CN101970397B - 制备2-氨基-5-氰基苯甲酸衍生物的方法 - Google Patents

制备2-氨基-5-氰基苯甲酸衍生物的方法 Download PDF

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Publication number
CN101970397B
CN101970397B CN200880126979.XA CN200880126979A CN101970397B CN 101970397 B CN101970397 B CN 101970397B CN 200880126979 A CN200880126979 A CN 200880126979A CN 101970397 B CN101970397 B CN 101970397B
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formula
reagent
compound
mixture
copper
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Chinese (zh)
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CN101970397A (zh
Inventor
D·J·杜马斯
A·L·卡萨尔诺沃
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Fmc Ip Technology Co ltd
FMC Corp
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EI Du Pont de Nemours and Co
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D401/00—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom
    • C07D401/02—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings
    • C07D401/04—Heterocyclic compounds containing two or more hetero rings, having nitrogen atoms as the only ring hetero atoms, at least one ring being a six-membered ring with only one nitrogen atom containing two hetero rings directly linked by a ring-member-to-ring-member bond
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • C07C253/14—Preparation of carboxylic acid nitriles by reaction of cyanides with halogen-containing compounds with replacement of halogen atoms by cyano groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
    • C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
    • C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/16—Halogen atoms or nitro radicals

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Pyridine Compounds (AREA)
  • Plural Heterocyclic Compounds (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
  • Acyclic And Carbocyclic Compounds In Medicinal Compositions (AREA)
  • Catalysts (AREA)
CN200880126979.XA 2007-12-19 2008-12-17 制备2-氨基-5-氰基苯甲酸衍生物的方法 Active CN101970397B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US845807P 2007-12-19 2007-12-19
US61/008458 2007-12-19
PCT/US2008/087151 WO2009085816A1 (en) 2007-12-19 2008-12-17 Process for preparing 2-amino-5-cyanobenzoic acid derivatives

Publications (2)

Publication Number Publication Date
CN101970397A CN101970397A (zh) 2011-02-09
CN101970397B true CN101970397B (zh) 2014-04-16

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Family Applications (1)

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CN200880126979.XA Active CN101970397B (zh) 2007-12-19 2008-12-17 制备2-氨基-5-氰基苯甲酸衍生物的方法

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Country Link
US (1) US8247570B2 (enExample)
EP (1) EP2231592B1 (enExample)
JP (1) JP5398734B2 (enExample)
KR (1) KR101587296B1 (enExample)
CN (1) CN101970397B (enExample)
AR (1) AR069838A1 (enExample)
AU (1) AU2008343227B2 (enExample)
BR (1) BRPI0819568B1 (enExample)
CA (1) CA2709952A1 (enExample)
CL (1) CL2008003756A1 (enExample)
CO (1) CO6300860A2 (enExample)
IL (1) IL206390A (enExample)
RU (1) RU2010129913A (enExample)
TW (1) TWI432421B (enExample)
WO (1) WO2009085816A1 (enExample)

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WO2009018657A1 (en) 2007-08-03 2009-02-12 Boehringer Ingelheim International Gmbh Viral polymerase inhibitors
EP2234977A4 (en) 2007-12-19 2011-04-13 Boehringer Ingelheim Int VIRAL POLYMERASE INHIBITORS
TWI431000B (zh) 2008-03-05 2014-03-21 Du Pont 製備２－胺基－５－氰基苯甲酸衍生物之方法
TW201247631A (en) 2011-04-28 2012-12-01 Du Pont Herbicidal pyrazinones
WO2013007603A1 (de) * 2011-07-08 2013-01-17 Bayer Intellectual Property Gmbh Verfahren zur herstellung von 2-amino-5-cyano-n,3-dimethylbenzamid
EP2742036A1 (en) 2011-08-12 2014-06-18 Basf Se N-thio-anthranilamide compounds and their use as pesticides
BR112014003221A2 (pt) 2011-08-12 2017-04-18 Basf Se composto da fórmula geral (i), método para preparação de um comporto da fórmula (i), composição agrícola ou veterinária, métodos para combater ou controlar pragas invertebradas, para a proteção de plantas em crecimento contra o ataque ou infestação por pragas invertebradas, para a proteção de sementes contra insetos terrestres e das raízes e galhos de mudas contra insetos terrestres e foliares, semente, uso de um composto e método para tratamento de um animal infestado ou infectado por parasitas ou para evitar que animais fiquem infestados ou infectados por parasitas ou para proteção de um animal contra infestação ou infecção por parasitas
BR112014003112A2 (pt) 2011-08-12 2017-02-21 Basf Se composto da fórmula geral (i), métodos para preparar um composto da fórmula (i), composição agrícola ou veterinária, método para combater ou controlar pragas invertebradas, método para proteger o cultivo de plantas, método para a proteção de sementes, semente, usos de um composto e método para tratar um animal
KR20140051402A (ko) 2011-08-12 2014-04-30 바스프 에스이 N-티오-안트라닐아미드 화합물 및 살충제로서의 그의 용도
WO2013092868A1 (en) 2011-12-21 2013-06-27 Basf Se N-thio-anthranilamide compounds and their use as pesticides
WO2013113789A1 (en) 2012-02-02 2013-08-08 Basf Se N-thio-anthranilamide compounds and their use as pesticides
CN104245666B (zh) 2012-02-07 2019-01-11 拜耳知识产权有限责任公司 取代的邻氨基苯甲酸衍生物的制备方法
CN104003976B (zh) * 2014-05-07 2016-03-16 肇庆市真格生物科技有限公司 多取代吡啶基吡唑酰胺及其制备方法和用途
TWI678354B (zh) 2014-05-29 2019-12-01 新加坡商艾佛艾姆希農業新加坡有限公司 藉空氣氧化製備３-甲基-２-硝基苯甲酸之製程
CN105461683B (zh) * 2015-11-18 2019-01-15 江苏省农用激素工程技术研究中心有限公司 邻氨基苯甲酰胺化合物的制备方法
EA202191554A1 (ru) * 2018-12-03 2021-09-02 Фмк Корпорейшн Способ получения n-фенилпиразол-1-карбоксамидов
CN113692406B (zh) 2019-02-18 2024-07-23 Pi工业有限公司 制备邻甲酰胺基苯甲酰胺类化合物及其中间体的方法
CN113614063A (zh) 2019-02-22 2021-11-05 Pi工业有限公司 合成氨茴二酰胺化合物及其中间体的方法
TW202222162A (zh) 2020-09-26 2022-06-16 印度商皮埃企業有限公司 鄰胺苯甲酸／醯胺化合物及其中間體的合成方法
US20240308988A1 (en) 2021-08-05 2024-09-19 Syngenta Crop Protection Ag Method For Controlling Diamide Resistant Pests and Compounds Therefor
US20260055052A1 (en) 2022-08-16 2026-02-26 Adama Makhteshim Ltd. Process for preparing cyantraniliprole via amino-cyano-benzene derivative
WO2024116197A1 (en) * 2022-11-30 2024-06-06 Natco Pharma Limited An improved process for the preparation of intermediate of cyantraniliprole
WO2026047667A1 (en) 2024-08-26 2026-03-05 Adama Makhteshim Ltd. Process for preparing amino-cyano-benzene derivatives
WO2026099847A1 (en) 2024-11-05 2026-05-15 Adama Makhteshim Ltd. Synthesis of cyano-anthranilic acid

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1829707A (zh) * 2003-01-28 2006-09-06 杜邦公司 氰基邻氨基苯甲酰胺杀虫剂
CN1988803A (zh) * 2004-07-26 2007-06-27 杜邦公司 邻氨基苯甲酰胺无脊椎害虫防治剂混合物
CN101072767A (zh) * 2004-12-07 2007-11-14 杜邦公司 制备n－苯基吡唑－1－甲酰胺的方法

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US6888032B2 (en) 2002-08-02 2005-05-03 Massachusetts Institute Of Technology Copper-catalyzed formation of carbon-heteroatom and carbon-carbon bonds
DE102006042439A1 (de) 2006-09-09 2008-03-27 Saltigo Gmbh Verfahren zur katalytischen Herstellung von aromatischen oder heteroaromatischen Nitrilen
TWI415827B (zh) * 2006-12-21 2013-11-21 Du Pont 製備２-胺基-５-氰基苯甲酸衍生物之方法
TWI431000B (zh) 2008-03-05 2014-03-21 Du Pont 製備２－胺基－５－氰基苯甲酸衍生物之方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1829707A (zh) * 2003-01-28 2006-09-06 杜邦公司 氰基邻氨基苯甲酰胺杀虫剂
CN1988803A (zh) * 2004-07-26 2007-06-27 杜邦公司 邻氨基苯甲酰胺无脊椎害虫防治剂混合物
CN101072767A (zh) * 2004-12-07 2007-11-14 杜邦公司 制备n－苯基吡唑－1－甲酰胺的方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
A State-of-the-Art Cyanation of Aryl Bromides: A novel and Versatile Copper Catalyst System Inspired by Nature;Thomas Schareina et al;《Chemistry-A European Journal》;20070507;第13卷(第21期);表1 *

Also Published As

Publication number Publication date
TWI432421B (zh) 2014-04-01
KR101587296B1 (ko) 2016-01-21
CL2008003756A1 (es) 2009-11-27
BRPI0819568A2 (pt) 2017-07-04
TW200934770A (en) 2009-08-16
WO2009085816A1 (en) 2009-07-09
IL206390A0 (en) 2010-12-30
CO6300860A2 (es) 2011-07-21
BRPI0819568B1 (pt) 2018-02-06
RU2010129913A (ru) 2012-01-27
EP2231592B1 (en) 2016-02-17
AU2008343227A1 (en) 2009-07-09
AR069838A1 (es) 2010-02-24
JP5398734B2 (ja) 2014-01-29
AU2008343227B2 (en) 2013-08-01
IL206390A (en) 2014-06-30
CN101970397A (zh) 2011-02-09
KR20100098443A (ko) 2010-09-06
US8247570B2 (en) 2012-08-21
US20120130080A1 (en) 2012-05-24
CA2709952A1 (en) 2009-07-09
JP2011507872A (ja) 2011-03-10
EP2231592A1 (en) 2010-09-29

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Effective date of registration: 20180716

Address after: Singapore Singapore

Co-patentee after: FMC Corp.

Patentee after: FMC agricultural Singapore Ltd.

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Patentee before: E. I. du Pont de Nemours and Co.

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Effective date of registration: 20260311

Address after: Switzerland

Patentee after: FMC IP Technology Co.,Ltd.

Country or region after: Switzerland

Patentee after: FMC Corp.

Country or region after: U.S.A.

Address before: Singapore, Singapore

Patentee before: FMC agricultural Singapore Ltd.

Country or region before: Singapore

Patentee before: FMC Corp.

Country or region before: U.S.A.

TR01 Transfer of patent right