CN101906001A - Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer - Google Patents
Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer Download PDFInfo
- Publication number
- CN101906001A CN101906001A CN2010102397474A CN201010239747A CN101906001A CN 101906001 A CN101906001 A CN 101906001A CN 2010102397474 A CN2010102397474 A CN 2010102397474A CN 201010239747 A CN201010239747 A CN 201010239747A CN 101906001 A CN101906001 A CN 101906001A
- Authority
- CN
- China
- Prior art keywords
- fertilizer
- medicine
- volaton
- chlorpyrifos
- tensio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003337 fertilizer Substances 0.000 title claims abstract description 181
- 239000002245 particle Substances 0.000 title claims abstract description 47
- 238000000034 method Methods 0.000 title abstract description 14
- 239000000843 powder Substances 0.000 title abstract 2
- 239000005944 Chlorpyrifos Substances 0.000 claims abstract description 46
- 238000002360 preparation method Methods 0.000 claims abstract description 46
- SBPBAQFWLVIOKP-UHFFFAOYSA-N chlorpyrifos Chemical compound CCOP(=S)(OCC)OC1=NC(Cl)=C(Cl)C=C1Cl SBPBAQFWLVIOKP-UHFFFAOYSA-N 0.000 claims abstract description 44
- 241000244206 Nematoda Species 0.000 claims abstract description 25
- 239000003814 drug Substances 0.000 claims description 150
- ATROHALUCMTWTB-WYMLVPIESA-N (z)-n-diethoxyphosphinothioyloxybenzenecarboximidoyl cyanide Chemical compound CCOP(=S)(OCC)O\N=C(/C#N)C1=CC=CC=C1 ATROHALUCMTWTB-WYMLVPIESA-N 0.000 claims description 64
- 239000000203 mixture Substances 0.000 claims description 52
- 238000009472 formulation Methods 0.000 claims description 45
- 239000011573 trace mineral Substances 0.000 claims description 36
- 235000013619 trace mineral Nutrition 0.000 claims description 36
- 239000013543 active substance Substances 0.000 claims description 33
- 239000002904 solvent Substances 0.000 claims description 33
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims description 28
- 239000002594 sorbent Substances 0.000 claims description 25
- KCXVZYZYPLLWCC-UHFFFAOYSA-N EDTA Chemical compound OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O KCXVZYZYPLLWCC-UHFFFAOYSA-N 0.000 claims description 24
- 239000012452 mother liquor Substances 0.000 claims description 24
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 18
- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 claims description 15
- 229910052921 ammonium sulfate Inorganic materials 0.000 claims description 15
- 235000011130 ammonium sulphate Nutrition 0.000 claims description 15
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 14
- LFVGISIMTYGQHF-UHFFFAOYSA-N ammonium dihydrogen phosphate Chemical compound [NH4+].OP(O)([O-])=O LFVGISIMTYGQHF-UHFFFAOYSA-N 0.000 claims description 14
- 239000011591 potassium Substances 0.000 claims description 14
- 229910052700 potassium Inorganic materials 0.000 claims description 14
- 239000004323 potassium nitrate Substances 0.000 claims description 14
- 235000010333 potassium nitrate Nutrition 0.000 claims description 14
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 claims description 13
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 13
- -1 polyoxyethylene Polymers 0.000 claims description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 13
- 229910019142 PO4 Inorganic materials 0.000 claims description 12
- 229960001484 edetic acid Drugs 0.000 claims description 12
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 12
- 239000010452 phosphate Substances 0.000 claims description 12
- 239000005995 Aluminium silicate Substances 0.000 claims description 10
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 10
- 235000012211 aluminium silicate Nutrition 0.000 claims description 10
- 239000004202 carbamide Substances 0.000 claims description 10
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 10
- 208000006558 Dental Calculus Diseases 0.000 claims description 9
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 9
- 235000019270 ammonium chloride Nutrition 0.000 claims description 9
- 239000006229 carbon black Substances 0.000 claims description 9
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 claims description 9
- 229910000396 dipotassium phosphate Inorganic materials 0.000 claims description 9
- 235000019797 dipotassium phosphate Nutrition 0.000 claims description 9
- 239000001508 potassium citrate Substances 0.000 claims description 9
- QEEAPRPFLLJWCF-UHFFFAOYSA-K potassium citrate (anhydrous) Chemical compound [K+].[K+].[K+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O QEEAPRPFLLJWCF-UHFFFAOYSA-K 0.000 claims description 9
- 235000015870 tripotassium citrate Nutrition 0.000 claims description 9
- 238000001035 drying Methods 0.000 claims description 8
- NVTRPRFAWJGJAJ-UHFFFAOYSA-L EDTA monocalcium salt Chemical compound [Ca+2].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O NVTRPRFAWJGJAJ-UHFFFAOYSA-L 0.000 claims description 7
- DHHVKJOKPFJOJF-UHFFFAOYSA-N [Mn].[Na].[Na] Chemical compound [Mn].[Na].[Na] DHHVKJOKPFJOJF-UHFFFAOYSA-N 0.000 claims description 7
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 claims description 7
- 239000004327 boric acid Substances 0.000 claims description 7
- 235000010338 boric acid Nutrition 0.000 claims description 7
- 238000005469 granulation Methods 0.000 claims description 7
- 230000003179 granulation Effects 0.000 claims description 7
- TVXXNOYZHKPKGW-UHFFFAOYSA-N sodium molybdate (anhydrous) Chemical compound [Na+].[Na+].[O-][Mo]([O-])(=O)=O TVXXNOYZHKPKGW-UHFFFAOYSA-N 0.000 claims description 7
- 238000004090 dissolution Methods 0.000 claims description 6
- 238000010298 pulverizing process Methods 0.000 claims description 6
- 238000005303 weighing Methods 0.000 claims description 6
- KSHPUQQHKKJVIO-UHFFFAOYSA-N [Na].[Zn] Chemical compound [Na].[Zn] KSHPUQQHKKJVIO-UHFFFAOYSA-N 0.000 claims description 5
- 235000018660 ammonium molybdate Nutrition 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- KWOLFJPFCHCOCG-UHFFFAOYSA-N Acetophenone Chemical compound CC(=O)C1=CC=CC=C1 KWOLFJPFCHCOCG-UHFFFAOYSA-N 0.000 claims description 4
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 4
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000000618 nitrogen fertilizer Substances 0.000 claims description 4
- 239000002686 phosphate fertilizer Substances 0.000 claims description 4
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- 229940072033 potash Drugs 0.000 claims description 4
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 claims description 4
- 235000015320 potassium carbonate Nutrition 0.000 claims description 4
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 2
- 229920001732 Lignosulfonate Polymers 0.000 claims description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 2
- ATSGLBOJGVTHHC-UHFFFAOYSA-N bis(ethane-1,2-diamine)copper(2+) Chemical compound [Cu+2].NCCN.NCCN ATSGLBOJGVTHHC-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- 229910052802 copper Inorganic materials 0.000 claims description 2
- 239000010949 copper Substances 0.000 claims description 2
- 229910000365 copper sulfate Inorganic materials 0.000 claims description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 2
- 229940071106 ethylenediaminetetraacetate Drugs 0.000 claims description 2
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 2
- 239000011790 ferrous sulphate Substances 0.000 claims description 2
- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 2
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims description 2
- 235000019357 lignosulphonate Nutrition 0.000 claims description 2
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 claims description 2
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 2
- 229910052750 molybdenum Inorganic materials 0.000 claims description 2
- 239000011733 molybdenum Substances 0.000 claims description 2
- 229910052757 nitrogen Inorganic materials 0.000 claims description 2
- 150000003014 phosphoric acid esters Chemical class 0.000 claims description 2
- NEUOBESLMIKJSB-UHFFFAOYSA-J tetrasodium;tetraacetate Chemical compound [Na+].[Na+].[Na+].[Na+].CC([O-])=O.CC([O-])=O.CC([O-])=O.CC([O-])=O NEUOBESLMIKJSB-UHFFFAOYSA-J 0.000 claims description 2
- 239000011701 zinc Substances 0.000 claims description 2
- 229910052725 zinc Inorganic materials 0.000 claims description 2
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 claims description 2
- 229910000368 zinc sulfate Inorganic materials 0.000 claims description 2
- 229960001763 zinc sulfate Drugs 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 9
- 229950001664 phoxim Drugs 0.000 abstract description 6
- 230000002265 prevention Effects 0.000 abstract description 5
- 241000238631 Hexapoda Species 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- IBSREHMXUMOFBB-JFUDTMANSA-N 5u8924t11h Chemical compound O1[C@@H](C)[C@H](O)[C@@H](OC)C[C@@H]1O[C@@H]1[C@@H](OC)C[C@H](O[C@@H]2C(=C/C[C@@H]3C[C@@H](C[C@@]4(O3)C=C[C@H](C)[C@@H](C(C)C)O4)OC(=O)[C@@H]3C=C(C)[C@@H](O)[C@H]4OC\C([C@@]34O)=C/C=C/[C@@H]2C)/C)O[C@H]1C.C1=C[C@H](C)[C@@H]([C@@H](C)CC)O[C@]11O[C@H](C\C=C(C)\[C@@H](O[C@@H]2O[C@@H](C)[C@H](O[C@@H]3O[C@@H](C)[C@H](O)[C@@H](OC)C3)[C@@H](OC)C2)[C@@H](C)\C=C\C=C/2[C@]3([C@H](C(=O)O4)C=C(C)[C@@H](O)[C@H]3OC\2)O)C[C@H]4C1 IBSREHMXUMOFBB-JFUDTMANSA-N 0.000 abstract 3
- 239000005660 Abamectin Substances 0.000 abstract 3
- 229950008167 abamectin Drugs 0.000 abstract 3
- ATROHALUCMTWTB-OWBHPGMISA-N phoxim Chemical compound CCOP(=S)(OCC)O\N=C(\C#N)C1=CC=CC=C1 ATROHALUCMTWTB-OWBHPGMISA-N 0.000 abstract 3
- 230000000361 pesticidal effect Effects 0.000 abstract 2
- 239000003153 chemical reaction reagent Substances 0.000 description 10
- 239000003795 chemical substances by application Substances 0.000 description 10
- 230000000857 drug effect Effects 0.000 description 10
- 239000004530 micro-emulsion Substances 0.000 description 8
- 241000196324 Embryophyta Species 0.000 description 5
- 241000607479 Yersinia pestis Species 0.000 description 5
- 240000008042 Zea mays Species 0.000 description 5
- 235000005824 Zea mays ssp. parviglumis Nutrition 0.000 description 5
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 5
- 235000005822 corn Nutrition 0.000 description 5
- 230000000052 comparative effect Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- 241000243785 Meloidogyne javanica Species 0.000 description 3
- 206010062701 Nematodiasis Diseases 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 235000013311 vegetables Nutrition 0.000 description 3
- 239000002131 composite material Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 241001136249 Agriotes lineatus Species 0.000 description 1
- 241001124076 Aphididae Species 0.000 description 1
- 235000017060 Arachis glabrata Nutrition 0.000 description 1
- 244000105624 Arachis hypogaea Species 0.000 description 1
- 235000010777 Arachis hypogaea Nutrition 0.000 description 1
- 235000018262 Arachis monticola Nutrition 0.000 description 1
- 241000243771 Bursaphelenchus xylophilus Species 0.000 description 1
- 241001481710 Cerambycidae Species 0.000 description 1
- 241000254171 Curculionidae Species 0.000 description 1
- 241000289763 Dasygaster padockina Species 0.000 description 1
- 241000399949 Ditylenchus dipsaci Species 0.000 description 1
- 241000482313 Globodera ellingtonae Species 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 241000241125 Gryllotalpa gryllotalpa Species 0.000 description 1
- 244000017020 Ipomoea batatas Species 0.000 description 1
- 235000002678 Ipomoea batatas Nutrition 0.000 description 1
- 241000238814 Orthoptera Species 0.000 description 1
- 235000021307 Triticum Nutrition 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 239000003905 agrochemical Substances 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000011363 dried mixture Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000010871 livestock manure Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000020232 peanut Nutrition 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003971 tillage Methods 0.000 description 1
- 231100000167 toxic agent Toxicity 0.000 description 1
- 239000003440 toxic substance Substances 0.000 description 1
Landscapes
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention provides a medicinal fertilizer and application thereof. The medicinal fertilizer comprises the following components in percentage by weight: 0.1 to 1 percent of abamectin, 1 to 20 percent of phoxim and/or chlorpyrifos, 15 to 40 percent of macro-element fertilizer, 1 to 5 percent of micro-element fertilizer and 34 to 72.4 percent of carrier. In the medicinal fertilizer, the abamectin, the phoxim and/or the chlorpyrifos, the macro-element fertilizer and the macro-element fertilizer are compounded so that the pesticide effects of the abamectin and the phoxim and/or the chlorpyrifos on nematode or/and underground insects are enhanced effectively and the medicinal fertilizer acts growth effect on crops. The medicinal fertilizer has excellent performance and pesticide effect so that the medicinal fertilizer can be applied in the prevention and control of the underground insects or/and nematode. The invention also provides a method for preparing a particle medicinal fertilizer and a powder medicinal fertilizer. The preparation method has the advantages of simple process, easily-controlled condition and suitability for industrialized production.
Description
Technical field
The invention belongs to the pesticide preparation field, relate in particular to the fertile preparation method of a kind of medicine fertilizer and application thereof, particle formulation medicine fertilizer and powder-type medicine.
Background technology
The many in the world countries and regions of plant nematode take place and cause harm, and kind is varied.In the world, the generation of plant nematode and harm are along with the variation of the development of agroforestry and tillage and cultivation system is serious day by day.According to estimates, it is 12.3% that plant nematode is caused the year rate of loss of world staple crops, surpasses 1,000 hundred million dollars, and actual loss is considerably beyond estimation.At present the deleterious nematode of plant there is kind more than 3000 approximately, mainly contains root knot nematode, Cyst nematode, pine wood nematode, sweet potato stem nematode etc. in China.After nematodiasiss takes place, the general underproduction about 10%, serious in more than 75%, even total crop failure.
In recent years, pest damage is on the rise under the vegetable field, is difficult to control, brings bigger financial loss to the vegetable grower.The subterranean pest-insect kind is a lot, comprises mainly that cutworm, grub, mole cricket, wireworm, root maggot, root aphid, root weevil, root are chrysomelid, root longicorn, cricket etc.How its host types complexity causes harm at spring and autumn, the seed of the crop of mainly causing harm, underground part and subaerial rhizome portion.Often cause and hinder root, dead seedling, so that the disconnected ridge that is short of seedling.Most subterranean pest-insects have more stable ecotope, a little less than life cycle long, the transport property, also have with ground temperature and change vertical active characteristics, form hazard boom in spring, two seasons of autumn.
At present the medicament kind of control nematode and subterranean pest-insect is more, makes that problems such as environment and the interior toxic substance of plant materials be residual are particularly outstanding but general problem is a large amount of chemical pesticides.Therefore, subterranean pest-insect and control of nematode medicament become the task of top priority more efficiently to develop more environmental protection.
Summary of the invention
In view of this, the invention provides a kind of can effectively promote Avrmectin, Volaton and/or Chlorpyrifos 94 to nematode or/and the drug effect of subterranean pest-insect, and crop is played the medicine fertilizer of accretion.
The present invention also provides above-mentioned medicine fertilizer preventing and treating subterranean pest-insect or/and the application in the nematode.
The technical solution adopted in the present invention is:
A kind of medicine fertilizer comprises following components in weight percentage content:
Avrmectin 0.1%～1%
Volaton and/or Chlorpyrifos 94 1%～20%
Macroelement fertilizer 15%～40%
Trace element fertilizer 1%～5%
Carrier 34%～72.4%.
And the fertile preparation method of a kind of particle formulation medicine comprises the steps:
Take by weighing Avrmectin, Volaton and/or Chlorpyrifos 94, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent, sorbent material and carrier by fertile each component concentration of particle formulation medicine, wherein, by gross weight 100%, Avrmectin 0.1%～1%, Volaton and/or Chlorpyrifos 94 1%～20%, macroelement fertilizer 15%～40%, trace element fertilizer 1%～5%, solvent 5%～15%, tensio-active agent 5%～10%, sorbent material 0.5%～2%, carrier 34%～72.4%;
With solvent, Avrmectin, Volaton and/or Chlorpyrifos 94, tensio-active agent mixed dissolution, be mixed with mother liquor;
With the mother liquor of above-mentioned preparation mix with macroelement fertilizer, trace element fertilizer, sorbent material, carrier, granulation, obtain described particle formulation medicine fertilizer.
And the fertile preparation method of a kind of powder-type medicine comprises the steps:
Take by weighing Avrmectin, Volaton and/or Chlorpyrifos 94, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent and sorbent material by fertile each component concentration of powder-type medicine, wherein, by gross weight 100%, Avrmectin 0.1%～1%, Volaton and/or Chlorpyrifos 94 1%～20%, macroelement fertilizer 15%～40%, trace element fertilizer 1%～5%, solvent 5%～15%, tensio-active agent 5%～10%, sorbent material 0.5%～2%, carrier 34%～72.4%;
With solvent, Avrmectin, Volaton and/or Chlorpyrifos 94, tensio-active agent mixed dissolution, be mixed with mother liquor;
Mother liquor and macroelement fertilizer, trace element fertilizer, sorbent material, carrier mixing after drying, pulverizing with above-mentioned preparation obtain described powder-type medicine fertilizer.
And above-mentioned medicine fertilizer is being prevented and treated subterranean pest-insect or/and the application in the nematode.
Medicine fertilizer of the present invention is composite with Avrmectin, Volaton and/or Chlorpyrifos 94 and macroelement fertilizer and trace element fertilizer, effectively promoted Avrmectin, Volaton and/or Chlorpyrifos 94 to nematode or/and the drug effect of subterranean pest-insect, and crop is played the medicine fertilizer of accretion.Because medicine fertilizer, particle formulation medicine fertilizer and powder-type medicine fertilizer have aforementioned premium properties and drug effect, make that medicine fertilizer, particle formulation medicine fertilizer or powder-type medicine fertilizer can be the control subterranean pest-insect or/and use in the nematode.Preparation technology fertile and powder-type medicine fertilizer is simple for particle formulation medicine, and condition is easily controlled, and is suitable for suitability for industrialized production.
Embodiment
In order to make purpose of the present invention, technical scheme and advantage clearer,, the present invention is further elaborated below in conjunction with embodiment.Should be appreciated that specific embodiment described herein only in order to explanation the present invention, and be not used in qualification the present invention.
A kind of medicine fertilizer that present embodiment provides comprises following components in weight percentage content:
Avrmectin 0.1%～1%
Volaton and/or Chlorpyrifos 94 1%～20%
Macroelement fertilizer 15%～40%
Trace element fertilizer 1%～5%
Carrier 34%～72.4%.
Further, above-mentioned Avrmectin weight percentage in described medicine fertilizer is preferably 0.5%; Volaton and/or Chlorpyrifos 94 weight percentage in described medicine fertilizer is preferably 10%.This Avrmectin and Volaton and/or Chlorpyrifos 94 component preferred content can make the drug effect of this medicine fertilizer reach optimum level.
Further, above-mentioned macroelement fertilizer is preferably at least a in nitrogenous fertilizer, phosphate fertilizer or the potash fertilizer, and at least a element in the nitrogen element in described nitrogenous fertilizer, phosphate fertilizer, the potash fertilizer, phosphoric, the potassium element preferably accounts for 5%～20% of the fertile gross weight of described medicine; Trace element in the described trace element fertilizer is preferably at least a in copper, iron, manganese, zinc, molybdenum, the boron, and this trace element preferably accounts for 0.5%～2% of the fertile gross weight of described medicine; Described carrier is preferably at least a in kaolin, diatomite, the nakrite, perhaps at least a in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, vitriolate of tartar, saltpetre or the Tripotassium Citrate.The existence of this macroelement fertilizer and trace element fertilizer component is combining with Avrmectin, Volaton and/or Chlorpyrifos 94 component, when improving Avrmectin, Volaton and/or Chlorpyrifos 94 component drug effect, for farm crop provide the nutrient support.
Further, above-mentioned macroelement fertilizer is preferably at least a in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, vitriolate of tartar, saltpetre or the Tripotassium Citrate; Described trace element fertilizer is preferably at least a in Sodium orthomolybdate, four water ammonium molybdates, zinc sulfate, manganous sulfate, copper sulfate, ferrous sulfate, boric acid, four water, eight Sodium Tetraboratees, ethylenediamine tetraacetic acid (EDTA) zinc sodium, calcium disodium edathamil, ethylenediamine tetraacetic acid (EDTA) manganese disodium or the cupric ethylene diamine tetraacetate sodium.
Further, above-mentioned medicine fertilizer preferably includes the fertile and powder-type medicine fertilizer of particle formulation medicine.
When above-mentioned medicine fertilizer was particle formulation medicine fertilizer, macroelement fertilizer preferably accounted for 15%～40% of the fertile gross weight of described medicine in the described particle formulation medicine fertilizer, and described particle formulation medicine fertilizer also can comprise the preferred ingredient of following weight percent:
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 0.5%～2%
Wherein, described carrier is at least a in kaolin, diatomite, the nakrite.
Therefore, when above-mentioned medicine fertilizer was particle formulation medicine fertilizer, the recipe ingredient of the fertile weight percent of this particle formulation medicine can be expressed as follows:
Avrmectin 0.1%～1%
Volaton and/or Chlorpyrifos 94 1%～20%
Macroelement fertilizer 15%～40%
Trace element fertilizer 1%～5%
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 0.5%～2%
Carrier 34%～72.4%,
Wherein, described carrier is at least a in kaolin, diatomite, the nakrite.
The fertile Preparation Method of above-mentioned particle formulation medicine preferably includes following steps:
S11. take by weighing Avrmectin, Volaton and/or Chlorpyrifos 94, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent, sorbent material and filler by fertile each component concentration of described particle formulation medicine;
S12. with solvent, Avrmectin, Volaton and/or Chlorpyrifos 94, tensio-active agent mixed dissolution, be mixed with mother liquor;
S13. the mother liquor with above-mentioned preparation mixes with macroelement fertilizer, trace element fertilizer, sorbent material, filler, carries out granulation then, obtains described particle formulation medicine fertilizer.
In the fertile preparation method's of above-mentioned particle formulation medicine the S11 step, described carrier is preferably at least a in kaolin, diatomite, the nakrite, because kaolin, diatomite, nakrite is insoluble or be slightly soluble in water, as carrier, can conveniently prepare particle formulation fertilizer with them.
In the fertile preparation method's of above-mentioned particle formulation medicine the S12 step, each component is mixed the preferred agitating procedure that adopts, and makes each component mix.
In the fertile preparation method's of above-mentioned particle formulation medicine the S13 step, each component is mixed the preferred agitating procedure that adopts, and makes each component mix.Prilling process can adopt present technique field prilling process commonly used, is preferably a kind of in extruder grain, mist projection granulating, rotation granulation, the fluidized bed prilling.
When above-mentioned medicine fertilizer was powder-type medicine fertilizer, described powder-type medicine fertilizer also can comprise the preferred ingredient of following weight percent:
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 0.5%～2%.
Wherein, described carrier is at least a in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, vitriolate of tartar, saltpetre or the Tripotassium Citrate.
Therefore, when above-mentioned medicine fertilizer was powder-type medicine fertilizer, the recipe ingredient of the fertile weight percent of this powder-type medicine can be expressed as follows:
Avrmectin 0.1%～1%
Volaton and/or Chlorpyrifos 94 1%～20%
Macroelement fertilizer 15%～40%
Trace element fertilizer 1%～5%
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 0.5%～2%
Carrier 34%～72.4%,
Wherein, described carrier is at least a in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, vitriolate of tartar, saltpetre or the Tripotassium Citrate.
The fertile Preparation Method of above-mentioned powder-type medicine preferably includes following steps:
S21. take by weighing Avrmectin, Volaton and/or Chlorpyrifos 94, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent, sorbent material and carrier by fertile each component concentration of powder-type medicine;
S22. with solvent, Avrmectin, Volaton and/or Chlorpyrifos 94, tensio-active agent mixed dissolution, be mixed with mother liquor;
S23. with the mother liquor and macroelement fertilizer, trace element fertilizer, sorbent material and carrier mixing after drying, pulverizing of above-mentioned preparation, obtain described powder-type medicine fertilizer.
In the fertile preparation method's of above-mentioned particle formulation medicine the S11 step, described carrier is preferably at least a in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, vitriolate of tartar, saltpetre or the Tripotassium Citrate, because ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, vitriolate of tartar, saltpetre or Tripotassium Citrate solvability are good, as carrier, can conveniently prepare powder-type fertilizer with them.
In the fertile preparation method's of above-mentioned powder-type medicine the S22 step, each component is mixed the preferred agitating procedure that adopts, and makes each component mix.
In the fertile preparation method's of above-mentioned powder-type medicine the S23 step, each component is mixed the preferred agitating procedure that adopts, and makes each component mix; Drying process can adopt pulvis or particle formulation agricultural chemicals type of heating commonly used, as Exposure to Sunlight, dry, mode such as oven for drying, the exsiccant temperature does not destroy preferably that composition is as the criterion in the powder-type medicine fertilizer; Disintegrating process is that dried mixture is pulverized, and pulverizes by present technique field common method.
Because the material of the carrier of above-mentioned powder-type medicine fertilizer is the macroelement class fertilizer of solubility, therefore, the fertile solubility property of this powder-type medicine is good.
Further, solvent is preferably one or more in 200# solvent oil, N-Methyl pyrrolidone, isopropylcarbinol, the methyl phenyl ketone in above-mentioned particle formulation medicine fertilizer and powder-type medicine fertilizer and preparation method thereof, this solvent must exist, and related component is fully dissolved and each component is fully disperseed; Described tensio-active agent is preferably one or more in JFC, 603# tensio-active agent, 600# tensio-active agent, alkylphenol polyoxyethylene or its phosphoric acid ester, fatty alcohol-polyoxyethylene ether, sulfonated lignin, the naphthalenesulfonate formaldehyde condensation compound, wherein, JFC, 603# tensio-active agent, all commercially available acquisition of 600# tensio-active agent; Described sorbent material is preferred but be not limited only to white carbon black.The interpolation of this tensio-active agent and sorbent material effectively improved the dispersiveness and the homogeneity of fertile and fertile each component of powder-type medicine of particle formulation medicine, effectively improved the stability of the fertile and powder-type medicine fertilizer drug effect of particle formulation medicine.
From the above mentioned as can be known, preparation technology fertile and powder-type medicine fertilizer is simple for particle formulation medicine, and condition is easily controlled, and is suitable for suitability for industrialized production.
The described medicine fertilizer of present embodiment is composite with Avrmectin, Volaton and/or Chlorpyrifos 94 and macroelement fertilizer and trace element fertilizer, effectively promoted Avrmectin, Volaton and/or Chlorpyrifos 94 drug effect, and crop has been played the medicine fertilizer of accretion nematode and subterranean pest-insect.
Because medicine fertilizer, particle formulation medicine fertilizer and powder-type medicine fertilizer have aforementioned premium properties and drug effect, make that medicine fertilizer, particle formulation medicine fertilizer or powder-type medicine fertilizer can be the control subterranean pest-insect or/and use in the nematode.Medicine fertilizer in use, preferably with seed dressing, spraying, seed manure, dash and execute or drench the control that mode such as execute is used for nematode and subterranean pest-insect on corn, wheat, soybean, peanut and the vegetables.
Below illustrate by a plurality of embodiment that the present embodiment medicine is fertile different to be formed and preparation method thereof, with and aspect such as performance.
Embodiment 1
The preparation of 20% A Wei Volaton particle formulation medicine fertilizer, its prescription is as follows:
Avrmectin 0.1%
Volaton 19.9%
S-200 15％
Fatty alcohol-polyoxyethylene ether 7%
Ammonium sulfate 25%
Potassium primary phosphate 15%
Four water, eight Sodium Tetraboratees 3%
Ethylenediamine tetraacetic acid (EDTA) zinc sodium 2%
Four water ammonium molybdates 1%
White carbon black 1.5%
Kaolin is adjusted to 100%.
Its preparation method is: elder generation dissolves the former medicine of Avrmectin, Phoxim original medicine and tensio-active agent fatty alcohol-polyoxyethylene ether with solvent S-200 and makes mother liquor, and obtained mother liquor and ammonium sulfate, potassium primary phosphate, four water, eight Sodium Tetraboratees, ethylenediamine tetraacetic acid (EDTA) zinc sodium, four water ammonium molybdates, white carbon black, kaolin are carried out the 20% A Wei Volaton particle formulation medicine fertilizer that granulation promptly obtains being used to prevent and treat subterranean pest-insect and nematode in the fluidized bed prilling mode.
Embodiment 2
The preparation of 16% A Wei Chlorpyrifos 94 particle formulation medicine fertilizer, its prescription is as follows:
Avrmectin 1%
Chlorpyrifos 94 15%
N-Methyl pyrrolidone 10%
Alkylphenol polyoxyethylene 6%
Primary ammonium phosphate 15%
Saltpetre 15%
Boric acid 8%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 3%
Sodium orthomolybdate 1%
Calcium disodium edathamil 15%
White carbon black 1.5%
Diatomite is adjusted to 100%
Its preparation method is: elder generation dissolves the former medicine of Avrmectin, the former medicine of Chlorpyrifos 94 and tensio-active agent alkylphenol polyoxyethylene with the solvent N-Methyl pyrrolidone and makes mother liquor, and obtained mother liquor and primary ammonium phosphate, saltpetre, boric acid, ethylenediamine tetraacetic acid (EDTA) manganese disodium, Sodium orthomolybdate, calcium disodium edathamil, white carbon black, diatomite are carried out the 16% A Wei Chlorpyrifos 94 particle formulation medicine fertilizer that granulation promptly obtains being used to prevent and treat subterranean pest-insect and nematode in the fluidized bed prilling mode.
Embodiment 3
The preparation of the A Wei Volaton powder-type medicine fertilizer of 10.5% solubility, its prescription is as follows:
Avrmectin 0.5%
Volaton 10%
N-Methyl pyrrolidone 10%
Alkylphenol polyoxyethylene 6%
Primary ammonium phosphate 15%
Saltpetre 15%
Boric acid 8%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 3%
Sodium orthomolybdate 1%
Calcium disodium edathamil 15%
White carbon black 1%
Ammonium sulfate is adjusted to 100%
Its preparation method is: earlier with the solvent N-Methyl pyrrolidone with the former medicine of Avrmectin, Phoxim original medicine and the dissolving of surface-active agent alkylphenol polyoxyethylene and make mother liquor, with obtained mother liquor and macroelement fertilizer, trace element fertilizer, carrier carry out combination drying also pulverizing promptly obtain being used to preventing and treating the A Wei Volaton powder-type medicine fertilizer of 10.5% solubility of subterranean pest-insect and nematode.
Embodiment 4
The preparation of 10.5% A Wei Volaton particle formulation medicine fertilizer, its prescription is as follows:
Avrmectin 0.5%
Volaton 10%
N-Methyl pyrrolidone 10%
Alkylphenol polyoxyethylene 6%
Primary ammonium phosphate 15%
Saltpetre 15%
Boric acid 8%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 3%
Sodium orthomolybdate 1%
Calcium disodium edathamil 15%
White carbon black 1%
Ammonium sulfate is adjusted to 100%
Its preparation method is: elder generation dissolves the former medicine of Avrmectin, Phoxim original medicine and surface-active agent alkylphenol polyoxyethylene with the solvent N-Methyl pyrrolidone and makes mother liquor, and obtained mother liquor and macroelement fertilizer, trace element fertilizer, carrier are carried out the 10.5% A Wei Volaton particle formulation medicine fertilizer that mixing granulation promptly obtains being used to prevent and treat subterranean pest-insect and nematode.
Embodiment 5
The preparation of the A Wei Chlorpyrifos 94 powder-type medicine fertilizer of 6% solubility, its prescription is as follows:
Avrmectin 1%
Chlorpyrifos 94 5%
N-Methyl pyrrolidone 8%
Alkylphenol polyoxyethylene 7%
Primary ammonium phosphate 15%
Saltpetre 15%
Boric acid 8%
Ethylenediamine tetraacetic acid (EDTA) manganese disodium 3%
Sodium orthomolybdate 1%
Calcium disodium edathamil 15%
White carbon black 1%
Ammonium sulfate is adjusted to 100%
Its preparation method is: earlier with the solvent N-Methyl pyrrolidone with the former medicine of Avrmectin, the former medicine of Chlorpyrifos 94 and the dissolving of surface-active agent alkylphenol polyoxyethylene and make mother liquor, with obtained mother liquor and macroelement fertilizer, trace element fertilizer, carrier carry out combination drying also pulverizing promptly obtain being used to preventing and treating the A Wei Chlorpyrifos 94 powder-type medicine fertilizer of 6% solubility of subterranean pest-insect and nematode.
Embodiment 6
15% A Wei Volaton-Chlorpyrifos 94 medicine fertilizer, its components in weight percentage content is as follows:
Avrmectin 0.5%
Volaton 9.5%
Chlorpyrifos 94 5%
Ammonium sulfate 20%
Potassium primary phosphate 10%
Four water, eight Sodium Tetraboratees 1%
Ethylenediamine tetraacetic acid (EDTA) zinc sodium 1%
Four water ammonium molybdates 1%
Kaolin/urea is adjusted to 100%.
Its preparation method is: by prescription earlier with the solvent N-Methyl pyrrolidone that accounts for the fertile gross weight 10% of medicine with the former medicine of Avrmectin, the former medicine of Chlorpyrifos 94 and account for the surface-active agent alkylphenol polyoxyethylene dissolving of the fertile gross weight 8% of medicine and make mother liquor, obtained mother liquor and macroelement fertilizer, trace element fertilizer, carrier are carried out A Wei Volaton-Chlorpyrifos 94 type medicine fertilizer of 15% that combination drying and pulverizing promptly obtain being used to preventing and treating subterranean pest-insect and nematode.
Drug effect Comparative Examples 1
The A Wei Volaton powder-type medicine of 10.5% solubility of embodiment 3 preparations is fertile to be reached to the crop yield effect relatively root knot nematode, controlling underground pest effect with common 10.5% A Wei Volaton microemulsion:
1) reagent agent:
A. the A Wei Volaton powder-type medicine fertilizer of 10.5% solubility of embodiment 3 preparation;
B. common 10.5% A Wei Volaton microemulsion, by gross weight 100%, its component is: Avrmectin 0.5%, Volaton 10%, N-Methyl pyrrolidone 15%, alkylphenol polyoxyethylene 11%, surplus are water.
2) test method:
The A Wei Volaton powder-type medicine fertilizer (reagent agent A) of 10.5% solubility of embodiment 3 preparation is prevented and treated prevention effect such as following table 1 with common 10.5% A Wei Volaton microemulsion (reagent agent B) with corn field to the test that obvious nematodiasiss and subterranean pest-insect insect pest are arranged:
The comparative efficacy test of table 1 reagent agent A and reagent agent B
According to experimental result, as table 1, A Wei Volaton powder-type medicine fertilizer with 10.5% solubility of embodiment 3 preparation is better than 10.5% traditional A Wei Volaton microemulsion on the prevention effect to corn nematode and subterranean pest-insect, the A Wei Volaton powder-type medicine fertilizer of 10.5% solubility of embodiment 3 preparations simultaneously can make crop yield more than 30%.
Drug effect Comparative Examples 2
10.5% A Wei Volaton particle formulation medicine of embodiment 4 preparations is fertile to be reached to the crop yield effect relatively root knot nematode, controlling underground pest effect with common 10.5% A Wei Volaton microemulsion:
1) reagent agent:
C. 10.5% A Wei Volaton particle formulation medicine fertilizer of embodiment 4 preparation;
B. common 10.5% A Wei Volaton microemulsion, by gross weight 100%, its component is: Avrmectin 0.5%, Volaton 10%, N-Methyl pyrrolidone 15%, alkylphenol polyoxyethylene 11%, surplus are water.
2) test method:
10.5% A Wei Volaton particle formulation medicine fertilizer (reagent agent C) of embodiment 4 preparations is prevented and treated prevention effect such as following table 2 with common 10.5% A Wei Volaton microemulsion (reagent agent B) with corn field to the test that obvious nematodiasiss and subterranean pest-insect insect pest are arranged:
The comparative efficacy test of table 2 reagent agent C and reagent agent B
According to experimental result, 10.5% A Wei Volaton particle formulation medicine fertilizer with embodiment 4 preparations is better than 10.5% traditional A Wei Volaton microemulsion on the prevention effect to corn nematode and subterranean pest-insect, the pulvis of the fertile solubility of 10.5% A Wei Volaton medicine that while the inventive method is prepared can make crop yield more than 30%.
The above only is preferred embodiment of the present invention, not in order to restriction the present invention, all any modifications of being done within the spirit and principles in the present invention, is equal to and replaces and improvement etc., all should be included within protection scope of the present invention.
Claims (13)
1. medicine fertilizer comprises following components in weight percentage content:
Avrmectin 0.1%～1%
Volaton and/or Chlorpyrifos 94 1%～20%
Macroelement fertilizer 15%～40%
Trace element fertilizer 1%～5%
Carrier 34%～72.4%.
2. medicine fertilizer according to claim 1 is characterized in that: described Avrmectin weight percentage in described medicine fertilizer is 0.5%.
3. medicine fertilizer according to claim 1 is characterized in that: described Volaton and/or Chlorpyrifos 94 weight percentage in described medicine fertilizer is 10%.
4. medicine fertilizer according to claim 1, it is characterized in that: described macroelement fertilizer is at least a in nitrogenous fertilizer, phosphate fertilizer or the potash fertilizer, and at least a element in the nitrogen element in described nitrogenous fertilizer, phosphate fertilizer, the potash fertilizer, phosphoric, the potassium element accounts for 5%～20% of the fertile gross weight of described medicine;
Trace element in the described trace element fertilizer is at least a in copper, iron, manganese, zinc, molybdenum, the boron, and described trace element accounts for 0.5%～2% of the fertile gross weight of described medicine.
5. according to claim 1 or 4 described medicine fertilizer, it is characterized in that: described macroelement fertilizer is at least a in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, vitriolate of tartar, saltpetre or the Tripotassium Citrate;
Described trace element fertilizer is at least a in Sodium orthomolybdate, four water ammonium molybdates, zinc sulfate, manganous sulfate, copper sulfate, ferrous sulfate, boric acid, four water, eight Sodium Tetraboratees, ethylenediamine tetraacetic acid (EDTA) zinc sodium, calcium disodium edathamil, ethylenediamine tetraacetic acid (EDTA) manganese disodium or the cupric ethylene diamine tetraacetate sodium.
6. medicine fertilizer according to claim 1, it is characterized in that: described carrier is at least a in kaolin, diatomite, the nakrite, perhaps at least a in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, vitriolate of tartar, saltpetre or the Tripotassium Citrate.
7. medicine fertilizer according to claim 1 is characterized in that: described medicine fertilizer is particle formulation medicine fertilizer or powder-type medicine fertilizer.
8. medicine fertilizer according to claim 7 is characterized in that: described medicine is fertile to be particle formulation medicine fertilizer, and described particle formulation medicine fertilizer also comprises following components in weight percentage:
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 0.5%～2%;
Described carrier is at least a in kaolin, diatomite, the nakrite.
9. medicine fertilizer according to claim 7 is characterized in that: described medicine is fertile to be powder-type medicine fertilizer, and described powder-type medicine fertilizer also comprises following components in weight percentage:
Solvent 5%～15%
Tensio-active agent 5%～10%
Sorbent material 1%～2%;
Described carrier is at least a in ammonium sulfate, ammonium chloride, primary ammonium phosphate, urea, potassium primary phosphate, potassium hydrogen phosphate, Repone K, vitriolate of tartar, saltpetre or the Tripotassium Citrate.
10. according to Claim 8 or 9 described medicine fertilizer, it is characterized in that: described solvent is one or more in 200# solvent oil, N-Methyl pyrrolidone, isopropylcarbinol, the methyl phenyl ketone;
Described tensio-active agent is one or more in JFC, 603# tensio-active agent, 600# tensio-active agent, alkylphenol polyoxyethylene or its phosphoric acid ester, fatty alcohol-polyoxyethylene ether, sulfonated lignin, the naphthalenesulfonate formaldehyde condensation compound;
Described sorbent material is a white carbon black.
11. the fertile preparation method of particle formulation medicine comprises the steps:
Take by weighing Avrmectin, Volaton and/or Chlorpyrifos 94, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent, sorbent material and carrier by fertile each component concentration of described particle formulation medicine, wherein, by gross weight 100%, Avrmectin 0.1%～1%, Volaton and/or Chlorpyrifos 94 1%～20%, macroelement fertilizer 15%～40%, trace element fertilizer 1%～5%, solvent 5%～15%, tensio-active agent 5%～10%, sorbent material 0.5%～2%, carrier 34%～72.4%;
With solvent, Avrmectin, Volaton and/or Chlorpyrifos 94, tensio-active agent mixed dissolution, be mixed with mother liquor;
With the mother liquor of above-mentioned preparation mix with macroelement fertilizer, trace element fertilizer, sorbent material, carrier, granulation, obtain described particle formulation medicine fertilizer.
12. the fertile preparation method of powder-type medicine comprises the steps:
Take by weighing Avrmectin, Volaton and/or Chlorpyrifos 94, macroelement fertilizer, trace element fertilizer, solvent, tensio-active agent and sorbent material by fertile each component concentration of powder-type medicine, wherein, by gross weight 100%, Avrmectin 0.1%～1%, Volaton and/or Chlorpyrifos 94 1%～20%, macroelement fertilizer 15%～40%, trace element fertilizer 1%～5%, solvent 5%～15%, tensio-active agent 5%～10%, sorbent material 0.5%～2%, carrier 34%～72.4%;
With solvent, Avrmectin, Volaton and/or Chlorpyrifos 94, tensio-active agent mixed dissolution, be mixed with mother liquor;
Mother liquor and macroelement fertilizer, trace element fertilizer, sorbent material, carrier mixing after drying, pulverizing with above-mentioned preparation obtain described powder-type medicine fertilizer.
13. preventing and treating subterranean pest-insect or/and the application in the nematode according to the arbitrary described medicine fertilizer of claim 1-10.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010239747.4A CN101906001B (en) | 2010-07-28 | 2010-07-28 | Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010239747.4A CN101906001B (en) | 2010-07-28 | 2010-07-28 | Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101906001A true CN101906001A (en) | 2010-12-08 |
| CN101906001B CN101906001B (en) | 2014-04-02 |
Family
ID=43261616
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010239747.4A Active CN101906001B (en) | 2010-07-28 | 2010-07-28 | Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101906001B (en) |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329177A (en) * | 2011-06-28 | 2012-01-25 | 安徽莱姆佳肥业有限公司 | Preparation and application of compound fertilizer for preventing and controlling underground pests of Chinese medicinal material |
| CN102633566A (en) * | 2012-03-27 | 2012-08-15 | 何勇 | Pesticide fertilizer |
| CN103044161A (en) * | 2012-12-21 | 2013-04-17 | 浙江建中竹业科技有限公司 | Method for preparing organic fertilizer from plant charcoal and wood vinegar |
| CN103242108A (en) * | 2013-05-16 | 2013-08-14 | 山东亿丰源生物科技股份有限公司 | Drug fertilizer preparation containing chlorpyrifos and organic fertilizer |
| CN103319278A (en) * | 2013-05-23 | 2013-09-25 | 锦州硕丰农药集团有限公司 | Multifunctional pesticide fertilizer and production method thereof |
| CN103588590A (en) * | 2013-11-19 | 2014-02-19 | 广西新方向化学工业有限公司 | Pesticide fertilizer special for root-knot nematode prevention |
| CN103848688A (en) * | 2014-03-21 | 2014-06-11 | 润禾泰华生物科技（北京）有限公司 | Special liquid pesticide-containing fertilizer capable of increasing output, killing pests and degrading pesticide residues of apples and preparation method thereof |
| CN103848689A (en) * | 2014-03-21 | 2014-06-11 | 润禾泰华生物科技（北京）有限公司 | Special liquid pesticide fertilizer for production increase, insect killing and residual reduction of tomatoes, and preparation method thereof |
| CN107105663A (en) * | 2014-12-02 | 2017-08-29 | 江苏龙灯化学有限公司 | Nematicidal composition and application thereof |
| CN108191526A (en) * | 2018-01-23 | 2018-06-22 | 安徽嘉联生物科技有限公司 | A kind of Pesticidal foliage fertilizer composition suitable for vegetables |
| CN108218591A (en) * | 2018-04-10 | 2018-06-29 | 内蒙古新威远生物化工有限公司 | A kind of medicine fertilizer containing Avermectin B2 |
| CN108329112A (en) * | 2018-03-30 | 2018-07-27 | 内蒙古拜克生物有限公司 | A kind of medicine fertilizer and preparation method thereof containing avermectin |
| CN114190398A (en) * | 2021-12-15 | 2022-03-18 | 内蒙古天创药业科技股份有限公司 | Preparation method of pesticide for preventing and controlling underground pests |
| CN114271288A (en) * | 2022-01-05 | 2022-04-05 | 安徽丰乐农化有限责任公司 | Granular pesticide fertilizer containing meptyldinocap and matrine and application thereof |
| CN115745693A (en) * | 2022-11-25 | 2023-03-07 | 中国农业大学 | Pesticide slow-release pesticide fertilizer granules and preparation method and application thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1654446A (en) * | 2005-02-25 | 2005-08-17 | 张洪昌 | Nuisance-free medicinal fertilizer for prevention and control of wireworm and soil insect and its production method |
| CN101016219A (en) * | 2007-02-14 | 2007-08-15 | 湖北农本化工有限公司 | Pharmaceutical bottom fertilizer granule for preventing cotton sprout plant diseases and insect pests |
| US20080200561A1 (en) * | 2004-09-14 | 2008-08-21 | Bayer Cropscience Gmbh | Emulsifiable Granules Formulations With Boron Containing Fertilisers |
| CN101514128A (en) * | 2009-04-07 | 2009-08-26 | 玉溪山水生物科技有限责任公司 | Micro-encapsulated broad spectrum pollution-free fertilizer with pesticide, preparation method and application thereof |
-
2010
- 2010-07-28 CN CN201010239747.4A patent/CN101906001B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20080200561A1 (en) * | 2004-09-14 | 2008-08-21 | Bayer Cropscience Gmbh | Emulsifiable Granules Formulations With Boron Containing Fertilisers |
| CN1654446A (en) * | 2005-02-25 | 2005-08-17 | 张洪昌 | Nuisance-free medicinal fertilizer for prevention and control of wireworm and soil insect and its production method |
| CN101016219A (en) * | 2007-02-14 | 2007-08-15 | 湖北农本化工有限公司 | Pharmaceutical bottom fertilizer granule for preventing cotton sprout plant diseases and insect pests |
| CN101514128A (en) * | 2009-04-07 | 2009-08-26 | 玉溪山水生物科技有限责任公司 | Micro-encapsulated broad spectrum pollution-free fertilizer with pesticide, preparation method and application thereof |
Non-Patent Citations (2)
| Title |
|---|
| 《中国农学通报》 20080630 吴传万等 一种防治线虫和地下害虫之生态药肥的研发 358-361 1-13 第24卷, 第6期 * |
| 《磷肥与复肥》 20070531 张洪昌等 防治线虫和地下害虫药肥的研发 47-49 1-13 第22卷, 第3期 * |
Cited By (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102329177A (en) * | 2011-06-28 | 2012-01-25 | 安徽莱姆佳肥业有限公司 | Preparation and application of compound fertilizer for preventing and controlling underground pests of Chinese medicinal material |
| CN102633566A (en) * | 2012-03-27 | 2012-08-15 | 何勇 | Pesticide fertilizer |
| CN102633566B (en) * | 2012-03-27 | 2014-04-30 | 何勇 | Pesticide fertilizer |
| CN103044161A (en) * | 2012-12-21 | 2013-04-17 | 浙江建中竹业科技有限公司 | Method for preparing organic fertilizer from plant charcoal and wood vinegar |
| CN103242108A (en) * | 2013-05-16 | 2013-08-14 | 山东亿丰源生物科技股份有限公司 | Drug fertilizer preparation containing chlorpyrifos and organic fertilizer |
| CN103319278A (en) * | 2013-05-23 | 2013-09-25 | 锦州硕丰农药集团有限公司 | Multifunctional pesticide fertilizer and production method thereof |
| CN103588590A (en) * | 2013-11-19 | 2014-02-19 | 广西新方向化学工业有限公司 | Pesticide fertilizer special for root-knot nematode prevention |
| CN103848689B (en) * | 2014-03-21 | 2016-03-23 | 润禾泰华生物科技（北京）有限公司 | Residual Special-purpose liquid pesticide-containing fertilizer and preparation method thereof falls in a kind of tomato volume increase desinsection |
| CN103848688B (en) * | 2014-03-21 | 2015-09-09 | 润禾泰华生物科技（北京）有限公司 | Residual Special-purpose liquid pesticide-containing fertilizer of a kind of apple volume increase desinsection degraded agriculture and preparation method thereof |
| CN103848688A (en) * | 2014-03-21 | 2014-06-11 | 润禾泰华生物科技（北京）有限公司 | Special liquid pesticide-containing fertilizer capable of increasing output, killing pests and degrading pesticide residues of apples and preparation method thereof |
| CN103848689A (en) * | 2014-03-21 | 2014-06-11 | 润禾泰华生物科技（北京）有限公司 | Special liquid pesticide fertilizer for production increase, insect killing and residual reduction of tomatoes, and preparation method thereof |
| GB2533082B (en) * | 2014-12-02 | 2019-10-16 | Rotam Agrochem Int Co Ltd | A nematicidal composition and the use thereof |
| CN107105663A (en) * | 2014-12-02 | 2017-08-29 | 江苏龙灯化学有限公司 | Nematicidal composition and application thereof |
| US11407691B2 (en) | 2014-12-02 | 2022-08-09 | Jiangsu Rotam Chemistry Co., Ltd. | Nematicidal composition and the use thereof |
| CN108191526A (en) * | 2018-01-23 | 2018-06-22 | 安徽嘉联生物科技有限公司 | A kind of Pesticidal foliage fertilizer composition suitable for vegetables |
| CN108329112A (en) * | 2018-03-30 | 2018-07-27 | 内蒙古拜克生物有限公司 | A kind of medicine fertilizer and preparation method thereof containing avermectin |
| CN108329112B (en) * | 2018-03-30 | 2021-04-09 | 内蒙古拜克生物有限公司 | Pesticide fertilizer containing abamectin and preparation method thereof |
| CN108218591A (en) * | 2018-04-10 | 2018-06-29 | 内蒙古新威远生物化工有限公司 | A kind of medicine fertilizer containing Avermectin B2 |
| CN114190398A (en) * | 2021-12-15 | 2022-03-18 | 内蒙古天创药业科技股份有限公司 | Preparation method of pesticide for preventing and controlling underground pests |
| CN114271288A (en) * | 2022-01-05 | 2022-04-05 | 安徽丰乐农化有限责任公司 | Granular pesticide fertilizer containing meptyldinocap and matrine and application thereof |
| CN115745693A (en) * | 2022-11-25 | 2023-03-07 | 中国农业大学 | Pesticide slow-release pesticide fertilizer granules and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101906001B (en) | 2014-04-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101906002B (en) | Pesticide fertilizer and application thereof as well as preparation methods of grain-type pesticide fertilizer and powder-type pesticide fertilizer | |
| CN101906001B (en) | Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer | |
| CN101891560A (en) | Pesticide-added fertilizer containing avermectins and oligosaccharide and preparation method thereof | |
| AU2014101391B4 (en) | Multifunctional organic agricultural fertilizer composition and process for preparation thereof | |
| CN102344309A (en) | Throwing applying agent and preparation method thereof | |
| CN104672029A (en) | Pesticide fertilizer containing lythidathion | |
| AU2016221585B2 (en) | Acid composition based on leonardite and amino acids | |
| CN102907424B (en) | Micro-capsule suspending agent containing pendimethalin | |
| CN101973822A (en) | Pollution-free medicinal fertilizer capable of trapping and killing pests and promoting plant growth and preparation method thereof | |
| CN102674947A (en) | Water-solubility foliar fertilizer for blue seedlings and application thereof | |
| CN105859421A (en) | Rice functional foliage fertilizer formulation and preparation method and application thereof | |
| CN106116886A (en) | Medicine containing avilamycin and fosthiazate is fertile and preparation method thereof | |
| CN107056465A (en) | A kind of wheat soil improvement type fertilizer | |
| CN103518729B (en) | Insecticidal acaricidal composition and application thereof | |
| CN102503739B (en) | Compound fertilizer of toxic fluorine-phosphorus and foliage fertilizer | |
| CN104151088A (en) | Pesticide fertilizer slow release preparation, as well as preparation method and application method thereof | |
| CN108432748A (en) | A kind of attapulgite and preparation method thereof for farm chemical carrier | |
| CN105851009A (en) | Synergistic weeding composition containing biscarfentrazone and tralkoxydim and application of synergistic weeding composition | |
| CN102150668B (en) | Herbicide composition, preparation and application thereof | |
| CN102302038B (en) | Weedicide for orchards and forest lands | |
| CN105541506A (en) | Paddy-field pesticide-fertilizer sustained release granules and preparing method and application method thereof | |
| CN105399565A (en) | Multifunctional suspending seed coating agent for corn and preparation method of multifunctional suspending seed coating agent | |
| CN101326918A (en) | Water-soluble granular formulation containing Imidacloprid, and preparation and use thereof | |
| CN103027051B (en) | Microcapsule suspending-suspending agent containing pendimethalin | |
| CN110240516A (en) | Add the liquid fertilizer and its preparation method and application of lignosulfonates synthesis urea phosphate |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C41 | Transfer of patent application or patent right or utility model | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20160829 Address after: 518102 Xixiang Reservoir Road, Shenzhen, Guangdong, No. 113, No. Patentee after: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Patentee after: Shenzhen elephant industry Ltd. Address before: 518102 Xixiang Reservoir Road, Shenzhen, Guangdong, No. 113, No. Patentee before: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. |
|
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee after: Shenzhen Novozon Crop Science Co.,Ltd. Country or region after: China Patentee after: Shenzhen elephant industry Ltd. Address before: 518102 No. 113 Reservoir Road, Baoan District, Guangdong, Shenzhen, Xixiang Patentee before: SHENZHEN NOPOSION AGROCHEMICALS Co.,Ltd. Country or region before: China Patentee before: Shenzhen elephant industry Ltd. |