CN101016219A - Pharmaceutical bottom fertilizer granule for preventing cotton sprout plant diseases and insect pests - Google Patents
Pharmaceutical bottom fertilizer granule for preventing cotton sprout plant diseases and insect pests Download PDFInfo
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- CN101016219A CN101016219A CNA2007100515544A CN200710051554A CN101016219A CN 101016219 A CN101016219 A CN 101016219A CN A2007100515544 A CNA2007100515544 A CN A2007100515544A CN 200710051554 A CN200710051554 A CN 200710051554A CN 101016219 A CN101016219 A CN 101016219A
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- thiram
- provado
- triazolone
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Abstract
The invention discloses a drug substrate fertilizer particle agent to prevent cotton seeding pest, which is characterized by the following: adopting nitrogen, phosphor, potassium or composite fertilizer as carrier; allocating imidacloprid, thiram, triazole ketone and adjuvant according to certain proportion; making the drug particle agent; modifying the nourishing condition and seeding growing environment; reinforcing pest-proof and growing property.
Description
Affiliated technical field
The present invention relates to the mixture of fertilizer and agricultural chemicals, be meant a kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest specifically.
Technical background
Cotton should transplanted the fertile nitrogen in ditch spread vola, cave, phosphorus, potassium to guarantee the needs of cotton in seedling stage process of growth fertilizer before transplanting.Cotton in seedling stage is the multiple phase of disease, insect pest, also has causing harm of subterranean pest-insect such as cutworm etc. as rhizoctonia rot of cotton, cotton anthracnose, red rot and cotton aphid.
China rural area is generally adopted when cotton replanting and is being transplanted the mode that the cave is located sealing fertilizer or added sterilant such as derosal, every mu of consumption is respectively about 20 kilograms, 1～2 kilogram of earthing, one, after two weeks again to cotton seedling spraying insecticide, not only take time but also can not guarantee drug effect.
The particulate state pesticide formulation that granular pesticide system is processed into by former medicine, carrier and auxiliary agent.It has advantages such as safe in utilization, convenient: micro mist flies upward when 1) avoiding spreading, pollutes surrounding environment.2) reduce the dispenser process, operator's health is non-cohesive or suck micro mist, can avoid intoxication accident.And when using formulations such as missible oil, pulvis, operator's health is adhered to or suck medicament, cause personal intoxication accident.3) release rate of effective constituent in the may command granule prolongs the lasting period.4) have directivity during dispenser, make the place that the granule of removing cloth can arrive really to be needed.5) be not attached on the stem leaves of plants, avoiding directly, contact produces poisoning.6) improve dispenser efficient, reduce the recruitment cost.In a word, granular pesticide is a kind of safe in utilization, and is convenient, the good formulation that the lasting period is long.
Provado makes imidacloprid, benefit reach genus anabasines such as amine, person who has rendered outstanding service, Gao Qiao, Amy pleasure again, is a kind of ultra-high efficiency sterilant of brand new, has the agriculture characteristic of the following aspects.1) insecticidal action mechanism uniqueness.It is a nerve poison, and its action target is the nicotinic acid acetylcholinesterase acceptor of pest body neural system postsynaptic membrane, disturb the pest movements neural system to stimulate conduction normally, thereby it is deadly to show as paralysis.2) wide spectrum, efficient, the lasting period is long.Provado uses more than 80 national 60 various crop, is the highest insecticide variety of global marketing volume.Insect such as the aphid of piercing-sucking mouthparts, leafhopper and coleopteran pest are had extraordinary prevention effect, the drug effect phase can reach around for.3) be more suitable for handling soil and seed.Insect had stomach toxicity and action of contace poison.Behind the foliar spray, though drug effect is good, the lasting period is also long, and the medicament that is trapped in cauline leaf is the primary structure of Provado always, and the interior suction effect of plant is relatively poor.
At present, the application of Provado on cotton mainly is control cotten aphid, cotton thrips.Thereby two problems deserving of attention on producing and use, China are arranged:
One, Provado product are spray method and use, but foliar spray is not the best using method of Provado.
Its two, the controlling object face of imidacloprid pesticide registration is too narrow, mostly is rice planthoppers of rice and wheat budworm, has not given play to the due advantage of Provado.
Thiram belongs to the dithiocarbamate sterilant; provide protection is strong, and has a broad antifungal spectrum is owing to have good prevention effect to the disease of seed transmission and soil infection in seedling stage; in very long one section, be mainly used in seed treatment and soil treatment, also be widely used in foliage-spray at present.Another important use of thiram is as the composite companion's medicine of systemic fungicide, promptly with the composite mixed bactericide of making of multiple interior suction therapeutical agent, and can be composite with other protective fungicide.Thereby thiram is widely used a kind of sterilant.Can prevent and treat damping-off, root rot, black root, ring spot etc.
Triazolone makes triadimefon, hundred li logical again, is the triazole bactericidal agent of first widespread use.
Triazolone can cauline leaf spraying, handle seed, handle multiple modes such as soil and use.It is the strong sterilant of interior absorption efficient, that the lasting period is long, and the lasting period can reach 80-100 days, has prevention, treats, roots out, fumigation action, and its mechanism of action mainly is suppress the germ ergosterol synthetic, thus inhibition mycelial growth and sporulation.Triazolone is mainly used in control cotton in seedling stage root disease, as the root disease that is caused by rhizoctonia rot of cotton, cotton anthracnose, cotton red rot etc.Triazolone also has certain growth regulating effect to cotton seedling in addition.
Chinese patent notification number: CN 1182084C, the day for announcing: on December 29th, 2004, denomination of invention " antibacterial compounded medicinal fertilizer ", proposed by nitrogen, phosphorus, potash fertilizer and how, m-tetrachlorophthalodinitrile, Trichlorphon, the formulated composite fertilizer with pesticide of Volaton, can effectively prevent and treat subterranean pest-insect, reduce the breeding potential of insect, reach purpose antibiotic, volume increase.Can be applicable to cash crop such as corn, cotton, vegetables.But this technical scheme toxicity is bigger, and environment is had certain pollution, and is not strong to the specific aim of the cotton in seedling stage root disease and the prevention and control of plant diseases, pest control, the interior absorption of its medicine a little less than, the desinsection lasting period is shorter.Particularly this composite fertilizer with pesticide is difficult for making shaped particles, is not easy to transportation and storage, and the volatilization concentration value is stable inadequately, is difficult to satisfy the requirement of chemical fertilizer or Pesticidal products standard,
Summary of the invention
The objective of the invention is to overcome existing in prior technology defective and deficiency, and then a kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest is provided.Its volatilization concentration value is more stable, and disinfection and desinsection efficiency time are long, meets chemical fertilizer or pesticide producing requirement, and is easy to use and safe and reliable.
The object of the present invention is achieved like this: a kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest, and the weight part content of each raw material is:
At least a 20-100 in nitrogenous fertilizer, phosphate fertilizer and the potash fertilizer
Provado 0.01-5
Thiram 0.01-35
Triazolone 0.01-15
Binding agent 2-30
Sorbent material 10-20
Disintegrating agent 1-10
Wetting agent 0.5-5
Stablizer 1-10
Lubricant 2-5
Signal coloration pigment 0.5-2
Wherein binding agent is polyvinyl alcohol water solution or gum arabic, sorbent material is a white carbon black, and disintegrating agent is that at least a, wetting, the dispersion agent in calcium chloride, magnesium chloride and the sulphur ammonium is sodium lignosulfonate or sodium alkyl benzene sulfonate, stablizer is a Zinic stearas, and lubricant is talcum powder or lubricating oil.
Provado, thiram and triazolone adopt the former medicine of pulvis among the present invention, and its fineness is the 100-200 order.
The present invention can also make wherein Provado: thiram: triazolone=3-5: 20: 5.
The present invention can also make the weight part content of each raw material be:
N: P
2O
5: K
2O=12: 7: 6 composite fertilizer 67.8
Provado 0.083
Thiram 0.556
Triazolone 0.15
Polyvinyl alcohol 6
White carbon black 10
Calcium chloride 5
Sodium lignosulfonate 3
Zinic stearas 5
Talcum powder 2
Signal coloration pigment 0.5
The present invention can also make the weight part content of each raw material be:
N: P
2O
5: K
2O=13: 9: 8 composite fertilizer 100
Provado 0.1
Thiram 0.66
Triazolone 0.165
Polyvinyl alcohol 8.5
White carbon black 14
Magnesium chloride 6
Sodium alkyl benzene sulfonate 4
Zinic stearas 7
Talcum powder 3
Signal coloration pigment 0.8
The present invention can also make the weight part content of each raw material be:
N: P
2O
5: K
2O=13: 11: 10 composite fertilizer 100
Provado 0.3
Thiram 2
Triazolone 0.5
Gum arabic 1
White carbon black 14
Sulphur ammonium 8
Sodium alkyl benzene sulfonate 4
Zinic stearas 7
Vegetables oil 3
Signal coloration pigment 0.8
The present invention can also make the weight part content of each raw material be:
The nitrogenous fertilizer of N=50 or P
2O
5=35 phosphate fertilizer 100
Provado 0.4
Good fortune U.S. 2
Triazolone 0.5
Polyvinyl alcohol 8.5
White carbon black 14
Calcium chloride 6
Sodium lignosulfonate 5
Zinic stearas 8
Mineral lubricating oils 3
Signal coloration pigment 0.7
Compared with prior art, beneficial effect of the present invention is: 1, and the former medicine of Provado is applied to granule and as the purposes of killing subterranean pest-insect and the cotton seedling insect pest of control, triazolone is used for preventing and treating disease in cotton seedling stage.After being mixed by suitable proportion, its Provado, thiram and triazolone good effect is all arranged for control disease in cotton seedling stage, cotton aphid and subterranean pest-insect.The domestic unregistered use at present of its Provado is in the control of subterranean pest-insect.The applicant finds by experimental study, soil or the seed handled through Provado, underground insect there is good insecticidal effect, and because its good interior absorption, it is higher to be absorbed the meta-bolites insecticidal activity enter behind the plant by root system of plant, promptly play insecticidal action jointly by Provado substance and meta-bolites thereof, disease-resistant, the pest-resistant harmful ability of plant strengthens, and prevention effect is higher.2, the present invention has determined with the chemical fertilizer to be carrier, and Provado, triazolone, thiram and auxiliary agent are mixed with fertilizer granules in certain science ratio.Can improve cotton growing stage desired nutritional condition and growth of seedlings environment, strengthen cotton seedling life entity resistance, resistant to diseases and insects and growth characteristics, the purpose of reach that seedling is neat, seedling is complete, seedling is strong makes the cotton plant branches and leaves luxuriant, satisfies high-quality, highly efficient and productive cultivation requirement.3, the adjuvant used process of the present invention is selected collocation meticulously, reasonable ratio, particularly used stablizer chemical property is stable, can not destroy its chemical ingredients when combining with medicine, the medicine usefulness of fertilizer granules is improved, heat storage stability is good, and the lasting period is long, good looking appearance, plastid metric model, indexs such as disintegrating property and chloride ion content all meet the specification of quality of granular pesticide and chemical fertilizer product.
Embodiment
Below the present invention is described in further detail by embodiment:
A kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest of the present invention, the weight part content of each raw material is:
At least a 20-100 in nitrogenous fertilizer, phosphate fertilizer and the potash fertilizer
Provado 0.01-5
Thiram 0.01-35
Triazolone 0.01-15
Binding agent 2-30
Sorbent material 10-20
Disintegrating agent 1-10
Wetting agent 0.5-5
Stablizer 1-10
Lubricant 2-5
Signal coloration pigment 0.5-2
Wherein binding agent is polyvinyl alcohol water solution or gum arabic, sorbent material is a white carbon black, and disintegrating agent is that at least a, wetting, the dispersion agent in calcium chloride, magnesium chloride and the sulphur ammonium is sodium lignosulfonate or sodium alkyl benzene sulfonate, stablizer is a Zinic stearas, and lubricant is talcum powder or lubricating oil.
For improving the uniformity coefficient of medicament mixed, strengthen desinsection and antiviral effect, Provado, thiram and triazolone adopt the former medicine of pulvis, and its fineness is the 100-200 order.Wherein three kinds of preferable combination matchings of medicine are: Provado: thiram: triazolone=3-5: 20: 5.
Embodiment 1:
By the weight part proportioning of the raw material processing fertilizer granules that feeds intake; be uniform mixing that guarantees pharmaceutical cpd and chemical fertilizer and auxiliary agent and the action effect that improves medicine; can be earlier with Provado that market is purchased (90%); it is 150 orders that the former medicine of pulvis of thiram (90%) and triazolone (85%) is ground to fineness respectively; restart tablets press and stir that slowly to drop into 678 kilograms of content again be 25% composite fertilizer (N: P: K=12: 7: 6); drop into 0.83 kilogram of Provado then; 5.56 kilograms of thiram; 1.5 kilograms of triazolones; drop into 60 kilograms of polyvinyl alcohol water solutions after the mixing and stirring respectively; 100 kilograms of white carbon blacks; 50 kilograms in calcium chloride; 30 kilograms of sodium lignosulfonates; 50 kilograms of Zinc Stearates; 20 kilograms of talcum powder; 5 kilograms of blue pigmentss stir.Routinely the chemical fertilizers production mode through granulation, screen smooth uniform pyrrole good fortune ketone agricultural chemicals fertilizer granular formulation.
Embodiment 2
By the weight part proportioning of the raw material processing fertilizer granules that feeds intake; earlier with Provado that market is purchased (90%); it is 150 orders that the former medicine of pulvis of thiram (90%) and triazolone (85%) is ground to fineness respectively; restart tablets press and stir that slowly to drop into 678 kilograms of content again be 30% composite fertilizer (N: P: K=13: 9: 8); drop into 0.83 kilogram of Provado then; 5.56 kilograms of thiram; 1.5 kilograms of triazolones; drop into 60 kilograms of polyvinyl alcohol water solutions after the mixing and stirring respectively; 100 kilograms of white carbon blacks; 50 kilograms in calcium chloride; 30 kilograms of sodium lignosulfonates; 50 kilograms of Zinc Stearates; 20 kilograms of talcum powder, 5 kilograms of blue pigmentss stir.Routinely the chemical fertilizers production mode through granulation, screen smooth uniform pyrrole good fortune ketone agricultural chemicals fertilizer granular formulation.
Embodiment 3
By the weight part proportioning of the raw material processing fertilizer granules that feeds intake; earlier with Provado that market is purchased (90%); it is 150 orders that the former medicine of pulvis of thiram (90%) and triazolone (85%) is ground to fineness respectively; restart tablets press and stir that slowly to drop into 678 kilograms of content again be 35% composite fertilizer (N: P: K=13: 11: 10); drop into 0.83 kilogram of Provado then; 5.56 kilograms of thiram; 1.5 kilograms of triazolones; drop into 60 kilograms of polyvinyl alcohol water solutions after the mixing and stirring respectively; 100 kilograms of white carbon blacks; 50 kilograms in calcium chloride; 30 kilograms of sodium lignosulfonates; 50 kilograms of Zinc Stearates; 20 kilograms of talcum powder, 5 kilograms of blue pigmentss stir.Routinely the chemical fertilizers production mode through granulation, screen smooth uniform pyrrole good fortune ketone agricultural chemicals fertilizer granular formulation.
Embodiment 4
Press the weight part proportioning processing fertilizer granules of raw material; earlier with Provado that market is purchased (90%); it is 150 orders that the former medicine of pulvis of thiram (90%) and triazolone (85%) is ground to fineness respectively; restart tablets press and stir that slowly to drop into 1000 kilograms of content again be 30% composite fertilizer (N: P: K=13: 9: 8); drop into 1 kilogram of Provado then; 1.65 kilograms of 6.6 kilograms of thiram and triazolones; drop into 85 kilograms of polyvinyl alcohol after the mixing and stirring respectively; 140 kilograms of white carbon blacks; 60 kilograms in magnesium chloride; 40 kilograms of sodium alkyl benzene sulfonates; 70 kilograms of Zinc Stearates; 30 kilograms of talcum powder, 8 kilograms of blue pigmentss stir.Routinely the chemical fertilizers production mode through granulation, screen smooth uniform pyrrole good fortune ketone agricultural chemicals fertilizer granular formulation.
Embodiment 5
Press the weight part proportioning processing fertilizer granules of raw material; earlier with Provado that market is purchased (90%); it is 180 orders that the former medicine of pulvis of thiram (90%) and triazolone (85%) is ground to fineness respectively; restart tablets press and stir that slowly to drop into 1000 kilograms of content again be 35% composite fertilizer (N: P: K=13: 11: 10); drop into 3 kilograms of Provados then; 20 kilograms of thiram; 5 kilograms of triazolones; drop into 10 kilograms of gum arabics after the mixing and stirring respectively; 140 kilograms of white carbon blacks; 80 kilograms of sulphur ammoniums; 40 kilograms of sodium alkyl benzene sulfonates; 70 kilograms of Zinc Stearates; 30 kilograms of vegetables oil; 8 kilograms of blue pigmentss stir.Routinely the chemical fertilizers production mode through granulation, screen smooth uniform pyrrole good fortune ketone agricultural chemicals fertilizer granular formulation.
Embodiment 6
Press the weight part proportioning processing fertilizer granules of raw material; earlier with Provado that market is purchased (90%); it is 180 orders that the former medicine of pulvis of thiram (90%) and triazolone (85%) is ground to fineness respectively; restart tablets press and stir the nitrogenous fertilizer that slowly drops into 1000 kilograms of content 50% again; drop into 4 kilograms of Provados then; 20 kilograms of thiram; 5 kilograms of triazolones; drop into 85 kilograms of polyvinyl alcohol after the mixing and stirring respectively; 140 kilograms of white carbon blacks; 60 kilograms in calcium chloride; 50 kilograms of sodium lignosulfonates; 80 kilograms of Zinc Stearates; 30 kilograms of mineral lubricating oilss; 7 kilograms of blue pigmentss stir.Routinely the chemical fertilizers production mode through granulation, screen smooth uniform pyrrole good fortune ketone agricultural chemicals fertilizer granular formulation.
The adjuvant used proportioning of above embodiment is by following experiment screening gained:
A is by the pyrrole good fortune ketone agricultural chemicals fertilizer granular formulation of 678 kilograms of composite fertilizers (N: P: K=13: 7: 6)+5.56 kilograms of (90%)+triazolones of 0.83 kilogram of (90%)+thiram of Provado 1.5 kilograms (85%) and auxiliary agent preparation among the embodiment 1 in table 1, table 2.
B is by the pyrrole good fortune ketone agricultural chemicals fertilizer granular formulation of 678 kilograms of composite fertilizers (N: P: K=13: 9: 8)+5.56 kilograms of (90%)+triazolones of 0.83 kilogram of (90%)+thiram of Provado 1.5 kilograms (85%) and auxiliary agent preparation among the embodiment 2.
C is by the pyrrole good fortune ketone agricultural chemicals fertilizer granular formulation of 678 kilograms of composite fertilizers (N: P: K=13: 11: 10)+5.56 kilograms of (90%)+triazolones of 0.83 kilogram of (90%)+thiram of Provado 1.5 kilograms (85%) and auxiliary agent preparation among the embodiment 3.
Table 1: the best proportioning screening of auxiliary agent table
| Auxiliary agent | A | The result |
| Calcium chloride | 60 | The chlorion index is defective |
| 50 | The chlorion index is qualified | |
| 40 | The chlorion index is qualified | |
| Sodium lignosulfonate | 20 | The disintegration rate is defective |
| 30 | The disintegration rate is qualified | |
| 40 | The disintegration rate is qualified | |
| Zinc Stearate | 50 | Heat storage stability is qualified |
| 40 | Heat storage stability is qualified | |
| 30 | Heat storage stability is defective | |
| Talcum powder | 15 | Stream fortune property is poor |
| 20 | Good fluidity | |
| 25 | Good fluidity | |
| Pigment | 4 | Appearance poor |
| 5 | Outward appearance is good | |
| 6 | Outward appearance is good | |
| Polyvinyl alcohol | 70 | Granularity is defective |
| 60 | Granularity is qualified | |
| 50 | Granularity is defective | |
| White carbon black | 86 | Moisture is defective |
| 100 | Moisture is qualified | |
| 114 | Granularity is defective |
According to The selection result in the table 1 and cost consideration, we have selected one group of optimum content proportioning to each component, and carry out the check of three groups of embodiment, and the result all reaches the product technology standard, and the result is referring to table 2:
Table 2: best auxiliary agent proportioning is mixed its performance table of back with different content fertilizer, medicine
| Auxiliary agent | A | B | C |
| Calcium chloride | 50 | 50 | 50 |
| Sodium lignosulfonate | 30 | 30 | 30 |
| Zinc Stearate | 40 | 40 | 40 |
| Talcum powder | 20 | 20 | 20 |
| Pigment | 5 | 5 | 5 |
| Polyvinyl alcohol | 60 | 60 | 60 |
| White carbon black | 100 | 100 | 100 |
| The result | Every index is all qualified | Every index is all qualified | Each lattice index is all qualified |
The medicine fertilizer that embodiment of the invention 1-3 is made detects its main physico-chemical parameter or control project by the technical indicator of the fertile granular preparation of medicine, and its result is referring to table 3:
Table 3: the main physico-chemical parameter master meter of fertilizer granules of the present invention
| Main physico-chemical parameter or control project | The qualified index of preparation | The embodiment check data | ||
| Embodiment 1 | Embodiment 2 | Embodiment 3 | ||
| The Provado mass percent, % 〉= | 0.075 | 0.081 | 0.079 | 0.078 |
| The thiram massfraction, % 〉= | 0.125 | 0.131 | 0.127 | 0.129 |
| The triazolone massfraction, % 〉= | 0.5 | 0.54 | 0.52 | 0.53 |
| Total nutrient (N+P 2O 5+K 2O)，％≥ | 25、30、35 | 26 | 30 | 34 |
| Chlorion (CI -)， ％≤ | 3.0 | 2.7 | 2.8 | 2.7 |
| Moisture, %≤ | 3.0 | 2.6 | 2.4 | 2.5 |
| Granularity (3.35mm～5.60mm), % 〉= | 90 | 3.8 | 4.2 | 4.5 |
| Expulsion rate, %≤ | 5.0 | 4.3 | 4.1 | 4.6 |
| Heat storage stability | Qualified | Qualified | Qualified | Qualified |
| Remarks: Provado, triazolone, thiram all adopt liquid chromatography to separate and mensuration, and external standard method is quantitative, and composite fertilizer's total nutrient adopts chemical determination. | ||||
The present invention has also done Toxicity Determination to the sample of embodiment 1-3, and the result shows that its medicine is fertile composite and have a synergism, and its data are referring to table 4, table 5, and table 6:
Annotate: on behalf of triazolone, F, S represent thiram, B to represent Provado in the following data
1. thiram+triazolone is tested cotton standing dead bacterium indoor biometrics
Be mixed back SF (1: 3) and SF (1: 4) increases to the virulence of cotton seedling blight germ, and synergism is arranged, and wherein the most obvious with triazolone and thiram 1: 4 o'clock, its cotoxicity coefficient reaches 134.14.The result is referring to table 4.
Table 4: the different proportionings with thiram of triazolone are to the toxicity test of cotton standing dead bacterium table as a result
| Handle | Virulence regression equation | Relation conefficient | ED 50 (μg/mL) | The actual toxicity index ATI of mixture | The theoretical toxicity index TTI of mixture | Cotoxicity coefficient CTC |
| Triazolone (S) | Y＝4.366+1.197X | 0.9419 | 3.38 | 100 | / | / |
| Thiram (F) | Y＝3.685+0.970X | 0.9074 | 22.68 | 14.93 | / | / |
| SF(1∶1) | Y＝4.031+1.045X | 0.9842 | 8.46 | 42.00 | 57.46 | 73.09 |
| SF(1∶2) | Y＝3.943+1.073X | 0.9315 | 9.66 | 35.04 | 43.28 | 80.95 |
| SF(1∶3) | Y＝4.100+0.933X | 0.9904 | 9.2 | 36.79 | 36.19 | 101.65 |
| SF(1∶4) | Y＝4.138+0.958X | 0.9777 | 7.9 | 42.84 | 31.94 | 134.14 |
| SF(1∶5) | Y＝3.369+1.370X | 0.9843 | 15.5 | 27.00 | 29.10 | 92.77 |
2. thiram+triazolone+Provado tests cotton standing dead bacterium indoor biometrics
Before this desinsection component is added thiram+triazolone mixture by suitable proportion, and select its ED
50The proportioning of minimum thiram+triazolone is carried out next step test.The result shows, the ED50 of thiram+triazolone and Provado+thiram+triazolone is respectively 8.12 and 7.27, cotoxicity coefficient is 111.81, and visible Provado+thiram+triazolone is higher than thiram+triazolone to the virulence of cotton seedling blight germ, certain synergism is arranged.The result is referring to table 5.
Table 5: the different proportionings of triazolone+thiram+Provado are to the toxicity test of cotton standing dead bacterium table as a result
| Handle | Virulence regression equation | Relation conefficient | ED50(μg/mL) | Cotoxicity coefficient CTC |
| SF(1∶4) SFB(1∶4∶0.6) | Y＝4.171+0.911X Y＝4.191+0.939X | 0.9900 0.9848 | 8.12 7.27 | 111.81 |
3. thiram+triazolone+Provado is tested the cotten aphid indoor biometrics
The result shows that Provado+thiram+triazolone and Provado are to the LD of cotton aphid
50Be respectively 2.1645 and 2.7862, cotoxicity coefficient is 128.72, and Provado+thiram+triazolone is higher than thiram+triazolone to the virulence of cotton aphid, and test-results is referring to table 6.
Table 6: the different proportionings of triazolone+thiram+Provado are to the toxicity test of cotton aphid table as a result
| Handle | Virulence regression equation | Relation conefficient | LD50(μg/mg) | Cotoxicity coefficient CTC |
| B SFB(1∶4∶0.6) | Y＝4.5836+0.9358X Y＝4.6508+1.0414X | 0.9900 0.9848 | 2.7862 2.1645 | 128.72 |
The present invention makes the fertilizer granules sample by the proportioning of embodiment 2,2006 on farm, the north of the Changjiang River, Jingzhou City with Hubei Province the assorted cotton volume increase that be object has carried out applying base fertilizer for No. four test.The using method of fertilizer granules and consumption are identical with common composite fertilizer using method and consumption, and its test-results is referring to table 7:
Table 7: volume increase test card in cotton field of the present invention
| The fertilizer title | Repeat | Flower rate % before the frost | Ginning outturn % | Velveteen length (mm) | Seed cotton yield (kg) |
| Blank | I II III IV | 78 74 76 79 | 38 38.5 39 39.4 | 30 29 28.5 30.2 | 290 300 294 303 |
| Medicine fertilizer of the present invention | I II III IV | 85 87 84 86 | 42.5 42.3 41.8 42 | 32.9 32.4 32.7 32.6 | 330 325 332 334 |
| Urea | I II III IV | 82 80 81 81 | 41.2 40.5 40.3 40.8 | 31.2 31.2 30.8 31.3 | 315 320 318 311 |
| Bicarbonate of ammonia | I II III IV | 80 79 79 81 | 39.8 39.9 40.2 39.8 | 30.5 30.7 31.2 30.9 | 305 312 315 309 |
| Calcium superphosphate | I II III IV | 79 78 79 80 | 39.3 38.7 39.2 39.4 | 30.5 30.4 30.9 30.6 | 308 311 309 312 |
| Salt lake potash fertilizer | I II III IV | 80 81 81 80 | 40.6 40.8 41.5 41.8 | 31.5 31.4 30.9 31.2 | 315 318 314 309 |
Claims (7)
1. medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest is characterized in that the weight part content of each raw material is:
At least a 20-100 in nitrogenous fertilizer, phosphate fertilizer and the potash fertilizer
Provado 0.01-5
Thiram 0.01-35
Triazolone 0.01-15
Binding agent 2-30
Sorbent material 10-20
Disintegrating agent 1-10
Wetting agent 0.5-5
Stablizer 1-10
Lubricant 2-5
Signal coloration pigment 0.5-2
Wherein binding agent is polyvinyl alcohol water solution or gum arabic, sorbent material is a white carbon black, and disintegrating agent is that at least a, wetting, the dispersion agent in calcium chloride, magnesium chloride and the sulphur ammonium is sodium lignosulfonate or sodium alkyl benzene sulfonate, stablizer is a Zinic stearas, and lubricant is talcum powder or lubricating oil.
2. a kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest according to claim 1 is characterized in that: Provado, thiram and triazolone adopt the former medicine of pulvis, and its fineness is the 100-200 order.
3. a kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest according to claim 1 and 2 is characterized in that: Provado wherein: thiram: triazolone=3-5: 20: 5.
4. a kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest according to claim 1 and 2 is characterized in that the weight part content of each raw material is:
N: P
2O
5: K
2O=12: 7: 6 composite fertilizer 67.8
Provado 0.083
Thiram 0.556
Triazolone 0.15
Polyvinyl alcohol 6
White carbon black 10
Calcium chloride 5
Sodium lignosulfonate 3
Zinic stearas 5
Talcum powder 2
Signal coloration pigment 0.5
5. a kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest according to claim 1 and 2 is characterized in that the weight part content of each raw material is:
N: P
2O
5: K
2O=13: 9: 8 composite fertilizer 100
Provado 0.1
Thiram 0.66
Triazolone 0.165
Polyvinyl alcohol 8.5
White carbon black 14
Magnesium chloride 6
Sodium alkyl benzene sulfonate 4
Zinic stearas 7
Talcum powder 3
Signal coloration pigment 0.8
6. a kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest according to claim 1 and 2,, it is characterized in that the weight part content of each raw material is:
N: P
2O
5: K
2O=13: 11: 10 composite fertilizer 100
Provado 0.3
Thiram 2
Triazolone 0.5
Gum arabic 1
White carbon black 14
Sulphur ammonium 8
Sodium alkyl benzene sulfonate 4
Zinic stearas 7
Vegetables oil 3
Signal coloration pigment 0.8
7. a kind of medicine base fertilizer granule of preventing and treating cotton seedling diseases insect pest according to claim 1 and 2,, it is characterized in that the weight part content of each raw material is:
The nitrogenous fertilizer of N=50 or P
2O
5=35 phosphate fertilizer 100
Provado 0.4
Thiram 2
Triazolone 0.5
Polyvinyl alcohol 8.5
White carbon black 14
Calcium chloride 6
Sodium lignosulfonate 5
Zinic stearas 8
Mineral lubricating oils 3
Signal coloration pigment 0.7
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100515544A CN100400480C (en) | 2007-02-14 | 2007-02-14 | Pharmaceutical bottom fertilizer granule for preventing cotton sprout plant diseases and insect pests |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNB2007100515544A CN100400480C (en) | 2007-02-14 | 2007-02-14 | Pharmaceutical bottom fertilizer granule for preventing cotton sprout plant diseases and insect pests |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101016219A true CN101016219A (en) | 2007-08-15 |
| CN100400480C CN100400480C (en) | 2008-07-09 |
Family
ID=38725462
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNB2007100515544A Expired - Fee Related CN100400480C (en) | 2007-02-14 | 2007-02-14 | Pharmaceutical bottom fertilizer granule for preventing cotton sprout plant diseases and insect pests |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN100400480C (en) |
Cited By (7)
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| CN101906002A (en) * | 2010-07-28 | 2010-12-08 | 深圳诺普信农化股份有限公司 | Pesticide fertilizer and application thereof as well as preparation methods of grain-type pesticide fertilizer and powder-type pesticide fertilizer |
| CN101906001A (en) * | 2010-07-28 | 2010-12-08 | 深圳诺普信农化股份有限公司 | Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer |
| CN102060630A (en) * | 2010-11-30 | 2011-05-18 | 福州康诺生态农业技术服务有限公司 | Insecticide-fertilizer special for sweet potato and preparation method thereof |
| CN102351610A (en) * | 2011-09-22 | 2012-02-15 | 安阳化学工业集团有限责任公司 | Insecticidal fertilizer |
| CN102613173A (en) * | 2012-02-24 | 2012-08-01 | 石家庄市龙汇精细化工有限责任公司 | Granule agent for control of soil insects and preparation method thereof |
| CN103004888A (en) * | 2012-05-16 | 2013-04-03 | 中国农业科学院植物保护研究所 | Metarrhizium anisopliae granular preparation and preparation method thereof |
| CN104140332A (en) * | 2014-08-08 | 2014-11-12 | 成都新柯力化工科技有限公司 | Water-soluble fertilizer synergist additive and preparation method thereof |
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| CN1072890C (en) * | 1999-01-15 | 2001-10-17 | 中国科学院生态环境研究中心 | Effervescence farm-chemical composition and production method thereof |
| CN1401238A (en) * | 2001-08-16 | 2003-03-12 | 付迎春 | Superfine powder seed treating agent |
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| AR056286A1 (en) * | 2005-03-24 | 2007-10-03 | Cheminova As | METHOD FOR PROTECTING A SOYBEAN PLANT WITH FLUTRIAFOL |
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| CN101906001A (en) * | 2010-07-28 | 2010-12-08 | 深圳诺普信农化股份有限公司 | Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer |
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| CN101906001B (en) * | 2010-07-28 | 2014-04-02 | 深圳诺普信农化股份有限公司 | Medicinal fertilizer, application thereof and method for preparing particle medicinal fertilizer and powder medicinal fertilizer |
| CN101906002B (en) * | 2010-07-28 | 2014-04-02 | 深圳诺普信农化股份有限公司 | Pesticide fertilizer and application thereof as well as preparation methods of grain-type pesticide fertilizer and powder-type pesticide fertilizer |
| CN102060630B (en) * | 2010-11-30 | 2013-06-26 | 福建美地有机农业有限公司 | Insecticide-fertilizer special for sweet potato and preparation method thereof |
| CN102060630A (en) * | 2010-11-30 | 2011-05-18 | 福州康诺生态农业技术服务有限公司 | Insecticide-fertilizer special for sweet potato and preparation method thereof |
| CN102351610A (en) * | 2011-09-22 | 2012-02-15 | 安阳化学工业集团有限责任公司 | Insecticidal fertilizer |
| CN102351610B (en) * | 2011-09-22 | 2013-04-17 | 安阳化学工业集团有限责任公司 | Insecticidal fertilizer |
| CN102613173A (en) * | 2012-02-24 | 2012-08-01 | 石家庄市龙汇精细化工有限责任公司 | Granule agent for control of soil insects and preparation method thereof |
| CN103004888A (en) * | 2012-05-16 | 2013-04-03 | 中国农业科学院植物保护研究所 | Metarrhizium anisopliae granular preparation and preparation method thereof |
| CN103004888B (en) * | 2012-05-16 | 2014-07-30 | 中国农业科学院植物保护研究所 | Metarrhizium anisopliae granular preparation and preparation method thereof |
| CN104140332A (en) * | 2014-08-08 | 2014-11-12 | 成都新柯力化工科技有限公司 | Water-soluble fertilizer synergist additive and preparation method thereof |
| CN104140332B (en) * | 2014-08-08 | 2016-04-06 | 成都新柯力化工科技有限公司 | A kind of Water soluble fertilizer Synergistic additives and preparation method thereof |
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|---|---|
| CN100400480C (en) | 2008-07-09 |
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