CN101785748A - Scalp nursing solution for use in hair dyeing - Google Patents
Scalp nursing solution for use in hair dyeing Download PDFInfo
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- CN101785748A CN101785748A CN201010108297A CN201010108297A CN101785748A CN 101785748 A CN101785748 A CN 101785748A CN 201010108297 A CN201010108297 A CN 201010108297A CN 201010108297 A CN201010108297 A CN 201010108297A CN 101785748 A CN101785748 A CN 101785748A
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Abstract
The invention discloses scalp nursing solution for use in hair dyeing, which is characterized by comprising the following raw materials in part by mass: 5 to 30 parts of polyving akohol, 2 to 10 parts of gelatin, 2 to 10 parts of carboxylating chitosan and 100 parts of water or 10 percent ethanol solution. The solution is applied to scalps, and compact high polymer protective membranes (microcellular structures beneath surface layers and membranes) can be formed quickly under the action of water-solubility high polymer strong hydrogen bonds; and the scalp nursing solution is insoluble in organic solvent, has the excellent gas barrier effect on organic volatile gas, can prevent hair colorant from being contacted, volatilizing and splashing to the scalps, so that harmful substances are prevented from permeating into hair follicles, the injuries caused by hair dye to human bodies are reduced, and the applying is convenient and the washing is easy.
Description
Technical field:
The present invention relates to the category of cosmetology with outer compress material, safeguard procedures and skin nursing, smear conveniently, film forming rapidly, be easy to clean, can prevent that harmful substance from infiltrating hair follicle, reduces the scalp nursing solution for use in hair dyeing that human body is damaged because of hair dyeing.
Background technology:
The brilliance that hair dyeing can not only increase life can also change people's mental attitude, and therefore hair dyeing has become current a kind of fashion.But, because hair dye is a kind of potent chemical substance, include chemical constituents such as aminoanisole, phenylenediamine, and phenylenediamine can generate volatile toxic substance-quinone diamidogen in oxidation reaction process, therefore, if hair dye directly contacts with scalp in the hair dyeing process, on the one hand scalp cells be easy to hair dye in chemical constituent react, on the other hand the excuse skin be the human body hair follicle at most, the most intensive position, harmful substance in the hair dye can enter human body by the scalp hair follicle, all human body is caused in various degree infringement.The lighter's aftersensation dry mouth and tougue of having hair dyed, scalp tingle even headache, the hair quality of hair is also worse and worse; Weight person can make the body's immunity disorder, symptoms such as erythema, blister, pruritus and allergic dermatitis occur such as partial skin, even the allergic phenomena of general can take place, such as the respiratory tract spasm etc., so that threat to life; More severe patient is that organic substance such as benzene class enters blood capillary by scalp, arrives bone marrow with blood circulation then, and the prolonged and repeated hematopoietic stem cell that acts on causes cancerating of hematopoietic stem cell, promptly suffers from leukemia; Experiment showed, if human body skin absorb 1% aminoanisole all can be carcinogenic, common have bladder cancer, renal carcinoma, breast carcinoma and a skin carcinoma etc.
In view of the above, expert advice 1 year hair dyeing number of times preferably is no more than twice, suffers from the patient of diseases such as hypertension, heart disease, asthma, man and wife and the women of anemia of pregnant woman and age of sucking who prepares fertility all should not have hair dyed.But this suggestion can not meet with a response because of the demand that does not satisfy the personage that likes to be beautiful.The authoritative sources also proposes should not wash hair before the hair dyeing, the faintly acid sebum secretion thing film (pH value is between 4.5～5.5) that as far as possible keeps scalp itself, but all be to have hair cut earlier afterwards to have hair dyed in fact mostly, just must wash hair (the bob stubble that produces in the flush away hair-cutting process) before the hair dyeing, sebum secretion thing film is difficult to keep.One deck vaseline is smeared in the suggestion that also has on scalp, still, not only smear inconvenience, and is difficult to clean the oils and fats balance of easier destruction scalp.
In order to solve the problem that hair dye and scalp directly contact; having invented many hair dyeing auxiliary equipment at present, is that 200820085618.2 utility model patent " scalp protective cover ", China Patent No. are 200620101753.2 utility model patent " hair dyeing is protected hair clip with scalp " etc. as China Patent No..But above facility can only avoid hair dye to contact with scalp when smearing, and after smearing, and hair dye still can flow on the scalp along hair and be absorbed by hair follicle; When hair washing, the volatile organic matter in the hair dye also still can contact with scalp along with steam, non-volatile matter and water, still can not tackle the problem at its root in addition.
Summary of the invention:
The present invention is in order to solve the above-mentioned technical problem of existing in prior technology, provide a kind of and smear conveniently, film forming rapidly, be easy to clean, can prevent that harmful substance from infiltrating hair follicle, reduces the scalp nursing solution for use in hair dyeing that human body is damaged because of hair dyeing.
Technical solution of the present invention is: a kind of scalp nursing solution for use in hair dyeing is characterized in that the raw material and the mass ratio that are contained are as follows:
5～30 parts of polyvinyl alcohol
2～10 parts in gelatin
2～10 parts of using carboxyl chitosans
100 parts of water or 10% alcoholic solution.
Also contain mass ratio in the described raw material and be 0.1～5 part antioxidant.
Also contain mass ratio in the described raw material and be 0.5～5 part plasticizer.
Also contain mass ratio in the described raw material and be 0.1～2 part surfactant.
Also contain mass ratio in the described raw material and be 0.05～3 part viscosity reductant.
Also contain mass ratio in the described raw material and be 0.01～0.5 part screening agent.
Also contain mass ratio in the described raw material and be 0.05～1 part cutaneous permeable agent.
Also contain mass ratio in the described raw material and be 0.1～5 part thickening agent.
Also contain functional component in the described raw material.
Also contain adjuvant in the described raw material.
The present invention is to be main component with the water soluble film-forming material, is adjusted to the solution of certain viscosity with aqueous solvent, is convenient to smear, is easy to clean; With this solution coating on scalp; effect because of the water soluble polymer strong hydrogen bonding; can form fine and close polymer protective film (microcellular structure under top layer and the film) rapidly; insoluble to organic solvent; organic volatile gas there is good gas-barrier properties; can avoid hair dye contact, volatilization, splash to scalp, prevent that harmful substance from infiltrating hair follicle, reduces the injury that human body is caused because of hair dyeing.
Concrete function and characteristics are as follows:
(1) when smearing hair dye, formed polymer protective film is covered with the scalp epidermis and prevents that it from directly contacting with hair dye, also hindered hair dye and infected scalp along hair;
When (2) hair dye rests on the hair, the fine and close relatively top layer of polymer protective film is the environment isolation of living in of appurtenances such as the epidermis of scalp, sebaceous gland, sweat gland, hair follicle and hair dye, stoped each oxious component that contains in the hair dye, and the intermediate (harmful substance) that in the redox reaction process, produces of hair dye, invade scalp by volatile form, scalp tissue is damaged;
(3) filmogen of polymer protective film has determined the microcellular structure of this protecting film to have certain " printing opacity, oxygen flow, water conservation " property, and under the effect of film tension force, make and pharmacology or physical therapy composition in the membrane go deep into the effect that the scalp hair follicle reaches the toxin expelling skin protection;
(4) hair dyeing back polymer protective film continues to stop hair dye volatilization composition to pollute scalp with steam, non-volatile matter and water; have only by using shampoo; cooperate and refer to the massage of thumb abdomen and the absorbability of high molecular surfactant (filmogen); the dirt that makes remaining heavy metallic salt and harmful components on the hair of scalp, remollescent sebum, secretions and accumulate etc.; along with water-soluble protecting film is washed and cleared-out together; scalp is painless, and hair is easily lubricated.
The specific embodiment:
The embodiment of the invention mainly is divided into two classes according to the raw material difference, and is promptly universal and at type.
(1) universal: for scalp provides protecting film and repairs the required necessary nutrition of hair, according to adding different components, product can be divided into a lot of models again.
(2) at type:,, add millimeter or nano level functional component (pharmacology composition) as hair of scalp diseases such as seborrheic dermatitis, tinea capitis, chronic eczema, atoipc dermatitis, the dandruff, alopecias to special population.Consumption and incompatibility are carried out according to the regulation on the pharmacopeia.
Embodiment 1 (universal):
Be raw material with water or concentration with polyvinyl alcohol, gelatin and using carboxyl chitosan be that 10% alcoholic solution mixes, make the liquid of certain viscosity.The quality proportioning of each raw material is as follows: 100 parts of 5～30 parts of polyvinyl alcohol, 2～10 parts in gelatin, 2～10 parts of using carboxyl chitosans, water or 10% alcoholic solution.
Preferably alcoholysis type of polyvinyl alcohol, gelatin be gelatin hydrolysate (collagen protein) preferably.
Embodiment 2 (universal):
Raw material and quality proportioning are as follows:
8～12 parts of polyvinyl alcohol
2～3 parts in gelatin
2～3 parts of carboxymethyl chitosans
100 parts in water
0.1～5 part of antioxidant.
Antioxidant can be at least a in butylated hydroxyarisol, ditertbutylparacresol, tea polyphenols, vitamin C, watermiscible vitamin E and the Herba Rosmarini Officinalis extract.
Embodiment 3 (universal):
Raw material and quality proportioning are as follows:
5～10 parts of polyvinyl alcohol
5～10 parts in gelatin
5～10 parts of using carboxyl chitosans
100 parts in water
0.1～4 part of antioxidant
0.5～5 part of plasticizer.
Plasticizer can be at least a in glycerol, propylene glycol, sorbitol, triacetyl glycerine, the dibutyl phthalate.
Embodiment 4 (universal):
10～20 parts of polyvinyl alcohol
5～10 parts in gelatin
5～10 parts of using carboxyl chitosans
100 parts in water
0.1～4 part of antioxidant
0.5～4 part of plasticizer
0.1～2 part in surfactant.
Surfactant is the Tweens surfactant, based on tween 80.
Embodiment 5 (universal):
5～20 parts of polyvinyl alcohol
2～5 parts in gelatin
5～10 parts of using carboxyl chitosans
100 parts in water
0.1～3 part of antioxidant
0.5～3 part of plasticizer
0.1～1 part in surfactant
0.05～3 part of viscosity reductant.
Viscosity reductant is at least a in water-soluble silicon oil, silicone, water solublity glyceride, the water solublity vaseline.
Embodiment 6 (universal):
5～10 parts of polyvinyl alcohol
5～10 parts in gelatin
5～10 parts of water-soluble carboxymethyl chitosans
100 parts in water
0.1～3 part of antioxidant
0.5～3 part of plasticizer
0.1～1 part in surfactant
0.05～2.5 part of viscosity reductant
0.01～0.5 part of screening agent.
Screening agent is that ethylenediaminetetraacetic acid is received.
Embodiment 7 (universal):
5～8 parts of polyvinyl alcohol
2～4 parts of gelatin hydrolysates
2～3 parts of carboxymethyl chitosans
100 parts in water
0.1～3 part of antioxidant
0.5～3 part of plasticizer
0.1～1 part in surfactant
0.05～2.5 part of viscosity reductant
0.01～0.5 part of screening agent
0.05～1 part of cutaneous permeable agent.
Cutaneous permeable agent is azone and analog, allantoin, Mentholum or oleic acid, based on the water solublity laurocapram.
Embodiment 8 (universal):
8～20 parts of polyvinyl alcohol
2～6 parts of gelatin hydrolysates
2～5 parts of carboxymethyl chitosans
100 parts in water
0.1～3 part of antioxidant
0.5～3 part of plasticizer
0.1～1 part in surfactant
0.05～2.5 part of viscosity reductant
0.01～0.5 part of screening agent
0.05～1 part of cutaneous permeable agent
0.1～5 part of thickening agent.
Thickening agent can be at least a in water-soluble cellulose, sodium alginate, water soluble starch, polyvinyl pyrrolidone, Polyethylene Glycol, water-soluble glue protoplasm, hyaluronic acid, polyacrylate and the graft copolymer.
Embodiment 9 (universal):
On the basis of embodiment 1,2,3,4,5,6,7 or 8, add an amount of millimeter or nanoscale functional component according to regulations such as pharmacopeia and (can produce the material of certain physiological health effect scalp and hair, as Chinese herbal medicine extract etc.) and adjuvants such as spice, pigment and anticorrosion and bactericidal agent, can be made into the universal of various effects.
As can add Aloe extract, Herba Lysimachiae foenum-graeci extract, Radix Ginseng extract, Radix Angelicae Sinensis grass extract, Radix Polygoni Multiflori grass extract, camomile extract, Flos Inulae extract, hundred is wrapped up in fragrant extract, Radix agastaches extract, tea tree extract, Radix Glycyrrhizae extract, life-prolonging time grass extract, hinokitiol and calcium pantothenate, compound vitamin B etc., can be made into lavandula angustifolia and nourish, Radix Polygoni Multiflori nourishes, Aloe nourishes, the pine profit is nourished, Camellia sinensis is nourished, repair nourish and plant anti-dandruff etc. universal.
Embodiment 10 (at type):
On the basis of embodiment 1,2,3,4,5,6,7 or 8, add an amount of millimeter or nanoscale functional component according to regulations such as pharmacopeia and (can produce the material of certain physiological health effect scalp and hair, as various healing potions) and adjuvants such as spice, pigment and anticorrosion and bactericidal agent, can be made into various effects at type.
As add compound vitamin B, active precious element, salicylic acid and the metronidazole done, can be made into " specially good effect is anti-dandruff at type "; Add compound vitamin B, Rhizoma Zingiberis Recens extract, Flos Pelargonii Hortori and Thymi Serpylli Herba extract etc. and can be made into " phalacrosis prevention and hair generation is at type "; Adding undecylenic acid derivant, benzalkonium bromide are made " sterilization control spindle is to type "; Adding Zinc Pyrithione, Herba Lysimachiae foenum-graeci extract are made " potent anti-dandruff at type ".
Experiment:
1. the made solution of embodiment is coated on the medical experimental filter paper, film forming is accelerated in electric heating blowing (50 ℃).Get 5 points at random at tested medical experimental filter paper, measure the paper film thickness with micrometer, average, deduct the thickness of filter paper again, the result is that film forming average thickness is 0.1～1.0mm.
2. the made solution of embodiment is coated on the thin corn paper film, electricity consumption blowing hot wind (50 ℃) is accelerated film forming, tested composite membrane is fixed in the test tube mouth, drip the water of 3 pH 6.8～7.0 on paper film surface, recording film was soaked into until the required time of the water droplet that leaks down, and was blank reference with the corn paper film that is not coated with liquid film.Investigate its water solublity with water droplet seepage time (min/mm)=soak into to the required time that leaks (min)/thickness (mm); Replace with oxidant (hydrogen peroxide) equally and drip, investigate its non-oxidizability.The result shows, water droplet seepage time 50～250min/mm, oxidation seepage time 200～1000min/mm, liquid film have its good swelling water solublity and non-oxidizability.
3. (length and width that adult's scalp epidermal thickness 5～7mm), " artificial head leather material " are prepared into are respectively on the square film of 2cm the made solution of embodiment being coated in 5mm thickness, film forming in the 5min under electric heating blowing (50 ℃) effect, its raw material of artificial head leather material and content are thermoplastic polyurethane 14～24% weight, dimethyl formamide 4.5～8.5% weight, butanone 68～85% weight, triclosan or calper calcium peroxide 0.01～0.3% weight.Under 30～34 ℃; Liquid film is towards diffuser casing, fixing (four jiaos bonding) is between airtight diffuser casing and receiving chamber, with sample injector with hair dye or aromatic compounds (benzene, toluene, dimethylbenzene, aniline, phenylenediamine etc.) the injection diffuser casing, the artificial scalp thin film of not smearing liquid film with same specification is blank reference, analyzes the organic gas permeability of liquid film with gas chromatogram.Blank directly enters through artificial scalp with reference to the organic gas that will have 2～10% in the receiving chamber as a result; Yet the organic gas that has only detected less than 0.2% in the receiving chamber in being coated with the test of present embodiment liquid film enters.
The embodiment of the invention is the same with conventional Chinese medicine liniment, it is with the macromolecular scaffold controlled release drug administration, effectively molecule of pharmaceutical in the transdermal penetration process except that be subjected to keratodermatitis, the resistance of live epidermis, skin corium, also to overcome polymeric film to the resistance that drug osmotic produced, reach in 30～60min slow release mechanism.Isotopic labeling by the pharmacology composition is followed the trail of, and its liniment was external external application transdermal test 2 hours, and the amount of the effective ingredient of absorption is 5～10% of total drug of topical application amount.
Claims (10)
1. scalp nursing solution for use in hair dyeing is characterized in that the raw material and the mass ratio that are contained are as follows:
5～30 parts of polyvinyl alcohol
2～10 parts in gelatin
2～10 parts of using carboxyl chitosans
100 parts of water or 10% alcoholic solution.
2. scalp nursing solution for use in hair dyeing according to claim 1 is characterized in that also containing in the described raw material mass ratio and is 0.1～5 part antioxidant.
3. scalp nursing solution for use in hair dyeing according to claim 2 is characterized in that also containing in the described raw material mass ratio and is 0.5～5 part plasticizer.
4. scalp nursing solution for use in hair dyeing according to claim 3 is characterized in that also containing in the described raw material mass ratio and is 0.1～2 part surfactant.
5. scalp nursing solution for use in hair dyeing according to claim 4 is characterized in that also containing in the described raw material mass ratio and is 0.05～3 part viscosity reductant.
6. scalp nursing solution for use in hair dyeing according to claim 5 is characterized in that also containing in the described raw material mass ratio and is 0.01～0.5 part screening agent.
7. scalp nursing solution for use in hair dyeing according to claim 6 is characterized in that also containing in the described raw material mass ratio and is 0.05～1 part cutaneous permeable agent.
8. scalp nursing solution for use in hair dyeing according to claim 7 is characterized in that also containing in the described raw material mass ratio and is 0.1～5 part thickening agent.
9. scalp nursing solution for use in hair dyeing according to claim 8 is characterized in that also containing in the described raw material functional component.
10. according to claim 1,2,3,4,5,6,7,8 or 9 described scalp nursing solution for use in hair dyeing, it is characterized in that also containing in the described raw material adjuvant.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010108297A CN101785748A (en) | 2010-02-10 | 2010-02-10 | Scalp nursing solution for use in hair dyeing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010108297A CN101785748A (en) | 2010-02-10 | 2010-02-10 | Scalp nursing solution for use in hair dyeing |
Publications (1)
| Publication Number | Publication Date |
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| CN101785748A true CN101785748A (en) | 2010-07-28 |
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| CN201010108297A Pending CN101785748A (en) | 2010-02-10 | 2010-02-10 | Scalp nursing solution for use in hair dyeing |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103690402A (en) * | 2013-12-25 | 2014-04-02 | 广州温雅日用化妆品有限公司 | Isolation cream for hair dyeing, and preparation method of isolation cream |
| CN107837212A (en) * | 2017-11-06 | 2018-03-27 | 广州市花安堂生物科技有限公司 | A kind of scalp release compositions being used for before dyeing and perm |
-
2010
- 2010-02-10 CN CN201010108297A patent/CN101785748A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103690402A (en) * | 2013-12-25 | 2014-04-02 | 广州温雅日用化妆品有限公司 | Isolation cream for hair dyeing, and preparation method of isolation cream |
| CN103690402B (en) * | 2013-12-25 | 2015-10-28 | 广州温雅日用化妆品有限公司 | A kind of hair dyeing sun screen and preparation method thereof |
| CN107837212A (en) * | 2017-11-06 | 2018-03-27 | 广州市花安堂生物科技有限公司 | A kind of scalp release compositions being used for before dyeing and perm |
| CN107837212B (en) * | 2017-11-06 | 2020-06-12 | 花安堂生物科技集团有限公司 | Scalp isolation composition used before dyeing and ironing |
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Application publication date: 20100728 |