CN101903571B - 低收缩、可染色的聚间苯二甲酰间苯二胺纱线 - Google Patents
低收缩、可染色的聚间苯二甲酰间苯二胺纱线 Download PDFInfo
- Publication number
- CN101903571B CN101903571B CN2008801216595A CN200880121659A CN101903571B CN 101903571 B CN101903571 B CN 101903571B CN 2008801216595 A CN2008801216595 A CN 2008801216595A CN 200880121659 A CN200880121659 A CN 200880121659A CN 101903571 B CN101903571 B CN 101903571B
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- water
- salt
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- 239000002904 solvent Substances 0.000 claims abstract description 77
- 229920000642 polymer Polymers 0.000 claims abstract description 73
- 238000000034 method Methods 0.000 claims abstract description 71
- 150000003839 salts Chemical class 0.000 claims abstract description 52
- 230000003750 conditioning effect Effects 0.000 claims abstract description 51
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 43
- 238000000578 dry spinning Methods 0.000 claims abstract description 17
- 239000000243 solution Substances 0.000 claims description 94
- 239000004760 aramid Substances 0.000 claims description 41
- 229920003235 aromatic polyamide Polymers 0.000 claims description 41
- 238000010791 quenching Methods 0.000 claims description 36
- 238000010438 heat treatment Methods 0.000 claims description 34
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- 238000005406 washing Methods 0.000 claims description 21
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- 229920001577 copolymer Polymers 0.000 claims description 6
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- 238000009736 wetting Methods 0.000 description 34
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- 239000007789 gas Substances 0.000 description 14
- 238000001035 drying Methods 0.000 description 13
- 238000004043 dyeing Methods 0.000 description 12
- 238000004804 winding Methods 0.000 description 11
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 9
- 239000013078 crystal Substances 0.000 description 9
- 230000036541 health Effects 0.000 description 9
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- 238000012360 testing method Methods 0.000 description 9
- 230000009477 glass transition Effects 0.000 description 8
- 239000007921 spray Substances 0.000 description 7
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 6
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 6
- 239000007787 solid Substances 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 239000006227 byproduct Substances 0.000 description 5
- 238000006386 neutralization reaction Methods 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 4
- 150000004985 diamines Chemical class 0.000 description 4
- 230000001965 increasing effect Effects 0.000 description 4
- WFKAJVHLWXSISD-UHFFFAOYSA-N isobutyramide Chemical compound CC(C)C(N)=O WFKAJVHLWXSISD-UHFFFAOYSA-N 0.000 description 4
- 238000002166 wet spinning Methods 0.000 description 4
- 238000001237 Raman spectrum Methods 0.000 description 3
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- 125000003118 aryl group Chemical group 0.000 description 3
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- 238000002425 crystallisation Methods 0.000 description 3
- 230000008025 crystallization Effects 0.000 description 3
- -1 dimethyl chloride Chemical compound 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
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- 239000004744 fabric Substances 0.000 description 3
- 239000013557 residual solvent Substances 0.000 description 3
- 238000004781 supercooling Methods 0.000 description 3
- 210000000689 upper leg Anatomy 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000001110 calcium chloride Substances 0.000 description 2
- 229910001628 calcium chloride Inorganic materials 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000001704 evaporation Methods 0.000 description 2
- 239000000675 fabric finishing Substances 0.000 description 2
- 238000009962 finishing (textile) Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
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- 238000013508 migration Methods 0.000 description 2
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- 229910052757 nitrogen Inorganic materials 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 238000005086 pumping Methods 0.000 description 2
- 238000000926 separation method Methods 0.000 description 2
- FQENQNTWSFEDLI-UHFFFAOYSA-J sodium diphosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])([O-])=O FQENQNTWSFEDLI-UHFFFAOYSA-J 0.000 description 2
- 235000019818 tetrasodium diphosphate Nutrition 0.000 description 2
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 229920002334 Spandex Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical group [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 150000008378 aryl ethers Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- FDQSRULYDNDXQB-UHFFFAOYSA-N benzene-1,3-dicarbonyl chloride Chemical compound ClC(=O)C1=CC=CC(C(Cl)=O)=C1 FDQSRULYDNDXQB-UHFFFAOYSA-N 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
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- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
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- 235000013399 edible fruits Nutrition 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000007380 fibre production Methods 0.000 description 1
- 239000003063 flame retardant Substances 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 150000004820 halides Chemical class 0.000 description 1
- 229920006253 high performance fiber Polymers 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000004433 nitrogen atom Chemical group N* 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 230000004044 response Effects 0.000 description 1
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- 229940048086 sodium pyrophosphate Drugs 0.000 description 1
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- 238000010186 staining Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
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- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
- D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
- D01F6/605—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides from aromatic polyamides
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/02—Heat treatment
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D10/00—Physical treatment of artificial filaments or the like during manufacture, i.e. during a continuous production process before the filaments have been collected
- D01D10/06—Washing or drying
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/04—Dry spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/12—Stretch-spinning methods
- D01D5/16—Stretch-spinning methods using rollers, or like mechanical devices, e.g. snubbing pins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/06—Dyes
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/78—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products
- D01F6/80—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides
- D01F6/805—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from copolycondensation products from copolyamides from aromatic copolyamides
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
- D02G3/047—Blended or other yarns or threads containing components made from different materials including aramid fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2401/00—Physical properties
- D10B2401/14—Dyeability
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2913—Rod, strand, filament or fiber
- Y10T428/2933—Coated or with bond, impregnation or core
- Y10T428/2964—Artificial fiber or filament
- Y10T428/2967—Synthetic resin or polymer
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Artificial Filaments (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Reinforced Plastic Materials (AREA)
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US12/004,332 US7998575B2 (en) | 2007-12-19 | 2007-12-19 | Low shrinkage, dyeable MPD-I yarn |
| US12/004332 | 2007-12-19 | ||
| PCT/US2008/087358 WO2009079619A1 (en) | 2007-12-19 | 2008-12-18 | Low shrinkage, dyeable mpd-i yarn |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101903571A CN101903571A (zh) | 2010-12-01 |
| CN101903571B true CN101903571B (zh) | 2012-03-21 |
Family
ID=40822943
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008801216595A Active CN101903571B (zh) | 2007-12-19 | 2008-12-18 | 低收缩、可染色的聚间苯二甲酰间苯二胺纱线 |
Country Status (8)
| Country | Link |
|---|---|
| US (2) | US7998575B2 (enExample) |
| EP (1) | EP2222904B1 (enExample) |
| JP (1) | JP5307832B2 (enExample) |
| KR (1) | KR101536793B1 (enExample) |
| CN (1) | CN101903571B (enExample) |
| AT (1) | ATE530681T1 (enExample) |
| BR (1) | BRPI0822647B8 (enExample) |
| WO (1) | WO2009079619A1 (enExample) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR101386429B1 (ko) * | 2012-12-28 | 2014-04-29 | 코오롱인더스트리 주식회사 | 파라-아라미드 섬유의 제조방법 |
| US10954609B2 (en) | 2015-07-29 | 2021-03-23 | Dupont Safety & Construction, Inc. | Yarn from polymers having different decomposition temperatures and process for forming same |
| US10982353B2 (en) * | 2016-09-01 | 2021-04-20 | Dupont Safety & Construction, Inc. | Carbon-containing aramid bicomponent filament yarns |
| JP7063574B2 (ja) * | 2017-10-30 | 2022-05-09 | 帝人株式会社 | 染色されたメタ型全芳香族ポリアミド繊維および紡績糸および布帛および繊維製品 |
| US20220380939A1 (en) * | 2019-10-07 | 2022-12-01 | Teijin Limited | Process for the manufacture of a fiber comprising meta-aramid |
| KR102586540B1 (ko) * | 2021-06-02 | 2023-10-11 | 주식회사 휴비스 | 염색성 및 광택성이 향상된 메타아라미드 섬유 및 그의 제조방법 |
| JP2025504656A (ja) | 2022-01-27 | 2025-02-14 | デュポン セイフティー アンド コンストラクション インコーポレイテッド | メタアラミド及びポリビニルピロリドンのポリマーブレンドを含む糸を有する耐火性衣服及び耐火性生地 |
| JP2025523125A (ja) | 2022-07-15 | 2025-07-17 | ディーディーピー スペシャルティ エレクトロニック マテリアルズ ユーエス リミテッド ライアビリティ カンパニー | 保護膜屋根のための耐火性シールド |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1140769A (zh) * | 1995-06-30 | 1997-01-22 | 普拉塞尔技术有限公司 | 纺制空心纤维膜的方法和装置 |
| CN1710160A (zh) * | 2005-06-17 | 2005-12-21 | 东华大学 | 一种制备间位芳香族聚酰胺纤维的方法 |
Family Cites Families (32)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2130948A (en) * | 1937-04-09 | 1938-09-20 | Du Pont | Synthetic fiber |
| US2210161A (en) * | 1937-10-23 | 1940-08-06 | Du Pont | Production of filamentary structures |
| US3063966A (en) * | 1958-02-05 | 1962-11-13 | Du Pont | Process of making wholly aromatic polyamides |
| BE565269A (enExample) * | 1957-03-27 | |||
| US3094511A (en) * | 1958-11-17 | 1963-06-18 | Du Pont | Wholly aromatic polyamides |
| US3133138A (en) * | 1958-12-19 | 1964-05-12 | Du Pont | Stretching and heat crystallization of poly(meta-phenylene isophthalamide) fibers |
| US3414645A (en) * | 1964-06-19 | 1968-12-03 | Monsanto Co | Process for spinning wholly aromatic polyamide fibers |
| US3287324A (en) * | 1965-05-07 | 1966-11-22 | Du Pont | Poly-meta-phenylene isophthalamides |
| US3300450A (en) * | 1966-04-12 | 1967-01-24 | Du Pont | Stabilized aromatic polyamide filaments |
| US3381506A (en) * | 1966-08-19 | 1968-05-07 | Du Pont | Liquid-stripper bar |
| US3391672A (en) * | 1966-09-07 | 1968-07-09 | Du Pont | Apparatus for removal of liquid from moving filamentary yarns |
| US3506990A (en) * | 1966-12-16 | 1970-04-21 | Du Pont | Process for dyeing drawn filaments of aromatic polyamides with basic dye-stuffs in the presence of an organic dye carrier |
| US3493422A (en) * | 1967-02-28 | 1970-02-03 | Du Pont | Apparatus and process for liquid treatment of shaped structures |
| US3725523A (en) * | 1971-08-03 | 1973-04-03 | Du Pont | Process for extracting and drawing a tow |
| US3765195A (en) * | 1972-02-22 | 1973-10-16 | Du Pont | Fluid stripping devices |
| JPS5181862A (enExample) * | 1975-01-16 | 1976-07-17 | Mitsubishi Rayon Co | |
| US4668234A (en) * | 1985-08-15 | 1987-05-26 | E. I. Du Pont De Nemours And Company | Aromatic polyamide fibers and process for stabilizing such fibers with surfactants |
| US4883496A (en) * | 1988-02-14 | 1989-11-28 | E. I. Du Pont De Nemours And Company | Process for dyeing crystalline aromatic polyamide fibers with water-insoluble dyes |
| AR244721A1 (es) * | 1988-10-14 | 1993-11-30 | Du Pont | Poliamida aromatica procesable por fusion y procedimiento para su preparacion. |
| US5076887A (en) * | 1990-09-25 | 1991-12-31 | E. I. Du Pont De Nemours And Company | Pressboard and process for its production |
| JP2815490B2 (ja) * | 1991-01-28 | 1998-10-27 | 帝人株式会社 | 芳香族コポリアミド繊維及びその製造法 |
| JP2662201B2 (ja) * | 1995-03-30 | 1997-10-08 | 財団法人工業技術研究院 | 改良された染色性を有する全芳香族ポリアミド繊維 |
| US5667743A (en) * | 1996-05-21 | 1997-09-16 | E. I. Du Pont De Nemours And Company | Wet spinning process for aramid polymer containing salts |
| TW562823B (en) * | 1999-10-21 | 2003-11-21 | Teijin Ltd | Process for producing meta-aromatic polyamide filaments |
| CA2369681C (en) * | 2000-02-16 | 2006-03-28 | Teijin Limited | Meta-type wholly aromatic polyamide filaments and process for producing same |
| FR2843975B1 (fr) * | 2002-09-04 | 2008-11-14 | Kermel | Fibres et fibrides, leur procede d'obtention, articles obtenus a partir de ces fibres et/ou fibrides. |
| US20050093198A1 (en) * | 2003-10-31 | 2005-05-05 | Rodini David J. | Wet spinning process for aramid polymer containing salts |
| JP2007262589A (ja) * | 2006-03-27 | 2007-10-11 | Teijin Techno Products Ltd | 易染性メタ型芳香族ポリアミド繊維およびその製造法 |
| US7780889B2 (en) * | 2007-12-19 | 2010-08-24 | E.I. Du Pont De Nemours And Company | Multistage draw with relaxation step |
| US7771636B2 (en) * | 2007-12-19 | 2010-08-10 | E. I. Du Pont De Nemours And Company | Single stage drawing for MPD-I yarn |
| US7771638B2 (en) * | 2007-12-19 | 2010-08-10 | E. I. Du Pont De Nemours And Company | Rapid plasticization of quenched yarns |
| US7771637B2 (en) * | 2007-12-19 | 2010-08-10 | E. I. Du Pont De Nemours And Company | High-speed meta-aramid fiber production |
-
2007
- 2007-12-19 US US12/004,332 patent/US7998575B2/en active Active
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2008
- 2008-12-18 WO PCT/US2008/087358 patent/WO2009079619A1/en not_active Ceased
- 2008-12-18 JP JP2010539778A patent/JP5307832B2/ja active Active
- 2008-12-18 AT AT08863119T patent/ATE530681T1/de not_active IP Right Cessation
- 2008-12-18 EP EP20080863119 patent/EP2222904B1/en active Active
- 2008-12-18 KR KR1020107015669A patent/KR101536793B1/ko active Active
- 2008-12-18 CN CN2008801216595A patent/CN101903571B/zh active Active
- 2008-12-18 BR BRPI0822647A patent/BRPI0822647B8/pt active IP Right Grant
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2011
- 2011-06-29 US US13/171,603 patent/US9080260B2/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1140769A (zh) * | 1995-06-30 | 1997-01-22 | 普拉塞尔技术有限公司 | 纺制空心纤维膜的方法和装置 |
| CN1710160A (zh) * | 2005-06-17 | 2005-12-21 | 东华大学 | 一种制备间位芳香族聚酰胺纤维的方法 |
Non-Patent Citations (1)
| Title |
|---|
| JP特开2004-277937A 2004.10.07 |
Also Published As
| Publication number | Publication date |
|---|---|
| EP2222904A1 (en) | 2010-09-01 |
| BRPI0822647B1 (pt) | 2018-06-12 |
| CN101903571A (zh) | 2010-12-01 |
| ATE530681T1 (de) | 2011-11-15 |
| KR101536793B1 (ko) | 2015-07-14 |
| JP5307832B2 (ja) | 2013-10-02 |
| WO2009079619A1 (en) | 2009-06-25 |
| US20110257359A1 (en) | 2011-10-20 |
| US9080260B2 (en) | 2015-07-14 |
| JP2011508100A (ja) | 2011-03-10 |
| BRPI0822647B8 (pt) | 2023-02-28 |
| BRPI0822647A2 (pt) | 2015-06-23 |
| US20090162655A1 (en) | 2009-06-25 |
| KR20100108381A (ko) | 2010-10-06 |
| EP2222904B1 (en) | 2011-10-26 |
| US7998575B2 (en) | 2011-08-16 |
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