CN101913675B - 一种改性废弃蛋壳去除水中磷的方法 - Google Patents
一种改性废弃蛋壳去除水中磷的方法 Download PDFInfo
- Publication number
- CN101913675B CN101913675B CN201010244818XA CN201010244818A CN101913675B CN 101913675 B CN101913675 B CN 101913675B CN 201010244818X A CN201010244818X A CN 201010244818XA CN 201010244818 A CN201010244818 A CN 201010244818A CN 101913675 B CN101913675 B CN 101913675B
- Authority
- CN
- China
- Prior art keywords
- phosphorus
- eggshell
- solution
- egg shell
- egg
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
- 102000002322 Egg Proteins Human genes 0.000 title claims abstract description 79
- 108010000912 Egg Proteins Proteins 0.000 title claims abstract description 79
- 210000003278 egg shell Anatomy 0.000 title claims abstract description 73
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 title claims abstract description 69
- 229910052698 phosphorus Inorganic materials 0.000 title claims abstract description 68
- 239000011574 phosphorus Substances 0.000 title claims abstract description 68
- 238000000034 method Methods 0.000 title claims abstract description 36
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000002699 waste material Substances 0.000 title abstract description 6
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 36
- 238000003756 stirring Methods 0.000 claims abstract description 13
- 239000012528 membrane Substances 0.000 claims abstract description 6
- 239000000843 powder Substances 0.000 claims abstract description 5
- 238000005303 weighing Methods 0.000 claims abstract description 5
- 238000002156 mixing Methods 0.000 claims abstract description 4
- 230000004048 modification Effects 0.000 claims description 42
- 238000012986 modification Methods 0.000 claims description 42
- 235000012054 meals Nutrition 0.000 claims description 32
- 239000000243 solution Substances 0.000 claims description 32
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 16
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 13
- 229910019142 PO4 Inorganic materials 0.000 claims description 9
- 239000010452 phosphate Substances 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 9
- 241000287828 Gallus gallus Species 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 210000004681 ovum Anatomy 0.000 claims description 7
- 239000000126 substance Substances 0.000 claims description 6
- 150000002505 iron Chemical class 0.000 claims description 5
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 3
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000012266 salt solution Substances 0.000 claims description 3
- 230000002045 lasting effect Effects 0.000 claims description 2
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 claims 1
- 238000005259 measurement Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 17
- 238000012545 processing Methods 0.000 abstract description 2
- 239000010865 sewage Substances 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract 2
- 150000003839 salts Chemical class 0.000 abstract 2
- 238000001035 drying Methods 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000007873 sieving Methods 0.000 abstract 1
- 230000000274 adsorptive effect Effects 0.000 description 19
- 238000001179 sorption measurement Methods 0.000 description 17
- 239000002351 wastewater Substances 0.000 description 7
- 239000000701 coagulant Substances 0.000 description 6
- 238000005345 coagulation Methods 0.000 description 5
- 230000015271 coagulation Effects 0.000 description 5
- 230000009102 absorption Effects 0.000 description 4
- 238000010521 absorption reaction Methods 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 238000004064 recycling Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 230000002195 synergetic effect Effects 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 241000195493 Cryptophyta Species 0.000 description 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 description 1
- WYWFMUBFNXLFJK-UHFFFAOYSA-N [Mo].[Sb] Chemical compound [Mo].[Sb] WYWFMUBFNXLFJK-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 229940037003 alum Drugs 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 159000000013 aluminium salts Chemical class 0.000 description 1
- 229910000329 aluminium sulfate Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000001458 anti-acid effect Effects 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010170 biological method Methods 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000008878 coupling Effects 0.000 description 1
- 238000010168 coupling process Methods 0.000 description 1
- 238000005859 coupling reaction Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000011026 diafiltration Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000012851 eutrophication Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000005189 flocculation Methods 0.000 description 1
- 230000016615 flocculation Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- -1 iron ion Chemical class 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 1
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000007483 microbial process Effects 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 238000007781 pre-processing Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229960004029 silicic acid Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 238000002798 spectrophotometry method Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
Abstract
Description
Claims (3)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201010244818XA CN101913675B (zh) | 2010-08-04 | 2010-08-04 | 一种改性废弃蛋壳去除水中磷的方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201010244818XA CN101913675B (zh) | 2010-08-04 | 2010-08-04 | 一种改性废弃蛋壳去除水中磷的方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101913675A CN101913675A (zh) | 2010-12-15 |
CN101913675B true CN101913675B (zh) | 2012-05-23 |
Family
ID=43321359
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201010244818XA Active CN101913675B (zh) | 2010-08-04 | 2010-08-04 | 一种改性废弃蛋壳去除水中磷的方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101913675B (zh) |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102161525A (zh) * | 2011-03-02 | 2011-08-24 | 大连民族学院 | 一种废水水解酸化除磷方法 |
CN102380350B (zh) * | 2011-10-24 | 2013-06-05 | 上海海洋大学 | 一种羟基磷灰石改性蛋壳吸附剂材料去除和回收废水中磷酸盐的方法 |
CN103252216B (zh) * | 2013-06-03 | 2014-12-24 | 江西理工大学 | 一种吸附剂及其制备工艺并应用于净化中低浓度氨氮废水 |
CN106111048A (zh) * | 2016-07-12 | 2016-11-16 | 成都理工大学 | 一种用于去除水中磷酸盐的蛋壳负载纳米铁材料及其制备方法 |
CN106378089A (zh) * | 2016-10-19 | 2017-02-08 | 中国科学院地球化学研究所 | 去除水体中五价锑的吸附剂及其制备方法 |
CN109052603A (zh) * | 2018-07-15 | 2018-12-21 | 南京信息工程大学 | 一种改性废弃水泥块去除雨水中磷的方法 |
CN109847774A (zh) * | 2019-03-16 | 2019-06-07 | 泉州师范学院 | 一种用于去除对硝基苯酚材料的制备方法和应用 |
CN111871371A (zh) * | 2020-07-16 | 2020-11-03 | 盐城工学院 | 一种改性生物炭吸附材料及其制备方法和应用 |
CN114307956A (zh) * | 2021-12-17 | 2022-04-12 | 西北农林科技大学 | 一种基于废弃蛋壳制备的污水除磷生物炭 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1850637A (zh) * | 2006-05-24 | 2006-10-25 | 湖南大学 | 一种高效重金属离子吸附剂碳羟磷灰石的制备方法 |
CN101058459A (zh) * | 2006-04-21 | 2007-10-24 | 韩国科学技术研究院 | 用于下水和废水处理的物质、内含该物质的载体及其制法 |
CN101269858A (zh) * | 2008-05-05 | 2008-09-24 | 同济大学 | 桂圆壳在吸附重金属离子中的应用及使用桂圆壳吸附重金属离子的方法 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2005218982A (ja) * | 2004-02-06 | 2005-08-18 | Juri Gakuen | 水中リン除去方法 |
-
2010
- 2010-08-04 CN CN201010244818XA patent/CN101913675B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101058459A (zh) * | 2006-04-21 | 2007-10-24 | 韩国科学技术研究院 | 用于下水和废水处理的物质、内含该物质的载体及其制法 |
CN1850637A (zh) * | 2006-05-24 | 2006-10-25 | 湖南大学 | 一种高效重金属离子吸附剂碳羟磷灰石的制备方法 |
CN101269858A (zh) * | 2008-05-05 | 2008-09-24 | 同济大学 | 桂圆壳在吸附重金属离子中的应用及使用桂圆壳吸附重金属离子的方法 |
Non-Patent Citations (1)
Title |
---|
JP特开2005-218982A 2005.08.18 |
Also Published As
Publication number | Publication date |
---|---|
CN101913675A (zh) | 2010-12-15 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101913675B (zh) | 一种改性废弃蛋壳去除水中磷的方法 | |
Li et al. | Removal of phosphate from aqueous solution by dolomite-modified biochar derived from urban dewatered sewage sludge | |
CN101913676B (zh) | 利用铁盐改性蛋壳去除水中磷的方法 | |
CN104971699B (zh) | 一种污水同步脱氮除磷的改性沸石有机物复合剂及其制备方法、应用和应用方法 | |
Yao et al. | Bivalve shell: not an abundant useless waste but a functional and versatile biomaterial | |
CN109012589B (zh) | 一种选择性吸附Cr(VI)的尿素改性生物炭及其制备方法和应用方法 | |
CN101716489A (zh) | 一种用于再生水处理的脱氮除磷抗菌复合水处理材料 | |
CN105771876B (zh) | 改性蛋壳磁性吸附剂的制备方法及去除水中重金属的方法 | |
CN108706745A (zh) | 一种高铁锰氨氮复合污染低温地下水的处理方法 | |
CN103071451A (zh) | 净化废水中重金属离子改性凹凸棒石粘土及制备方法 | |
CN105540726A (zh) | 一种磁性壳聚糖/生物炭复合材料去除废水中五价砷的方法 | |
CN108686627A (zh) | 一种镧水合氧化物改性壳聚糖吸附剂的制备方法 | |
CN103288164A (zh) | 采用改性沸石和改性蛋壳联合对污水同步脱氮除磷的方法 | |
CN101913674B (zh) | 采用铝盐改性蛋壳去除水中磷的方法 | |
CN107758823B (zh) | 一种生活污水处理剂及其制备方法 | |
CN113461026B (zh) | 一种用于高盐废液的沸石型除磷剂制备方法与应用 | |
CN106552615A (zh) | 凹凸棒石粘土复合催化材料的制备方法 | |
CN113559820A (zh) | 一种磷霉素制药废水除磷吸附剂的制备及其应用回收方法 | |
JP5713735B2 (ja) | リン吸着材ならびにそれを用いた土壌改良剤または肥料 | |
CN101921009B (zh) | 改性废弃蛋壳去除水中磷的方法 | |
CN102872794A (zh) | 一种去除水中溴酸根的复合吸附材料及其制备方法 | |
CN103521168A (zh) | 磁性矿物复合材料的制备方法和应用 | |
CN110790337B (zh) | 一种去除水体中重金属Cd的组合物及其制备方法与应用 | |
CN102847518A (zh) | 一种去除水中亚磷酸根的复合吸附材料及其制备方法 | |
CN106966756A (zh) | 一种利用畜禽粪便和污泥制备水质净化功能生态混凝土的方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: CHANGSHU NJNU DEVELOPMENT INSTITUTE Free format text: FORMER OWNER: NANJING UNIVERSITY OF INFORMATION SCIENCE AND TECHNOLOGY Effective date: 20120816 |
|
C41 | Transfer of patent application or patent right or utility model | ||
COR | Change of bibliographic data |
Free format text: CORRECT: ADDRESS; FROM: 210044 NANJING, JIANGSU PROVINCE TO: 215500 SUZHOU, JIANGSU PROVINCE |
|
TR01 | Transfer of patent right |
Effective date of registration: 20120816 Address after: 215500 Changshou City South East Economic Development Zone, Jiangsu, Jin Road, No. 8 Patentee after: Changshu Nanjing Normal University Development Research Institute Co.,Ltd. Address before: 210044 Nanjing City, Pukou Province, Nanjing Road, No. 219, No. six, No. Patentee before: Nanjing University of Information Science and Technology |
|
TR01 | Transfer of patent right |
Effective date of registration: 20201228 Address after: Building 3, No.88, Xianshi Road, high tech Zone, Changshu City, Suzhou City, Jiangsu Province Patentee after: Changshu Zijin Intellectual Property Service Co.,Ltd. Address before: 215500 8 Jindu Road, Changshou City Southeast Economic Development Zone, Jiangsu Patentee before: CHANGSHU NANJING NORMAL UNIVERSITY DEVELOPMENT RESEARCH INSTITUTE Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20231229 Address after: 215500 No.72 Wenwen street, Guli Town, Changshu City, Suzhou City, Jiangsu Province Patentee after: Changshu Guli Technology Venture Service Co.,Ltd. Address before: Building 3, No.88, Xianshi Road, high tech Zone, Changshu City, Suzhou City, Jiangsu Province Patentee before: Changshu Zijin Intellectual Property Service Co.,Ltd. |
|
TR01 | Transfer of patent right |