant of Φ 20～40cm is all selected in test, at the bottom of being inserted to nest in anthill centre of surface position under vertical with the iron staff of Φ 3cm, I with absorption 10ml, II, 1～5 of the sponge block that contains the miscible oil of d-citrene or d-citrene or edible vegetable oil for III number is rendered to and is extracted in the cave that stays behind the iron staff, live the hole with grave, input is adsorbed with I, II, the test nest number that contains the miscible oil of d-citrene for III number respectively is 45 ant nests, test has obtained containing for I number the d-citrene after 7 days the miscible oil nest effect of going out is 91.1%, the nest effect of going out that contains the miscible oil of d-citrene for II number is 93.3%, the nest effect 97.8% of going out that contains the miscible oil of d-citrene for III number, the nest effect of going out of pure d-citrene are 84.4% and edible vegetable oil result that red fire ant is had no adverse effects.Input is adsorbed with I, II and contains for III number in the peripheral 2m of anthill of test ant nest of miscible oil of d-citrene and there is no new red fire ant ant nest.And throw in the nest of the sponge block that is adsorbed with pure d-citrene, some anthill edge has than the multi-activity worker ant, and in the peripheral 2m of anthill 1～2 tiny anthill is arranged, and does not reach the desirable nest effect of going out.
Above embodiment explanation, the miscible oil that utilizes the d-of containing citrene of the present invention is according to method killing red ant of the present invention, can realize the purpose of killing red ant ant nest, red fire ant is had no adverse effects and the miscible oil that contains the d-citrene confirms that than the pure d-citrene nest obvious results result of going out edible vegetable oil has reduced the repellent reaction of red fire ant to the d-citrene from edible vegetable oil.
Utilize the miscible oil of (R)-4-isopropenyl-1-methyl-1-cyclohexene that contains of the present invention according to method killing red ant of the present invention, have that dosage is little, application method is easy, time saving and energy saving, the significant advantage of nest effect of all can using and go out throughout the year, therefore, the method is to adopt the technical innovation of (R)-4-isopropenyl-1-methyl-1-cyclohexene killing red ant.
Claims (7)
1. a miscible oil that contains the d-citrene that kills red fire ant is characterized in that, by total volume fraction 100%, is made up of d-citrene 80%～90% and edible vegetable oil 10%～20%.
2. the miscible oil that contains the d-citrene according to claim 1 is characterized in that, by total volume fraction 100%, described d-citrene is 90%, and edible vegetable oil is 10%.
3. the miscible oil that contains the d-citrene according to claim 1 and 2 is characterized in that, described edible vegetable oil is peanut oil, rapeseed oil, sesame oil, sunflower seed oil or soybean oil.
4. an application rights requires the method for the miscible oil killing red ant of the 1 described d-of containing citrene, it is characterized in that, may further comprise the steps: the carrier that will be adsorbed with the miscible oil of the described d-of the containing citrene of claim 1 is put into the red fire ant ant nest, and the every nest consumption that contains the miscible oil of d-citrene is 10～50ml.
5. the method for killing red ant according to claim 4 is characterized in that, described carrier is a sponge.
6. the method for killing red ant according to claim 5, it is characterized in that, it is in red fire ant anthill center that the described sponge that will be adsorbed with the miscible oil of the described d-of the containing citrene of claim 1 is put into the red fire ant ant nest, get into the cave vertically downward at the bottom of the nest, the sponge block that will be adsorbed with the miscible oil that contains the d-citrene then drops in the cave, the sealing hole.
7. the method for killing red ant according to claim 6 is characterized in that, and is described in red fire ant anthill center, and getting into the cave vertically downward at the bottom of the nest is at the bottom of iron staff with Φ 3～6cm is inserted to nest in the anthill center under vertical, to produce the cave.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010599201 CN101999349B (en) | 2010-12-21 | 2010-12-21 | D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010599201 CN101999349B (en) | 2010-12-21 | 2010-12-21 | D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101999349A true CN101999349A (en) | 2011-04-06 |
| CN101999349B CN101999349B (en) | 2013-02-27 |
Family
ID=43807237
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010599201 Active CN101999349B (en) | 2010-12-21 | 2010-12-21 | D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101999349B (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614492A (en) * | 2016-12-26 | 2017-05-10 | 宁德市植保植检站 | Preventing and controlling method for red-imported-fire-ant epidemic situation |
| CN106982808A (en) * | 2017-03-02 | 2017-07-28 | 广东省生物资源应用研究所 | A kind of termite bait, termite-killing trapping device and its manufacture method |
| CN108184829A (en) * | 2017-12-15 | 2018-06-22 | 广西壮族自治区农业科学院植物保护研究所 | A kind of red fire ant smoked kill composition |
| CN112825836A (en) * | 2021-02-24 | 2021-05-25 | 金华市恒安生物技术有限公司 | Red fire ant escape-prevention rapid processing technology |
| CN113180044A (en) * | 2021-04-23 | 2021-07-30 | 四川桐稷科技有限公司 | Solenopsis invicta pheromone attractant and killing agent containing the same |
| WO2023074396A1 (en) * | 2021-10-29 | 2023-05-04 | 信越化学工業株式会社 | Ant control agent and ant control method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1678191A (en) * | 2002-09-04 | 2005-10-05 | 托尔·迈克帕特兰德 | Ant spray containing D-limonene |
| WO2007031561A2 (en) * | 2005-09-16 | 2007-03-22 | W. Neudorff Gmbh Kg | Wide spectrum insecticide and miticide composition |
| CN101049106A (en) * | 2006-11-14 | 2007-10-10 | 红河森菊生物有限责任公司 | Oil preparation for trapping and killing cockroach by natural pyrethrum element and preparation method |
-
2010
- 2010-12-21 CN CN 201010599201 patent/CN101999349B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1678191A (en) * | 2002-09-04 | 2005-10-05 | 托尔·迈克帕特兰德 | Ant spray containing D-limonene |
| WO2007031561A2 (en) * | 2005-09-16 | 2007-03-22 | W. Neudorff Gmbh Kg | Wide spectrum insecticide and miticide composition |
| CN101049106A (en) * | 2006-11-14 | 2007-10-10 | 红河森菊生物有限责任公司 | Oil preparation for trapping and killing cockroach by natural pyrethrum element and preparation method |
Non-Patent Citations (2)
| Title |
|---|
| 《中国环保产业》 20010830 孟祥栋 "安全优良的植物源杀虫剂已投产" 第11页 权利要求1-8 , * |
| 孟祥栋: ""安全优良的植物源杀虫剂已投产"", 《中国环保产业》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106614492A (en) * | 2016-12-26 | 2017-05-10 | 宁德市植保植检站 | Preventing and controlling method for red-imported-fire-ant epidemic situation |
| CN106982808A (en) * | 2017-03-02 | 2017-07-28 | 广东省生物资源应用研究所 | A kind of termite bait, termite-killing trapping device and its manufacture method |
| CN108184829A (en) * | 2017-12-15 | 2018-06-22 | 广西壮族自治区农业科学院植物保护研究所 | A kind of red fire ant smoked kill composition |
| CN112825836A (en) * | 2021-02-24 | 2021-05-25 | 金华市恒安生物技术有限公司 | Red fire ant escape-prevention rapid processing technology |
| CN113180044A (en) * | 2021-04-23 | 2021-07-30 | 四川桐稷科技有限公司 | Solenopsis invicta pheromone attractant and killing agent containing the same |
| WO2023074396A1 (en) * | 2021-10-29 | 2023-05-04 | 信越化学工業株式会社 | Ant control agent and ant control method |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101999349B (en) | 2013-02-27 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103548895B (en) | Botanical vegetable insecticide | |
| CN100382707C (en) | A botanical pesticide | |
| CN101999349B (en) | D-limonene-containing mixed oil agent for killing solenopsis invicta buren and method for killing the solenopsis invicta buren | |
| CN104397058B (en) | A kind of Chinese herbal medicine green pesticide and preparation method thereof | |
| CN101720791B (en) | Matrine pure plant source pesticide | |
| CN103636660B (en) | A kind of for preventing and treating the Environmental-protection particle agent of Sugarcane Pests | |
| CN102283258A (en) | Plant protecting agent for plant source and preparation method thereof | |
| CN105076214B (en) | A kind of method for improving entomopathogenic nematode prevention fragrant-flowered garlic maggot effect | |
| CN106508991A (en) | Biological pesticide and preparation method thereof | |
| CN105613147A (en) | Method for controlling pests of greenhouse vegetables based on biological experiment of senior high schools | |
| CN105053020B (en) | Application of the cherry heterorhabditis indica in rice water weevil is prevented | |
| CN104522054A (en) | Biological source synergistic compound insecticide, preparation method and application thereof | |
| CN106508996A (en) | Greenhouse pesticide and preparation method thereof | |
| CN104663728A (en) | Microbial pesticide composition for preventing plant diseases | |
| CN109265235A (en) | Special fertilizer with insecticidal activity | |
| CN102626092B (en) | Azadirachtin aqueous solution for treating root-knot nematode disease and preparation method thereof | |
| CN102626116B (en) | Plant pesticide and its preparation method | |
| CN100438766C (en) | Herbal synergistic formulation effective against mosquito-larvae and use thereof in controlling malarial vector | |
| CN103875714A (en) | Bacillus thuringiensis.spinosyns.trisiloxane polyoxyethylene ether composition and use of bacillus thuringiensis.spinosyns.trisiloxane polyoxyethylene ether composition for preventing and controlling rice boring insects | |
| Malungane | Effect of crude extracts of Tulbaghia violacea (wild garlic) on growth of tomato and supression of Meloidogyne species | |
| Widmer et al. | Reducing infection and secondary inoculum of Phytophthora ramorum on Viburnum tinus roots grown in potting medium amended with Trichoderma asperellum isolate 04-22 | |
| CN106490077A (en) | A kind of botanical pesticide for urban greening project and preparation method thereof | |
| CN102524271A (en) | Cytisine and matrine insecticide water emulsion | |
| CN106259515A (en) | A kind of mango insecticide and preparation method thereof | |
| CN102498984B (en) | Method for preventing and treating plutella xylostella by applying lemongrass essential oil |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C56 | Change in the name or address of the patentee | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 510260 Xingang West Road, Guangdong, Guangzhou, No. 105, No. Patentee after: Guangdong Institute of biological resources application Patentee after: Guangzhou Yuekunyuan Bio-technology Development Co., Ltd. Address before: 510260 Xingang West Road, Guangdong, Guangzhou, No. 105, No. Patentee before: Guangdong Entomological Institute Patentee before: Guangzhou Yuekunyuan Bio-technology Development Co., Ltd. |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20190618 Address after: 510260 No. 105 Xingang West Road, Haizhu District, Guangzhou City, Guangdong Province Co-patentee after: Guangdong Institute of biological resources application Patentee after: Guangzhou Yuekunyuan Bio-technology Development Co., Ltd. Address before: 510260 No. 105 Xingang West Road, Haizhu District, Guangzhou City, Guangdong Province Co-patentee before: Guangzhou Yuekunyuan Bio-technology Development Co., Ltd. Patentee before: Guangdong Institute of biological resources application |
|
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 510260 No. 105 West Xingang Road, Guangzhou, Guangdong, Haizhuqu District Patentee after: GUANGZHOU YUEKUNYUAN BIOTECHNOLOGY DEVELOPMENT Co.,Ltd. Patentee after: Institute of zoology, Guangdong Academy of Sciences Address before: 510260 No. 105 West Xingang Road, Guangzhou, Guangdong, Haizhuqu District Patentee before: GUANGZHOU YUEKUNYUAN BIOTECHNOLOGY DEVELOPMENT Co.,Ltd. Patentee before: Guangdong Institute of Applied Biological Resources |