CN101794892B - 含有烷基醚接枝链的高分子电解质膜及其制造方法 - Google Patents

含有烷基醚接枝链的高分子电解质膜及其制造方法 Download PDF

Info

Publication number
CN101794892B
CN101794892B CN201010109458.2A CN201010109458A CN101794892B CN 101794892 B CN101794892 B CN 101794892B CN 201010109458 A CN201010109458 A CN 201010109458A CN 101794892 B CN101794892 B CN 101794892B
Authority
CN
China
Prior art keywords
vinyl
electrolyte membrane
styrene
fuel cell
derivatives
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201010109458.2A
Other languages
English (en)
Chinese (zh)
Other versions
CN101794892A (zh
Inventor
前川康成
榎本一之
木原伸浩
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kanagawa University
National Institutes for Quantum Science and Technology
Original Assignee
Kanagawa University
Japan Atomic Energy Agency
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanagawa University, Japan Atomic Energy Agency filed Critical Kanagawa University
Publication of CN101794892A publication Critical patent/CN101794892A/zh
Application granted granted Critical
Publication of CN101794892B publication Critical patent/CN101794892B/zh
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1039—Polymeric electrolyte materials halogenated, e.g. sulfonated polyvinylidene fluorides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/16—Chemical modification with polymerisable compounds
    • C08J7/18—Chemical modification with polymerisable compounds using wave energy or particle radiation
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/102—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer
    • H01M8/1023—Polymeric electrolyte materials characterised by the chemical structure of the main chain of the ion-conducting polymer having only carbon, e.g. polyarylenes, polystyrenes or polybutadiene-styrenes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1086—After-treatment of the membrane other than by polymerisation
    • H01M8/1088—Chemical modification, e.g. sulfonation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/12—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Sustainable Energy (AREA)
  • Electrochemistry (AREA)
  • Sustainable Development (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Toxicology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Fuel Cell (AREA)
  • Conductive Materials (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Manufacture Of Macromolecular Shaped Articles (AREA)
CN201010109458.2A 2009-02-03 2010-02-03 含有烷基醚接枝链的高分子电解质膜及其制造方法 Expired - Fee Related CN101794892B (zh)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2009022352A JP5333913B2 (ja) 2009-02-03 2009-02-03 アルキルエーテルグラフト鎖からなる高分子電解質膜、及び、その製造方法
JP022352/09 2009-02-03

Publications (2)

Publication Number Publication Date
CN101794892A CN101794892A (zh) 2010-08-04
CN101794892B true CN101794892B (zh) 2014-04-09

Family

ID=42587395

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201010109458.2A Expired - Fee Related CN101794892B (zh) 2009-02-03 2010-02-03 含有烷基醚接枝链的高分子电解质膜及其制造方法

Country Status (4)

Country Link
US (2) US8470895B2 (enExample)
JP (1) JP5333913B2 (enExample)
CN (1) CN101794892B (enExample)
DE (1) DE102010006563A1 (enExample)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5376485B2 (ja) * 2007-02-21 2013-12-25 独立行政法人日本原子力研究開発機構 アルキルグラフト鎖からなる高分子電解質膜、及び、その製造方法
JP5333913B2 (ja) * 2009-02-03 2013-11-06 独立行政法人日本原子力研究開発機構 アルキルエーテルグラフト鎖からなる高分子電解質膜、及び、その製造方法
JP5776095B2 (ja) * 2010-11-16 2015-09-09 日東電工株式会社 耐酸化性に優れたプロトン伝導性高分子電解質膜およびその製造方法
JP2013189595A (ja) * 2012-03-15 2013-09-26 Nitto Denko Corp グラフト鎖を有する高分子電解質膜およびその製造方法
TWI589610B (zh) * 2013-12-31 2017-07-01 財團法人工業技術研究院 聚電解質與儲能元件
US11512156B2 (en) * 2017-09-28 2022-11-29 University Of Delaware Poly(aryl piperidinium) polymers including those with stable cationic pendant groups for use as anion exchange membranes and ionomers
US20200295394A1 (en) * 2019-03-15 2020-09-17 University Of Maryland, College Park Ionic liquid conductive membrane and methods of fabricating same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6670065B2 (en) * 2000-09-29 2003-12-30 Hitachi, Ltd. Solid polymer electrolyte, a membrane using thereof, a solution for coating electrode catalyst, a membrane/electrode assembly, and a fuel cell
CN1688624A (zh) * 2002-09-20 2005-10-26 百拉得动力系统公司 制备膜用接枝共聚物的方法

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS538692A (en) * 1976-07-14 1978-01-26 Japan Atom Energy Res Inst Preparation of graft copolymer for ion-exchange membrane
JPH11111310A (ja) 1997-09-30 1999-04-23 Aisin Seiki Co Ltd 燃料電池用の固体高分子電解質膜およびその製造方法
JP4568848B2 (ja) 2000-06-07 2010-10-27 独立行政法人 日本原子力研究開発機構 広範囲なイオン交換容量のフッ素樹脂イオン交換膜及びその製造方法
JP4063596B2 (ja) * 2002-06-03 2008-03-19 株式会社カネカ プロトン伝導性高分子化合物およびプロトン伝導性高分子膜
JP2004087137A (ja) * 2002-08-22 2004-03-18 Aisin Seiki Co Ltd 燃料電池用固体高分子電解質膜
JP4748410B2 (ja) 2004-12-22 2011-08-17 独立行政法人 日本原子力研究開発機構 架橋構造を導入した高耐久性燃料電池用高分子電解質膜の製造方法
JP2007294408A (ja) * 2006-03-29 2007-11-08 Toyota Central Res & Dev Lab Inc Ppp型炭化水素電解質及びその製造方法、ppp、並びに、ppp型炭化水素電解質を用いた電解質膜、触媒層及び固体高分子型燃料電池
JP5545609B2 (ja) 2006-08-24 2014-07-09 独立行政法人日本原子力研究開発機構 芳香族高分子膜基材からなる高分子電解質膜、及び、その製造方法
JP5376485B2 (ja) 2007-02-21 2013-12-25 独立行政法人日本原子力研究開発機構 アルキルグラフト鎖からなる高分子電解質膜、及び、その製造方法
JP5333913B2 (ja) * 2009-02-03 2013-11-06 独立行政法人日本原子力研究開発機構 アルキルエーテルグラフト鎖からなる高分子電解質膜、及び、その製造方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6670065B2 (en) * 2000-09-29 2003-12-30 Hitachi, Ltd. Solid polymer electrolyte, a membrane using thereof, a solution for coating electrode catalyst, a membrane/electrode assembly, and a fuel cell
CN1688624A (zh) * 2002-09-20 2005-10-26 百拉得动力系统公司 制备膜用接枝共聚物的方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
JP特开2004-10631A 2004.01.15

Also Published As

Publication number Publication date
JP2010182436A (ja) 2010-08-19
JP5333913B2 (ja) 2013-11-06
US20100216901A1 (en) 2010-08-26
CN101794892A (zh) 2010-08-04
US8470895B2 (en) 2013-06-25
US20130288159A1 (en) 2013-10-31
US9379405B2 (en) 2016-06-28
DE102010006563A1 (de) 2010-09-30

Similar Documents

Publication Publication Date Title
JP4748410B2 (ja) 架橋構造を導入した高耐久性燃料電池用高分子電解質膜の製造方法
WO2008044405A1 (en) Polymer electrolyte film for fuel cell which has silane crosslinked structure, and electrode assembly for fuel cell comprising the polymer electrolyte film
JP5004178B2 (ja) 機械的強度に優れる高プロトン伝導性高分子電解質膜及びその製造方法
JP4682358B2 (ja) 機能性無機/グラフト高分子ハイブリッドイオン交換膜の製造方法および燃料電池用電解質膜
JP5376485B2 (ja) アルキルグラフト鎖からなる高分子電解質膜、及び、その製造方法
US9379405B2 (en) Polymer electrolyte membrane having alkylether graft chain
US20140066528A1 (en) Anion exchange membrane and producing method thereof
JP4532812B2 (ja) 架橋フッ素樹脂基材からなる燃料電池用電解質膜
WO2008023801A1 (en) Polymer electrolyte membrane composed of aromatic polymer membrane base and method for producing the same
JP5673922B2 (ja) 架橋芳香族高分子電解質膜とその製造方法、および架橋芳香族高分子電解質膜を用いた高分子形燃料電池
US20070224480A1 (en) Process for producing polymer electrolyte membranes for fuel cells, polymer electrolyte membranes for fuel cells produced by the process, and fuel cell membrane-electrode assemblies using the membranes
JP5959046B2 (ja) アニオン伝導電解質膜およびその製造方法
JP4670074B2 (ja) 耐酸性の優れた燃料電池用電解質膜
JP4822389B2 (ja) 耐酸化性の優れた電解質膜
JP4986219B2 (ja) 電解質膜
JP2005063778A (ja) 耐酸化性に優れた燃料電池用電解質膜
JP5641457B2 (ja) 芳香族高分子膜基材からなる高分子電解質膜、及び、その製造方法
JP5305283B2 (ja) 燃料電池用高分子電解質膜の製造方法、その電解質膜及びその膜を使用した燃料電池用膜電極接合体
JP2005142014A (ja) 耐酸性に優れた燃料電池用電解質膜
JPWO2009034965A1 (ja) 固体高分子電解質膜及び固体高分子電解質膜の製造方法並びに燃料電池
JP2009151938A (ja) 燃料電池用固体高分子電解質膜及び燃料電池
JP4814860B2 (ja) 架橋フッ素樹脂基材からなる燃料電池用電解質膜の製造方法
US20080044710A1 (en) Electrolyte Membrane Having Excellent Adhesion To Electrodes

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
C56 Change in the name or address of the patentee

Owner name: NATIONAL INSTITUTE OF?JAPAN ATOMIC ENERGY AGENCY

Free format text: FORMER NAME: JAPAN ATOMIC ENERGY AGENCY

CP01 Change in the name or title of a patent holder

Address after: Ibaraki

Patentee after: JAPAN ATOMIC ENERGY AGENCY

Patentee after: KANAGAWA University

Address before: Ibaraki

Patentee before: JAPAN ATOMIC ENERGY AGENCY

Patentee before: KANAGAWA University

Address after: Ibaraki

Patentee after: JAPAN ATOMIC ENERGY AGENCY

Patentee after: KANAGAWA University

Address before: Ibaraki

Patentee before: Japan Atomic Energy Agency

Patentee before: KANAGAWA University

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20190325

Address after: Chiba County, Japan

Co-patentee after: KANAGAWA University

Patentee after: NATIONAL INSTITUTE OF RADIOLOGICAL SCIENCES

Address before: Ibaraki

Co-patentee before: KANAGAWA University

Patentee before: JAPAN ATOMIC ENERGY AGENCY

CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20140409

Termination date: 20200203