CN101811881A - 钢包用MgO-C材质渣线砖 - Google Patents
钢包用MgO-C材质渣线砖 Download PDFInfo
- Publication number
- CN101811881A CN101811881A CN201010151588A CN201010151588A CN101811881A CN 101811881 A CN101811881 A CN 101811881A CN 201010151588 A CN201010151588 A CN 201010151588A CN 201010151588 A CN201010151588 A CN 201010151588A CN 101811881 A CN101811881 A CN 101811881A
- Authority
- CN
- China
- Prior art keywords
- slag line
- brick
- steel ladle
- mgo
- parts
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 239000011449 brick Substances 0.000 title claims abstract description 46
- 239000002893 slag Substances 0.000 title claims abstract description 39
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 24
- 239000010959 steel Substances 0.000 title claims abstract description 24
- 239000000463 material Substances 0.000 title claims abstract description 19
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Chemical compound 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[Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 20
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicium dioxide Chemical compound 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O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 20
- OKTJSMMVPCPJKN-UHFFFAOYSA-N carbon Chemical compound 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[C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000010439 graphite Substances 0.000 claims abstract description 15
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 15
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 10
- 239000004411 aluminium Substances 0.000 claims abstract description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminum Chemical compound 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[Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000000843 powder Substances 0.000 claims abstract description 10
- 239000000377 silicon dioxide Substances 0.000 claims abstract description 10
- 239000002994 raw material Substances 0.000 claims abstract description 9
- ZLNQQNXFFQJAID-UHFFFAOYSA-L Magnesium carbonate Chemical compound 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- 208000008425 Protein Deficiency Diseases 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N Silicic acid Chemical class 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O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000005087 graphitization Methods 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 230000001590 oxidative Effects 0.000 description 1
- 238000010587 phase diagram Methods 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000011819 refractory material Substances 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
Abstract
本发明公开了一种钢包用MgO-C材质渣线砖，按重量份包括以下原料：电熔镁砂85～89，鳞片石墨10～14，铝粉1～1.5，硅粉1～1.5，结合剂3.5～4，该渣线砖可满足大容积钢包(210t钢包)，原始使用寿命75次以上，挖修使用寿命达到45次以上，总体保证钢包渣线挖修一次包身砖寿命达到120次以上的使用要求，并与包身砖、水口座砖的寿命匹配良好。
Description
钢包用MgO-C材质渣线砖
技术领域
[0001] 本发明涉及耐火材料，特别涉及一种钢包用MgO-C材质渣线砖。
背景技术
[0002] 钢包是用于炼钢厂、铸造厂在平炉、电炉或转炉前承接钢水、进行浇注作业的设 备，由于钢包常在高温条件下使用，与钢水接触的部分需进行耐火处理，通常是通过砌耐火 砖并用耐火泥嵌封砖缝的方式来达到使用要求，因此，耐火砖的使用寿命将对生产效率产 生重大影响；另外，由于钢水中的熔渣在高温下更容易对耐火砖产生侵蚀，需在渣线处使用 专用的渣线砖，为达到渣线砖与包身砖、水口座砖的寿命匹配，渣线砖需满足更高的要求。
[0003] 现有的钢包包壁、包底目前大多采用铝镁质耐火浇注料砌筑熔池部位，使用寿命 视钢厂的冶炼状况波动在100-120炉之间，还有一些在100次以下的。渣线部位使用寿命波 动在60-70炉之间，钢包使用中需对钢包渣线进行修补，修补一般采用冷修，修补方式为挖 补或涂抹，此种方法费时费料，而且使用效果不很理想，尤其对于大容积钢包（210t钢包）， 难以达到原始使用寿命75次以上，挖修使用寿命达到45次以上，总体保证钢包渣线挖修一 次包身砖寿命达到120次以上的使用要求。
[0004] 针对上述不足，需探索一种钢包用渣线砖，使其与包身砖寿命匹配，并满足大容积 钢包对耐火砖的寿命要求，以降低修补和更换频率，提高生产效率。
发明内容
[0005] 有鉴于此，本发明提供一种钢包用MgO-C材质渣线砖，该渣线砖可满足大容积钢 包的使用要求，并与包身砖、水口座砖的寿命匹配良好。
[0006] 本发明的钢包用MgO-C材质渣线砖，按重量份包括以下原料：电熔镁砂85〜89， 鳞片石墨10〜14，铝粉1〜1. 5，硅粉1〜1. 5，结合剂3. 5〜4。
[0007] 进一步，所述电熔镁砂为MgO含量> 98 %的大结晶电熔镁砂，其杂质中的C和S含 量的比例大于或等于2;
[0008] 进一步，所述鳞片石墨为+896的大鳞片石墨；
[0009] 进一步，所述结合剂按重量份包括以下成份：酚醛树脂65〜75，改性浙青25〜 35。
[0010] 发明的有益效果：本发明的钢包用MgO-C材质渣线砖，按重量份包括以下原料：电 熔镁砂85〜89，鳞片石墨10〜14，铝粉1〜1. 5，硅粉1〜1. 5，结合剂3. 5〜4，该渣线砖 可满足大容积钢包（210t钢包），原始使用寿命75次以上，挖修使用寿命达到45次以上，总 体保证钢包渣线挖修一次包身砖寿命达到120次以上的使用要求，并与包身砖、水口座砖 的寿命匹配良好。
具体实施方式
[0011] 实施例1[0012] 本实施例的钢包用MgO-C材质渣线砖，按重量份包括以下原料：电熔镁砂85，鳞片 石墨14，铝粉1，硅粉1，结合剂3. 5〜4，铝粉和硅粉为抗氧化剂，可加强材质的抗氧化性 能。
[0013] 本实施例中，电熔镁砂为MgO含量> 98 %的大结晶电熔镁砂，其杂质中的C和S含 量的比例大于或等于2含有C和S的比例C/S彡2，从而使副晶组成相落在Ca0-Mg0-Si02 三元相图中Ca0-Mg0-C2S三相之间的高熔点区，以提高MgO-C砖高温稳定性，MgO含量越高， 杂质相对越少，硅酸盐相分割程度降低，方镁石直接结合程度提高，抗熔渣的渗透熔损能力 提高；C/S比控制着镁砂的副晶相类型，C/S越高可以减少MgO与C的高温反应，同时C/S比 越高方镁石直接结合程度亦高，提高MgO-C砖高温稳定性。
[0014] 本实施例中，鳞片石墨为+896的大鳞片石墨，可提高高温抗折强度、抗氧化性能、 抗侵蚀能力和热震稳定性能。
[0015] 本实施例中，所述结合剂按重量份包括酚醛树脂75和改性浙青25，酚醛树脂的碳 化组织是玻璃状结构，韧性不够，而浙青的碳化组织为镶嵌结构，可以提高制品的性能，但 普通浙青存在环境污染问题，改性浙青不但污染小且提高了浙青的碳化组织的石墨化度和 碳化组织的氧化温度，提高制品的抗氧化性。
[0016] 经实践验证：采用上述渣线砖的钢包平均寿命达到78+48. 75次（前为使用次数， 后为进LF炉精炼次数）。
[0017] 实施例2
[0018] 本实施例的钢包用MgO-C材质渣线砖，按重量份包括以下原料：MgO含量彡98%且 含有C和S的比例C/S彡2的大结晶电熔镁砂87，+896的大鳞片石墨12，铝粉1，硅粉1， 含酚醛树脂70和改性浙青30的结合剂3. 5。
[0019] 经实践验证：采用上述渣线砖的钢包平均寿命达到80+49次。
[0020] 实施例3
[0021] 本实施例的钢包用MgO-C材质渣线砖，按重量份包括以下原料：MgO含量彡98%且 含有C和S的比例C/S彡2的大结晶电熔镁砂89，+896的大鳞片石墨10，铝粉1. 5，硅粉 1. 5，含酚醛树脂65和改性浙青35的结合剂3. 6。
[0022] 经实践验证：采用上述渣线砖的钢包平均寿命达到84+52. 02次。
[0023] 实施例4
[0024] 本实施例的钢包用MgO-C材质渣线砖，按重量份包括以下原料：MgO含量彡98%且 含有C和S的比例C/S彡2的大结晶电熔镁砂87，+896的大鳞片石墨12，铝粉1. 5，硅粉 1. 5，含酚醛树脂70和改性浙青30的结合剂3. 5。
[0025] 经实践验证：采用上述渣线砖的钢包平均寿命达到83. 75+53. 75次。
[0026] 由实施例1〜4可知，该渣线砖可满足210t钢包，原始使用寿命75次以上，挖修 使用寿命达到45次以上，总体保证钢包渣线挖修一次包身砖寿命达到120次以上的使用要 求，并与包身砖、水口座砖的寿命匹配良好。
[0027] 最后说明的是，以上实施例仅用以说明本发明的技术方案而非限制，尽管参照较佳实施例对本发明进行了详细说明，本领域的普通技术人员应当理解，可以对本发明的技 术方案进行修改或者等同替换，而不脱离本发明技术方案的宗旨和范围，其均应涵盖在本 发明的权利要求范围当中。
Claims (5)
- 一种钢包用MgO-C材质渣线砖，其特征在于：按重量份包括以下原料：电熔镁砂85～89，鳞片石墨10～14，铝粉1～1.5，硅粉1～1.5，结合剂3.5～4。
- 2.根据权利要求1所述的钢包用MgO-C材质渣线砖，其特征在于：按重量份包括以下 原料：电熔镁砂87，鳞片石墨12，铝粉1. 5，硅粉1. 5，结合剂3. 5。
- 3.根据权利要求2所述的钢包用MgO-C材质渣线砖，其特征在于：所述电熔镁砂为MgO 含量彡98%的大结晶电熔镁砂，其杂质中的C和S含量的比例大于或等于2。
- 4.根据权利要求3所述的钢包用MgO-C材质渣线砖，其特征在于：所述鳞片石墨为 +896的大鳞片石墨。
- 5.根据权利要求4所述的钢包用MgO-C材质渣线砖，其特征在于：所述结合剂按重量 份包括以下成份：酚醛树脂65〜75，改性浙青25〜35。
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