CN101991515B - Anti-lampblack composition - Google Patents
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- CN101991515B CN101991515B CN 200910056185 CN200910056185A CN101991515B CN 101991515 B CN101991515 B CN 101991515B CN 200910056185 CN200910056185 CN 200910056185 CN 200910056185 A CN200910056185 A CN 200910056185A CN 101991515 B CN101991515 B CN 101991515B
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Abstract
The invention discloses an anti-lampblack composite and a cosmetic composite thereof. The anti-lampblack composite comprises the following components: (a) an astragalus mongholicus extract and components; and (b) catechin compounds, wherein the weight ratio of components (a) to (b) is 1:1 to 7:1 and the two components are dissolved in an aquiferous medium. The anti-lampblack cosmetic composite comprises water phase and oil phase, wherein the water phase is the anti-lampblack composite and accounts for 75-92% by weight of the cosmetic composite. The anti-lampblack composite can inhibit absorption of lampblack effectively, reduce or completely remove the side effect and the damaging effect of benzopyrene to skins and help the skin restore luster and activity effectively so that the skins are maintained in a healthy state.
Description
Technical field
The present invention relates to care composition, specifically, relate to the nursing of the isolating oil smoke compositions that applies some make up.
Background technology
The traditional food culinary art custom meeting high temperature cooking of China will produce a lot of oil smoke like this.The oil smoke sample of collecting from resident family is analyzed as can be known, contained 220 number of chemical materials in oil smoke, wherein mainly contain the chemical substances such as aldehyde, ketone, hydrocarbon, fatty acid, alcohol, aromatic compound, ester, lactone, heterocyclic compound.Oil smoke can reduce gradually along with the rising molecular weight of temperature, when temperature reaches 170 ℃ of the smoke points of edible oil, the blue smoke mist that the appearance initial stage decomposes, along with temperature continues to raise, decomposition rate is accelerated, and when reaching 250 ℃, a large amount of oil smoke occur, and with pungent abnormal smells from the patient, the oil smoke granularity is at the 0.01-0.3 micron.The permeability of the micromolecule particulate matter after these high temperature actions is very strong, and the meeting rapid permeability makes skin produce strong Oxidation to deep skin, accelerates skin aging, causes skin low and deep, jaundice, tarnish and life.
The oil smoke that cooking at ordinary times produces is the source of the crime of " yellow-faced woman-my wife " just.A kind of material that exists in oil smoke smog---benzopyrene is a kind of common high activity indirect acting carcinogens.Benzopyrene has stronger stimulation to eyes and skin, it can by suck, eat, the number of ways such as percutaneous absorption enters in body, health is threatened.The long-time oil smoke that sucks can make tissue generation pathological changes, and the ill ratio of the 40-60 of Long Term Contact oil smoke year women will increase several times.In addition, oil smoke is larger to the injury of female skin, and smoke particle is attached on female skin, causes pore to block, and accelerates the female skin failure, causes the skin roughening, wrinkle occurs, melanin increases and change mottle, and people Geng Yi is got fat.Oil smoke also can damage immune system in human body, and the people of 5 years experience that cook is arranged, and also has alopecia in various degree.Cosmetic at ordinary times and beauty treatment can not fundamentally solve the suffered infringement of skin, cure the symptoms, not the disease.Only have from the generation stage of kitchen fume and effect a radical cure fume pollution, could protect thoroughly the breathing of distaffer and skin to preserve from.This shows, prevent that oil smoke from having arrived instant stage for the damaging effect of skin.
Existing sun screen has certain buffer action for oil smoke, but it is mainly to set for the wavelength of ultraviolet light, for the granule of some the specific sizes in oil smoke high temperature with there are some compositions of Oxidation can not play effective buffer action.
The medical material Radix Astagali contains a large amount of useful chemical compositions, comprise bioflavonoids (flavonoids), astragalus polysaccharides (polysaccharides), triterpene glycoside triterpene glycosides (e.g., such as astragalosides I-VII), aminoacid amino acids, and other trace element.The Radix Astragali has multiple pharmacological effect, and particularly it has toxin expelling granulation promoting, antioxidation, removing oxygen-derived free radicals, keeps the functions such as normal structure form of skin, thereby can reach skin care, supports antidotal effect.Contain a lot of biological active ingredients in Radix Astragali extract, as astragaloside (total Astragloside), triterpene glycoside (triterpeneglycosides), astragalus polysaccharides (polysaccharides).The effective ingredient of the Radix Astragali can be absorbed by skin, thereby the Skin Cell nutriture is improved, and the collagen protein synthesis ability strengthens.
Catechin compounds is the important component in the Folium Camelliae sinensis extract tea polyphenols, has the performance of a lot of excellences.Catechin is natural oil antioxidant, and antioxidant activity is even also high than vitamin e; And can remove the free radical that human body produces, with the Cell protection film.It can also delaying aging, because the function of removing free radical is arranged, so can delaying senility.
Although Radix Astragali extract and catechin compounds all have respectively the effect of nursing skin preferably, one-component is in the effect that often is difficult to aspect isolation oil smoke, opposing oil smoke reach desirable.
Also there is no at present a kind of cosmetics or skin care item for the special exploitation of oil smoke contactee, these type of cosmetics and skin care item are on existing cosmetics market or a kind of space state, therefore develop a cover and can satisfy specially modern metropolitan cities people's demand for the cosmetics that prevent oil smoke and skin care item, boundless market prospect is arranged.
Summary of the invention
Radix Astragali extract and catechin compounds are used in the discovery that the present inventor is surprised simultaneously, can effectively isolate oil smoke, play the effect of anti-oil smoke.
An object of the present invention is to provide a kind of anti-lampblack composite.
Particularly, anti-lampblack composite of the present invention comprises component a) Radix Astragali extract and components b) catechin compounds.Described component a) and b) be dissolved in water-bearing media.
In the present invention, described water-bearing media can be water, can be also the mixing material of water and other water-soluble solvents.Those skilled in the art can select as required voluntarily, preferably use deionized water.
In anti-lampblack composite of the present invention, described component is Radix Astragali extract and b a)) catechin compounds is used in conjunction with, and can effectively resist oil smoke, their weight ratio can be 1: 5～7: 1, preferred 1: 1～7: 1, more preferably 5: 4～5: 1, most preferably 5: 4～5: 2.
In anti-lampblack composite of the present invention, described component is Radix Astragali extract and b a)) catechin compounds is dissolved in water-bearing media.Rule according to cosmetics and/or skin care item production technology and formula, those skilled in the art can be according to the character of DNA purity and composition itself, the choose reasonable component a) and b) concentration in water-bearing media, the percentage by weight of preferred two component sums in described compositions is 0.02%～11%, more preferably 2%～8%, with the total restatement of described compositions.The inventor finds, component a) and b) when the concentration of sum in water-bearing media was about 4～5%, the effect of anti-oil smoke was best.
In the preferred embodiment of anti-lampblack composite of the present invention, described component a) and b) weight ratio be 5: 4～5: 1; The percentage by weight of two component sums is 0.02%～11%, with the total restatement of described compositions.More preferably, described component a) and b) weight ratio be 5: 4～5: 2.
In another preferred embodiment of anti-lampblack composite of the present invention, described component a) and b) weight ratio be 5: 4～5: 1; And the percentage by weight of two component sums is 2%～8%, with the total restatement of described compositions.More preferably, described component a) and b) weight ratio be 5: 4～5: 2.
In anti-lampblack composite of the present invention, described component a) Radix Astragali extract is plant extract.The material of Radix Astragali extract for being made through water extraction or alcohol extraction by the Radix Astragali wherein contains active component astragalus polysaccharides, Radix Astragali total flavones etc.The preferred Radix Astragali extract that uses the astragalus polysaccharides that contains 40-60wt%.Due to the content of other compositions, compositions of the present invention is suppressed the not special impact of effect of oil smoke, those skilled in the art can select the Radix Astragali extract of different size as required.In actual applications, also can be as required the Radix Astragali extract that extracts of suitable selection distinct methods, or use their combination.
In anti-lampblack composite of the present invention, described catechin compounds is the main component of Folium Camelliae sinensis extract tea polyphenols, contains epigallocatechin gallate (EGCG) (EGCG), epigallo catechin (EGC), L-Epicatechin gallate (ECG), epicatechin (EC).The preferred catechin compounds that uses natural extract, wherein the content of each material on the not special impact of the effect of the inhibition oil smoke of compositions of the present invention, can be selected the catechin compounds of different size as required.Usually the catechin compounds of natural extract is left-handed, therefore, in anti-lampblack composite of the present invention, preferably uses left-handed catechin compounds.
In anti-lampblack composite of the present invention, can also comprise amount of component b), described amount of component b) be selected from least a in Semen Juglandis elite and biological peptide.
In a preferred embodiment of anti-lampblack composite of the present invention, described amount of component b) be the Semen Juglandis elite, component a) and amount of component b) weight ratio be 10: 0.1～10: 0.6.
In another preferred embodiment of anti-lampblack composite of the present invention, described amount of component b) be biological peptide, component a) and amount of component b) weight ratio be 10: 0.01～10: 0.08.
In another preferred embodiment of anti-lampblack composite of the present invention, described amount of component b) be Semen Juglandis elite and biological peptide, component is a) 10: 0.1: 0.01～10: 0.6: 0.08 with the weight ratio of Semen Juglandis elite and biological peptide.
In the present invention, anti-lampblack composite of the present invention is called for short BCC, the efficient of BCC chelating benzopyrene is higher.BCC can be directly used in cosmetics as forms such as gel agent, water preparation, essences; Also can with oil phase emulsifying after, be used for the cosmetics of the forms such as cream cream, Emulsion.Anti-lampblack composite of the present invention is added to (as liquid, emulsion, gel, cream frost, powder) in the cosmetics and skin care item of any state, can play the chelating benzopyrene, effectively suppress oil smoke, improve the effect of skin state.
The experiment in vitro of anti-lampblack composite of the present invention shows, BCC can the benzopyrene of chelating more than 90%, and it is become the water soluble chelate compound that colorless and odorless has no side effect.
Another object of the present invention is to provide a kind of cosmetic composition of anti-oil smoke.
The cosmetic composition of anti-oil smoke of the present invention comprises water and oil phase, and wherein said water is anti-lampblack composite BCC noted earlier.
The percentage by weight that preferred described water accounts for described cosmetic composition is 75～92%.
The form of described cosmetic composition is not limit, and can comprise a lot, and such as cream cream, Emulsion, concrete can be cream, frost, emulsion, facial film etc.
According to the rule of cosmetics or skin care item production technology and formula, those skilled in the art can according to the form of cosmetics, select the ratio of water and oil phase voluntarily.According to the feel requirement to mastic, preferred water shared ratio in cosmetic composition is 75-92%.On the basis of this principle, inventor's discovery, when the ratio of water and oil phase was about 76: 24, the sensation of mastic was best.
In cosmetic composition of the present invention, described oil phase can be the normally used materials of cosmetic field such as hydro carbons, oils, wax class, sclerosis oils, fatty acid, silicone oil or fat soluble vitamin class.
In cosmetic composition of the present invention, can also contain the following additive that can use at cosmetic field, as fatty material, solvent, thickening agent, emulsifying agent, suction product, sun optical filtering thing, antioxidant, spice, surfactant etc.
Composition in cosmetic composition of the present invention is generally used in cosmetics, so without particular limitation of.
The cosmetic composition of anti-oil smoke of the present invention comprises water and oil phase, and the percentage by weight that wherein said water accounts for described cosmetic composition is 75～92%; Component is Radix Astragali extract and components b a)) catechin compounds is dissolved in described aqueous phase.According to the rule of cosmetics and/or skin care item production technology and formula, according to the character of DNA purity and composition itself, the active ingredient component of interpolation a) and b) be 0.02%～8% at the percentage by weight of described cosmetic composition, preferred 2～6%.
Preferably, in described cosmetic composition, component a) and b) weight ratio be 1: 1～7: 1, more preferably 5: 4～5: 1, most preferably 5: 4～5: 2.
Preferably, in described cosmetic composition, also contain Semen Juglandis elite and/or biological peptide.More preferably, component is a) 10: 0.1～10: 0.6 with the weight ratio of Semen Juglandis elite; Component is a) 10: 0.01～10: 0.08 with the weight ratio of biological peptide.
The cosmetic composition of anti-oil smoke of the present invention can use general cosmetics preparation method preparation, preferably can prepare by the following method:
(1) preparation of oil phase adds the oil phase pot with oils and fats, wax, emulsifying agent and other oil-soluble compositions (high temperature resistant, as at high temperature to be difficult for oxidation oiliness raw material), constantly being heated to 80-85 ℃ under stirring condition, it is fully melted or be uniformly dissolved stand-by;
(2) preparation of water first adds deionized water the water pot, can add wherein by resistant to elevated temperatures water soluble ingredient, be heated under stirring 80-85 ℃ stand-by;
(3) emulsifying with above-mentioned oil phase and water raw material according to water---oil phase---water order (laboratory is drawn a design and directly added oil phase---water is to the emulsifying pot) add in the emulsifying pot, stir, be warming up to 80-85 ℃, insulation 20min sterilization, insulation finishes to be cooled to 70 ℃, add easy oxidation oil content, be uniformly dissolved, carry out the homogenizing of certain hour;
(4) the cooling homogenizing finishes, and is cooled to 45 ℃ of left and right, adds antiseptic, essence and the interpolation raw material of other need under low temperature condition.
Anti-lampblack composite of the present invention and cosmetic composition thereof have the following advantages:
1, the component in anti-lampblack composite BCC of the present invention is the special micromolecular compound of a class formation, has higher homology; BCC can deep enough skin deep layer, catch rapidly the residual benzopyrene of skin deep layer, be combined into a kind of chelate that can be water-soluble with it, and the metabolism by skin, with the chelate of benzopyrene excrete with skin outside.Therefore, BCC can play effective inhibition oil smoke and absorb, and reduces or dispels benzopyrene fully for the side effect of skin and the effect of injury.
2, cosmetic composition of the present invention contain can effectively suppress and the chelating oil smoke in the BCC of benzopyrene composition, can effectively help skin again to recover brilliance and vigor, the state that skin is kept fit.
3, anti-lampblack composite of the present invention is take active ingredient of natural plant as main, and the main component of taking from natural plants is safe and effective.
The specific embodiment
Below with reference to specific embodiment, the technique effect of design of the present invention and generation is described further, to understand fully the present invention.
The source of each component of using in an embodiment of the present invention is as shown in table 1.
Table 1
| Producer | Trade name | Goods number | Specification | |
| Radix Astragali extract | Upper sea green guarantor's development in science and technology company limited | Radix Astragali extract polysaccharide 50% | 50％ | |
| Catechin compounds | Upper sea green guarantor's development in science and technology company limited | Catechin compounds | TGP-98A | 98％ |
| The Semen Juglandis elite | French cosmetics research and development group | The Semen Juglandis elite | ||
| Biological peptide | French cosmetics research and development group | Biological peptide |
Embodiment 1-11
With component a) Radix Astragali extract and b) catechin compounds is water-soluble respectively, and both weight ratios were selected in 1: 5～7: 1, mixing then, and the weight content of both sums is about 5 % by weight; Obtain according to anti-lampblack composite BCC of the present invention.Wherein the weight ratio of Radix Astragali extract and catechin compounds is 4: 1～5: 1, and isolation effect is good.Proportioning and the effect of component Radix Astragali extract and catechin compounds see Table 2.
Table 2
| Embodiment | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | 10 | 11 |
| Component is a): b) | 1∶5 | 1∶4 | 1∶3 | 1∶2 | 1∶1 | 2∶1 | 3∶1 | 4∶1 | 5∶1 | 6∶1 | 7∶1 |
| Effect | Generally | Generally | Generally | Generally | Generally | Generally | Good | Good | Good | Generally | Generally |
As can be seen from Table 2, along with the raising of catechin compounds concentration, the chelating benzopyrene degree of component does not significantly improve; Along with the raising of astragalus extraction substrate concentration, the degree of component chelating benzopyrene has improved, if but the excessive concentration of Radix Astragali extract, the chelating benzopyrene ability of component can reduce again, this shows, and Radix Astragali extract plays than major effect.
Embodiment 12-27
Embodiment 12-27 is the cosmetic composition according to anti-oil smoke of the present invention, be specially the cream cream by following preparation method preparation, wherein, the weight ratio of water and oil phase is 76: 24, and the gross weight that Radix Astragali extract and catechin compounds sum account for the cream cream is 3.8 % by weight approximately.
Radix Astragali extract and catechin compounds, and and proportioning and the result of use thereof of other composition see Table 3～table 6.
The below illustrates the preparation method of cosmetic composition of the present invention take the cream cream as example.
Water: first deionized water is added the water pot, Radix Astragali extract and catechin compounds is water-soluble respectively, mixing then, be heated under stirring 80-85 ℃ stand-by; Wherein the weight ratio of Radix Astragali extract and catechin compounds was selected in 5: 4～5: 2, and both sums are about 5 % by weight at the content of aqueous phase;
Oil phase: oil can be mineral oil, vegetable oil; Oils and fats is added the oil phase pot, constantly being heated to 80-85 ℃ under stirring condition, it is fully melted or be uniformly dissolved stand-by;
With above-mentioned oil phase and water raw material with water and the oil phase part by weight with 76: 24,---oil phase---water sequentially adds in the emulsifying pot according to water, stir, be warming up to 80-85 ℃, insulation 20min sterilization, insulation finishes to be cooled to 70 ℃, adds easy oxidation oil content, be uniformly dissolved, carry out the homogenizing of certain hour;
Homogenizing finishes, and is cooled to 45 ℃ of left and right, adds antiseptic, essence and the interpolation raw material of other need under low temperature condition.
In embodiment 17-26, also add Semen Juglandis elite or biological peptide at aqueous phase, wherein the 3rd composition is all in the situation that Radix Astragali extract: the catechin compounds weight ratio is to add at 73: 27.The weight ratio of aqueous phase Radix Astragali extract and Semen Juglandis elite can be 73: 1～73: 4; The weight ratio of the described Radix Astragali extract of aqueous phase and biological peptide can be 73: 0.1～73: 0.6.
In embodiment 27, add simultaneously Semen Juglandis elite and biological peptide at aqueous phase, Radix Astragali extract: catechin compounds: the Semen Juglandis elite: the concrete weight ratio of biological peptide is: 73: 27: 3: 0.3.
Following formula is the basic components of the cream cream that uses of embodiments of the invention, and the component of anti-oil smoke of the present invention is added according to institute's column data in table 3-6, finally according to the amount of the ratio-dependent deionized water of all additives, obtains the cosmetics of embodiment 12-27.
Concrete cream frost basic components is as follows:
Composition W/%
Stearic acid 9.0
C16-C18 alcohol 3.2
Glyceryl monostearate 1.0
White oil 2.0
Glycerol 8.0
KOH 0.5
Essence is appropriate
Methyl hydroxybenzoate 0.2
Propylparaben 0.1
The deionized water surplus
Table 3
| Embodiment | 12 | 13 | 14 | 15 | 16 |
| Radix Astragali extract: catechin compounds | 5∶4 | 4∶3 | 3∶2 | 5∶3 | 5∶2 |
| Effect | Better | Very good | Good | Very good | Fine |
As can be seen from Table 3, work as Radix Astragali extract: catechin compounds is best results in 5: 4 to 5: 2 scopes, further screening in this scope, and when Radix Astragali extract: catechin compounds has optimum efficiency when being 73: 27.
Table 4
| Embodiment | 17 | 18 | 19 | 20 |
| Radix Astragali extract: Semen Juglandis elite | 73∶1 | 73∶2 | 73∶3 | 73∶4 |
| Effect | Generally | Good | Fine | Generally |
Table 5
| Embodiment | 21 | 22 | 23 | 24 | 25 | 26 |
| Radix Astragali extract: biological peptide | 73∶0.1 | 73∶0.2 | 73∶0.3 | 73∶0.4 | 73∶0.5 | 73∶0.6 |
| Effect | Generally | Generally | Fine | Good | Good | Generally |
According to the above results, we have selected Radix Astragali extract: catechin compounds: the Semen Juglandis elite is 73: 27: 3, and Radix Astragali extract: catechin compounds: biological peptide is the proportioning of 73: 27: 0.3, is best proportioning.
Table 6
| Embodiment | Radix Astragali extract: catechin compounds: Semen Juglandis elite: biological peptide | Effect |
| 27 | 73∶27∶3∶0.3 | Very good |
Particularly, the compositions in table 2～table 6 is broken into sample, break into sample and try out experiment.
Need to prove, the effect of the embodiment 1-26 that mentions in the specific embodiment of the present invention compares embodiment grouping and draws, and does not compare for the effect between on the same group embodiment not.Concrete, to list in respectively embodiment in each table (table 2-5) as one group, as embodiment 1-11, embodiment 12-16, embodiment 17-20, embodiment 21-26 respectively do for oneself one group.Used the best proportioning of each component in embodiment 27, the effect of anti-oil smoke is best in all embodiments.
We are on probation with the possible oil smoke exposed population group that sample is distributed to east, the whole nation, south, west, each area, north, according to experimental result, statistical analysis shows, any compositions that adopts embodiment 1-11 can reach 68.24% for the chelation percent of benzopyrene in oil smoke, can reach 40.12% for the opposing rate of oil smoke; Adopt embodiment 12-18,20-22, any compositions of 24-26 can reach 65.32% for the chelation percent of benzopyrene in oil smoke, can reach 39.79% for the opposing rate of oil smoke; Adopt embodiment 19,23 or 27 compositions, can reach 91.86% for the chelation percent of benzopyrene in oil smoke, can reach 52.14% for the opposing rate of oil smoke.Effect of the present invention is the assessment of the sense organ that provides by statistical method.
By those of ordinary skill is scrutable in the art, described in this description is a kind of better embodiment of the present invention, and all changes of making under this invention's idea or modification all should be in claim protection domains of the present invention.
Claims (5)
1. anti-lampblack composite, composed of the following components:
Component is Radix Astragali extract and components b a)) catechin compounds, and described component a) and b) be dissolved in water-bearing media, it is characterized in that, described component a) and b) weight ratio be: 5:4～5:1, and the percentage by weight of two component sums in described compositions is 0.02%～11%, described component a) and b) be plant extract, described Radix Astragali extract comprises the astragalus polysaccharides of 40-60wt%.
2. anti-lampblack composite according to claim 1, is characterized in that, described component a) and b) weight ratio be: 5:4～5:2, and the percentage by weight of two component sums in described compositions is 2%～8%.
3. anti-lampblack composite, composed of the following components:
component is Radix Astragali extract a), components b) catechin compounds and amount of component b), described amount of component b) be Semen Juglandis elite and/or biological peptide, and described component a), b) and c) be dissolved in water-bearing media, it is characterized in that, described component a) and b) weight ratio be: 5:4～5:1, and the percentage by weight of two component sums in described compositions is 0.02%～11%, described component a) and b) be plant extract, described Radix Astragali extract comprises the astragalus polysaccharides of 40-60wt%, when described amount of component b) be the Semen Juglandis elite, component is Radix Astragali extract and amount of component b a)) weight ratio of Semen Juglandis elite is 10:0.1～10:0.6, when described amount of component b) be biological peptide, component is Radix Astragali extract and amount of component b a)) weight ratio of biological peptide is 10:0.01～10:0.08, when described amount of component b) be Semen Juglandis elite and biological peptide, component a) the weight ratio of Radix Astragali extract and Semen Juglandis elite and biological peptide is 10:0.1:0.01～10:0.6:0.08.
4. the cosmetic composition of an anti-oil smoke, it is characterized in that, described cosmetic composition comprises water and oil phase, and wherein said water is the described anti-lampblack composite of one of claim 1-3, and the percentage by weight that described water accounts for described cosmetic composition is 75～92%.
5. cosmetic composition according to claim 4, is characterized in that, described cosmetic composition is cream cream or Emulsion.
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