CN101831315B - 使用基于镍和钼的催化剂以受限制的脱羧转化率将源于可再生来源的原料加氢脱氧的方法 - Google Patents

使用基于镍和钼的催化剂以受限制的脱羧转化率将源于可再生来源的原料加氢脱氧的方法 Download PDF

Info

Publication number
CN101831315B
CN101831315B CN201010151752.XA CN201010151752A CN101831315B CN 101831315 B CN101831315 B CN 101831315B CN 201010151752 A CN201010151752 A CN 201010151752A CN 101831315 B CN101831315 B CN 101831315B
Authority
CN
China
Prior art keywords
range
catalyst
group vib
hydrogen
hydrodeoxygenation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201010151752.XA
Other languages
English (en)
Chinese (zh)
Other versions
CN101831315A (zh
Inventor
A·多丁
L·伯尼
T·查普斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Publication of CN101831315A publication Critical patent/CN101831315A/zh
Application granted granted Critical
Publication of CN101831315B publication Critical patent/CN101831315B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/883—Molybdenum and nickel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/72—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65 containing iron group metals, noble metals or copper
    • B01J29/74—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/28—Phosphorising
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/42—Catalytic treatment
    • C10G3/44—Catalytic treatment characterised by the catalyst used
    • C10G3/45—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof
    • C10G3/46—Catalytic treatment characterised by the catalyst used containing iron group metals or compounds thereof in combination with chromium, molybdenum, tungsten metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/50—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids in the presence of hydrogen, hydrogen donors or hydrogen generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G3/00—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
    • C10G3/54—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed
    • C10G3/55—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds
    • C10G3/56—Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids characterised by the catalytic bed with moving solid particles, e.g. moving beds suspended in the oil, e.g. slurries, ebullated beds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/62—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing platinum group metals or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/12—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation
    • C11C3/123—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by hydrogenation using catalysts based principally on nickel or derivates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/20—After treatment, characterised by the effect to be obtained to introduce other elements in the catalyst composition comprising the molecular sieve, but not specially in or on the molecular sieve itself
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1014—Biomass of vegetal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/10—Feedstock materials
    • C10G2300/1011—Biomass
    • C10G2300/1018—Biomass of animal origin
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/20—Characteristics of the feedstock or the products
    • C10G2300/201—Impurities
    • C10G2300/202—Heteroatoms content, i.e. S, N, O, P
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4006—Temperature
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4012—Pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2300/00—Aspects relating to hydrocarbon processing covered by groups C10G1/00 - C10G99/00
    • C10G2300/40—Characteristics of the process deviating from typical ways of processing
    • C10G2300/4018—Spatial velocity, e.g. LHSV, WHSV
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P30/00—Technologies relating to oil refining and petrochemical industry
    • Y02P30/20—Technologies relating to oil refining and petrochemical industry using bio-feedstock

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Catalysts (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
CN201010151752.XA 2009-03-10 2010-03-02 使用基于镍和钼的催化剂以受限制的脱羧转化率将源于可再生来源的原料加氢脱氧的方法 Active CN101831315B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR0901081A FR2943071B1 (fr) 2009-03-10 2009-03-10 Procede d'hydrodesoxygenation de charges issues de sources renouvelables avec conversion limitee en decarboxylation mettant en oeuvre un catalyseur a base de nickel et de molybdene
FR09/01081 2009-03-10

Publications (2)

Publication Number Publication Date
CN101831315A CN101831315A (zh) 2010-09-15
CN101831315B true CN101831315B (zh) 2014-10-29

Family

ID=41137091

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201010151752.XA Active CN101831315B (zh) 2009-03-10 2010-03-02 使用基于镍和钼的催化剂以受限制的脱羧转化率将源于可再生来源的原料加氢脱氧的方法

Country Status (13)

Country Link
US (1) US8552235B2 (enExample)
EP (1) EP2228423B1 (enExample)
JP (1) JP5525865B2 (enExample)
KR (1) KR101673597B1 (enExample)
CN (1) CN101831315B (enExample)
AT (1) ATE544838T1 (enExample)
BR (1) BRPI1000560B1 (enExample)
CA (1) CA2693350C (enExample)
ES (1) ES2382231T3 (enExample)
FR (1) FR2943071B1 (enExample)
MY (1) MY150429A (enExample)
PL (1) PL2228423T3 (enExample)
SG (1) SG165244A1 (enExample)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8309783B2 (en) 2008-11-04 2012-11-13 Energy & Environmental Research Center Foundation Process for the conversion of renewable oils to liquid transportation fuels
FR2949476B1 (fr) * 2009-09-02 2012-08-03 Inst Francais Du Petrole Procede de conversion de charges issues de sources renouvelables en co-traitement avec une charge petroliere mettant en oeuvre un catalyseur a base de nickel et de molybdene
FR2953854B1 (fr) * 2009-12-16 2012-12-28 Inst Francais Du Petrole Procede de conversion de charges issues de sources renouvelables avec pretraitement des charges par dephosphatation a chaud
EP2611884A4 (en) * 2010-08-31 2014-02-12 Chevron Usa Inc MACHINING A HYDROCARBON CIRCULATION
ES2700990T3 (es) 2010-09-08 2019-02-20 Ifp Energies Now Proceso para la hidrogenación continua de materiales de partida que contienen triglicéridos usando un catalizador basado en níquel y molibdeno
US8487148B2 (en) * 2010-12-13 2013-07-16 Exxonmobil Research And Engineering Company Hydrothermal treatment of biomass with heterogeneous catalyst
FR2969642B1 (fr) 2010-12-22 2012-12-28 IFP Energies Nouvelles Production de carburants paraffiniques a partir de matieres renouvelables par un procede d'hydrotraitement en continu
EP3517591A1 (en) 2011-02-15 2019-07-31 Neste Oil Oyj Use of renewable oil in hydrotreatment process
CN102794181B (zh) * 2011-05-27 2015-04-22 中科合成油技术有限公司 一种费托合成油品加氢脱氧催化剂、其制备方法和应用
FR2981360B1 (fr) * 2011-10-14 2015-08-07 IFP Energies Nouvelles Procede de production de distillats moyens a partir d'un melange d'une charge issue de sources renouvelables et d'un effluent paraffinique
FR2982271B1 (fr) 2011-11-08 2013-11-08 Ifp Energies Now Production de carburants paraffiniques a partir de matieres renouvelables par un procede d'hydrotraitement en continu comprenant une etape de pretraitement sous hydrogene
FR2982270B1 (fr) 2011-11-08 2013-11-08 IFP Energies Nouvelles Production de carburants paraffiniques a partir de matieres renouvelables par un procede d'hydrotraitement en continu comprenant une etape de pretraitement
WO2013073528A1 (ja) * 2011-11-15 2013-05-23 公益財団法人北九州産業学術推進機構 燃料油の製造方法
EP2781580A1 (en) * 2011-11-15 2014-09-24 Kitakyushu Foundation for the Advancement of Industry, Science and Technology Method for producing fuel oil
CN103130600B (zh) * 2011-11-24 2016-01-20 中国石油化工股份有限公司 一种利用动植物油脂及其废弃油生产低碳烯烃的方法
RU2472764C1 (ru) * 2011-11-28 2013-01-20 Федеральное государственное унитарное предприятие "Государственный научный центр "Научно-исследовательский институт органических полупродуктов и красителей" (ФГУП "ГНЦ "НИОПИК") Способ получения углеводородов топливного ряда из возобновляемого сырья
WO2013096326A1 (en) * 2011-12-22 2013-06-27 Energy & Environmental Research Center Foundation Process for the conversion of renewable oils to liquid transportation fuels
FR2984911B1 (fr) 2011-12-22 2014-08-29 IFP Energies Nouvelles Procede de conversion de charges paraffiniques issues de la biomasse en bases distillats moyens mettant en oeuvre au moins un catalyseur a base de zeolithe izm-2
FR2988399B1 (fr) 2012-03-20 2014-03-28 IFP Energies Nouvelles Procede de pretraitement de charges issues de sources renouvelables utilisant un oxyde refractaire poreux impregne de phosphate d'alcalino terreux
EP2695660B1 (en) * 2012-08-08 2018-01-10 Neste Oyj Method of purifying gas streams derived from hydrogenation, hydrodeoxygenation or hydrocracking of fatty acids, their esters and glycerides
US9162938B2 (en) 2012-12-11 2015-10-20 Chevron Lummus Global, Llc Conversion of triacylglycerides-containing oils to hydrocarbons
US9024096B2 (en) 2012-12-11 2015-05-05 Lummus Technology Inc. Conversion of triacylglycerides-containing oils
CN103614155B (zh) * 2013-09-11 2016-08-10 浙江工业大学 一种藻油生产烃类燃料的制备方法
KR20160097203A (ko) 2013-12-11 2016-08-17 이데미쓰 고산 가부시키가이샤 수소화 분해 처리용 촉매 및 탄화수소의 제조 방법
CN103920506A (zh) * 2014-05-08 2014-07-16 湘潭大学 一种高加氢脱氧活性的双金属硫化物催化剂及其制备方法
CZ305662B6 (cs) * 2014-06-30 2016-01-27 Unipetrol Výzkumně Vzdělávací Centrum, A. S. Způsob výroby molybdenového katalyzátoru s dalším aktivním kovem
FR3051682B1 (fr) 2016-05-30 2021-03-19 Ifp Energies Now Dispositif anti-colmatant pour la circulation ascendante d'un fluide
JP6742020B2 (ja) * 2016-09-06 2020-08-19 国立大学法人東京農工大学 炭化水素組成物の製造方法及び触媒
IT201700037970A1 (it) 2017-04-06 2018-10-06 Eni Spa Idrotrattamento di cariche da fonti rinnovabili con catalizzatori ad elevato contenuto di fase attiva
RU2652991C1 (ru) * 2017-12-28 2018-05-04 Федеральное государственное автономное образовательное учреждение высшего образования "Новосибирский национальный исследовательский государственный университет" (Новосибирский государственный университет, НГУ) Способ гидрооблагораживания триглицеридов жирных кислот в смеси с нефтяными фракциями
CN110756196B (zh) * 2018-07-26 2022-10-04 中国石油天然气股份有限公司 一种植物油加氢脱氧催化剂的制备方法
CN113293024B (zh) * 2020-04-26 2023-05-26 江西尊创新能源有限公司 一种三段式选择加氢脱氧制备生物柴油的方法
AU2021295570A1 (en) * 2020-06-26 2023-02-02 Topsoe A/S Method for selective decarboxylation of oxygenates
FR3122661B1 (fr) 2021-05-04 2024-05-17 Ifp Energies Now Procede optimise d'hydrotraitement et d’hydroconversion de charges issues de sources renouvelables
CN113617343A (zh) * 2021-08-31 2021-11-09 福州大学 一种生物质油脱氧催化剂及其制备方法和应用
PL246187B1 (pl) * 2022-07-11 2024-12-16 Politechnika Wroclawska Sposób wytwarzania biokomponentu paliw płynnych
FR3157422A1 (fr) 2023-12-21 2025-06-27 IFP Energies Nouvelles Procede de production de kerosene ou de gazole renouvelable par hydroprocessing en 2 etapes utilisant un catalyseur specifique pour l’etape d’hydroconversion sans recycle
FR3157421A1 (fr) 2023-12-21 2025-06-27 IFP Energies Nouvelles Procede de production de kerosene renouvelable par hydroprocessing en 2 etapes utilisant un catalyseur specifique dans l’etape d’hydroconversion avec recyclage d’une fraction lourde
FR3157424A1 (fr) 2023-12-21 2025-06-27 IFP Energies Nouvelles Procede de co-production de kerosene et de gazole renouvelable par hydroprocessing en 2 etapes utilisant un catalyseur specifique pour l’etape d’hydroconversion sans recycle
FR3157420A1 (fr) 2023-12-21 2025-06-27 IFP Energies Nouvelles Procede de production de kerosene renouvelable comprenant deux etapes d’hydroconversion et utilisant un catalyseur specifique dans la seconde etape d’hydroconversion

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1396531A2 (en) * 2002-09-06 2004-03-10 Fortum OYJ Process for producing a hydrocarbon component of biological origin
WO2006100584A2 (en) * 2005-03-21 2006-09-28 Ben-Gurion University Of The Negev Research & Development Authority Production of diesel fuel from vegetable and animal oils
WO2007141293A1 (en) * 2006-06-09 2007-12-13 Albemarle Netherlands B.V. Catalytic hydrodeoxygenation of an oxygenate feedstock
WO2008058664A1 (en) * 2006-11-15 2008-05-22 Eni S.P.A. Process for producing hydrocarbon fractions from mixtures of a biological origin

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3031557C2 (de) 1980-08-21 1986-05-22 Basf Ag, 6700 Ludwigshafen Kristalliner Borsilikatzeolith ZBM-30 und Verfahren zu seiner Herstellung
EP0065400B1 (en) 1981-05-20 1986-03-05 Imperial Chemical Industries Plc Zeolites
NZ202099A (en) 1981-10-21 1986-07-11 Ici Plc Preparation of zeolite nu-10
US4992605A (en) 1988-02-16 1991-02-12 Craig Wayne K Production of hydrocarbons with a relatively high cetane rating
CA2149685C (en) 1994-06-30 1999-09-14 Jacques Monnier Conversion of depitched tall oil to diesel fuel additive
JP2003171670A (ja) 2001-12-07 2003-06-20 Kawaken Fine Chem Co Ltd 炭化水素類の製造方法および炭化水素類製造用触媒
FR2843050B1 (fr) * 2002-08-01 2005-04-15 Inst Francais Du Petrole Catalyseur a base de metaux du groupe vi et du groupe viii presents au moins en partie sous la forme d'heteropolyanions dans le precurseur oxyde
US7232935B2 (en) * 2002-09-06 2007-06-19 Fortum Oyj Process for producing a hydrocarbon component of biological origin
EP1681337B2 (en) 2005-01-14 2020-05-13 Neste Oil Oyj Method for the manufacture of hydrocarbons
FR2882744B1 (fr) 2005-03-07 2008-06-06 Inst Francais Du Petrole Solide cristallise cok-7, procede de preparation et utilisation pour la transformation d'hydrocarbures
US20060264684A1 (en) * 2005-05-19 2006-11-23 Petri John A Production of diesel fuel from biorenewable feedstocks
US7288685B2 (en) * 2005-05-19 2007-10-30 Uop Llc Production of olefins from biorenewable feedstocks
ES2550259T5 (es) 2005-07-04 2023-06-08 Neste Oyj Proceso para la fabricación de hidrocarburos en el intervalo del diésel
DK1795576T3 (da) * 2005-12-12 2014-07-14 Neste Oil Oyj Fremgangsmåde til fremstilling af carbonhydrider
WO2007068800A2 (en) * 2005-12-12 2007-06-21 Neste Oil Oyj Process for producing a saturated hydrocarbon component
FR2911866B1 (fr) 2007-01-30 2009-03-06 Inst Francais Du Petrole Solide cristalise izm-1 et son procede de preparation.
WO2008124607A1 (en) * 2007-04-06 2008-10-16 Syntroleum Corporation Process for co-producing jet fuel and lpg from renewable sources
FR2917423B1 (fr) * 2007-06-12 2012-11-30 Inst Francais Du Petrole Hydrotraitement en deux etapes d'une charge issue d'une source renouvelable mettant en oeuvre un premier catalyseur metallique et un deuxieme catalyseur sulfure
US8084655B2 (en) * 2007-06-15 2011-12-27 E. I. Du Pont De Nemours And Company Catalytic process for converting renewable resources into paraffins for use as diesel blending stocks
JP5005451B2 (ja) * 2007-07-13 2012-08-22 Ｊｘ日鉱日石エネルギー株式会社 炭化水素油の製造方法
US8026401B2 (en) * 2007-12-20 2011-09-27 Syntroleum Corporation Hydrodeoxygenation process
FR2940144B1 (fr) * 2008-12-23 2016-01-22 Inst Francais Du Petrole Methode de transformation d'effluents d'origine renouvelable en carburant d'excellente qualite mettant en oeuvre un catalyseur a base de molybdene

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1396531A2 (en) * 2002-09-06 2004-03-10 Fortum OYJ Process for producing a hydrocarbon component of biological origin
WO2006100584A2 (en) * 2005-03-21 2006-09-28 Ben-Gurion University Of The Negev Research & Development Authority Production of diesel fuel from vegetable and animal oils
WO2007141293A1 (en) * 2006-06-09 2007-12-13 Albemarle Netherlands B.V. Catalytic hydrodeoxygenation of an oxygenate feedstock
WO2008058664A1 (en) * 2006-11-15 2008-05-22 Eni S.P.A. Process for producing hydrocarbon fractions from mixtures of a biological origin

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
Effect of sulphiding agents on the hydrodeoxygenation of aliphatic esters on sulphided catalysts;Senol等;《Applied Catalysis A: General》;20070421;第326卷(第2期);第236-244页 *
Senol等.Effect of sulphiding agents on the hydrodeoxygenation of aliphatic esters on sulphided catalysts.《Applied Catalysis A: General》.2007,第326卷(第2期),236-244.

Also Published As

Publication number Publication date
EP2228423B1 (fr) 2012-02-08
BRPI1000560B1 (pt) 2019-11-05
US20100240942A1 (en) 2010-09-23
FR2943071A1 (fr) 2010-09-17
BRPI1000560A2 (pt) 2011-03-22
ES2382231T3 (es) 2012-06-06
JP5525865B2 (ja) 2014-06-18
CN101831315A (zh) 2010-09-15
JP2010209330A (ja) 2010-09-24
EP2228423A1 (fr) 2010-09-15
ATE544838T1 (de) 2012-02-15
MY150429A (en) 2014-01-30
FR2943071B1 (fr) 2011-05-13
KR20100102050A (ko) 2010-09-20
CA2693350A1 (fr) 2010-09-10
PL2228423T3 (pl) 2012-07-31
KR101673597B1 (ko) 2016-11-07
US8552235B2 (en) 2013-10-08
SG165244A1 (en) 2010-10-28
CA2693350C (fr) 2017-12-12

Similar Documents

Publication Publication Date Title
CN101831315B (zh) 使用基于镍和钼的催化剂以受限制的脱羧转化率将源于可再生来源的原料加氢脱氧的方法
CN101773843B (zh) 通过使用钼基催化剂将可再生源的流出物转化为高质量燃料的方法
EP2334757B1 (en) Hydroconversion process and catalyst
US8324439B2 (en) Method of converting feedstocks from renewable sources to good-quality diesel fuel bases using a zeolite type catalyst
US8282815B2 (en) Method of converting feedstocks from renewable sources to good-quality diesel fuel bases using a zeolite catalyst without intermediate gas-liquid separation
US10858594B2 (en) Hydrodeoxigenation process of vegetable oils for obtaining green diesel
US20110094149A1 (en) Method of hydrotreating feeds from renewable sources with indirect heating using a catalyst based on molybdenum
US20110098494A1 (en) Method of hydrotreating feeds from renewable sources with indirect heating using a catalyst based on nickel and molybdenum having a particular atomic ratio
CN121079383A (zh) 使用至少一种硫化物催化剂与单独的或与fau结构沸石混合的bea结构沸石的一步植物油加氢处理和加氢异构化的方法
CN117280014A (zh) 用于源自可再生资源的原料的加氢处理和加氢转化的优化方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant