CN106116886A - Medicine containing avilamycin and fosthiazate is fertile and preparation method thereof - Google Patents
Medicine containing avilamycin and fosthiazate is fertile and preparation method thereof Download PDFInfo
- Publication number
- CN106116886A CN106116886A CN201610496094.5A CN201610496094A CN106116886A CN 106116886 A CN106116886 A CN 106116886A CN 201610496094 A CN201610496094 A CN 201610496094A CN 106116886 A CN106116886 A CN 106116886A
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- Prior art keywords
- fertilizer
- medicine
- fosthiazate
- avilamycin
- fertile
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/32—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing heterocyclic radicals
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C1/00—Ammonium nitrate fertilisers
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05C—NITROGENOUS FERTILISERS
- C05C3/00—Fertilisers containing other salts of ammonia or ammonia itself, e.g. gas liquor
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Fertilizers (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of nuisance-free medicinal fertilizer preventing and treating nematicide and subterranean pest-insect, wherein, pesticide activity component is avilamycin and fosthiazate, fertilizer be arbitrary in chitin or humic acids in.The medicine fertilizer composition of the present invention, is respectively provided with a certain degree of raising to nematicide and volume increase, is worthy of popularization.
Description
Technical field
The present invention relates to pesticide new product field, be specifically related to a kind of medicine containing avilamycin and fosthiazate fertilizer and system thereof
Preparation Method, this insecticide fertilizer is a kind of new drug fertilizer having parasite killing and Fertilizer nutrient concurrently.
Background technology
Nematicide and subterranean pest-insect are very harmful to agricultural production, it was reported that typically make crop failure more than 30%, time serious
Up to more than 60%.Preventing and treating nematicide and subterranean pest-insect are still mainly based on height pesticide at present, and expenses for prevention and control is high, and use not side
Just, environment is also brought many adverse effects.
Avilamycin (Abamectin) is first developed with Merck company of the U.S. by North university of Japan big village intelligence etc.
One class has ten hexa-atomic Macrocyclic lactone compounds of sterilization, parasite killing, mite killing, eelworm-killing activity, is to separate from soil microorganism
Natural product, insecticide and demodicid mite class are had and tag and stomach poison function by faint fumigation action, without systemic action.It is to leaf
Sheet has the strongest osmosis, can kill subepidermal insect, and the longevity of residure is long.
Fosthiazate (fosthiazate) is organic phosphates nematicide, and main effect model is suppression root-knot nematode acetyl
The synthesis of acetylcholine esterase, can be used for preventing and treating all kinds of root-knot nematode, aphid etc..In China achieved with on Fructus Cucumidis sativi, Fructus Lycopersici esculenti, Citrullus vulgaris
Registration, can be widely applied to the crops such as vegetable, Fructus Musae, fruit tree, medical material.
Medicine fertilizer is the new technique used in agricultural in recent years, refers to have parasite killing, weeding, bactericidal action and effect raw
Two or more function in long regulation, and nutrition can be provided for crops or there is offer nutrition simultaneously and improve fertilizer and agriculture
The multi-Functional Fertilizers of medicine utilization rate, has simplification operation, saves the features such as labour force.Therefore, develop novel have concurrently pesticide and
The medicine fertilizer of fertilizer is significant.
Inventor, through substantial amounts of lab screening and field control effectiveness test, finds avilamycin and the Insecticidal combinations of fosthiazate
After thing and fertilizer mixture, the double effects of parasite killing and fertilizer can not only be played, and both compounding after than be used alone chemical fertilizer and
Pesticide is compared, and all increases significantly in terms of insecticidal effect, crop yield, it is possible to decrease use cost, joint medicine joint fertilizer, right
Crop safety is high.
Summary of the invention
It is an object of the invention to provide a kind of effective, safety and stability containing avilamycin and the insecticide fertilizer of fosthiazate
And production method.
For realizing above-mentioned technical purpose, reaching above-mentioned technique effect, the present invention is achieved through the following technical solutions:
The medicine fertilizer of the present invention contains: pesticide active ingredient avilamycin and fosthiazate, fertilizer and insecticides adjuvant.
The weight percent content composition of each component is as follows:
Avilamycin: 0.1-15%
Fosthiazate: 0.1-15%,
Fertilizer: 1-60%
Pesticidal preparations auxiliary element: 10-70%
Wherein, described fertilizer is humic acid fertilizer or chitin.
Further, described fertilizer also includes other fertilizer, selected from compound fertilizer, potash fertilizer, phosphate fertilizer, nitrogenous fertilizer, moderate-element
One or more in fertilizer, marsh gas dregs fertilizer, alga fertilizer, amino acid fertilizer, humic acid fertilizer, chitin, carbamide etc..
Preferably, the content of described insecticide fosthiazate and clothianidin is than for 1:15-15:1.
Preferably, described humic acid fertilizer is selected from humic acids, sodium humate, potassium humate.
Preferably, described pesticidal preparations auxiliary element is selected from solvent, emulsifying agent, dispersant, thickening agent, antifreezing agent, disappears
One or more in infusion, stabilizer, filler.
Preferably, one or more in water, methanol, toluene, dimethylbenzene, DMF etc. of described solvent.
Preferably, described emulsifying agent selected from Nongru-700 #, agriculture breast 500#, agriculture breast 600#, agriculture breast 4003, agriculture breast 1601#,
One or more in this dish-60#, Tween-60 #, TX-10, alkylphenol polyoxyethylene;
Preferably, described dispersant is selected from lignosulfonates, NNO, dibutyl naphthalenesulfonic acid salt, oleic acid methylaminoethyl sulfonic acid
One or more in sodium, alkylaryl polyoxyethylene ether.
Preferably, described thickening agent selected from cellulose derivative, polyvinyl alcohol, bentonite, gelatin, seaweeds, xanthan gum,
One or more in aluminium-magnesium silicate.
Preferably, one or more in ethylene glycol, propylene glycol, glycerol, sorbitol of described antifreezing agent.
Preferably, described defoamer one in polydimethylsiloxane, organosilicon ketone, isooctanol, n-octyl alcohol
Or it is several.
Preferably, the dosage form of the medicine fertilizer composition of the present invention is granule, suspending agent or suspension emulsion.
Compared with prior art, the invention has the beneficial effects as follows: after the composition pesticide of (1) present invention is compounding with fertilizer,
Collaborative effect can be played each other, preferably play pesticide efficacy and the double effects of fertilizer;(2) medicine of the present invention is fertile
Compositions can reduce the usage amount of pesticide and fertilizer, reduces cost accounting, reduces environmental pollution, thus alleviates the pressure to environment
Power;(3) the insecticide fertilizer product preparation process of the present invention is simple, and condition is easily-controllable, is suitable to industrialized production.
Detailed description of the invention
The present invention will be further described to survey embodiment below in conjunction with example of formulations and life.
Example of formulations 1 5% avilamycin fosthiazate suspension emulsion
Avilamycin 4%
Fosthiazate 1%
Humic acids 5%
Ethylenediaminetetraacetic acid 2%
Four water ammonium molybdates 5%
Ammonium sulfate 18%
Alkylphenol polyoxyethylene 5%
Sodium lignin sulfonate 3%
Gelatin 8%
Ethylene glycol 6%
Organic silicone 2%
Dimethylformamide 10%
Water surplus
Preparation method is: (1) is by avilamycin, sodium lignin sulfonate, ethylene glycol, dimethylformamide, water, humic acids, second two
Amine tetraacethyl, four water ammonium molybdates, ammonium sulfate, according to described consumption, the abrasive media of the quality such as addition, carry out frosted, no after mixing
After being interrupted frosted two hours, add organic silicone and all put, obtain aqueous suspension agent;(2) by fosthiazate, alkylphenol-polyethenoxy
Ether, ethylene glycol, water and dimethylformamide weigh according to described consumption, and it is 10000r/ that high-speed shearing machine shears 10min(rotating speed
Min), all put and obtain aqueous emulsion;(3) by gained aqueous emulsion and suspending agent mix and blend 5min, medicine fertilizer suspension emulsion is obtained.
Example of formulations 2 15% avilamycin fosthiazate suspension emulsion
Avilamycin 3%
Fosthiazate 12%
Chitin 10%
Ammonium nitrate 11%
Phosphoric acid diformazan 3%
Fulvic acid 3%
Zinc sulphate heptahydrate 5%
Carbamide 7%
Agriculture breast 600# 6%
Alkylphenol polyoxyethylene 4%
Aluminium-magnesium silicate 9%
Glycerol 5%
Polydimethylsiloxane 2%
Methanol 15%
Water surplus
Preparation method is with embodiment 1.
Example of formulations 3 25% avilamycin fosthiazate suspension emulsion
Avilamycin 10%
Fosthiazate 15%
Chitin 7%
Dimethylformamide 15%
Alkylphenol polyoxyethylene 9%
Ammonium sulfate 8%
Potassium dihydrogen phosphate 12%
Ammonium nitrate 8%
Potassium nitrate 7%
Boric acid 5%
Kaolin 4%
Kieselguhr surplus
Preparation method is: first avilamycin, fosthiazate, alkylphenol polyoxyethylene is dissolved with solvent and prepares mother solution,
By mother liquid obtained and other fertilizer components chitin, ammonium sulfate, potassium dihydrogen phosphate, ammonium nitrate, potassium nitrate, boric acid, Kaolin, silicon
Diatomaceous earth carries out pelletize in fluidized bed prilling mode, i.e. obtains fertilizer granules.
Comparative example 1: compared with Example 1, does not contains humic acids;
Comparative example 2: compared with Example 1, without avilamycin, fosthiazate;
Comparative example 3: compared with Example 2, does not contains chitin;
Comparative example 4: compared with Example 2, without avilamycin, fosthiazate;
Comparative example 5: compared with Example 3, does not contains chitin;
Comparative example 6: compared with Example 3, without avilamycin, fosthiazate;
Biological Examples 1
The medicine of embodiment of the present invention 1-3 is fertile, the medicine fertilizer of comparative example 1-6 carries out preventing and treating the test of nematicide and volume increase and compares, and is tried
With crop: Fructus Cucumidis sativi;Subjects: root-knot nematode;Application method: embodiment 1,2 is diluted 1500 times, and granular pesticide fertilizer is according to often
Mu 10Kg uses, and comparative example 1-4 carries out root irrigation after diluting 800 times, and comparative example 5,6 is used according to every mu of consumption 15Kg, executed
Carrying out according to normal field management after medicine, each cell management is consistent, within after medicine 20 days, 40 days, carries out preventive effect investigation, preventing and treating
Effect is as follows.
Field test results shows, with the medicine fertilizer composition of embodiments of the invention, i.e. avilamycin and the compositions of fosthiazate
With the medicine fertilizer composition of chitin or humic acids, it is better than the medicine by being used alone between the two fertile, the medicine fertilizer group of the present invention simultaneously
Compound has preferable effect of increasing production.
Described above to the disclosed embodiments, makes professional and technical personnel in the field be capable of or uses the present invention.
Multiple amendment to these embodiments will be apparent from for those skilled in the art, as defined herein
General Principle can realize without departing from the spirit or scope of the present invention in other embodiments.Therefore, the present invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and principles disclosed herein and features of novelty phase one
The widest scope caused.
Claims (5)
1. a medicine fertilizer, it is characterised in that it includes the auxiliary element in pesticide activity component, fertilizer and Pesticide formulation,
Wherein, described pesticide activity component contains avilamycin and fosthiazate, and described fertilizer includes humic acid fertilizer or chitin.
Medicine the most according to claim 1 is fertile, it is characterised in that described fertilizer also includes other fertilizer, such as compound fertilizer, potassium
In fertilizer, phosphate fertilizer, nitrogenous fertilizer, moderate-element fertilizer, marsh gas dregs fertilizer, alga fertilizer, amino acid fertilizer, humic acid fertilizer, chitin, carbamide etc. one
Plant or multiple.
Medicine the most according to claim 1 and 2 is fertile, it is characterised in that consisting of of each composition: avilamycin: 0.1-15%
Fosthiazate: 0.1-15%,
Fertilizer: 1-60%
Pesticidal preparations auxiliary element: 10-70%.
4. fertile according to the medicine described in claim any one of claim 1-3, it is characterised in that its dosage form be granule,
In suspending agent, suspension emulsion any one.
5. according to the medicine fertilizer described in claim any one of claim 1-4 for preventing and treating the purposes of root-knot nematode.
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CN201610496094.5A CN106116886A (en) | 2016-06-30 | 2016-06-30 | Medicine containing avilamycin and fosthiazate is fertile and preparation method thereof |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106538596A (en) * | 2016-11-01 | 2017-03-29 | 佛山市盈辉作物科学有限公司 | A kind of medicine fertilizer composition containing avilamycin and fosthiazate |
CN106748305A (en) * | 2017-02-21 | 2017-05-31 | 山东康德源农业科技有限公司 | A kind of medicine fertilizer with preventing and treating root-knot nematode function and preparation method and application |
CN106748306A (en) * | 2017-02-21 | 2017-05-31 | 山东康德源农业科技有限公司 | A kind of Multifunctional pesticide fertilizer and preparation method and application |
CN107047609A (en) * | 2017-04-20 | 2017-08-18 | 深圳诺普信农化股份有限公司 | A kind of microcapsule suspending agent |
CN108059547A (en) * | 2018-01-22 | 2018-05-22 | 中国农业大学 | A kind of growth-promoting anti-insect type amino acid Water soluble fertilizer and preparation method thereof |
CN109485491A (en) * | 2018-11-20 | 2019-03-19 | 北京源农炭肥技术有限公司 | The charcoal base medicine fertilizer and preparation method thereof for preventing and treating root-knot nematode |
CN112335675A (en) * | 2020-11-20 | 2021-02-09 | 江苏精禾界面科技有限公司 | Pesticide preparation containing fosthiazate and preparation method thereof |
CN113956111A (en) * | 2021-09-24 | 2022-01-21 | 广东清远金正大农业研究院有限公司 | Nematode-preventing growth-promoting liquid pesticide fertilizer and preparation method and application thereof |
Citations (2)
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CN103588590A (en) * | 2013-11-19 | 2014-02-19 | 广西新方向化学工业有限公司 | Pesticide fertilizer special for root-knot nematode prevention |
CN105061084A (en) * | 2015-08-21 | 2015-11-18 | 西安炬光生物科技有限公司 | Controlled-release pesticide fertilizer and preparing method thereof |
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- 2016-06-30 CN CN201610496094.5A patent/CN106116886A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103588590A (en) * | 2013-11-19 | 2014-02-19 | 广西新方向化学工业有限公司 | Pesticide fertilizer special for root-knot nematode prevention |
CN105061084A (en) * | 2015-08-21 | 2015-11-18 | 西安炬光生物科技有限公司 | Controlled-release pesticide fertilizer and preparing method thereof |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106538596A (en) * | 2016-11-01 | 2017-03-29 | 佛山市盈辉作物科学有限公司 | A kind of medicine fertilizer composition containing avilamycin and fosthiazate |
CN106748305A (en) * | 2017-02-21 | 2017-05-31 | 山东康德源农业科技有限公司 | A kind of medicine fertilizer with preventing and treating root-knot nematode function and preparation method and application |
CN106748306A (en) * | 2017-02-21 | 2017-05-31 | 山东康德源农业科技有限公司 | A kind of Multifunctional pesticide fertilizer and preparation method and application |
CN107047609A (en) * | 2017-04-20 | 2017-08-18 | 深圳诺普信农化股份有限公司 | A kind of microcapsule suspending agent |
CN108059547A (en) * | 2018-01-22 | 2018-05-22 | 中国农业大学 | A kind of growth-promoting anti-insect type amino acid Water soluble fertilizer and preparation method thereof |
CN109485491A (en) * | 2018-11-20 | 2019-03-19 | 北京源农炭肥技术有限公司 | The charcoal base medicine fertilizer and preparation method thereof for preventing and treating root-knot nematode |
CN112335675A (en) * | 2020-11-20 | 2021-02-09 | 江苏精禾界面科技有限公司 | Pesticide preparation containing fosthiazate and preparation method thereof |
CN113956111A (en) * | 2021-09-24 | 2022-01-21 | 广东清远金正大农业研究院有限公司 | Nematode-preventing growth-promoting liquid pesticide fertilizer and preparation method and application thereof |
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