CN101890504B - 片状纳米铜粉的制备方法 - Google Patents
片状纳米铜粉的制备方法 Download PDFInfo
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- CN101890504B CN101890504B CN2010102196757A CN201010219675A CN101890504B CN 101890504 B CN101890504 B CN 101890504B CN 2010102196757 A CN2010102196757 A CN 2010102196757A CN 201010219675 A CN201010219675 A CN 201010219675A CN 101890504 B CN101890504 B CN 101890504B
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- surfactant
- mixed solution
- copper powder
- aqueous solution
- flaky nano
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- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 238000002360 preparation method Methods 0.000 title claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 36
- 239000007864 aqueous solution Substances 0.000 claims abstract description 21
- 239000011259 mixed solution Substances 0.000 claims abstract description 21
- 150000001875 compounds Chemical class 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 13
- 239000007787 solid Substances 0.000 claims abstract description 13
- 150000001879 copper Chemical class 0.000 claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 10
- 239000007788 liquid Substances 0.000 claims abstract description 7
- 238000005406 washing Methods 0.000 claims abstract description 7
- 238000000926 separation method Methods 0.000 claims abstract description 5
- 238000001291 vacuum drying Methods 0.000 claims abstract description 5
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 13
- 229920000053 polysorbate 80 Polymers 0.000 claims description 13
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 claims description 12
- 239000012279 sodium borohydride Substances 0.000 claims description 12
- 229910000033 sodium borohydride Inorganic materials 0.000 claims description 12
- 229910052802 copper Inorganic materials 0.000 claims description 8
- 239000010949 copper Substances 0.000 claims description 8
- 239000012266 salt solution Substances 0.000 claims description 8
- 239000012153 distilled water Substances 0.000 claims description 6
- 239000013504 Triton X-100 Substances 0.000 claims description 5
- 229920004890 Triton X-100 Polymers 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 239000003093 cationic surfactant Substances 0.000 claims description 5
- -1 2-ethylhexyl Chemical group 0.000 claims description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- PLMFYJJFUUUCRZ-UHFFFAOYSA-M decyltrimethylammonium bromide Chemical compound [Br-].CCCCCCCCCC[N+](C)(C)C PLMFYJJFUUUCRZ-UHFFFAOYSA-M 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000006479 redox reaction Methods 0.000 claims description 4
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 4
- NWZSZGALRFJKBT-KNIFDHDWSA-N (2s)-2,6-diaminohexanoic acid;(2s)-2-hydroxybutanedioic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O.NCCCC[C@H](N)C(O)=O NWZSZGALRFJKBT-KNIFDHDWSA-N 0.000 claims description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- ORTQZVOHEJQUHG-UHFFFAOYSA-L copper(II) chloride Chemical compound Cl[Cu]Cl ORTQZVOHEJQUHG-UHFFFAOYSA-L 0.000 claims description 3
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine monohydrate Substances O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 claims description 3
- 229910052700 potassium Inorganic materials 0.000 claims description 3
- 239000011591 potassium Substances 0.000 claims description 3
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 claims description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims description 2
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 2
- 150000008064 anhydrides Chemical class 0.000 claims description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 claims description 2
- 229940049964 oleate Drugs 0.000 claims description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 2
- 229910052708 sodium Inorganic materials 0.000 claims description 2
- 239000011734 sodium Substances 0.000 claims description 2
- 239000000600 sorbitol Substances 0.000 claims description 2
- 239000001384 succinic acid Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 2
- 238000009776 industrial production Methods 0.000 abstract 1
- 238000002156 mixing Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 7
- 229910000365 copper sulfate Inorganic materials 0.000 description 6
- 239000000463 material Substances 0.000 description 5
- 230000010358 mechanical oscillation Effects 0.000 description 4
- 238000005303 weighing Methods 0.000 description 4
- NWGKJDSIEKMTRX-AAZCQSIUSA-N Sorbitan monooleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O NWGKJDSIEKMTRX-AAZCQSIUSA-N 0.000 description 3
- WPMWEFXCIYCJSA-UHFFFAOYSA-N Tetraethylene glycol monododecyl ether Chemical compound CCCCCCCCCCCCOCCOCCOCCOCCO WPMWEFXCIYCJSA-UHFFFAOYSA-N 0.000 description 3
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001914 filtration Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002105 nanoparticle Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 2
- CDOUZKKFHVEKRI-UHFFFAOYSA-N 3-bromo-n-[(prop-2-enoylamino)methyl]propanamide Chemical compound BrCCC(=O)NCNC(=O)C=C CDOUZKKFHVEKRI-UHFFFAOYSA-N 0.000 description 1
- OSOSMTZOKLTVFS-UHFFFAOYSA-N S(=O)(=O)(O)C(C(=O)O)CC(=O)O.C(C)C(C[Na])CCCC Chemical compound S(=O)(=O)(O)C(C(=O)O)CC(=O)O.C(C)C(C[Na])CCCC OSOSMTZOKLTVFS-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 235000019329 dioctyl sodium sulphosuccinate Nutrition 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 239000000314 lubricant Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- 238000007738 vacuum evaporation Methods 0.000 description 1
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- Manufacture Of Metal Powder And Suspensions Thereof (AREA)
Abstract
Description
实施例3 | 实施例4 | 实施例5 | 实施例6 | |
铜盐水溶液 | 100.0g的硫酸铜水溶液 | 100.0g的氯化铜水溶液 | 100.0g的醋酸铜水溶液 | 100.0g的硫酸铜水溶液 |
还原剂水溶液 | 100.0g的硼氢化钾水溶液 | 100.0g的硼氢化钠水溶液 | 100.0g的硼氢化钠水溶液 | 100.0g的水合肼水溶液 |
表面活性剂 | 10.0g的CTAB和10.0g的Triton X-100 | 10.0g的SDBS和10.0g的Span-80 | 10.0g的AOT和10.0g的Brij-30 | 10.0g的DTAB 和10.0g的Tween-80 |
反应温度 | 35℃ | 40℃ | 30℃ | 25℃ |
滴加速度 | 2mL/min | 1.5mL/min | 1.5mL/min | 1mL/min |
干燥温度 | 70℃ | 80℃ | 75℃ | 65℃ |
Claims (3)
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CN2010102196757A CN101890504B (zh) | 2010-07-07 | 2010-07-07 | 片状纳米铜粉的制备方法 |
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CN2010102196757A CN101890504B (zh) | 2010-07-07 | 2010-07-07 | 片状纳米铜粉的制备方法 |
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CN101890504A CN101890504A (zh) | 2010-11-24 |
CN101890504B true CN101890504B (zh) | 2012-06-27 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102896322A (zh) * | 2012-11-01 | 2013-01-30 | 广东东硕科技有限公司 | 一种有抗氧化性及分散性的纳米铜制备方法 |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102601383A (zh) * | 2012-03-30 | 2012-07-25 | 电子科技大学 | 一种室温下制备超细铜粉的方法 |
CN105268993B (zh) * | 2012-11-29 | 2019-01-25 | 江苏理工学院 | 一种制备片状纳米银粉的方法 |
CN103537711B (zh) * | 2013-10-30 | 2016-09-14 | 宇辰新能源材料科技无锡有限公司 | 一种球形亚微米钴粉的制备方法 |
CN104475750A (zh) * | 2014-12-02 | 2015-04-01 | 广西大学 | 一种超细铜粉的制备方法 |
CN106363165B (zh) * | 2016-09-05 | 2019-02-15 | 国核电力规划设计研究院 | 一种片状铜颗粒及其制备方法、催化剂、电极 |
CN106544078A (zh) * | 2016-10-07 | 2017-03-29 | 常州创索新材料科技有限公司 | 一种减磨材料的制备方法 |
CN108127125B (zh) * | 2016-12-01 | 2020-01-14 | 中国科学院大连化学物理研究所 | 一种高稳定性的铜纳米片的制备方法 |
US10626021B2 (en) * | 2017-03-31 | 2020-04-21 | Honda Motor Co., Ltd. | Method of making metal and metal oxide nanoparticles |
CN108620601B (zh) * | 2018-05-14 | 2021-06-22 | 哈尔滨理工大学 | 一种室温条件下制备片状Cu纳米晶的方法 |
CN109483092B (zh) * | 2018-12-12 | 2020-03-13 | 中国矿业大学 | 一种基于铜纳米颗粒焊接材料的制备方法 |
CN110369911A (zh) * | 2019-06-27 | 2019-10-25 | 上海三一重机股份有限公司 | 一种铜纳米焊接材料及其制备方法 |
CN113275586B (zh) * | 2021-05-31 | 2023-03-31 | 广东省江门市质量计量监督检测所 | 一种利用表面活性剂制备不同粒径纳米银的方法 |
Family Cites Families (3)
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CN1196553C (zh) * | 2002-03-01 | 2005-04-13 | 中国科学院理化技术研究所 | 金属纳米粉体的制备方法 |
CN100506439C (zh) * | 2005-09-29 | 2009-07-01 | 江苏大学 | 一种制备纳米Cu的方法 |
KR20090010477A (ko) * | 2007-07-23 | 2009-01-30 | 삼성전기주식회사 | 니켈 나노입자의 제조방법 |
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CN102896322A (zh) * | 2012-11-01 | 2013-01-30 | 广东东硕科技有限公司 | 一种有抗氧化性及分散性的纳米铜制备方法 |
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Effective date of registration: 20130805 Address after: 226600 Chengdong Road, Haian Development Zone, Haian County, Nantong, Jiangsu Patentee after: Jiangsu Omar Machinery Co. Ltd. Patentee after: Jiangsu University of Technology Address before: 213001 Changzhou Province in the Clock Tower District, Jiangsu, Wu Road, No. 1801 Patentee before: Jiangsu Teachers University of Technology |
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