CN103690402B - A kind of hair dyeing sun screen and preparation method thereof - Google Patents
A kind of hair dyeing sun screen and preparation method thereof Download PDFInfo
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- CN103690402B CN103690402B CN201310733136.9A CN201310733136A CN103690402B CN 103690402 B CN103690402 B CN 103690402B CN 201310733136 A CN201310733136 A CN 201310733136A CN 103690402 B CN103690402 B CN 103690402B
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- 230000000475 sunscreen effect Effects 0.000 title claims abstract description 43
- 239000000516 sunscreening agent Substances 0.000 title claims abstract description 43
- 238000004043 dyeing Methods 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 25
- 239000003995 emulsifying agent Substances 0.000 claims abstract description 24
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 24
- 230000002421 anti-septic effect Effects 0.000 claims abstract description 23
- 150000002191 fatty alcohols Chemical class 0.000 claims abstract description 23
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 21
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 21
- 229920002545 silicone oil Polymers 0.000 claims abstract description 20
- 229940099259 vaseline Drugs 0.000 claims abstract description 18
- 239000002480 mineral oil Substances 0.000 claims abstract description 17
- 235000010446 mineral oil Nutrition 0.000 claims abstract description 17
- 239000002562 thickening agent Substances 0.000 claims abstract description 16
- 239000001993 wax Chemical class 0.000 claims description 31
- 238000002156 mixing Methods 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 14
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 claims description 13
- 230000001804 emulsifying effect Effects 0.000 claims description 12
- 239000003607 modifier Substances 0.000 claims description 12
- 235000010352 sodium erythorbate Nutrition 0.000 claims description 11
- 239000004320 sodium erythorbate Substances 0.000 claims description 11
- RBWSWDPRDBEWCR-RKJRWTFHSA-N sodium;(2r)-2-[(2r)-3,4-dihydroxy-5-oxo-2h-furan-2-yl]-2-hydroxyethanolate Chemical compound [Na+].[O-]C[C@@H](O)[C@H]1OC(=O)C(O)=C1O RBWSWDPRDBEWCR-RKJRWTFHSA-N 0.000 claims description 11
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 claims description 11
- 229920001577 copolymer Polymers 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 9
- -1 parabens Chemical compound 0.000 claims description 9
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 8
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 claims description 7
- 239000005977 Ethylene Substances 0.000 claims description 7
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 7
- 229920000642 polymer Polymers 0.000 claims description 7
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 6
- 239000007766 cera flava Substances 0.000 claims description 6
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 claims description 6
- 229960005215 dichloroacetic acid Drugs 0.000 claims description 6
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 6
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 claims description 6
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 claims description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 6
- WYVVKGNFXHOCQV-UHFFFAOYSA-N 3-iodoprop-2-yn-1-yl butylcarbamate Chemical compound CCCCNC(=O)OCC#CI WYVVKGNFXHOCQV-UHFFFAOYSA-N 0.000 claims description 5
- 239000004322 Butylated hydroxytoluene Substances 0.000 claims description 5
- NLZUEZXRPGMBCV-UHFFFAOYSA-N Butylhydroxytoluene Chemical compound CC1=CC(C(C)(C)C)=C(O)C(C(C)(C)C)=C1 NLZUEZXRPGMBCV-UHFFFAOYSA-N 0.000 claims description 5
- BAPJBEWLBFYGME-UHFFFAOYSA-N acrylic acid methyl ester Natural products COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 5
- 235000010354 butylated hydroxytoluene Nutrition 0.000 claims description 5
- 229940095259 butylated hydroxytoluene Drugs 0.000 claims description 5
- WSDISUOETYTPRL-UHFFFAOYSA-N dmdm hydantoin Chemical compound CC1(C)N(CO)C(=O)N(CO)C1=O WSDISUOETYTPRL-UHFFFAOYSA-N 0.000 claims description 5
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 229920002678 cellulose Polymers 0.000 claims description 4
- 229960005323 phenoxyethanol Drugs 0.000 claims description 4
- 235000010265 sodium sulphite Nutrition 0.000 claims description 4
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 claims description 3
- 239000005711 Benzoic acid Substances 0.000 claims description 3
- 229920002125 Sokalan® Polymers 0.000 claims description 3
- 150000003863 ammonium salts Chemical group 0.000 claims description 3
- 235000010233 benzoic acid Nutrition 0.000 claims description 3
- 239000004204 candelilla wax Substances 0.000 claims description 3
- 229940073532 candelilla wax Drugs 0.000 claims description 3
- 235000013868 candelilla wax Nutrition 0.000 claims description 3
- 239000004203 carnauba wax Substances 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 229960000735 docosanol Drugs 0.000 claims description 3
- IUJAMGNYPWYUPM-UHFFFAOYSA-N hentriacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC IUJAMGNYPWYUPM-UHFFFAOYSA-N 0.000 claims description 3
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 claims description 3
- 229920000592 inorganic polymer Polymers 0.000 claims description 3
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 claims description 3
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- GQEZCXVZFLOKMC-UHFFFAOYSA-N n-alpha-hexadecene Natural products CCCCCCCCCCCCCCC=C GQEZCXVZFLOKMC-UHFFFAOYSA-N 0.000 claims description 3
- 229920001206 natural gum Polymers 0.000 claims description 3
- 239000012875 nonionic emulsifier Substances 0.000 claims description 3
- 239000012188 paraffin wax Substances 0.000 claims description 3
- 239000004584 polyacrylic acid Substances 0.000 claims description 3
- 229920000570 polyether Polymers 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 2
- 239000004200 microcrystalline wax Substances 0.000 claims description 2
- 229940056211 paraffin Drugs 0.000 claims description 2
- 239000012177 spermaceti Substances 0.000 claims description 2
- 229940084106 spermaceti Drugs 0.000 claims description 2
- 239000003760 tallow Substances 0.000 claims description 2
- 239000000118 hair dye Substances 0.000 abstract description 29
- 239000013521 mastic Substances 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000010408 film Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000002537 cosmetic Substances 0.000 description 4
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000001681 protective effect Effects 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 210000001061 forehead Anatomy 0.000 description 2
- 230000037308 hair color Effects 0.000 description 2
- 238000002955 isolation Methods 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 239000002884 skin cream Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- 230000007480 spreading Effects 0.000 description 2
- 229910021653 sulphate ion Inorganic materials 0.000 description 2
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical group CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical group CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 1
- KGRVJHAUYBGFFP-UHFFFAOYSA-N 2,2'-Methylenebis(4-methyl-6-tert-butylphenol) Chemical group CC(C)(C)C1=CC(C)=CC(CC=2C(=C(C=C(C)C=2)C(C)(C)C)O)=C1O KGRVJHAUYBGFFP-UHFFFAOYSA-N 0.000 description 1
- 241000283153 Cetacea Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 230000002159 abnormal effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229940073669 ceteareth 20 Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 230000008570 general process Effects 0.000 description 1
- 229940075529 glyceryl stearate Drugs 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229940057995 liquid paraffin Drugs 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 230000004060 metabolic process Effects 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- 235000014593 oils and fats Nutrition 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 229940100460 peg-100 stearate Drugs 0.000 description 1
- 239000002861 polymer material Substances 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- 230000001846 repelling effect Effects 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 230000035943 smell Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
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- 239000000052 vinegar Substances 0.000 description 1
- 235000021419 vinegar Nutrition 0.000 description 1
- 238000004078 waterproofing Methods 0.000 description 1
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- Cosmetics (AREA)
Abstract
The invention discloses a kind of hair dyeing sun screen, it comprises following component by weight and mixes: vaseline 10 ~ 50 parts, white mineral oil 5 ~ 25 parts, fatty alcohol and wax class 1 ~ 8 part, silicone oil 0.5 ~ 15 part, emulsifying agent 1 ~ 9 part, hydrophobic film-forming agent 0.5 ~ 8 part, antioxidant 0.1 ~ 2 part, chelating agen 0.1 ~ 0.8 part, thickening agent 0 ~ 1 part, antiseptic 0.04 ~ 1 part, 0 ~ 0.5 part, essence, water are appropriate.Skin and hair dye can be isolated by hair dyeing sun screen of the present invention effectively, enable the hair dye sticked in hair dye on skin be cleaned or wipe examination easily totally, protect skin and do not caught color.
Description
Technical field
The present invention relates to hair color technology field, be specifically related to a kind of sun screen spread upon on human body skin, this sun screen spreads upon after on human body skin and can prevent from making skin also catch color because hair dye in hair dye sticks on human body skin.
Background technology
Along with improving constantly of people's living standard, hair dyeing has become the fashion of pursuit U.S. of the upper a kind of common existence of society.The general process of hair dyeing spreads upon on hair by hair dye mastic, rinses again, hair color is changed after certain hour.Spread in the process of hair dye mastic being coated with on hair, hair dye mastic easily sticks on the skin near hairline, as on ear, on forehead, on arm or neck.These positions once be stained with catch agent after be just difficult to cleaning or wipe examination clean, skin can be made also to catch color, and need the exfoliation waiting for a few days skin metabolism poststaining, the color caught just really disappears.
One or two people are had to spread upon around hairline with some protective skin cream before hair dyeing, to protect skin.But existing protective skin cream Main Function is skin care, cannot isolate hair dye.
In sum, in existing hair dyeing industry, be badly in need of wanting one can isolate hair dye, make skin be stained with hair dye after easily cleaned or wiped examination totally, protect the skin-protection product that skin is not colored.
Summary of the invention
The object of invention is the defect overcoming above-mentioned prior art; a kind of hair dyeing sun screen is provided; skin and hair dye can be isolated by this sun screen effectively, enable the hair dye sticked in hair dye on skin be cleaned or wipe examination easily totally, protect skin and do not caught color.
For achieving the above object, the present invention adopts following technical scheme:
A kind of hair dyeing sun screen, it comprises following component by weight: vaseline 10 ~ 50 parts, white mineral oil 5 ~ 25 parts, fatty alcohol and wax class 1 ~ 8 part, silicone oil 0.5 ~ 15 part, emulsifying agent 1 ~ 9 part, hydrophobic film-forming agent 0.5 ~ 8 part, antioxidant 0.1 ~ 2 part, chelating agen 0.1 ~ 0.8 part, thickening agent 0 ~ 1 part, antiseptic 0.04 ~ 1 part, 0 ~ 0.5 part, essence, water are appropriate.
Preferably, hair dyeing sun screen of the present invention comprises following component by weight: vaseline 25 ~ 35 parts, white mineral oil 10 ~ 20 parts, fatty alcohol and wax class 2 ~ 6 parts, silicone oil 5 ~ 8 parts, emulsifying agent 2 ~ 6 parts, hydrophobic film-forming agent 3 ~ 6 parts, antioxidant 0.1 ~ 2 part, chelating agen 0.1 ~ 0.8 part, thickening agent 0 ~ 1 part, antiseptic 0.1 ~ 1 part, 0 ~ 0.5 part, essence, water add to 100 parts.
Preferably, fatty alcohol of the present invention is one or more mixing in tetradecyl alchohol conventional in cosmetics, hexadecanol, octadecanol, docosanol, and described wax class is one or more mixing in Cera Flava conventional in cosmetics, ceresine, palm wax, paraffin, spermaceti, candelilla wax, microwax, Fischer-Tropsch wax, Tissuemat E, haze tallow.
Preferably, silicone oil of the present invention is the mixture (low viscosity product of below 100cps and the high-viscosity products of more than 10000cps) of polydimethylsiloxane or dimethiconol or their one or more different viscosities, or the mixture of one or more high viscositys (more than 10000cps) and the mixture of ring five polydimethylsiloxane above.
Preferably, emulsifying agent of the present invention is one or more mixing in polyethers nonionic emulsifier or anion emulsifier.
Preferably, hydrophobic film-forming agent of the present invention is one or more mixing in styrene, poly-amino modified resin, methyl acrylate copolymer, polyvinyl pyrrolidone/hexadecene copolymer, ethylene/vinyl acetate polymer wax.
Preferably, antioxidant of the present invention is one or more mixing in butylated hydroxytoluene, sodium sulfite, sodium erythorbate.
Preferably, chelating agen of the present invention is EDETATE SODIUM or EDTA tetra-sodium or more two kinds mixing.
Preferentially, thickening agent of the present invention is one or more mixing in natural gum and modifier, cellulose and modifier thereof, polyacrylic acid and modifier, inorganic polymer and modifier thereof, and described antiseptic is imidazolidinyl urea, DMDMH(dimethyloldimethylhydantoin), IPBC(IPBC), one or more mixing in parabens, phenoxyethanol, Methylisothiazolinone, methylchloroisothiazandnone, benzoic acid, polyquaternary ammonium salt 15.
Another object of the present invention is to the preparation method providing above-mentioned hair dyeing sun screen, it comprises the following steps:
Step one, the vaseline of oil phase component, white mineral oil, fatty alcohol and wax class, silicone oil, emulsifying agent are mixed and heated to 75 ~ 80 DEG C;
Step 2, the thickening agent of water phase components, chelating agen and water are mixed and heated to 75 ~ 80 DEG C;
Step 3, mixed oil phase component and water phase components to be stirred, and emulsifying;
Add antioxidant after step 4, emulsifying, stir cooling, and then add hydrophobic film-forming agent, antiseptic and essence, stir.
Compared with prior art, the invention has the beneficial effects as follows:
1, the present invention has initiated sun screen human body skin and hair dye can isolated; from the skin care of the sun screen of existing skin-protection product, provide the effect such as nutrient, moisturizing different for skin; sun screen of the present invention is not only not easy the inside that penetrates to the skin; and one deck waterproofing membrane can also be formed at skin surface; make hair dye mastic can not penetrate this layer of protecting film and touch skin, thus reach isolation skin contact with hair dye.Before spreading hair dye mastic toward hair; get sun screen of the present invention and spread upon the position of being easily stained with hair dye mastic; as ear, neck, forehead etc.; even if hair dye drips and sticks in these positions in hair dye; also can wash or wipe examination easily falls hair dye, protection skin being infected with not by hair dye.
2, sun screen of the present invention is developed into for existing hair dye, by the excellent that hair dye and skin are isolated, and various raw material to be all low-cost cosmetics commonly use raw material, with low cost, be applicable to wide popularization and application.
Detailed description of the invention
Below by specific embodiment, the present invention is described in further detail.
A kind of hair dyeing sun screen, it comprises following component by weight: vaseline 10 ~ 50 parts, white mineral oil 5 ~ 25 parts, fatty alcohol and wax class 1 ~ 8 part, silicone oil 0.5 ~ 15 part, emulsifying agent 1 ~ 9 part, hydrophobic film-forming agent 0.5 ~ 8 part, antioxidant 0.1 ~ 2 part, chelating agen 0.1 ~ 0.8 part, thickening agent 0 ~ 1 part, antiseptic 0.1 ~ 1 part, 0 ~ 0.5 part, essence, water are appropriate.
In above-mentioned sun screen, the effect of various component is as follows:
Vaseline: vaseline is to the good oils and fats of skin closure, can not infiltrate through skin, can form the isolation oil film of one deck waterproof, block skin at skin surface.
White mineral oil: white mineral oil is liquid paraffin shape is colourless transparent oil liquid, better with the compatibility of vaseline, is not easy to infiltrate through skin, has good closed performance to skin.Because vaseline is more greasy, be not easy to smear, be also not easy after using to wash away, therefore can spreading property be increased after coordinating white mineral oil under the prerequisite ensureing closure.
Fatty alcohol and Wax: fatty alcohol described in formula is one or more mixing mixing in tetradecyl alchohol conventional in cosmetics, hexadecanol, octadecanol, docosanol, described wax class is one or more mixing in Cera Flava, ceresine, palm wax, paraffin, candelilla wax, fatty alcohol and Wax and general gel compatibility good, have thickening to product, help emulsifying and stable effect.
Silicone oil: silicone oil is a kind of water white synthesized polymer material, there is special slipping, flexibility, hydrophobicity, good chemical stability, excellent electrical insulating property and high and low temperature resistance, the splendid thin film of one deck hydrophobicity can be formed at skin surface.Silicone oil has multiple different viscosity, and range of viscosities is generally 5 ~ 8,000,000 cps, the silicone oil that viscosity is higher, and its film forming water resistance is better, but smear is poorer, and emulsion dispersion is stable more difficult.Silicone oil of the present invention is preferably the mixture (low viscosity product of below 100cps and the high-viscosity products of more than 10000cps) of polydimethylsiloxane or dimethiconol or their one or more different viscosities by viscosity, or the above mixture of one or more high viscositys (more than 10000cps) and the mixture of ring five polydimethylsiloxane, these mixing silicon oil viscosities are approximately 3000cps ~ 30000cps, mix with vaseline in formula, white mineral oil and can form good mobility and smear, film forming water resistance is also better.
Emulsifying agent: one or more of emulsifying agent use polyethers nonionic emulsifier of the present invention or negative ion emulsification agent are composite, and the grease emulsifying that can close high-load is stablized, and sun screen can be made after being stained with hair dye can to use warm water and shampoo eluting simultaneously.
Hydrophobic film-forming agent: can form one deck hydrophobic film at skin surface, not easily by water dissolution, can increase the water repelling property of sun screen.In formula, hydrophobic film-forming agent first can use styrene, poly-amino modified resin, methyl acrylate copolymer polyvinyl pyrrolidone/hexadecene copolymer, also can select ethylene/vinyl acetate polymer wax etc.
Thickening agent: depending on product denseness and suitably add, natural gum and modifier thereof can be selected, cellulose and modifier thereof, polyacrylic acid and modifier thereof, one or more mixing in inorganic polymer and modifier thereof, antiseptic: microbial growth in product can be resisted, prevent corruption, imidazolidinyl urea can be selected, DMDMH(dimethyloldimethylhydantoin), IPBC(IPBC), parabens, phenoxyethanol, Methylisothiazolinone, methylchloroisothiazandnone, benzoic acid, one or more mixing in polyquaternary ammonium salt 15.
Antioxidant: existingly slow down Oxidation of Fat and Oils, maintain the stable effect of product, there is again the effect slowing down the variable color of hair dye mastic, make the dye cream not easy oxidation discoloration being stained with skin, thus make skin not easily be caught color by hair dye, butylated hydroxytoluene, sodium sulfite, sodium erythorbate can be selected.
Chelating agen: have collaborative effect with the antiseptic in formula; Oxidation of Fat and Oils and the variable color of product can be slowed down, increase the stability of product, the metal ion in chelating raw material and the metal ion in hair dye; there is protective effect to skin, EDETATE SODIUM, EDTA tetra-sodium can be selected.
Essence: the abnormal smells from the patient that can regulate product, makes product use pleasant more, suitably can add according to the hobby of user.
Sun screen of the present invention can be above-mentioned each component mixing obtained, and also can obtain in accordance with the following methods:
Steps A, the vaseline of oil phase component, white mineral oil, fatty alcohol and wax class, silicone oil, emulsifying agent are mixed and heated to 75 ~ 80 DEG C;
Step B, the thickening agent of water phase components, chelating agen and water are mixed and heated to 75 ~ 80 DEG C;
Step C, mixed oil phase component and water phase components to be stirred, and emulsifying;
Add antioxidant after step D, emulsifying, stir cooling, and then add hydrophobic film-forming agent, antiseptic and essence, stir, sun screen of the present invention can be obtained.
Embodiment 1
Sun screen of the present invention comprises following component by weight: vaseline 10 parts, white mineral oil 25 parts, fatty alcohol and wax class 8 parts, silicone oil 6 parts, emulsifying agent 6 parts, hydrophobic film-forming agent 4 parts, antioxidant 1 part, 0.5 part, essence, chelating agen 0.5 part, antiseptic 0.1 part, 42 parts, water.
Described fatty alcohol is hexadecanol 4 parts, and described wax class is 4 parts, Cera Flava.
Described emulsifying agent is ceteareth 20.
Described hydrophobic film-forming agent is poly-amino modified resin.
Described antioxidant is butylated hydroxytoluene.
Described chelating agen is EDETATE SODIUM.
Sun screen of the present invention obtains in accordance with the following methods:
Steps A, the vaseline of oil phase component, white mineral oil, hexadecanol, Cera Flava, silicone oil, ceteareth 20 are mixed and heated to 75 DEG C;
Step B, the EDETATE SODIUM of water phase components and water are mixed and heated to 75 DEG C;
Step C, mixed oil phase component and water phase components to be stirred, and emulsifying;
Add butylated hydroxytoluene after step D, emulsifying, stir and be cooled to room temperature, and then add poly-amino modified resin, antiseptic and essence, stir, sun screen of the present invention can be obtained.
Embodiment 2
Sun screen of the present invention comprises following component by weight: vaseline 50 parts, white mineral oil 5 parts, fatty alcohol and wax class 1 part, silicone oil 0.5 part, emulsifying agent 5.3 parts, hydrophobic film-forming agent 8 parts, thickening agent 0.5 part, antiseptic 0.8 part, antioxidant 0.1 part, chelating agen 0.1 part, water add to 100 parts.
Described fatty alcohol is octadecanol 0.5 part, and described wax class is 0.5 part, ceresine.
Described emulsifying agent is oleyl alcohol ether 5.
Described hydrophobic film-forming agent is ethylene/vinyl acetate polymer wax.
Described thickening agent is card ripple.
Described antioxidant is sodium erythorbate.
Described antiseptic is that methyl hydroxybenzoate and propylparaben, phenoxyethanol mix.
Described chelating agen is EDETATE SODIUM.
Described sun screen obtains in accordance with the following methods:
Steps A, the vaseline of oil phase component, white mineral oil, octadecanol, ceresine, silicone oil, oleyl alcohol ether 5 are mixed and heated to 80 DEG C;
Step B, the EDETATE SODIUM of water phase components, Ka Bo and water are mixed and heated to 80 DEG C;
Step C, mixed oil phase component and water phase components to be stirred, and emulsifying;
Add sodium erythorbate after step D, emulsifying, stir and be cooled to room temperature, and then add ethylene/vinyl acetate polymer wax and antiseptic, stir, sun screen of the present invention can be obtained.
Embodiment 3
Sun screen of the present invention comprises following component by weight: vaseline 25 parts, white mineral oil 10 parts, fatty alcohol and wax class 4 parts, silicone oil 15 parts, emulsifying agent 3 parts, hydrophobic film-forming agent 0.5 part, thickening agent 1 part, antiseptic 0.6 part, antioxidant 2 parts, 0.5 part, essence, chelating agen 0.5 part, water add to 100 parts.
Described fatty alcohol is hexadecanol 1 part, octadecanol 1 part mixing, and described wax class is 1 part, ceresine, the mixing of 1 part, Cera Flava.
Described emulsifying agent is stearic alcohol ether 20 mixture of sodium cetostearyl sulphate and whale vinegar.
Described hydrophobic film-forming agent is acrylate copolymer.
Described thickening agent is HANSHENGJIAO.
Described antioxidant is sodium sulfite and sodium erythorbate mixing.
Described chelating agen is EDTA tetra-sodium.
Described sun screen obtains in accordance with the following methods:
Steps A, stearic to the vaseline of oil phase component, white mineral oil, octadecanol, hexadecanol, Cera Flava, ceresine, silicone oil, sodium cetostearyl sulphate and whale vinegar alcohol ether 20 is mixed and heated to 75 DEG C;
Step B, the EDTA tetra-sodium HANSHENGJIAO of water phase components and water are mixed and heated to 80 DEG C;
Step C, mixed oil phase component and water phase components to be stirred, and emulsifying;
Add sodium erythorbate after step D, emulsifying, stir and be cooled to room temperature, and then add acrylate copolymer, antiseptic, stir, sun screen of the present invention can be obtained.
Embodiment 4
Sun screen of the present invention comprises following component by weight: vaseline 35 parts, white mineral oil 15 parts, fatty alcohol and wax class 2 parts, silicone oil 5 parts, emulsifying agent 2 parts, hydrophobic film-forming agent 3 parts, antioxidant 0.1 part, chelating agen 0.8 part, antiseptic 1 part, water adds to 100 parts.
Described fatty alcohol is hexadecanol 1 part, and described wax class is 1 part, ceresine.
Described emulsifying agent is sodium cetostearyl sulphate.
Described hydrophobic film-forming agent is methyl acrylate copolymer.
Described thickening agent is cellulose.
Described antioxidant is sodium erythorbate.
Described chelating agen is EDTA tetra-sodium.
Described sun screen obtains in accordance with the following methods:
Steps A, the vaseline of oil phase component, white mineral oil, hexadecanol, ceresine, silicone oil, sodium cetostearyl sulphate are mixed and heated to 80 DEG C;
Step B, EDTA tetra-sodium of water phase components, cellulose and water are mixed and heated to 80 DEG C;
Step C, mixed oil phase component and water phase components to be stirred, and emulsifying;
Add sodium erythorbate after step D, emulsifying, stir and be cooled to room temperature, and then add methyl acrylate copolymer, antiseptic, stir, sun screen of the present invention can be obtained.
Embodiment 5
Sun screen of the present invention comprises following component by weight: vaseline 30 parts, white mineral oil 20 parts, fatty alcohol and wax class 6 parts, silicone oil 8 parts, emulsifying agent 8 parts, hydrophobic film-forming agent 6 parts, antioxidant 0.5 part, chelating agen 0.3 part, water add to 100 parts.
Described fatty alcohol is octadecanol 2 parts, and described wax class is 4 parts, Cera Flava.
Described emulsifying agent is glyceryl stearate, PEG-100 stearate mixture.
Described hydrophobic film-forming agent is ethylene/vinyl acetate polymer wax.
Described antioxidant is sodium erythorbate.
Described chelating agen is EDTA tetra-sodium.
Described sun screen obtains in accordance with the following methods:
Steps A, the vaseline of oil phase component, white mineral oil, octadecanol, Cera Flava, silicone oil, glyceryl stearate, PEG-100 stearate are mixed and heated to 80 DEG C;
Step B, EDTA tetra-sodium of water phase components and water are mixed and heated to 80 DEG C;
Step C, mixed oil phase component and water phase components to be stirred, and emulsifying;
Add sodium erythorbate after step D, emulsifying, stir and be cooled to room temperature, and then add antiseptic, ethylene/vinyl acetate polymer wax, stir, sun screen of the present invention can be obtained.
The announcement of book and instruction according to the above description, those skilled in the art in the invention can also change above-mentioned embodiment and revise.Therefore, the present invention is not limited to detailed description of the invention disclosed and described above, also should fall in the protection domain of claim of the present invention modifications and changes more of the present invention.In addition, although employ some specific terms in this description, these terms just for convenience of description, do not form any restriction to the present invention.
Claims (6)
1. a hair dyeing sun screen, is characterized in that comprising following component by weight: vaseline 10 ~ 50 parts, white mineral oil 5 ~ 25 parts, fatty alcohol and wax class 1 ~ 8 part, silicone oil 0.5 ~ 15 part, emulsifying agent 1 ~ 9 part, hydrophobic film-forming agent 0.5 ~ 8 part, antioxidant 0.1 ~ 2 part, chelating agen 0.1 ~ 0.8 part, thickening agent 0 ~ 1 part, antiseptic 0.04 ~ 1 part, 0 ~ 0.5 part, essence, water are appropriate;
Described emulsifying agent is one or more mixing in polyethers nonionic emulsifier or anion emulsifier;
Described antioxidant is one or more mixing in butylated hydroxytoluene, sodium sulfite, sodium erythorbate;
Described chelating agen is EDETATE SODIUM or EDTA tetra-sodium or more two kinds mixing;
Described antiseptic is one or more mixing in imidazolidinyl urea, dimethyloldimethylhydantoin, IPBC, parabens, phenoxyethanol, Methylisothiazolinone, methylchloroisothiazandnone, benzoic acid, polyquaternary ammonium salt 15;
Described hydrophobic film-forming agent is one or more mixing in styrene, poly-amino modified resin, methyl acrylate copolymer, polyvinyl pyrrolidone/hexadecene copolymer, ethylene/vinyl acetate polymer wax.
2. hair dyeing sun screen as claimed in claim 1, is characterized in that comprising following component by weight: vaseline 25 ~ 35 parts, white mineral oil 10 ~ 20 parts, fatty alcohol and wax class 2 ~ 6 parts, silicone oil 5 ~ 8 parts, emulsifying agent 2 ~ 6 parts, hydrophobic film-forming agent 3 ~ 6 parts, antioxidant 0.1 ~ 2 part, chelating agen 0.1 ~ 0.8 part, thickening agent 0 ~ 1 part, antiseptic 0.04 ~ 1 part, 0 ~ 0.5 part, essence, water add to 100 parts.
3. hair dyeing sun screen as claimed in claim 1 or 2, it is characterized in that: described fatty alcohol is one or more mixing in tetradecyl alchohol, hexadecanol, octadecanol, docosanol, described wax class is one or more mixing in Cera Flava, ceresine, palm wax, paraffin, spermaceti, candelilla wax, microwax, Fischer-Tropsch wax, Tissuemat E, haze tallow.
4. hair dyeing sun screen as claimed in claim 1 or 2, it is characterized in that: described silicone oil is the mixture of one or more different viscosities in polydimethylsiloxane or dimethiconol, or one or both viscosity are the mixture of more than 10000cps and the mixture of ring five polydimethylsiloxane above.
5. hair dyeing sun screen as claimed in claim 1 or 2, is characterized in that: described thickening agent is that one or more in natural gum and modifier, cellulose and modifier thereof, polyacrylic acid and modifier, inorganic polymer and modifier thereof mix.
6. the preparation method of hair dyeing sun screen according to claim 1, is characterized in that comprising the following steps:
Step one, the vaseline of oil phase component, white mineral oil, fatty alcohol and wax class, silicone oil, emulsifying agent are mixed and heated to 75 ~ 80 DEG C;
Step 2, the thickening agent of water phase components, chelating agen and water are mixed and heated to 75 ~ 80 DEG C;
Step 3, mixed oil phase component and water phase components to be stirred, and emulsifying;
Add antioxidant after step 4, emulsifying, stir cooling, and then add hydrophobic film-forming agent, antiseptic and essence, stir.
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| CN201310733136.9A CN103690402B (en) | 2013-12-25 | 2013-12-25 | A kind of hair dyeing sun screen and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN109172428A (en) * | 2018-11-24 | 2019-01-11 | 雷明龙 | A kind of black composition for hair dying |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107049916B (en) * | 2017-04-12 | 2020-11-06 | 赵朋伦 | Hair dyeing skin care cream and preparation method thereof |
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| CN1886115A (en) * | 2003-11-28 | 2006-12-27 | 威娜股份有限公司 | Use of peptides to protect skin from hair treatment agents |
| DE10028723B4 (en) * | 2000-06-09 | 2009-04-02 | Kpss-Kao Professional Salon Services Gmbh | Method of dyeing human hair |
| CN101785748A (en) * | 2010-02-10 | 2010-07-28 | 北京国合建筑工程总承包有限责任公司大连分公司 | Scalp nursing solution for use in hair dyeing |
| CN103040865A (en) * | 2013-01-28 | 2013-04-17 | 彭贵书 | Hair dyeing harm preventing agent and making method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| JP2002363053A (en) * | 2001-05-30 | 2002-12-18 | Sanei Kagaku Kk | Irritation-suppressing agent for hair-dyeing agent |
| JP3876208B2 (en) * | 2002-09-09 | 2007-01-31 | 株式会社アリミノ | Skin protectant composition for hair treatment agent |
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| DE10028723B4 (en) * | 2000-06-09 | 2009-04-02 | Kpss-Kao Professional Salon Services Gmbh | Method of dyeing human hair |
| CN1886115A (en) * | 2003-11-28 | 2006-12-27 | 威娜股份有限公司 | Use of peptides to protect skin from hair treatment agents |
| CN101785748A (en) * | 2010-02-10 | 2010-07-28 | 北京国合建筑工程总承包有限责任公司大连分公司 | Scalp nursing solution for use in hair dyeing |
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| CN109172428A (en) * | 2018-11-24 | 2019-01-11 | 雷明龙 | A kind of black composition for hair dying |
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